CN103518711B - The flying pest repellent of aqueous gel pearl type - Google Patents
The flying pest repellent of aqueous gel pearl type Download PDFInfo
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- CN103518711B CN103518711B CN201310269070.2A CN201310269070A CN103518711B CN 103518711 B CN103518711 B CN 103518711B CN 201310269070 A CN201310269070 A CN 201310269070A CN 103518711 B CN103518711 B CN 103518711B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
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Abstract
The invention provides and avoid keep away flavor compositions by adding specific flying pest in specific water absorbent polymer, flying pest is avoided and is kept away composition plays the aqueous gel pearl type of excellent flying pest Repellency effect flying pest repellent in specified time limit.In addition, also provide the flying pest employing aromaticity in described flying pest repellent to avoid and the fragrance at initial stage when keeping away composition, can be made to continue, and gel beads is steady in a long-term, does not go bad, from the flying pest repellent of the aqueous gel pearl type of the problems such as liquid.The flying pest repellent of the aqueous gel pearl type keeping away flavor compositions and water is avoided containing acrylic acid series water absorbent polymer, flying pest.Described flying pest is avoided and is kept away flavor compositions, avoid as flying pest and keep away composition, the one kind or two or more fragrance component selected from acetic acid esterified compound and/or allylester compound containing (a) and (b) are the one kind or two or more fragrance component selected the aromatic alcohols of 10 from monoterpene system alcohol or carbon number, preferably, avoid the Repellency effect after keeping away being vaporized of composition as described flying pest and continue composition, the vapour pressure also coordinating 20 DEG C is the glycol of 0.2 ~ 20Pa and/or the one kind or two or more of glycol ethers.
Description
Technical field
The present invention relates to the flying pest repellent of aqueous gel pearl type.
Background technology
So far, for flying pests such as mosquito, buffalo gnat, midge, fly classes, the method that the repellent that will comprise Metadelphene (N, N-DEET) coats skin surface widely uses.But Metadelphene is compared with common fragrance component, and fluidization property is lower slightly, the Repellency effect in space therefore can not be expected.On the other hand, make the insecticidal constituent of normal temperature fluidization property, such as the empenthrin etc. of pyrethroid system is spatially vaporized, and can realize the Repellency effect for flying pest, but the scene that the use that there is many insecticidal constituents to normal temperature fluidization property is kept someone at a respectful distance.
Therefore, propose several as avoid keep away composition use the natural essential oil of fluidization property, the trial of its constituent.Such as, well-known citronella oil, as the citronellal of its principal component, Repellency effect is shown for mosquito, in the U.S., commercially available as the candle of active ingredient containing citronella oil.But, the citronellal of the method utilizing the heat of candle that citronellal is diffused be vaporized efficiency difference, do not produce practical Repellency effect.
In addition, flying pest repellent is described in Japanese Unexamined Patent Publication 2002-173407 publication (patent document 1), except citronella oil, using the natural essential oil selected from orange oil, Chinese cassia tree wet goods as active ingredient, as the solvent used in liquor, the aliphatic hydrocarbons such as ester class, hexane, kerosene, paraffin such as the alcohols such as methyl alcohol, ethanol, diethyl phthalate, isopropyl myristate, aromatic hydrocarbon based, ethers etc. can be enumerated multiple.
In addition, Japanese Unexamined Patent Publication 2003-201203 publication (patent document 2) discloses insect repellent and is vaporized composition, avoid as insect and keep away composition (A), containing citronellal and from terpineol, menthol, citrene, geraniol, citronellol, lauro lene etc. select one kind or two or more, the content that insect avoids the citronellal kept away in composition (A) is 2 ~ 10 quality %.But although these repellents relieve the misgivings to pursuing natural product and safety, the continuation of its Repellency effect is poor, may not satisfy the demand.
In addition, in Japanese Laid-Open Patent Publication 61-289002 publication (patent document 3), propose " the arthropods class using glycol ethers as active ingredient, mollusc and reptile class repellent ".Describe glycol ethers in patent document 3 for the excellent Repellency effect of blattaria, the display of mite class, but whether its effect is actually abundant hardly, and for the Repellency effect of flying pest without any mentioning.
Like this, the useful flying pest that the continuation being conceived to flying pest Repellency effect and then being also conceived to fragrance improves avoids that to keep away flavor compositions not yet known, strongly wishes that it is developed.
, fill in the container possessing liquid-sucking core and avoid containing flying pest the liquid keeping away spices, make to avoid via liquid-sucking core the flying pest repellent keeping away the so-called liquid-type that spices is vaporized to space at leisure and popularize widely.Which has can make to avoid and is vaporized with keeping away perfume stable, can easily depending on recognizing the advantage of the final period of use by the minimizing of liquid, but when container overturning, the danger that liquid spills is inevitable.Therefore, propose use water absorbent polymer, avoid the flying pest repellent of the aqueous gel pearl type keeping away spices containing flying pest, severally supply practicality, but the flying pest repellent of form that Repellency effect is excellent, easily supply uses not yet is developed.
Therefore, when the present inventor develops the flying pest repellent of useful aqueous gel pearl type, recognize and select the raw material of water absorbent polymer, avoid with specific flying pest that to keep away combinations of perfumes be most important, repeatedly study.
Such as, describe in Japanese Unexamined Patent Publication 2007-291146 publication (patent document 4) containing the water-absorbing resins comprising acrylamide/acrylic acid copolymer, water, polyoxyalkylene alkyl, aqueous gel as the fragrance ingredient of functional components.In addition, Japanese Unexamined Patent Publication 2010-162327 publication (patent document 5) discloses aqueous gel aromatic, and it comprises (a) amine oxide, (b) spices, (c) comprise using acrylamide and acrylic acid or its salt as the cross-linking type water-absorbing resins of copolymer and the water that are formed monomer.
In patent document 4, patent document 5, as water absorbent polymer, employ the copolymer of acrylamide/acrylic acid or its salt, but the result of the research such as the present inventor, with certain flying pest avoid keep away combinations of perfumes when, confirm that aqueous gel goes bad slightly due to light, leave the leeway of improvement.Namely, as general fragrance ingredient, functionally different flying pests is avoided keep away flavor compositions be applied to aqueous gel formula time, patent document 4, patent document 5 do not become reference, in order to find best water absorbent polymer, the enforcement of various test is indispensable, has to repeatedly carry out trial and error, and this is present situation.
Prior art document
Patent document
[patent document 1] Japanese Unexamined Patent Publication 2002-173407 publication
[patent document 2] Japanese Unexamined Patent Publication 2003-201203 publication
[patent document 3] Japanese Laid-Open Patent Publication 61-289002 publication
[patent document 4] Japanese Unexamined Patent Publication 2007-291146 publication
[patent document 5] Japanese Unexamined Patent Publication 2010-162327 publication
Summary of the invention
The problem that invention will solve
The object of the present invention is to provide by specific water absorbent polymer by having coordinated flying pest to avoid to keep away composition, the specific flying pest that preferably also coordinated Repellency effect to continue composition avoids and keeps away flavor compositions and water combination, described flying pest is avoided and is kept away composition plays the aqueous gel pearl type of excellent flying pest Repellency effect flying pest repellent in specified time limit.In addition, its object is to be provided in the flying pest employing aromaticity in described flying pest repellent avoid the fragrance at initial stage when keeping away composition, can be made to continue, and gel beads is steady in a long-term, do not produce rotten, from the flying pest repellent of the aqueous gel pearl type of the problems such as liquid.
For solving the means of problem
Find that following formation of the present invention plays excellent effect to achieve these goals.
(1) a flying pest repellent for aqueous gel pearl type, is characterized in that, avoids keep away flavor compositions and water containing acrylic acid series water absorbent polymer, flying pest.
(2) the flying pest repellent of the aqueous gel pearl type as described in (1), wherein, described acrylic acid series water absorbent polymer is acrylic acid/acrylate copolymer.
(3) the flying pest repellent of the aqueous gel pearl type as described in (1) or (2), it is also containing surfactant.
(4) the flying pest repellent of the aqueous gel pearl type as described in any one of (1) ~ (3), wherein, described flying pest is avoided and is kept away flavor compositions, avoid as flying pest and keep away composition, containing the one kind or two or more fragrance component that (a) selects from the allylester compound shown in the acetic acid esterified compound shown in general formula (I) and/or general formula (II);
CH
3-COO-R
1···(I)
(R
1: carbon number is the alcohol residue of 6 ~ 12)
R
2-CH
2-COO-CH
2-CH＝CH
2···(II)
(R
2: carbon number be 4 ~ 7 alkyl, alkoxyl, cycloalkyl, cycloalkyloxy or phenoxy group)
And (b) is the one kind or two or more fragrance component selected the aromatic alcohols of 10 from monoterpene system alcohol or carbon number.
(5) the flying pest repellent of the aqueous gel pearl type as described in (4), wherein, (a) is 0.1 ~ 1.0 times amount relative to the compounding ratio of (b).
(6) the flying pest repellent of the aqueous gel pearl type as described in (4) or (5), wherein, acetic acid esterified compound shown in described (a) general formula (I) is from p-tert-butylcyclohexyl acetate, acetic acid o-tert-butyl cyclohexyl, acetic acid is to tertiary pentyl cyclohexyl, acetic acid tricyclodecenyl esters, benzyl acetate, acetoxyphenyl group ethyl ester, acetic acid styracin, anisyl acetate, cinnamyl acetate, terpinyl acetate, acetic acid dihydro terpinyl acetate, acetic acid virtue camphor tree ester, acetic acid ethyl virtue camphor tree ester, citronellyl acetate, geranyl acetate, acetic acid flores aurantii ester, at least 1 that selects in bornyl acetate and isobornyl acetate,
Allylester compound shown in general formula (II) is at least 1 that selects from allyl hexanoate, allyl heptanoate, allyl octanoate, n-pentyloxy allyl acetate, cyclohexyl allyl acetate, cyclohexyloxy allyl acetate and phenoxyethanoic acid allyl ester.
(7) the flying pest repellent of the aqueous gel pearl type as described in any one in (4) ~ (6), wherein, described (b) monoterpene system's alcohol or carbon number be 10 aromatic alcohols be from terpineol, geraniol, dihydromyrcenol, borneol, menthol, citronellol, nerol, linalool, ethyl linalool, thymol, eugenol and at least 1 that selects in terpane-3,8-glycol.
(8) the flying pest repellent of the aqueous gel pearl type as described in any one in (4) ~ (7), wherein, described flying pest is avoided and is kept away flavor compositions, avoid the Repellency effect after keeping away being vaporized of composition as described flying pest and continue composition, the vapour pressure also coordinating 20 DEG C is the glycol of 0.2 ~ 20Pa and/or the one kind or two or more of glycol ethers.
(9) the flying pest repellent of the aqueous gel pearl type as described in (8), wherein, described glycol and/or glycol ethers are at least 1 that selects from ethylene glycol monobenzyl ether, propane diols, dipropylene glycol, tripropylene glycol, 1,3-BDO, hexylene glycol, diethylene glycol monobutyl ether, dipropylene glycol monobutyl ether and tripropylene glycol methyl ether.
(10) the flying pest repellent of the aqueous gel pearl type as described in (9), wherein, described glycol and/or glycol ethers are dipropylene glycol.
The effect of invention
The flying pest repellent of aqueous gel pearl type of the present invention, by in specific water absorbent polymer by having coordinated flying pest to avoid to keep away composition, the specific flying pest that preferably also coordinated Repellency effect to continue composition avoids and keeps away flavor compositions and water combination, described flying pest is avoided and is kept away composition and play excellent flying pest Repellency effect in specified time limit.In addition, the flying pest employing aromaticity in described flying pest repellent is avoided when keeping away composition, the fragrance at initial stage can be made to continue, and gel beads is steady in a long-term, do not produce rotten, from problems such as liquid, therefore its serviceability is high.
Embodiment
Flying pest for the flying pest repellent of aqueous gel pearl type of the present invention is avoided and is kept away flavor compositions, does not use insecticidal constituent in fact, uses fragrance component to avoid as flying pest and keeps away composition.Below such fragrance component being called that flying pest is avoided and keeping away spices, such as, is the acetic acid esterified compound shown in (a) general formula (I):
CH
3-COO-R
1···(I)
(R
1: carbon number is the alcohol residue of 6 ~ 12)
Such as p-tert-butylcyclohexyl acetate, acetic acid o-tert-butyl cyclohexyl, acetic acid can be enumerated to tertiary pentyl cyclohexyl, acetic acid tricyclodecenyl esters, benzyl acetate, acetoxyphenyl group ethyl ester, acetic acid styracin, anisyl acetate, cinnamyl acetate, terpinyl acetate, acetic acid dihydro terpinyl acetate, acetic acid virtue camphor tree ester, acetic acid ethyl virtue camphor tree ester, citronellyl acetate, geranyl acetate, acetic acid flores aurantii ester, bornyl acetate and isobornyl acetate etc.These acetic acid esterified compounds can be used alone, and also can at random combinationally use.
On the other hand, as the allylester compound shown in general formula (II),
R
2-CH
2-COO-CH
2-CH＝CH
2···(II)
(R
2: carbon number be 4 ~ 7 alkyl, alkoxyl, cycloalkyl, cycloalkyloxy or phenoxy group)
Such as allyl hexanoate, allyl heptanoate, allyl octanoate, isobutoxy allyl acetate, n-pentyloxy allyl acetate, cyclohexyl allyl acetate, allyl cyclohexyl propionate, cyclohexyloxy allyl acetate, phenoxyethanoic acid allyl ester etc. can be enumerated.These allylester compound can be used alone, and also can at random combinationally use.
In addition, (b) monoterpene system's alcohol or carbon number be 10 aromatic alcohols also useful, such as, terpineol, geraniol, dihydromyrcenol, borneol, menthol, citronellol, nerol, linalool, ethyl linalool, thymol, eugenol and to terpane-3,8-glycol etc. be representative compound.These monoterpene system alcohol or carbon number be 10 aromatic alcohols can be used alone, also can at random combinationally use.
In the present invention, the one kind or two or more fragrance component (a) must selected from the allylester compound shown in the acetic acid esterified compound shown in general formula (I) and/or general formula (II) and (b) are the one kind or two or more fragrance component selected the aromatic alcohols of 10 from monoterpene system alcohol or carbon number and use.And the result of the further investigation of the present inventor, has found (a) compounding ratio particularly preferably 0.1 ~ 1.0 times amount for (b).
In addition, in the present invention, avoid as flying pest and keep away spices, can suitably add fragrance component other than the above, the monoterpene system hydrocarbon such as such as citrene, menthones, carvol, pulegone, camphor, reach the monoterpene system ketone such as agate ketone, citral, citronellal, neral, the monoterpene system aldehyde such as perillaldehyde, cinnamyl benzoate, the ester compounds such as geranyl formate, benzyl carbinol, diphenyl ether, indoles spices etc., also suitably can add the various essential oil classes comprising above-mentioned fragrance component, such as jasmin oil, neroli oil, peppermint oil, bergamot oil, orange oil, geranium oil, petit grain oil, lemon oil, citronella oil, lemongrass oil, cinnamon oil, eucalyptus oil, lemon eucalyptus oil, thyme wet goods.
The flying pest used in the present invention is avoided and is kept away flavor compositions, and avoid the Repellency effect after keeping away being vaporized of spices as flying pest and continue composition, the vapour pressure preferably coordinating 20 DEG C is the glycol of 0.2 ~ 20Pa and/or the one kind or two or more of glycol ethers.Such glycol and/or glycol ethers, in patent document 2, with the same columns such as ethanol, isopropyl alcohol, lam-oil enumerate as solvent, in addition, in patent document 3, although describe the excellent Repellency effect of blattaria, the display of mite class, for the effect of flying pest without any mentioning.
But, the present inventor knows that this glycol and/or glycol ethers are not only as solvent for the first time, and above-mentioned flying pest avoided keep away the continuous action that spices also produces Repellency effect specifically, the flying pest employing aromaticity avoids the fragrance that also can maintain the initial stage when keeping away spices.
As its concrete typical example (recording the vapour pressure of 20 DEG C in the lump), propane diols (10.7Pa), dipropylene glycol (1.3Pa), tripropylene glycol (0.67Pa), diethylene glycol (DEG) (3Pa), triethylene glycol (1Pa), 1 can be enumerated, 3-butanediol, hexylene glycol (6.7Pa), ethylene glycol monobenzyl ether (2.7Pa), diethylene glycol monobutyl ether (3Pa), dipropylene glycol monobutyl ether and tripropylene glycol methyl ether, wherein, dipropylene glycol is applicable to object of the present invention.In addition, above-mentioned glycol and/or glycol ethers can be used alone, and also can at random combinationally use.
Glycol and/or glycol ethers avoid the compounding ratio of keeping away spices relative to flying pest, about 0.05 ~ 5 times is suitable.
Avoiding at flying pest keeps away in flavor compositions, only otherwise bring obstacle to effect of the present invention, can coordinate other functional components, can enumerate such as insecticidal constituent, deodorizing composition, degerming antimicrobial component etc.As insecticidal constituent, the empenthrin of normal temperature fluidization property pyrethroid system, the third Flumethrin, transfluthrin, metofluthrin etc. can be enumerated, according to purport of the present invention, when cooperation, preferably do one's utmost to rest on trace.As deodorizing composition, the plant extracts selected from grass family, Theaceae, Ginkgoaceae, Oleaceae, mulberry section, oranges and tangerines section, Malpighiaceae, Ebenaceae is representational composition.In addition, the patchouli alcohol, greenery aldehyde etc. that also can add and be called " green fragrance " give relaxation effect.These functional components can be used alone, and also can at random combinationally use.
The flying pest repellent of aqueous gel pearl type of the present invention, it is characterized in that, its be modulation containing above-mentioned flying pest avoid keep away flavor compositions and water containing immersion liquid, added in acrylic acid series water absorbent polymer and made, but preferably containing matching surface activating agent in immersion liquid.
Surfactant positively makes flying pest avoid to keep away the inside that flavor compositions remains on gel beads, contribute to its slowly-releasing, therefore, it is possible to play flying pest Repellency effect steady in a long-term.
As surfactant, the nonionic system surfactants such as such as Crodaret, polyoxyethylene higher alkyl ether (polyoxyethylene laurel ether, polyoxyl 10 oleyl ether etc.), polyoxyethylene alkyl phenyl ether class, polyoxyethylene higher fatty esters of gallic acid, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerol fatty esters of gallic acid, polyoxyethylene polyoxy-propylene can be enumerated, the senior alkyl amine oxide system surfactants such as dodecyl amine oxide, octadecyl amine oxide, lauramido dimethyl amine.These surfactants can be used alone, and also can at random combinationally use.
The use level of surfactant, avoids relative to flying pest and keeps away flavor compositions, be about 0.5 ~ 4 times is suitable.In addition, anion system surfactant declines owing to making the water absorbing force of water absorbent polymer, is therefore not suitable for purport of the present invention.
Acrylic acid series water absorbent polymer has water imbibition excellence, absorbs the character of the water of more than 100 times of deadweight.If particle diameter is about the acrylic acid series water absorbent polymer of about 2mm, be roughly expanded to transparent, that particle diameter is about about 10mm bead after water suction, therefore object according to the invention.
As the acrylic acid series water absorbent polymer used in the present invention, acrylic acid/acrylate copolymer (acrylic acid/sodium acrylate salt copolymer, acrylic acid/potassium acrylate salt copolymer etc.) can be enumerated, the copolymer of acrylamide/acrylic acid or its salt.Acrylamide/the acrylic acid of the latter or the copolymer of its salt are as previously mentioned, there is its aqueous gel and slightly produce rotten tendency due to light, and relatively, the gel stability of the former acrylic acid/acrylate copolymer is excellent, realize cost to reduce, therefore can use more suitably.
In addition, the use level of this water absorbent polymer relative to containing immersion liquid, be about 0.01 ~ 0.1 times just enough.
When modulating aqueous gel pearl of the present invention, such as, usually there is on top the water absorbent polymer loading ormal weight in opening portion, the plastics system of suitable capacity or the container of glass, then, injecting containing immersion liquid of flavor compositions and water etc. can be kept away by avoiding containing flying pest.In addition, water absorbent polymer and the ordering in launching containing immersion liquid can be contrary, and, containing in immersion liquid, only otherwise obstacle is brought to effect of the present invention, bitters, pH adjusting agent, the colouring agent etc. such as the preservative such as the stabilization agent such as solvent, BHT, isothiazoline system, Denatonium Benzoate (Bitrex) can suitably be coordinated as required.
As the solvent for modulating, the hydrocarbon system solvents etc. such as the such as lower alcohol such as ethanol, isopropyl alcohol, ketone series solvent, ester series solvent, n-alkane and isoparaffin can be enumerated.
The flying pest contained in aqueous gel pearl of the present invention avoid keep away flavor compositions use level, aqueous gel pearl capacity, according to the use of this repellent, between the operating period and the kind of water absorbent polymer, its specification etc., suitably can determine.Such as, if with 200 days, also different because of the size of opening portion, but the capacity of aqueous gel pearl is about 400g is effective.Such as, and as the ratio of each gradation composition, make flying pest avoid keeping away flavor compositions is 1 ~ 7 quality %, makes surfactant be 0.5 ~ 10 quality %, makes water be 90 quality %, it is suitable for making water absorbent polymer be about 1 ~ 5 quality %.
In addition, according to the result of the test of the present inventor, the impact being vaporized the formula being subject to flavor compositions from aqueous gel pearl of spices is confirmed.The flying pest used in the present invention is avoided and keeps away flavor compositions, continue the glycol of components matching and/or glycol ethers as the Repellency effect after being vaporized to contribute to being vaporized stabilisation from aqueous gel pearl, on the other hand, when not containing the spices of this glycol and/or glycol ethers, confirm the tendency that the amount of volatilization at initial stage slightly increases.
The flying pest repellent of aqueous gel pearl type of the present invention, flavor compositions and water combination is kept away by being avoided by specific flying pest in specific water absorbent polymer, thus described flying pest is avoided and is kept away composition and play excellent flying pest Repellency effect in specified time limit, the flying pest simultaneously employing aromaticity is avoided can make the fragrance at initial stage continue when keeping away composition, and gel beads is steady in a long-term, therefore do not produce rotten, from problems such as liquid, therefore its serviceability is high.
Usually, use with the form be filled in transparent vessel, but also by multiple colored beads is mixed, or the pearl of sizes different for size can be combined, thus give ornamental.
The flying pest repellent of the aqueous gel pearl type of the present invention obtained like this, by using outside the medium space of the indoor in main entrance, kitchen, toilet, living room, bedroom etc., warehouse, car, courtyard, room, for culex, the flying pests such as the mosquito such as player whose turn comes next mosquito, wall scroll mosquito class, buffalo gnat, midge class, fly class, little fly class (fruit bat class, eye fly class etc.), moth fly class, bag casemaking clothes moth class, during regulation, play excellent flying pest Repellency effect.And, the flying pest employing aromaticity is avoided when keeping away spices, specified time limit is continued when fragrance in the early stage does not go bad, and these goods are not owing to containing insecticidal constituent in fact, even therefore do not like the people of use of insecticide, also can without using in revolt, therefore its practicality is high.
Next, based on specific embodiment and test example, the flying pest repellent of aqueous gel pearl type of the present invention is further described.But, the present invention is not limited to these embodiments and test example.
Embodiment 1
Modulate using avoid as flying pest keep away spices (a) general formula (I) shown in the acetic acid styracin 9.2 quality % of acetic acid esterified compound and acetoxyphenyl group ethyl ester 3.0 quality %, as the allyl heptanoate 2.1 quality % of the allylester compound shown in general formula (II), as the linalool 21.3 quality % that (b) monoterpene system's alcohol or carbon number are the aromatic alcohols of 10, terpineol 14.9 quality % and dihydromyrcenol 11.5 quality %, the dipropylene glycol 29.3 quality % of composition is continued as Repellency effect, and other flying pest is avoided and is kept away flying pest of the present invention that spices 8.7 quality % (comprising the benzyl carbinol of 7.5 quality %) coordinates and avoid and keep away flavor compositions.This flying pest avoids that to keep away (a) in flavor compositions relative to the compounding ratio of (b) be 0.30 times.
Next, the Crodaret 1.2 parts and dodecyl amine oxide 1.4 parts keeping away in flavor compositions 2.5 parts and add as surfactant is avoided at this flying pest, and then coordinate the ethanol 3.0 parts as solvent, the green-tea extract 0.1 part as deodorizing composition, the BHT0.2 part as stabilizing agent, micro-isothiazoline system preservative, micro-bitters (Bitrex) and appropriate water, make entirety be 100 parts, modulation is containing immersion liquid.
There is above gross area 24cm
2opening portion, capacity be the acrylic acid/sodium acrylate salt copolymer 12g that the particle diameter being loaded as water absorbent polymer in the plastic containers (φ: 8cm, height: 10cm) of the cylindrical shape of 500mL is about 2mm.Inject above-mentioned containing immersion liquid 388g wherein, result water absorbent polymer expands, and obtains the flying pest repellent that particle diameter is about the aqueous gel pearl type of the present invention of 10mm.
The canopy this flying pest repellent being placed on main entrance uses, and result was not bothered by the flying pest such as mosquito, little fly during about 200 days, confirmed practical Repellency effect.This aqueous gel pearl, along with the process of time, slowly reduces, but not along with rotten, from liquid, gel stability is excellent, also can confirm the terminal used clearly.In addition, to drift the fragrance of initial stage fragrance at the surrounding space of main entrance, can provide comfortable frankness sense to surrounding, practicality is high.
[test example 1]
According to embodiment 1, the p-tert-butylcyclohexyl acetate 12mg of the acetic acid esterified compound shown in (a) general formula (I) being used as flying pest to avoid to keep away spices and as the allyl octanoate 4mg of the allylester compound shown in general formula (II), be the geraniol 28mg of the aromatic alcohols of 10 as (b) monoterpene system's alcohol or carbon number, coordinate each Repellency effect to continue composition wherein, in preparation the present invention, the flying pest that uses is avoided and is kept away flavor compositions.For the flavor compositions obtained, implement following Sustainability Assessment test.In this test, to kill the active index as Sustainability Assessment for culex adult (♀).
[Sustainability Assessment test]
Make to comprise above-mentioned flying pest to avoid and keep away after acetone soln 0.5mL that spices and each Repellency effect continue the reagent agent of composition 70mg is impregnated in the filter paper of diameter 15cm, air-dry, modulate each reagent agent process filter paper.
Plastics rounding cylinder (internal diameter 20cm, high 43cm) is set, places each reagent agent process filter paper wherein.Cylinder is placed and by separating up and down, 20 the second cylinders (internal diameter 20cm, high 20cm) for examination culex adult is housed with 12 object wire nettings, and then place the 3rd cylinder (internal diameter 20cm, high 43cm) thereon.With the process of time, what counting was killed supplies examination borer population, obtains KT
50value (until the time killed for the half trying borer population).In addition, in order to evaluate the continuation of each reagent agent, the sample (0h in table 1) after providing the wind in upper space of reagent agent process filter paper to do and reagent agent process filter paper is vaporized after air drying in other room 2 kinds of sample (4h in table 1) of 4 hours.
[table 1]
The result of test, is glycol and/or the glycol ethers of 0.2 ~ 20Pa for the vapour pressures of 20 DEG C, confirms the continuous action of killing effect, namely continue the serviceability of composition as Repellency effect.In addition, by ethylene glycol system and the contrast of propane diols system, the favourable tendency of the latter is observed.And for the isopropyl myristate beyond glycol and/or glycol ethers, NEOTHIOZOL, even if be the scope of 0.2 ~ 20Pa the vapour pressure of 20 DEG C, the continuous action of killing effect also lacks.
[test example 2]
Based on the result of test example 1, next for hexylene glycol and dipropylene glycol, change flying pest and avoid the kind and use level of keeping away spices, carried out the test same with test example 1.Show the result in table 2.
[table 2]
The result of test, the Repellency effect used in the present invention continues composition, using avoid as flying pest keep away spices (a) general formula (I) shown in acetic acid esterified compound and/or the allylester compound shown in general formula (II) and (b) monoterpene system's alcohol or carbon number be the aromatic alcohols of 10 preferably when (a) is the range combinations of 0.1 ~ 1.0 relative to the compounding ratio of (b), show the continuous action of more efficient killing effect.
Embodiment 2
According to embodiment 1, as shown in table 3, modulation flying pest avoid keep away flavor compositions (10g) and comprise its contain immersion liquid (about 385g).And then, the water-soluble polymer of ormal weight is loaded in advance in the plastic containers used in embodiment 1, inject to it described containing immersion liquid, make total amount be 400g, obtain the flying pest repellent that effective duration is the aqueous gel pearl type of the present invention of about 200 days.
(about 6m in laboratory
3) in be arranged side by side the plastic cup (about 1L) that 2 are not joined the open state of lid.In the plastic cup of a side, load fruit bat lure and draw source and for examination flying pest repellent (treatment region), in the plastic cup of the opposing party, only load a fruit bat lure and draw source (check plot).Use after 120 days, put into about 100 fruit bat adults in indoor, count the intrusion worm in two district's plastic cups, calculate according to the following formula and avoid the rate of keeping away.
Avoid the rate of keeping away=[the intrusion borer population of (the intrusion borer population of the intrusion borer population-treatment region of check plot)/check plot] × 100
[table 3]
The flying pest repellent of aqueous gel pearl type of the present invention, add in water-soluble polymer form by avoiding at flying pest the immersion liquid that contains keeping away combination water in flavor compositions (flying pest is avoided and kept away spices, is also preferably the glycol of 0.2 ~ 20Pa and/or the one kind or two or more of glycol ethers containing the vapour pressure continuing 20 DEG C of composition as the Repellency effect after being vaporized) and preferably surfactant.The result of test, confirms that the flying pest repellent of aqueous gel pearl type of the present invention also plays excellent flying pest Repellency effect after a procedure after 120 days.
In addition, as acrylic acid series water absorbent polymer, acrylic acid/acrylate copolymer compared with acrylamide/acrylic acid copolymer more preferably, and, avoid as flying pest and keep away spices, be that the aromatic alcohols of 10 is when being 0.1 ~ 1.0 times amount combination with (a) relative to the compounding ratio of (b) by the allylester compound shown in the acetic acid esterified compound shown in (a) general formula (I) and/or general formula (II) and (b) monoterpene system's alcohol or carbon number, the effect that Repellency effect continues composition more efficiently manifests, not only avoid the rate of keeping away, and the continuation of fragrance also meets.In addition, also the cooperation confirming surfactant really makes flying pest avoid and keeps away the inside that flavor compositions remains on gel beads, contribute to its slowly-releasing, flying pest Repellency effect steady in a long-term can be played, and specific glycol and/or glycol ethers to continue composition as Repellency effect useful.
And employ polyoxyalkylene cross-linking agent comparison 1, employ be not flying pest avoid comparison 2 of the jasmin oil keeping away spices when, there is no sufficient Repellency effect.
Therefore known, in specific water-soluble polymer by having coordinated flying pest to avoid to keep away spices, the specific flying pest that preferably also coordinated Repellency effect to continue composition avoid keep away flavor compositions, He Shui, be more preferably combined with the aqueous gel pearl type of the present invention of surfactant the practicality of flying pest repellent excellent.
Industry utilizes possibility
The flying pest repellent of aqueous gel pearl type of the present invention not only for flying pest, and can utilize for the purpose of the pest repelling widely.
Claims (6)
1. a flying pest repellent for aqueous gel pearl type, is characterized in that, avoids keep away flavor compositions and water containing acrylic acid/acrylate copolymer, flying pest,
Described flying pest is avoided and is kept away in flavor compositions, avoids and keeps away composition, contain as flying pest:
(a) composition: at least a kind of acetic acid esterified compound selected from acetic acid tricyclodecenyl esters, benzyl acetate, acetoxyphenyl group ethyl ester, acetic acid styracin, anisyl acetate, cinnamyl acetate and geranyl acetate, and/or
The fragrance component of at least a kind of allylester compound selected from allyl hexanoate, allyl heptanoate, allyl octanoate, n-pentyloxy allyl acetate, phenoxyethanoic acid allyl ester and allyl cyclohexyl propionate; With
(b) composition: from terpineol, geraniol, dihydromyrcenol, borneol, citronellol, nerol, linalool, ethyl linalool, thymol, eugenol be the fragrance component of the aromatic alcohols of 10 at least a kind of monoterpene system alcohol selected in terpane-3,8-glycol or carbon number.
2. the flying pest repellent of aqueous gel pearl type as claimed in claim 1, is characterized in that, also containing surfactant.
3. the flying pest repellent of aqueous gel pearl type as claimed in claim 1, it is characterized in that, described (a) composition is 0.1 ~ 1.0 times amount relative to the compounding ratio of described (b) composition.
4. the flying pest repellent of aqueous gel pearl type as claimed in claim 1 or 2, it is characterized in that, described flying pest is avoided and is kept away in flavor compositions, avoid the Repellency effect after keeping away being vaporized of composition as described flying pest and continue composition, the vapour pressure also coordinating 20 DEG C is the glycol of 0.2 ~ 20Pa and/or the one kind or two or more of glycol ethers.
5. the flying pest repellent of aqueous gel pearl type as claimed in claim 4, it is characterized in that, described glycol and/or glycol ethers are at least 1 that selects from ethylene glycol monobenzyl ether, propane diols, dipropylene glycol, tripropylene glycol, 1,3-BDO, hexylene glycol, diethylene glycol monobutyl ether, dipropylene glycol monobutyl ether and tripropylene glycol methyl ether.
6. the flying pest repellent of aqueous gel pearl type as claimed in claim 5, it is characterized in that, described glycol and/or glycol ethers are dipropylene glycol.
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| CN201610006403.6A CN105613487B (en) | 2012-06-29 | 2013-06-28 | The flying pest repellent of aqueous gel pearl type |
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| CN201310269070.2A Active CN103518711B (en) | 2012-06-29 | 2013-06-28 | The flying pest repellent of aqueous gel pearl type |
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| JP6279485B2 (en) * | 2012-12-03 | 2018-02-14 | 住友精化株式会社 | Water absorbent resin composition |
| JP6378047B2 (en) * | 2013-11-13 | 2018-08-22 | 大日本除蟲菊株式会社 | Insecticide for clothing |
| JP6326382B2 (en) * | 2015-01-23 | 2018-05-16 | 大日本除蟲菊株式会社 | Flying pest repellent |
| AU2017241474B2 (en) * | 2016-03-31 | 2019-09-12 | Dainihon Jochugiku Co., Ltd. | Flying insect pest repellent product and method for repelling flying insect pest |
| CN109310085A (en) * | 2016-06-20 | 2019-02-05 | 理研香料控股株式会社 | Flying pest attractant |
| JP7023107B2 (en) * | 2017-12-27 | 2022-02-21 | 大日本除蟲菊株式会社 | Flying pest repellent composition and flying pest repellent containing it |
| KR102458111B1 (en) * | 2018-04-09 | 2022-10-21 | 다이니혼 죠츄기쿠 가부시키가이샤 | Emergency Pest Repellent Products, and Emergency Pest Repellent Methods |
| CN113598163A (en) * | 2021-09-10 | 2021-11-05 | 姜兆伟 | Mosquito-repellent incense liquid for preventing children from eating by mistake and application of bitter essence as raw material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778176A (en) * | 2004-11-17 | 2006-05-31 | 大日本除虫菊株式会社 | Aerosol composition for attracting flying insect and device set therewith |
| CN101999345A (en) * | 2010-10-20 | 2011-04-06 | 周端午 | Environmentally-friendly, long-acting, bacteriostatic, mildewproof and pesticidal sol preparation |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5869568A (en) * | 1981-10-22 | 1983-04-25 | 小林香料株式会社 | Light permeable gel containing room temperature volatile substance |
| JPS5892357A (en) * | 1981-11-26 | 1983-06-01 | 小林香料株式会社 | Accommodating body |
| JPH03249270A (en) * | 1990-02-22 | 1991-11-07 | Showa Electric Wire & Cable Co Ltd | Harmful organism-repelling fiber product |
| JP3810668B2 (en) * | 2001-11-01 | 2006-08-16 | 高砂香料工業株式会社 | Fragrance composition having mosquito repellent effect |
| JP2003201203A (en) * | 2001-12-28 | 2003-07-18 | Johnson Co Ltd | Volatile insect pest repellent composition |
| JP4743825B2 (en) * | 2004-06-11 | 2011-08-10 | 大日本除蟲菊株式会社 | Mosquito, moth, chironomid repellent |
| JP5006512B2 (en) * | 2004-10-28 | 2012-08-22 | 株式会社ダイゾー | Aerosol products for space |
| JP4829589B2 (en) * | 2005-10-25 | 2011-12-07 | 大日本除蟲菊株式会社 | Flying pest repellent |
| JP2010126486A (en) * | 2008-11-27 | 2010-06-10 | Bio Eco:Kk | New insect pest repellent |
| JP2010138117A (en) * | 2008-12-12 | 2010-06-24 | Dainippon Jochugiku Co Ltd | Flying insect pest repellent and method of repelling flying insect pest using the same |
| JP5584008B2 (en) * | 2009-05-15 | 2014-09-03 | 花王株式会社 | Gel deodorant fragrance |
| JP5275895B2 (en) * | 2009-05-15 | 2013-08-28 | 花王株式会社 | Air freshener manufacturing method |
| JP5665359B2 (en) * | 2010-05-07 | 2015-02-04 | 大日本除蟲菊株式会社 | Insecticide for clothing pests |
| JP5587109B2 (en) * | 2010-09-16 | 2014-09-10 | 花王株式会社 | Aqueous gel air freshener |
| JP6017120B2 (en) * | 2011-06-09 | 2016-10-26 | エステー株式会社 | Solid volatilization preparation and composition used therefor |
-
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778176A (en) * | 2004-11-17 | 2006-05-31 | 大日本除虫菊株式会社 | Aerosol composition for attracting flying insect and device set therewith |
| CN101999345A (en) * | 2010-10-20 | 2011-04-06 | 周端午 | Environmentally-friendly, long-acting, bacteriostatic, mildewproof and pesticidal sol preparation |
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| CN105613487A (en) | 2016-06-01 |
| JP2018065842A (en) | 2018-04-26 |
| CN105613487B (en) | 2017-11-24 |
| CN103518711A (en) | 2014-01-22 |
| JP2014237622A (en) | 2014-12-18 |
| HK1218838A1 (en) | 2017-03-17 |
| JP6466551B2 (en) | 2019-02-06 |
| JP6254371B2 (en) | 2017-12-27 |
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