CN104610817A - Interior wall coating with formaldehyde purifying and antibacterial effects as well as preparation method of interior wall coating - Google Patents
Interior wall coating with formaldehyde purifying and antibacterial effects as well as preparation method of interior wall coating Download PDFInfo
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- CN104610817A CN104610817A CN201510018803.4A CN201510018803A CN104610817A CN 104610817 A CN104610817 A CN 104610817A CN 201510018803 A CN201510018803 A CN 201510018803A CN 104610817 A CN104610817 A CN 104610817A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an interior wall coating with formaldehyde purifying and antibacterial effects as well as a preparation method of the interior wall coating. The interior wall coating comprises 100-500 parts of a vinyl acetate/vinyl versatate copolymer emulsion, 20-400 parts of a styrene-acrylic emulsion, 5-150 parts of nano-titanium dioxide, 1-10 parts of hydroxyethyl cellulose, 1-10 parts of a dispersing agent, 0.1-8 parts of a wetting agent, 0.1-8 parts of a preservative, 1-10 parts of an antifoaming agent, 10-400 parts of filler, 0-400 parts of a pigment, 2-30 parts of an antifreeze agent, 2-50 parts of a coalescing agent, 0.1-8 parts of a thickener and 100-400 parts of water. The interior wall coating is prepared from all the components after even mixing. According to the coating, emulsion types, the content of the nano-titanium dioxide and the like are adjusted, and all components have a synergistic effect, the coating has the excellent function of purifying indoor harmful gases such as formaldehyde and the like and has the significant antibacterial effect. The coating can form films which are flat, soft, smooth and capable of adsorbing and purifying the formaldehyde through spray coating, roll coating or brush coating.
Description
Technical field
The present invention relates to a kind of interior wall coating, particularly relate to and a kind of there is interior wall coating of purifying formaldehyde and anti-microbial effect and preparation method thereof.
Background technology
The indoor harmful gas such as formaldehyde are objectionable impuritiess contained in the materials such as material of construction, finishing material and furniture, and discharge step by step, long-term is detrimental to health.Such as, the free monomer existed in emulsion and auxiliary agent in building coating, easily produce the hazardous property volatile matters such as a large amount of VOC, formaldehyde, benzene, these volatile matters not only pollute the environment, and serious harm HUMAN HEALTH, easily cause chronic respiratory tract disease, leukemia etc.For problems, international environmental protection tissue and various countries also formulate regulation and standard one after another, limit unwanted volatile content such as VOC, formaldehyde, benzene, building trade also using VOC, formaldehyde, benzene equal size as the important indicator of product export.
Formaldehyde is the important component of VOC in emulsion paint, be a kind of colourless, have special odor, slightly overweight air, volatile organic matter soluble in water, formaldehyde all has very strong pungency to the skin of people, eyes and respiratory mucosa, the symptoms such as acute poisoning can cause runny nose, sheds tears, cough, cause various respiratory tract disease; Chronic inhalation of low concentration formaldehyde can cause unrelenting headache, unable, insomnia etc.; Chronic skin Formaldehyde Exposed can cause dermatitis, also can produce detrimentally affect to the respiratory system of human body, Digestive tract and central nervous system, cause lung and liver immunologic dysfunction, be classified as one of mankind's suspect carcinogen matter by IARC.Therefore, also more and more higher containing quantitative limitation cry to finishing material Free-formaldehyde.Produce the important development trend that clean aldehyde interiro wall latex paint becomes current interiro wall latex paint.
Dope for inner wall of architecture, with the feature such as variation, the simplicity of construction, good cost performance of its color and decorative effect, becomes the building facing material be most widely used.Along with improving constantly of people's quality of life, environment protection health requires also more and more higher, is the indoor harmful gas etc. such as purifying formaldehyde to the further requirement of coating (interior wall paint).In addition, due to the deterioration of environment and ecological damage serious, reduce the natural immunity function of human body, meanwhile, various prevailing disease is but propagated rapidly, and therefore people's demand that can have antibacterial to coating is also more and more higher.
In sum, this area needs one badly can antibacterial, environmental protection again, can also keep the interior wall coating product of good conventional application performance simultaneously.
Summary of the invention
The object of the invention is to overcome at present on the market interior wall coating exist and cannot even discharge objectionable impurities by the obnoxious flavour such as purifying formaldehyde, the defect of anti-microbial property difference simultaneously, there is provided a kind of and there is interior wall coating of purifying formaldehyde and anti-microbial effect and preparation method thereof, interior wall coating of the present invention while the conventional application performance that maintenance is good, can have the obnoxious flavoures such as purifying formaldehyde and antibacterial function.
First aspect of the present invention is to provide a kind of interior wall coating with purifying formaldehyde and anti-microbial effect, and according to weight parts, its composition comprises:
Vinyl acetate/tertiary ethylene carbonate class copolymer emulsion (V8 emulsion) 100 ~ 500 parts,
Preferably, according to weight parts, the composition of described interior wall coating comprises:
Further preferably, according to weight parts, the composition of described interior wall coating comprises:
Wherein, pigment can be pigment conventional in paint field, can be mineral dye can be also pigment dyestuff, and the present invention is not construed as limiting it.
Wherein, filler can be filler conventional in paint field, and such as water-ground limestone, talcum powder and barium sulfate etc., the present invention is not construed as limiting it.
Wherein, the auxiliary agents such as dispersion agent, wetting agent, defoamer, film coalescence aid, antifreezing agent, thickening material and sanitas all can select kind conventional in paint field, and such as antifreezing agent can be propylene glycol, glycerol etc., and the present invention is not construed as limiting it.
Preferably, the mass ratio of V8 emulsion and benzene emulsion is 1 ~ 3: 1.
Preferably, in described interior wall coating, the total amount of V8 emulsion and benzene emulsion is 15 ~ 45% (w/w).
Preferably, in described interior wall coating, nanometer titanium dioxide titanium content is 2 ~ 12% (w/w).
Preferably, in described interior wall coating, the total amount of color stuffing is 15 ~ 46% (w/w).
Preferably, in described interior wall coating, the content of pigment is 10 ~ 25% (w/w).
Second aspect of the present invention is to provide the preparation method of the interior wall coating described in the present invention first aspect, by each component mixing and stirring of described interior wall coating, both.
Preferably, described preparation method is specially: after water, Natvosol, filler, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, adds organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.
Vinyl acetate/tertiary ethylene carbonate class copolymer emulsion (V8 emulsion), containing secondary nitrogen groups, effectively can catch the formaldehyde CH grabbed in absorbing environmental
2o discharges with water molecules form after carrying out chemical absorption reaction, thus permanent purification consumes formaldehyde.Benzene emulsion is not because possess purifying formaldehyde ability containing secondary nitrogen groups, and main rigidity, the scrub performance strengthening V8 emulsion, produces synergistic effect to V8 emulsion.Nano titanium oxide makes TiO under the effect of daylight or light middle-ultraviolet lamp
2activate and generate the radical with high catalytic activity, very strong photoxidation and reduction antibacterial ability can be produced, capable of purifying air, deodorizing taste removal, can effective kill harmful bacterium, catalysis, photodissociation can be attached to the organic volatile materials such as the various Formaldehyde and benzenes of surface of wall.
This coating, by each component synergies such as adjustment emulsion kind, nanometer titanium dioxide titanium contents, has the function of the indoor harmful gas such as excellent purifying formaldehyde and significant antibacterial effect.By spraying, roller coating or brush and form smooth film that is soft and smooth, adsorbable purifying formaldehyde.Be applicable to decoration and the protection on the surfaces such as the concrete of interior wall, uralite, masonry.
figure of description
Fig. 1 is the principle analysis figure of V8 emulsion purifying methanol.
Embodiment
The invention provides a kind of interior wall coating with purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises:
Wherein, pigment can be pigment conventional in paint field, can be mineral dye can be also pigment dyestuff, and the present invention is not construed as limiting it.
Wherein, filler can be filler conventional in paint field, and such as water-ground limestone, talcum powder and barium sulfate etc., the present invention is not construed as limiting it.
Wherein, the auxiliary agents such as dispersion agent, wetting agent, defoamer, film coalescence aid, antifreezing agent, thickening material and sanitas all can select kind conventional in paint field, and such as antifreezing agent can be propylene glycol, glycerol etc., and the present invention is not construed as limiting it.
The filmogen of interior wall coating provided by the invention adopt the vinyl acetate/tertiary ethylene carbonate class copolymer emulsion (V8 emulsion) containing the secondary nitrogen groups of formaldehyde autoreaction polymer segment and the benzene emulsion that obtained by vinylbenzene and acrylate monomer copolymerization composite.The secondary nitrogen groups of V8 emulsion effectively can catch the formaldehyde CH grabbed in absorbing environmental
2o discharges with water molecules form after carrying out chemical absorption reaction, thus permanent purification consumes formaldehyde, as shown in Figure 1.Benzene emulsion is not because possess purifying formaldehyde ability containing secondary nitrogen groups, and main rigidity, the scrub performance strengthening V8 emulsion, produces synergistic effect to V8 emulsion.Preferably, the mass ratio of V8 emulsion and benzene emulsion is 1 ~ 3: 1.
Total emulsion content is too low, and can cause film porous, emulsion content is too high, and coating thickness also can reduce, and affects scrubbing resistance number of times, and preferably, in described interior wall coating, the total amount of V8 emulsion and benzene emulsion is 15 ~ 45% (w/w).
Nano titanium oxide makes TiO under the effect of daylight or light middle-ultraviolet lamp
2activate and generate the radical with high catalytic activity, very strong photoxidation and reduction antibacterial ability can be produced, capable of purifying air, deodorizing taste removal, can effective kill harmful bacterium, catalysis, photodissociation can be attached to the organic volatile materials such as the various Formaldehyde and benzenes of surface of wall.General nanometer titanium dioxide titanium content higher film degradation adsorptive power is then stronger, more effective lasting.Nanometer titanium dioxide titanium content is preferably 2 ~ 12% (w/w).
Usually, (not needing during translucent cover lac varnish to add pigment) is as the criterion to obtain enough opacifying powers when adding pigment, add filler and can increase coating thickness, but too much color stuffing can cause PVC too high, film porousness is unfavorable for cleaning, so preferably, in described interior wall coating, the consumption of color stuffing is preferably 15 ~ 46% (w/w), and in described interior wall coating, the content of pigment is 10 ~ 25% (w/w).
By each component mixing and stirring of described interior wall coating, both the interior wall coating with purifying formaldehyde and anti-microbial effect of the present invention.Preferably, preparation method is specially: after water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, adds organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.
Below in conjunction with specific embodiment, the invention will be further described, to understand the present invention better.
Embodiment 1
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 85.1%, and purifying formaldehyde effect persistence is 70.4%; Detect according to national standard anti-microbial property, germ resistance is 99.99%, and antibacterial weather resistance is 99.9%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Embodiment 2
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 86.8%, and purifying formaldehyde effect persistence is 72.1%; Detect according to national standard anti-microbial property, germ resistance is 99.99%, and antibacterial weather resistance is 99.9%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Embodiment 3
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 87.4%, and purifying formaldehyde effect persistence is 72.7%; Detect according to national standard anti-microbial property, germ resistance is 99.99%, and antibacterial weather resistance is 99.9%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Embodiment 4
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 88.6%, and purifying formaldehyde effect persistence is 73.4%; Detect according to national standard anti-microbial property, germ resistance is 99.99%, and antibacterial weather resistance is 99.9%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Embodiment 5
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 89%, and purifying formaldehyde effect persistence is 73.4%; Detect according to national standard anti-microbial property, germ resistance is 99.99%, and antibacterial weather resistance is 99.9%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Embodiment 6
Have an interior wall coating for purifying formaldehyde and anti-microbial effect, according to weight parts, its composition comprises
After water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 90.1%, and purifying formaldehyde effect persistence is 75%.
Comparative example 1
This comparative example and the difference of embodiment 6, be not containing V8 emulsion.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 20.1%, and purifying formaldehyde effect persistence is 12.3%; Detect according to national standard anti-microbial property, germ resistance is 98.6%, and antibacterial weather resistance is 98.1%, and antifungal reaches 0 grade, and antifungal weather resistance reaches 0 grade.
Comparative example 2
This comparative example and the difference of embodiment 6, be not containing organosilicon crylic acid latex.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 82.4%, and purifying formaldehyde effect persistence is 65.3%.
Comparative example 3
This comparative example and the difference of embodiment 6, be not containing nano titanium oxide.According to method therefor in JC/T1074-2008 " function of purifying indoor air coating material purifying property ", purifying property detection is carried out to this coating, under fluorescent lamp and common solar light irradiation, detected result is purifying formaldehyde performance 76.3%, and purifying formaldehyde effect persistence is 54.2%.
Be described in detail specific embodiments of the invention above, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.
Claims (10)
1. have an interior wall coating for purifying formaldehyde and anti-microbial effect, it is characterized in that, according to weight parts, its composition comprises:
2. interior wall coating according to claim 1, is characterized in that, according to weight parts, its composition comprises:
3. interior wall coating according to claim 1, is characterized in that, according to weight parts, its composition comprises:
4. according to the interior wall coating in claims 1 to 3 described in any one, it is characterized in that, the mass ratio of vinyl acetate/tertiary ethylene carbonate class copolymer emulsion and benzene emulsion is 1 ~ 3: 1.
5. according to the interior wall coating in claims 1 to 3 described in any one, it is characterized in that, in described interior wall coating, the total amount of vinyl acetate/tertiary ethylene carbonate class copolymer emulsion and benzene emulsion is 15 ~ 45% (w/w).
6. according to the interior wall coating in claims 1 to 3 described in any one, it is characterized in that, in described interior wall coating, nanometer titanium dioxide titanium content is 2 ~ 12% (w/w).
7. according to the interior wall coating in claims 1 to 3 described in any one, it is characterized in that, in described interior wall coating, the total amount of color stuffing is 15 ~ 46% (w/w).
8. interior wall coating according to claim 7, is characterized in that, in described interior wall coating, the content of pigment is 10 ~ 25% (w/w).
9. a preparation method for the interior wall coating in claim 1 ~ 8 described in any one, is characterized in that, by each component mixing and stirring of described interior wall coating, both.
10. according to preparation method according to claim 9, it is characterized in that, after water, Natvosol, filler, nano titanium oxide, pigment, dispersion agent, wetting agent and sanitas mixing high-speed stirring is dispersed to Xi Du≤40 micron, add organosilicon crylic acid latex, benzene emulsion, film coalescence aid, thickening material, defoamer, antifreezing agent be uniformly mixed.
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Cited By (9)
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| CN105925091A (en) * | 2016-06-14 | 2016-09-07 | 烟台蒙特防水材料有限公司 | Water-borne corrosion-resistant and waterproof coating for concrete structure |
| CN108546017A (en) * | 2018-05-16 | 2018-09-18 | 四川文希科技有限公司 | One kind removing formaldehyde building coating and preparation method |
| CN108892812A (en) * | 2018-06-01 | 2018-11-27 | 汕头市优森活新材料科技有限公司 | Crust promotor composition and preparation method, application method with purifying formaldehyde function |
| CN109878161A (en) * | 2019-02-18 | 2019-06-14 | 浙江健煦环境科技有限公司 | One kind is except formaldehyde decorative panel and preparation method thereof |
| CN110585910A (en) * | 2019-09-25 | 2019-12-20 | 深圳市绿安居科技有限公司 | Indoor formaldehyde scavenger and preparation method thereof |
| CN112812629A (en) * | 2021-02-19 | 2021-05-18 | 管仲洲 | Water-based wood paint with air purification function and preparation method thereof |
| CN112876994A (en) * | 2021-02-04 | 2021-06-01 | 三棵树(上海)新材料研究有限公司 | Aldehyde-removing antibacterial coating based on titanium-based metal organic framework material and preparation method thereof |
| CN113861772A (en) * | 2021-09-24 | 2021-12-31 | 四川汇园宝新材料科技有限公司 | Anti-formaldehyde coating and preparation method thereof |
| CN115820021A (en) * | 2022-12-06 | 2023-03-21 | 卓芳菲 | Preparation method of anticorrosive, antibacterial and formaldehyde-removing coating |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925091A (en) * | 2016-06-14 | 2016-09-07 | 烟台蒙特防水材料有限公司 | Water-borne corrosion-resistant and waterproof coating for concrete structure |
| CN108546017A (en) * | 2018-05-16 | 2018-09-18 | 四川文希科技有限公司 | One kind removing formaldehyde building coating and preparation method |
| CN108892812A (en) * | 2018-06-01 | 2018-11-27 | 汕头市优森活新材料科技有限公司 | Crust promotor composition and preparation method, application method with purifying formaldehyde function |
| CN109878161A (en) * | 2019-02-18 | 2019-06-14 | 浙江健煦环境科技有限公司 | One kind is except formaldehyde decorative panel and preparation method thereof |
| CN109878161B (en) * | 2019-02-18 | 2021-06-15 | 浙江健煦环境科技有限公司 | Formaldehyde-removing decorative plate and preparation method thereof |
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| CN112876994A (en) * | 2021-02-04 | 2021-06-01 | 三棵树(上海)新材料研究有限公司 | Aldehyde-removing antibacterial coating based on titanium-based metal organic framework material and preparation method thereof |
| CN112812629A (en) * | 2021-02-19 | 2021-05-18 | 管仲洲 | Water-based wood paint with air purification function and preparation method thereof |
| CN113861772A (en) * | 2021-09-24 | 2021-12-31 | 四川汇园宝新材料科技有限公司 | Anti-formaldehyde coating and preparation method thereof |
| CN115820021A (en) * | 2022-12-06 | 2023-03-21 | 卓芳菲 | Preparation method of anticorrosive, antibacterial and formaldehyde-removing coating |
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