CN104627542A - Volatilization vessel and medicament volatilization device - Google Patents
Volatilization vessel and medicament volatilization device Download PDFInfo
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- CN104627542A CN104627542A CN201410643813.2A CN201410643813A CN104627542A CN 104627542 A CN104627542 A CN 104627542A CN 201410643813 A CN201410643813 A CN 201410643813A CN 104627542 A CN104627542 A CN 104627542A
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Abstract
The invention provides a volatilization vessel, wherein the effective volatilization of volatile materials is realized. Meanwhile, a carrier is prevented from flowing out of the vessel even when the vessel is inclined. The volatilization vessel (100) comprises a vessel main body (10) provided with an opening part used for accommodating a carrier containing volatile materials; and a cover body (20). The cover body (20) is arranged to cover the vessel main body (10) in a non-contact manner. The inner side of the cover body is provided with a limiting part (22).
Description
Technical field
The present invention relates to the volatilization container that volatile matter is externally volatilized and the medicine volatilizer employing this volatilization container.
Background technology
In order to pest, commercially sale has and has volatile insect-proof agent at normal temperatures.This kind of insect-proof agent is generally peddled with following state, that is, will have volatile carrier and load in container body, by sealings such as the peristome leakproofing materials of container body, and cover lid on container body.In container body or lid, be provided with multiple hole to make volatile ingredient volatilize.In use, temporarily lid container body is taken off, peel off the leakproofing material of the peristome of covering container main body, lid is arranged on container body.Owing to being that this kind is formed, being therefore the situation that defence container is toppled over, needing to be designed container body, lid, insect-proof agent can not be overflowed.
In the past, about the container receiving volatile ingredient, have while making volatile ingredient effectively volatilize, avoid the container for aromatics (for example, referring to patent documentation 1) that isolated moisture outwards spills from gel aromatic.According to patent documentation 1, disclose following container, namely, the volatilization opening of aromatic is set in lid, and be provided with installation direction limiting mechanism, its mode configured face to face with top part and the master face of lid with the top part of the container body of the volatilization opening by being formed with aromatic and master face, restriction aromatic case is to the installation direction on lid; And orientation maintaining means, aromatic case is positioned at the top part of the container body of mounted aromatic case, the inside of side surface part entirety by it.By formation like this, the volatile ingredient of the aromatic that just can effectively volatilize, even if when being placed vertically by lid, also can avoid isolated moisture from gel aromatic outwards to spill.
On the other hand, even if there is the container (such as with reference to patent documentation 2) being designed to topple over its content and also can not overflowing.According to patent documentation 2, form as shown below, that is, in the outer container being provided with funnelform mouth, install the endogenous pyrogen with small hole, when adding powder in outer container, the powder of trace will enter in endogenous pyrogen through this small hole.Even if container is toppled over, the powder entering endogenous pyrogen is also very micro-, and in addition, the mouth due to outer container is funnel-form, and the powder being therefore difficult to landing is parked in the way of funnel, so be the container that can not outwards overflow.
Prior art document
Patent documentation
Patent documentation 1: Japanese Unexamined Patent Publication No. 201240254 publications
Patent documentation 2: real public clear No. 5771042 publications of Japan
Summary of the invention
Invent problem to be solved
For the container of the carrier of the volatile matter of storage containing insect-proof agent and so on, first, requirement is expeditiously and effectively makes the formation of volatile substances.In addition, the formation that carrier can not overflow outside container when container is toppled over is set to also very important.
In this, according to patent documentation 1, be intended to the formation by the container of design storage gel aromatic and the lid of this container, avoid isolated moisture from gel aromatic to overflow outside container, and realize the raising of volatilization efficiency.But owing to not having the carrier estimating to be supported with volatile matter to overflow outside container, therefore once container is toppled over, carrier just likely overflows outside container, can think and can impact volatilization efficiency.
On the other hand, according to patent documentation 2, form as shown below, that is, the peristome of outer container is funnel-form, and therefore when container is toppled over, the powder of accommodation is difficult to, in funnelform surperficial landing, thus stop on the way, can not overflow outside container.But, the powder in outer container, endogenous pyrogen enters in large quantities, would not stop in funnelform way, and likely overflow outside container.In addition, owing to there is no providing holes above container, be therefore unsuitable for the container being used as the volatile matter such as storage insect-proof agent.
The present invention completes in view of the above problems, its object is to, for the container of the carrier of the volatile matter of storage containing insect-proof agent etc. and so on, even if provide to make volatile matter effectively volatilize and the volatilization container that formed of the mode that carrier also can not overflow outside container when container is toppled over.In addition, the present invention also aims to, the medicine volatilizer employing this volatilization container is provided.
For the method for dealing with problems
Characteristic formation for the volatilization container of the present invention solved the problem is,
The volatilization container that volatile matter is externally volatilized,
Possess:
Container body, it has the peristome of the carrier of storage containing described volatile matter; With
Lid, it is provided with the evaporation hole of externally being released by the described volatile matter volatilized from described carrier, the mode that described peristome covers is installed in described container body with the discontiguous state of described peristome,
Be provided with limiting unit in the inner side of described lid, when being installed in described container body by described lid, described limiting unit prevents described carrier surrounding's spilling to described container body from described peristome.
Generally speaking, in the volatilization container of storage volatile matter, in order to use start time before can not to volatilize and by sealings such as the peristome leakproofing materials of container body, peel off leakproofing material etc. when using and starting and lid be installed.Now, when by the peristome of container body, fully mulched ground installs lid, due to can only from being located at the area identical with the face of peristome and the evaporation hole being arranged in the upper surface portion of the lid directly over this face volatilizees, therefore to volatilize deterioration of efficiency, be difficult to give play to effect of volatilizing fully.
But, according to the volatilization container of this formation, comprise container body that top is peristome and be provided with the lid in the hole (evaporation hole) for making volatile matter externally volatilize, when this lid is installed on container body, will be formed to make the mode that lid and peristome are contactless state.That is, lid also indirectly contacts with peristome, but forms gap between.In addition, because volatile matter can be released through this gap from the evaporation hole be located at lid, efficiency of therefore volatilizing improves, and volatile matter can be made promptly to be full of usage space.
In addition, in the inner side of lid, be provided with the limiting unit of overflowing towards periphery for preventing from being accommodated in the carrier in container body.Thus, when container is toppled over, even if carrier moves near peristome, limiting unit also can become block, stops carrier and prevents from overflowing from peristome.In addition, when making container upright, the carrier colliding limiting unit will get back to the inside of container body.
Thus, if the volatilization container of this formation, the volatilization efficiency of volatile matter just can be made well and with being effective to volatilize, even and if when container is toppled over, also can prevent carrier from overflowing towards periphery.
In volatilization container of the present invention,
Preferred described limiting unit is located at the inner crest face of described lid, is formed in the mode forming the gap less than the size of described carrier between itself and described peristome as the cylindrical member extended downwards from described inner crest face.
According to the volatilization container of this formation, limiting unit is set at the inner crest face of lid, when lid is installed on container body, the gap of the size less than the size of the carrier be accommodated in container body will be formed between limiting unit and peristome.Thus, even if when container is toppled over, limiting unit also can be utilized reliably to stop the carrier moved near peristome, when making container upright, the inside of container body will be got back to.
In addition, limiting unit is the upper cylindrical member extended downwards from lid, can along surrounding's setting of peristome.Thus, no matter which direction container swings to, and can prevent carrier from overflowing towards periphery.
In addition, owing to being formed with gap between the whole periphery and limiting unit of peristome, therefore volatile matter can from the whole periphery volatilization of peristome.Thus, volatile matter would not produce uneven on the direction of volatilization, can volatilize with making it good efficiency in whole usage space.
In volatilization container of the present invention,
Preferably in described cylindrical member, the throughput that the size of carrier described in the ratio for making described volatile matter circulate is little is set.
According to the volatilization container of this formation, in the cylindrical member being construed as limiting portion, be provided with throughput.Thus, add the gap be formed between above-mentioned limiting unit and peristome, volatile matter just can be released from the evaporation hole be located at lid through this throughput.Thus, volatilization efficiency improves, and volatilization effect is more excellent.
In addition, due to make throughput be formed for the mode of the size less than the size of carrier, even if therefore when container is toppled over, do not worry that the carrier stopped by limiting unit overflows outside container through this throughput yet.Thus, while raising volatilization efficiency and volatilization effect, can prevent carrier from overflowing towards periphery.
In volatilization container of the present invention,
Preferably by making the inner crest face of described lid close to the upper end of described peristome, form described limiting unit.
According to the volatilization container of this formation, lid self can be utilized to be construed as limiting portion.If so formed, then when container is toppled over, due to carrier by lid above and the periphery of peristome stop, therefore can not the oriented container situation of overflowing outward.In addition, because volatile matter through the gap be formed at lid and peristome, can be released from the evaporation hole be located at lid, therefore volatilization efficiency can be improved.
In addition, because lid self is formed as limiting unit, therefore do not need to use attached component, volatilization container can be made at low cost, can be supplied to customer as the product of cheapness yet.
In volatilization container of the present invention,
Preferably by making the inner side surface of described lid close to the surrounding of described peristome, form described limiting unit.
According to the volatilization container of this formation, lid self can be utilized to be construed as limiting portion.If so formed, then when container is toppled over, because carrier is stopped by the surrounding of the inner side surface of lid and peristome, therefore can not the oriented container situation of overflowing outward.In addition, because volatile matter through the gap be formed at lid and peristome, can be released from the evaporation hole be located at lid, therefore volatilization efficiency can be improved.
In addition, because lid self is formed as limiting unit, therefore do not need attached component, with low-cost production's volatilization container, can be supplied to customer as the product of cheapness yet.
In volatilization container of the present invention,
Preferably formed in the mode making to be located at described evaporation hole in described lid less than the size of described carrier.
According to the volatilization container of this formation, formed to make the mode being located at the evaporation hole in lid less than the size of carrier.Thus, even if container is toppled over, just in case overflow in the peristome of carrier container body, the evaporation hole due to lid is less than the size of carrier, therefore also can reliably prevent from spilling into outside volatilization container through evaporation hole.
In addition, when making volatilization container upright, carrier will be got back in container body, therefore can reuse.
In addition, owing to the size of evaporation hole to be set smaller than the size of carrier, therefore evaporation hole can be located at multiple positions of lid.Thus, just can increase the number of evaporation hole and improve the volatilization efficiency of volatile matter, thus volatilization effect can be played well.
Characteristic formation for the medicine volatilizer of the present invention solved the problem is,
Be the use of the medicine volatilizer of the volatilization container recorded in above-mentioned any one,
As described carrier, receive and made water absorbent polymer at least absorb the aqueous system of described volatile matter or the microspheric medicament of aqueous gel of aqueous suspension.
According to the medicine volatilizer of this formation, due in volatilization container of the present invention, be accommodated with the microspheric medicament of aqueous gel, therefore form the medicine volatilizer of safety and convenience excellence.
In medicine volatilizer of the present invention,
Described volatile matter is preferably selected from least one in flying pest repellent composition, flying pest repellent fragrance component, dress material insect protected repellent composition, dress material insect protected fragrance component and fragrance component.
According to the medicine volatilizer of this formation, because volatile matter is selected from least one in each composition of enumerating above, therefore best volatile matter can be selected according to the purposes application target of medicine volatilizer.Thus, the convenience of medicine volatilizer will be improved, realize the use relating to many aspects.
Accompanying drawing explanation
Fig. 1 is the block diagram of the volatilization container of the first embodiment, and (a) represents the exploded perspective view of lid and container body, (b) represent container body lid has been installed time block diagram.
Fig. 2 is the section-drawing of the volatilization container of the first embodiment.
Fig. 3 is the section-drawing of the volatilization container of the second embodiment.
Fig. 4 is the section-drawing of the volatilization container of the 3rd embodiment.
Fig. 5 is the section-drawing of the volatilization container of the 4th embodiment.
Fig. 6 is the section-drawing of the volatilization container of the 5th embodiment.
Fig. 7 is the use of the block diagram of the medicine volatilizer of the volatilization container of the first embodiment.
Detailed description of the invention
Below, based on Fig. 1 ~ Fig. 6, the embodiment of volatilization container for the present invention is described.For medicine volatilizer of the present invention, be described compactly with reference to while Fig. 7.But, be not intended to the present invention to be defined as the formation recorded in the embodiment of following explanation, accompanying drawing.
< first embodiment >
Fig. 1 is the block diagram of the volatilization container 100 of the first embodiment of the present invention.A () is the exploded perspective view of volatilization container 100, (b) is block diagram when having installed lid in container body.Fig. 2 is the section-drawing of the volatilization container 100 of the first embodiment of the present invention.Volatilization container 100 is the containers used to make volatile matter described later externally volatilize, and possesses container body 10 and lid 20.And comprise Fig. 2, the section-drawing of the volatilization container 100 later illustrated is easy to understand container bodies 10 and the relation of lid 20 and the figure that is described, omissions of detail part.Thus, the figure of the section of actual volatilization container 100 is not necessarily critically reflected.
As shown in Fig. 1 (a), container body 10 is the containers with the end possessing peristome 11, makes the shape of ampuliform.Can at the inside of the main body 10 storage carrier comprising volatile matter described later.
As long as the material forming container body 10 can not make the volatile matter of the inside being accommodated in container body 10 go bad and container body 10 can not be made because of received volatile matter self to suffer the material of deterioration, etch, corrosion etc.As this kind of material, such as can enumerate polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), polystyrene (PS), polymethyl methacrylate (PMMA), polyphenylene oxide (PPE), polyamide (PA), polycarbonate (PC), acrylonitrile butadient styrene (ABS), polyphenylene sulfide (PPS), polyetheretherketone (PEEK), PEKK (PEKK), and the thermoplastic base resin such as polyformaldehyde (POM), or phenol resin (PF), urea formaldehyde resin (UF), melamine resin (MF), epoxy resin (EP), and the thermosetting resin such as urethane resin (PUR).In the middle of these resins, the polyethylene terephthalate (PET) of preferred intensity and transparency excellence.And, contain the situations such as organic solvent at volatile matter under, likely make resin dissolves, therefore also can replace resin, such as, form container body 10 by inorganic material such as metal, glass, potteries.When the constituent material as container body 10 uses resin material, the forming processs such as injection moulding, extrusion molding, blow molding, compression forming can be utilized to make container body 10.
The capacity of container body 10 can adjust according to the amount of the carrier of the volatile matter be accommodated in container body 10.The amount being accommodated in the carrier of the volatile matter of container body 10 by wanting to make the place of volatile substances or range, to make between the used life of volatilization lasts etc. to decide.From the viewpoint of the viewpoint of the lasting effect of volatilization efficiency or volatile matter and guarantee the safety of container body 10, the capacity of container is preferably set to about 50 ~ 500cc.The outward appearance preferably clear of container body 10 or semi-transparently form, the state of the volatile matter received can be confirmed from outside.But, when volatile matter is easily decomposed by light, also can by container body 10 arbitrary color dyes or the leakproofing material attaching light-proofness.
As shown in Fig. 1 (b), lid 20 as the peristome 11 of covering container main body 10 container with the end and form.As shown in Fig. 1 (b), lid 20 is formed as follows, that is, when being installed on container body 10, to be covered by peristome 11 with peristome 11 discontiguous state.As shown in Fig. 1 (a), in lid 20, be provided with evaporation hole 21 and limiting unit 22.Evaporation hole 21 is the holes for making the volatile matter of the inside being accommodated in container body 10 externally release.The shape of evaporation hole 21 and number can be arranged arbitrarily.Limiting unit 22 is located at the inner crest face of lid 20, is the cylindrical member extended towards peristome 11.As shown in Fig. 1 (b), when lid 20 is installed on container body 10, between peristome 11 and limiting unit 22, form gap 23.Gap 23 is sized to less than the size of the carrier containing volatile matter being accommodated in container body 10.Utilize this kind to form, when volatilization container 100 is toppled over, even if carrier moves near peristome 11, limiting unit 22 also can become block, carrier can be stopped.Thus, carrier can not be full of in lid 20, also not have and overflow in carrier container body 10 and be scattering into the situation of surrounding.Thus, because carrier residence is in container body 10, thus do not worry the volatilization efficiency to volatile matter, volatilization effect cause harmful effect.In addition, if make carrier be scattering into around container body because volatilization container is toppled over, just have the danger that carrier is put into mouth by the place of making dirty and placing volatilization container or children, but if the volatilization of present embodiment container 100, then need not produce this kind and worry.Thus, user can dispose volatilization container 100 safely.
In addition, in limiting unit 22, be provided with the throughput 24 in the hole less than the size of the carrier being accommodated in container body 10.Utilize this kind to form, the volatile matter that the evaporation hole 21 on the surface being located at lid 20 just can be utilized to be supported by loaded body is released through throughput 24.Herein, due to make throughput 24 be that the mode in the hole of the size less than the size of the carrier being accommodated in container body 10 is formed, therefore when volatilization container 100 is toppled over, carrier just can not overflow in container body 10 through throughput 24.Thus, volatile matter not only utilizes the gap 23 be located between peristome 11 and limiting unit 22, also utilizes throughput 24 to volatilize, and releases from evaporation hole 21.Thus, volatilization efficiency and the volatilization effect of volatile matter can just be improved further.
As mentioned above, be provided with evaporation hole 21 in lid 20, its shape and number can be arranged arbitrarily, and the size of evaporation hole 21 is formed in the mode less than the size of the carrier being accommodated in container body 10.Owing to being that this kind is formed, even if therefore topple at volatilization container 100, just in case when carrier overflows and is full of lid 20 from peristome 11, do not have the situation of overflowing outside volatilization container 100 through evaporation hole 21 yet.Thus, carrier just reliably can be prevented to be scattering into volatilization container 100 around, not worry the pollution that position is set, the child entrance moderate risk that produce volatilization container 100.Thus, user can dispose volatilization container 100 safely.In addition, because evaporation hole 21 is sizes as above, therefore multiple position can be set in lid 20.When so forming, because the hole for releasing volatile matter increases, therefore volatilization efficiency can be improved further.Thus, the effect of volatile matter just promptly can be played to usage space.In addition, when the evaporation hole 21 of size as above is arranged on the whole surface of lid 20 equably, because volatile matter can be released from the whole surrounding of volatilization container 100, therefore make volatile matter volatilize throughout usage space, thus can be difficult to produce in usage space: play the position of the effect of volatile matter well and the difference at the position of this effect can not be played well.
As long as the material forming lid 20 does not make the volatile matter of the inside being accommodated in container body 10 go bad and lid 20 can not be made because of received volatile matter self to suffer the material of deterioration, etch, corrosion etc., the material identical with previously described formation container body 10 material can be used.
The size of lid 20 will set matchingly with container body 10, as long as but the degree reliably covered by the peristome 11 of container body 10.The outward appearance of lid 20 both can be formed identically with container body 10 transparent or semitransparently, or also can by lid 20 arbitrary color dyes or the leakproofing material attaching light-proofness.
As long as the material being construed as limiting portion 22 does not make the volatile matter of the inside being accommodated in container body 10 go bad and limiting unit 22 can not be made because of received volatile matter self to suffer the material of deterioration, etch, corrosion etc., the material identical with the material of previously described formation container body 10, lid 20 can be used.
The size of limiting unit 22 can carry out various setting.The volatilization of present embodiment with container 100 as shown in Figure 2, with make the periphery of limiting unit 22 be positioned at the periphery of peristome 11 roughly directly over, mode that the width of limiting unit 22 is roughly the same with the width of peristome 11 formed.By formation like this, even if when volatilization container 100 is toppled over, do not have the situation of overflowing in the carrier container body 10 containing volatile matter yet, excellent volatilization efficiency as above and volatilization effect can be played.
< second embodiment >
Fig. 3 is the section-drawing of the volatilization container 200 of the second embodiment of the present invention.As shown in Figure 3, volatilization container 200 is formed in the mode making the width of limiting unit 22 (external diameter) larger than the width (external diameter) of peristome 11.That is, formed in the mode making the periphery of limiting unit 22 be positioned at the outside of peristome 11.Formed in the mode that the size in the gap 23 making to be formed at horizontal direction between the periphery of limiting unit 22 and peristome 11 and vertical direction is less than the size of the carrier be accommodated in volatilization container 200.Other formation is identical with the first embodiment, therefore omits detailed description.By such as forming shown in the second embodiment, even if when volatilization container 200 is toppled over, do not have the situation of overflowing in the carrier container body 10 containing volatile matter, the volatilization efficiency of the excellence identical with the first embodiment and effect of volatilizing can be played yet.
< the 3rd embodiment >
Fig. 4 is the section-drawing of the volatilization container 300 of the 3rd embodiment of the present invention.As shown in Figure 4, volatilization container 300 is formed in the mode making the width of limiting unit 22 (external diameter) less than the width (external diameter) of peristome 11.That is, formed in the mode making the periphery of limiting unit 22 be positioned at the inner side of peristome 11.Formed in the mode that the size in the gap 23 making to be formed at horizontal direction between the periphery of limiting unit 22 and peristome 11 and vertical direction is less than the size of the carrier be accommodated in volatilization container 300.Other formation is identical with the first embodiment, therefore omits detailed description.By such as forming shown in the 3rd embodiment, even if when volatilization container 300 is toppled over, do not have the situation of overflowing in the carrier container body 10 containing volatile matter, the volatilization efficiency of the excellence identical with the first embodiment and effect of volatilizing can be played yet.
< the 4th embodiment >
Fig. 5 is the section-drawing of the volatilization container 400 of the 4th embodiment of the present invention.As shown in Figure 5, volatilization container 400 is construed as limiting portion by making the inner crest face 20a of lid 20 near the upper end of peristome 11.That is, lid 20 self can be utilized to be construed as limiting portion.The size in the gap 25 formed by inner crest face 20a and the peristome 11 by lid 20 is set as less than the size of the carrier containing volatile matter be accommodated in volatilization container 400.Even if when volatilization container 400 is toppled over, carrier also cannot pass gap 25, does not therefore worry overflowing in container body 10.Thus, the volatilization efficiency of the excellence identical with the first embodiment and effect of volatilizing can be played.In addition, because lid 20 is formed as limiting unit self, therefore do not need to use attached component, volatilization container 400 can be made at low cost, can be supplied to customer as the product of cheapness yet.
< the 5th embodiment >
Fig. 6 is the section-drawing of the volatilization container 500 of the 5th embodiment of the present invention.As shown in Figure 6, volatilization container 500 is construed as limiting portion by making the inner side surface 20b of lid 20 near the surrounding of peristome 11.That is, lid 20 self can be utilized to be construed as limiting portion.The size in the gap 26 formed by inner side surface 20b and the peristome 11 by lid 20 is set as less than the size of the carrier containing volatile matter be accommodated in volatilization container 500.Even if when volatilization container 500 is toppled over, carrier also cannot pass gap 26, does not therefore worry overflowing in container body 10.And, volatilization in figure 6 with container 500 when, once volatilization container 500 is toppled over, carrier will temporarily above peristome 11 and lid 20 between overflow, when making volatilization container 500 upright, the inside of container body 10 promptly will be got back to.Thus, the volatilization efficiency of the excellence identical with the first embodiment and effect of volatilizing can be played.In addition, because lid 20 is formed as limiting unit self, therefore do not need to use attached component, volatilization container 500 can be made at low cost, can be supplied to customer as the product of cheapness yet.
< volatile matter >
[flying pest repellant]
Volatilization container 100 ~ 500 of the present invention such as can use as the medicine volatilizer used in order to flying pests such as repellent mosquito, buffalo gnat, midge, fly class, little fly classes.In this situation, receive in the volatilization inside of container 100 ~ 500 the flying pest repellant containing flying pest repellent composition as volatile matter.Although flying pest repellant also can be accommodated in volatilization container 100 ~ 500 with the state that former state is constant, but if the high material of volatility, then have the situation being difficult to the volatile quantity controlled from container.Thus, become easy to make the disposal of flying pest repellant, preferably appropriate flying pest repellant be dissolved in the water and prepare as the aqueous system, or when flying pest repellant water fast, prepared by the aqueous suspension as flying pest repellant, to make it the form storage of the aqueous gel microballoon remained in gel micro-ball.The microspheric flying pest repellant of aqueous gel prepares by making water absorbent polymer absorption contain the flying pest repellent flavor compositions of flying pest repellent composition (also continuing composition containing flying pest repellent fragrance component, repellent effect as required) and water.Flying pest repellent composition has volatile material, in this specification sheets, this flying pest repellent composition or the flying pest repellent flavor compositions containing this flying pest repellent composition disposed as volatile matter.Be the way selection volatile matter of 0.01 ~ 50Pa to make the vapor tension of 20 DEG C.Below, the flying pest repellent composition of part or all forming volatile matter is described.
Flying pest repellent composition contains:
A () is selected from general formula (I):
CH
3-COO-R
1···(I)
(R
1: carbon number is the alcohol residue of 6 ~ 12)
Represent acetate compound and/or with general formula (II):
R
2-CH
2-COO-CH
2-CH＝CH
2···(II)
(R
2: cycloalkyloxy or phenoxy group that the naphthenic base that the alkoxy that the alkyl that carbon number is 4 ~ 7, carbon number are 4 ~ 7, carbon number are 4 ~ 7, carbon number are 4 ~ 7)
More than one fragrance component in the allyl ester compound represented; With
B () is selected from monoterpene system alcohol or carbon number is more than one fragrance component in the aromatic alcohols of 10.
As the acetate compound represented with general formula (I), such as, can enumerate vertenex, verdox, acetic acid to tertiary pentyl cyclohexyl, cyclacet, benzyl acetate, phenethyl acetate, methyl phenyl carbinyl acetate, acetic acid fennel ester, cinnamyl acetate, terpinyl acetate, dihydroterpinyl acetate, bergamio, ethyl linalyl acetate, Vanillin acetate, geranyl acetate, neryl acetate, borneolacetate and isobornyl acetate etc.These acetate compounds both can use individually, also can at random combinationally use.
As the allyl ester compound represented with general formula (II), such as, can enumerate allyl hexanoate, allyl heptanoate, allyl octanoate, isobutoxy allyl acetate, n-pentyloxy allyl acetate, allyl cyclohexane acetate, allyl cyclohexyl propionate, cyclohexyloxy allyl acetate, Allyl Phenoxyacetate etc.These allyl ester compounds both can use individually, also can at random combinationally use.
As the representational example that monoterpene system alcohol or carbon number are the aromatic alcohols of 10, be such as terpilenol, geraniol, dihydromyrcenol, borneol, menthol, citronellol, nerol, linalool, ethyl linalool, Thymol, eugenol and to terpane-3,8-glycol etc.These monoterpene system alcohol or carbon number be 10 aromatic alcohols both can use individually, also can at random combinationally use.
Flying pest repellent flavor compositions also can as flying pest repellent fragrance component, suitably add fragrance component other than the above, the monoterpene system hydrocarbon such as such as citrene, menthones, carvol, pulegone, down ketone, the monoterpene system ketone such as damascone (Damascone), citral, citronellal, neral, the monoterpene system aldehyde such as perillaldehyde, cinnamyl formate, the ester compounds such as geranyl formate, phenylethyl alcohol, diphenyl ether, dihydro indenyl-2, 4-diox (Dihydroindenyl-2, 4-dioxane, indolarome) etc., in addition, suitably can also add the various essential oil classes containing above-mentioned fragrance component, such as jasmin oil, neroli oil, peppermint oil, bergamot oil, orange oil, pelargonium oil, petit grain oil, lemon oil, citronella oil, lemongrass oil, cassia oil, eucalyptus oil, eucalyptus citriodora oil, thyme wet goods.
Flying pest repellent flavor compositions preferably continues composition as the repellent effect after the volatilization of flying pest repellent fragrance component, coordinates the vapor tension of 20 DEG C to be more than one ethylene glycol and/or the glycol ether of 0.2 ~ 20Pa.As its concrete example, propylene glycol (10.7Pa), DPG (1.3Pa), tripropylene glycol (0.67Pa), diethylene-glycol (3Pa), triethylene glycol (TEG) (1Pa), 1,3 butylene glycolss, hexandiol (6.7Pa), ethylene glycol benzyl ether (2.7Pa), diethylene glycol monobutyl ether (3Pa), Dipropylene glycol mono-n-butyl Ether and Tripropylene glycol monomethyl Ether can be enumerated.The vapor tension of the numeric representation in the bracket after material name 20 DEG C.These repellent effects continue, in the middle of composition, preferably to use DPG.And above-mentioned ethylene glycol and/or glycol ether both can use individually, also can at random combinationally use.
In flying pest repellent flavor compositions, such as, also can coordinate other the functional components such as insecticidal constituent, deodorizing composition, degerming antimicrobial component.As insecticidal constituent, the Prallethrin of normal temperature volatility pyrethroid system, the third Flumethrin, transfluthrin, metofluthrin etc. can be enumerated.As deodorizing composition, representational is be selected from the plant extracts in Gramineae, Theaceae, Ginkgoaceae, Oleaceae, Moraceae, Rutaceae, Malpighiaceae, Ebenaceae.In addition, the leaf alcohol, leaf aldehyde etc. that are referred to as " green perfume (or spice) " can also be added and give relaxation effect.These functional components both can use individually, also can at random combinationally use.
When preparing the microspheric flying pest repellant of aqueous gel, preferably in advance to mating surfaces activating agent in the flying pest repellent flavor compositions (infiltration liquid) of infiltration water absorbent polymer.Flying pest repellent flavor compositions is reliably remained on the inside of gel micro-ball by inhibiter, contributes to its slowly-releasing.Consequently, the flying pest repellent effect can played stably for a long time.As inhibiter, such as can enumerate polyoxyethylene rilanit special, polyoxyethylene senior alkyl ethers (polyoxyethylenelauryl ether, polyoxyethylene oleyl ether etc.), polyoxyethylene phenyl ethers, polyoxyethylene high-grade aliphatic ester class, polyoxyethylene sorbitan fatty acid ester class, polyoxyethylene fatty acid glyceride class, the nonionic system inhibiters such as polyoxyethylene polyoxypropylene alkyl ether, lauryl amine oxide, stearic amine oxide, the senior alkyl amine oxide system inhibiters such as dodecanamide propyl dimethylamine oxide.These inhibiters both can use individually, also can at random combinationally use.
In water absorbent polymer, preferably use acrylic acid series water absorbent polymer.The hygroscopic character of acrylic acid series water absorbent polymer is excellent, can absorb the water of more than 100 times of deadweight.If particle diameter is about the acrylic acid series water absorbent polymer of about 2mm, then also while the state that maintenance is roughly transparent, particle diameter can be expand into and is about about 10mm after absorbing infiltration liquid.As acrylic acid series water absorbent polymer, the copolymer of acrylic acid/acrylate copolymer (acrylic acid/sodium acrylate salt copolymer, acrylic acid/potassium acrylate salt copolymer etc.), acrylamide/acrylic acid or its salt can be enumerated.
In the preparation of the microspheric flying pest repellant of aqueous gel, such as, to have peristome suitable capacity transparent vessel in add the water absorbent polymer of specified amount, next carry out the operation of the infiltration liquid injected containing flying pest repellant.Now, as the container preparing the microspheric flying pest repellant of aqueous gel, volatilization container of the present invention also can be used.In this situation, the time changed to by microspheric for prepared aqueous gel flying pest repellant in other volatilization containers can be saved.When the preparation of the microspheric flying pest repellant of aqueous gel, water absorbent polymer and infiltration liquid to the ordering in launching in container whichsoever before can.In addition, in infiltration liquid, as required, also anti fouling composition, the Bitrex etc. such as the stabilization agent such as solvent, BHT, isothiazoline system bitters, pH adjusting agent, colorant etc. can suitably be coordinated.
Solvent used in preparation as aqueous gel microspheric flying pest repellant, such as, can enumerate the hydrocarbon system solvents etc. such as the lower alcohol such as ethanol, isopropyl alcohol, ketone series solvent, ester series solvent, normal paraffin, iso-paraffins.These solvents both can use individually, also can at random combinationally use.
[dress material insect-proof agent]
Being accommodated in volatile matter in volatilization container 100 ~ 500 of the present invention except flying pest repellant as above, such as, can also be have the vermins-proof effect of dress material insect, the dress material insect-proof agents of insecticidal effect such as casemaking clothes moth class, khapra beetle class, tassel tail classes.That is, flying pest repellant preferably with above-mentioned is identical, appropriate dress material insect-proof agent is dissolved in the water and prepares as the aqueous system, or when dress material is with insect-proof agent water fast, prepared by the aqueous suspension as dress material insect-proof agent, to make it the form storage of the aqueous gel microballoon remained in gel micro-ball.The microspheric dress material insect-proof agent of aqueous gel prepares by making water absorbent polymer absorb dress material insect protected composition (as required, also having dress material insect protected fragrance component, pyrethroid system insecticidal constituent, continuation fragrance component).
The dress material insect-proof agent be accommodated in volatilization container 100 ~ 500 of the present invention is prepared with can comprising following composition, that is, (c) as dress material insect protected composition with following formula (III):
CH
3-COO-R
3···(III)
(R
3: carbon number is the alcohol residue of 6 ~ 12)
More than one the acetate compound, (d) that represent have more than one pyrethroid system insecticidal constituent volatile at normal temperatures.In addition, the dress material insect-proof agent be accommodated in volatilization container 100 ~ 500 of the present invention can be prepared except dress material insect protected composition and pyrethroid system insecticidal constituent with also comprising following composition, that is, (e) dress material insect protected fragrance component and (f) have the continuation fragrance component of the continuation longer than dress material insect protected fragrance component.Below, each composition is described.
(c) dress material insect protected composition
The specific acetate compound represented with described formula (III) used as dress material insect protected composition is the ester compounds similar on chemical constitution with pyrethroid system described later insecticidal constituent.The volatility of acetate compound has following characteristic, that is, be roughly equal degree with the volatility of the terpene compound that can add as dress material insect protected fragrance component described later, and larger than the volatility of pyrethroid system insecticidal constituent.Thus, acetate compound can with pyrethroid system insecticidal constituent synergistically from the vermins-proof effect enhanced played in use initial stage more than the several months long-time based on cooperative effect.In addition, dress material insect protected composition duration in, also utilize acetate compound to improve aromaticity.
As the alcohol residue (R in the acetate compound represented with described formula (III)
3), phenylalkyl (carbon number between phenyl and ester group is 1 ~ 3), terpenol residue etc. that naphthenic base, the carbon number that can replace with the alkyl that carbon number is 1 ~ 5 are 1 ~ 3 can be enumerated.Namely, as acetate compound, vertenex, verdox, acetic acid can be enumerated to tertiary pentyl cyclohexyl, cyclacet, benzyl acetate, phenethyl acetate, methyl phenyl carbinyl acetate, acetic acid fennel ester, cinnamyl acetate, terpinyl acetate, dihydroterpinyl acetate, bergamio, ethyl linalyl acetate, Vanillin acetate, geranyl acetate, neryl acetate, borneolacetate and isobornyl acetate etc.In the middle of them, suitable acetate compound is vertenex, verdox, cyclacet, benzyl acetate, terpinyl acetate, dihydroterpinyl acetate and ethyl linalyl acetate.These acetate compounds can use individually, but also can use as two or more compounds.
(d) pyrethroid system insecticidal constituent
As the pyrethroid system insecticidal constituent combinationally used with above-mentioned dress material insect protected composition, Prallethrin, the third Flumethrin, transfluthrin, metofluthrin and terallethrin etc. can be enumerated.These pyrethroid system insecticidal constituents can use individually, but also can use as two or more compounds.In addition, in these pyrethroid system insecticidal constituents, have optical isomer, the geometric isomer based on asymmetric carbon, double bond, but also they can be used individually or as arbitrary compound.
(e) dress material insect protected fragrance component
Be accommodated in dress material insect-proof agent in volatilization container 100 ~ 500 of the present invention to strengthen the vermins-proof effect using initial stage further, can as dress material insect protected fragrance component, containing terpene compound.The confirmations such as the present inventor, if also with terpene compound in above-mentioned dress material insect protected composition, then use the vermins-proof effect president time remaining of initial stage.In addition, terpene compound also has the function as deodorant tune, thus, can improve aromaticity within the longer time.As terpene compound, the terpenic series ketone etc. such as terpenic series aldehyde, carvol, dihydro carvone, pulegone, menthones such as the terpenic series alcohol such as terpilenol, citronellol, geraniol, nerol, linalool, dihydro linalool, tetrahydrolinalool, dihydromyrcenol, menthol, borneol, isoborneol, citronellal, citral, dimethyl octanal can be enumerated.These terpene compounds can use individually, but also can use as two or more compounds.Terpene compound also can be the form of the plants essential oil containing terpene compound.As plants essential oil, citronella oil, orange oil, lemon oil, limette oil, grape-fruit seed oil, lavender oil, peppermint oil, cassia oil, eucalyptus oil, eucalyptus citriodora oil, Japan cypress oil, oil of grapefruit, cedar oil, pelargonium oil, thyme white oil, peppermint oil, jasmin oil, oil of juniper wood, green tea essential oil etc. can be enumerated.
(f) continuation fragrance component
Being accommodated in dress material insect-proof agent in volatilization container 100 ~ 500 of the present invention to improve the continuation of vermins-proof effect and fragrance further, can continuation fragrance component being contained.If outside above-mentioned dress material insect protected composition and dress material insect protected fragrance component, also use continuation fragrance component, then use going down of the vermins-proof effect of later stage to tail off, the dress material insect protected composition of the long-term use that can stand 6 ~ about 12 months can be realized.As continuation fragrance component, Jiale muskiness, muskone, jasminolene, brazilic acid glycol ester, oak moss (methyl atrarate), 1-Hexyl salicylate, tangerine crystalline substance (oranger crystal) etc. can be enumerated.These continuation fragrance components can use individually, but also can use as two or more compounds.
(composition of dress material insect-proof agent)
The compounding ratio ((c): (d)) of dress material insect protected composition and pyrethroid system insecticidal constituent is preferably set to 0.02: 1 ~ 0.4: 1 with mass ratio range.If this scope, then can while strengthening the vermins-proof effect using initial stage, interiorly pyrethroid system insecticidal constituent whole duration make the effect of dress material insect protected ingredient exerts.Consequently, the cooperative effect of insecticidal effect and the vermins-proof effect brought by dress material insect protected composition brought by pyrethroid system insecticidal constituent can be utilized, long-time effect and the aromaticity continuing performance enhancing.Even if the compounding ratio ((c): (d)) of dress material insect protected composition and pyrethroid system insecticidal constituent exceedes above-mentioned scope, the insecticidal effect brought by pyrethroid system insecticidal constituent also culminates with the cooperative effect of the vermins-proof effect to be brought by dress material insect protected composition, not too can the further raising of desired effects.If the compounding ratio ((c): (d)) of dress material insect protected composition and pyrethroid system insecticidal constituent is below above-mentioned scope, then have the situation that cannot obtain insecticidal effect and the cooperative effect of the vermins-proof effect brought by dress material insect protected composition brought by pyrethroid system insecticidal constituent fully.
The compounding ratio ((f): (d)) of continuation fragrance component and pyrethroid system insecticidal constituent is preferably set to 0.02: 1 ~ 0.4: 1 with mass ratio range.If this scope, then outside above-mentioned dress material insect protected composition, continuation fragrance component can also be utilized between the used life extending dress material insect-proof agent, simultaneously can pyrethroid system insecticidal constituent whole duration in continuation fragrance component is played a role.Consequently, the cooperative effect of the insecticidal effect that brought by pyrethroid system insecticidal constituent and the vermins-proof effect brought by dress material insect protected composition and continuation fragrance component can be utilized, for longer periods continue to play the effect and aromaticity that are further enhanced.If the compounding ratio ((f): (d)) of continuation fragrance component and pyrethroid system insecticidal constituent exceedes above-mentioned scope, then the volatile quantity of pyrethroid system insecticidal constituent is suppressed, thus have cannot during use in obtain the situation of sufficient insecticidal effect.If the compounding ratio ((f): (d)) of continuation fragrance component and pyrethroid system insecticidal constituent is below above-mentioned scope, then have the prolongation between the used life that cannot realize the dress material insect-proof agent brought by continuation fragrance component fully.
The dress material insect-proof agent be accommodated in volatilization container 100 ~ 500 of the present invention except above-mentioned each composition, also can contain various additive.Such as can suitably contain mildew inhibitor (2-phenylphenol (OPP), 4-isopropyl-3-methylphenol (IPMP), Kathon, isopropyl methyl phenol, o-phenyl phenol etc.), antiseptic (thujaplicin, eugenol, allyl isothiocyanate etc.), aromatic (citrene, australene, phenylethanol, amyl cinnamic aldehyde, benzyl acetate etc.), degerming composition, the stabilization agents such as BHT, pH adjusting agent, colorant, hydrocarbon system compound (hexane, paraffin etc.), various petroleum solvents etc.In addition, can also suitably containing the spices such as leaf alcohol, leaf aldehyde being referred to as " green perfume (or spice) ".By adding green perfume (or spice) in dress material insect-proof agent, just relaxation effect can be given when opening the accommodating container of clothing to user.
< medicine volatilizer >
Preparation as described above contains the microspheric flying pest repellant of aqueous gel or the dress material insect-proof agent of volatile matter, be accommodated in volatilization container 100 ~ 500 of the present invention, the device of gained can use as medicine volatilizer of the present invention.Fig. 7 is the use of the block diagram of the medicine volatilizer 100 ' of the volatilization container 100 of the first embodiment.In the inside of this medicine volatilizer 100 ', microspheric for aqueous gel flying pest repellant 50 is accommodated in volatilization container 100 '.For the size of aqueous gel microballoon, when liquid measure of infiltrating is more than 20 times of the weight of acrylic acid series water absorbent polymer, prepare in the mode of the diameter reaching 5 ~ 15mm.Medicine volatilizer 100 ' can in indoor, warehouse, the cars such as entry, kitchen, sanitary accomodation, state room, bedroom etc. outside space or courtyard, room, for the purposes of the flying pests such as the mosquito classes such as repellent culex, underground mosquito, aedes albopictus, buffalo gnat, midge class, fly class, little fly class (fruit bat class, eye fly class etc.), moth fly class, casemaking clothes moth class, safety and convenience excellence.
Particularly, when the dress material insect-proof agent that the middle storage of medicine volatilizer 100 ' is above-mentioned, medicine volatilizer 100 ' can make dress material insect protected composition volatilize expeditiously and effectively.As long as be placed in wardrobe, drawer, closet, dress material containing box etc. by this medicine volatilizer 100 ', excellent vermins-proof effect, insecticidal effect just can be played.
And the medicament being accommodated in the inside of medicine volatilizer 100 ' of the present invention is not limited in flying pest repellant as above, dress material insect-proof agent.Also can using having deodorizing effect, the volatile matter of fragrance effect prepared as medicament, make it to support in aqueous gel microballoon, be accommodated in medicine volatilizer 100 '.In such cases, medicine volatilizer 100 ' can use in the accommodation space such as space or wardrobe, drawer, closet, dress material containing box in indoor, warehouse, the cars such as entry, kitchen, sanitary accomodation, state room, bedroom etc.
As mentioned above, volatilization container 100 ~ 500 of the present invention can as forming by the medicine volatilizer 100 ' very outstanding according to the convenience being accommodated in the kind of inner volatile matter, purposes uses in various place.
Utilizability in industry
Volatilization container of the present invention may be used for the container receiving the medicaments such as flying pest repellant, dress material insect-proof agent, deodorizer, aromatic.
Nomenclature
10 container bodies
11 peristomes
20 lids
Above 20a lid
20b lid side
21 evaporation holes
22 limiting units
23,25,26 gaps
24 throughput
The microspheric flying pest repellant of 50 aqueous gel
100 volatilization containers
100 ' medicine volatilizer
Claims (8)
1. a volatilization container is the volatilization container that volatile matter is externally volatilized,
Possess:
Container body, it has the peristome of the carrier of storage containing described volatile matter; With
Lid, it is provided with the evaporation hole of externally being released by the described volatile matter volatilized from described carrier, the mode that described peristome covers is installed in described container body with the discontiguous state of described peristome,
Be provided with limiting unit in the inner side of described lid, when being installed in described container body by described lid, described limiting unit prevents described carrier surrounding's spilling to described container body from described peristome.
2. volatilization container according to claim 1, wherein,
Described limiting unit is located at the inner crest face of described lid, to form the mode in the gap less than the size of described carrier between itself and described peristome, forms as the cylindrical member extended downwards from described inner crest face.
3. volatilization container according to claim 2, wherein,
In described cylindrical member, be provided with the throughput that the size of carrier described in the ratio for making described volatile matter circulate is little.
4. the volatilization container according to any one of claims 1 to 3, wherein,
By making the inner crest face of described lid near the upper end of described peristome, and form described limiting unit.
5. the volatilization container according to any one of Claims 1 to 4, wherein,
By making the inner side surface of described lid around described peristome, and form described limiting unit.
6. the volatilization container according to any one of Claims 1 to 5, wherein,
The described evaporation hole be located in described lid is formed in the mode less than the size of described carrier.
7. a medicine volatilizer, is the use of the medicine volatilizer of the volatilization container according to any one of claim 1 ~ 6,
Be accommodated in the microspheric medicament of aqueous gel of the aqueous system or the aqueous suspension at least absorbing described volatile matter in water absorbent polymer as described carrier.
8. medicine volatilizer according to claim 7, wherein,
Described volatile matter is selected from least one in flying pest repellent composition, flying pest repellent fragrance component, dress material insect protected composition, dress material insect protected fragrance component and fragrance component.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013236309A JP6189185B2 (en) | 2013-11-14 | 2013-11-14 | Volatilization container and chemical volatilization device |
| JP2013-236309 | 2013-11-14 |
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| Publication Number | Publication Date |
|---|---|
| CN104627542A true CN104627542A (en) | 2015-05-20 |
| CN104627542B CN104627542B (en) | 2017-07-07 |
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| CN (1) | CN104627542B (en) |
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| JP2017209095A (en) * | 2016-05-23 | 2017-11-30 | 保司 黒田 | Container for snake and insect pest repellant |
| CN208388071U (en) * | 2017-12-27 | 2019-01-18 | 宁波香木町日用品有限公司 | Container containing |
Citations (6)
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|---|---|---|---|---|
| JP2000185090A (en) * | 1998-12-24 | 2000-07-04 | T Hasegawa Co Ltd | Liquid volatilization device |
| CN2836808Y (en) * | 2005-01-10 | 2006-11-15 | 花仙子企业股份有限公司 | Improved volatile cotton body for aroma device |
| JP2007176529A (en) * | 2005-12-27 | 2007-07-12 | Earth Chem Corp Ltd | Volatile chemical agent container |
| CN200994935Y (en) * | 2006-10-20 | 2007-12-26 | 刘新明 | Essence bottle |
| JP2008289755A (en) * | 2007-05-28 | 2008-12-04 | Dainippon Printing Co Ltd | Medicine vaporizer |
| CN201424213Y (en) * | 2009-03-24 | 2010-03-17 | 陈红斌 | Solid-state volatile substance container |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4310654B2 (en) * | 2006-02-14 | 2009-08-12 | 小林製薬株式会社 | Transpiration container |
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2013
- 2013-11-14 JP JP2013236309A patent/JP6189185B2/en active Active
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000185090A (en) * | 1998-12-24 | 2000-07-04 | T Hasegawa Co Ltd | Liquid volatilization device |
| CN2836808Y (en) * | 2005-01-10 | 2006-11-15 | 花仙子企业股份有限公司 | Improved volatile cotton body for aroma device |
| JP2007176529A (en) * | 2005-12-27 | 2007-07-12 | Earth Chem Corp Ltd | Volatile chemical agent container |
| CN200994935Y (en) * | 2006-10-20 | 2007-12-26 | 刘新明 | Essence bottle |
| JP2008289755A (en) * | 2007-05-28 | 2008-12-04 | Dainippon Printing Co Ltd | Medicine vaporizer |
| CN201424213Y (en) * | 2009-03-24 | 2010-03-17 | 陈红斌 | Solid-state volatile substance container |
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| CN104627542B (en) | 2017-07-07 |
| JP2015093733A (en) | 2015-05-18 |
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