CN104610755A - Organic silicon elastomer - Google Patents
Organic silicon elastomer Download PDFInfo
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- CN104610755A CN104610755A CN201510107819.2A CN201510107819A CN104610755A CN 104610755 A CN104610755 A CN 104610755A CN 201510107819 A CN201510107819 A CN 201510107819A CN 104610755 A CN104610755 A CN 104610755A
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Abstract
The invention relates to an organic silicon elastomer and a composite glass milk bottle prepared from the organic silicon elastomer. A protective layer of the organic silicon elastomer is good in bonding property and forms an integral structure together with a glass milk bottle body. A production process is simple and reliable; the protective layer of the organic silicon elastomer is good in transparency and high in strength and is not separated from the surface of the glass body; glass fragments can be reserved in the protective layer and prevented from being splashed outwards when glass is broken, so that the safety is good.
Description
Technical field
The present invention relates to the technical field of silicone elastomer, what be specifically related to is a kind of silicone elastomer that can be used for preparing compound glass feeding bottle.
Background technology
At present, the feeding bottle material of market being sold is mainly plastic and glass two kinds.Wherein, the feeding bottle of plastic material is made primarily of PC (poly-carbon fiber) material, the space glass material be namely commonly called as.It has light weight, and toughness is high, inexpensive advantage.But its high temperature resistance is not good, and easily aging.The feeding bottle of glass quality has good stability, the feature of easy cleaning, and high-temperature sterilization also can not reduce its quality repeatedly.But Glass breadks easily, can work the mischief to user especially infant.And due in fact good heat conductor, easily scald one's hand when loading the liquid of heat, experience is not good.
CN102512327A announces a kind of " safe silica gel glass feeding bottle and production technique thereof "; it is silicone spray supercoat on glass feeding bottle body; and at described glass feeding bottle body and silica gel protected painting interlayer, there is glass silicon knot adhesion coating; and the toluene level prepared in glass silicon knot adhesion coating is up to 80 ~ 90%, and production process is more complicated.
Based on the above problem of glass feeding bottle, solve in the urgent need to a kind of new method and mode.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art; there is provided a kind of structure simple; protective membrane is single component high-strength elastomerics; firmly bonding with glass feeding bottle; easy construction simple and stable; health, hand-held being not easy is skidded, even if still stick to the unseparated safe silicone glass composite nursing bottle in protective membrane surface after fragmentation.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
Manufacture a kind of organosilicon compound glass feeding bottle, there is the silicone elastomer of glass feeding bottle body and glass feeding bottle body outer surface, silicone elastomer has unitary structure with glass feeding bottle body, this organosilicone elastic shape is two composition curing type rubber, the ratio being counted 90:10--95:5 by component A and B component is by weight mixed with, wherein component A raw material comprises vinyl polysiloxane, the nano silicon of surface treatment and activation, containing the silicone resin of active group, containing hydrogen silicone oil linking agent, rate controlling substance, dimethylbenzene, B component raw material comprises platinum group catalyst, dimethylbenzene.
In the silicone elastomer of this glass feeding bottle, the raw material of component A is counted by weight: nano silicon 3-9, the silicone resin 1.5-4.5 containing active group of the polysiloxane 18-24 of vinyl, surface treatment and activation, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70.
In silicone elastomer, the raw material of the raw material of B component B component is by weight counted by weight: platinum group catalyst 0.03-0.3, dimethylbenzene 5-10.
Described organosilicon compound glass feeding bottle, its preparation method comprises the following steps:
(1) preparation of component A: by weight, will stir for subsequent use containing nano silicon 3-9, the silicone resin 1.5-4.5 containing active group of the polysiloxane 18-24 of vinyl, surface treatment and activation, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70;
(2) preparation of B component: by weight, is placed in clean container by platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 and is uniformly mixed for subsequent use;
(3) component A and B group are counted by weight the ratio mixing of 90:10--95:5, and vacuum get rid of bubble, then by prepare mixed solution spraying or dip-coating in clean glass feeding bottle surface, baking-curing, wherein storing temperature is 140-180 DEG C, and baking time is 10-30min.
The present invention increases the ratio of tackifier in this organosilicon materials proportioning, thus improves the cementability to base material.Make it have adhesive power strong, solidification is convenient, to base material non-corrosiveness, and the feature that chemical property is more stable.
Further, described organosilicone elastic body thickness is 0.03-0.5mm.
Accompanying drawing explanation
One embodiment of the present of invention shown in the drawings, Fig. 1 represents the overall cut-away view of organosilicon compound glass feeding bottle of the present invention, wherein: (1) is organosilicon compound glass feeding bottle, (2) be glass feeding bottle body, (3) are the silicone elastomer at bottle body outside surface.
Embodiment
Below, the preferred embodiment of the present invention is described.In addition, the necessary item of enforcement of the present invention beyond the item mentioned especially in this specification sheets, can understand as the design item of the those skilled in the art based on the prior art in this area.The present invention can implement based on the technology general knowledge combination of content disclosed in this specification and this area.
With reference to the accompanying drawings shown in 1, the organosilicon compound glass feeding bottle (1) described in the present embodiment, includes glass feeding bottle body (2) and the silicone elastomer (3) at bottle body outside surface
The ratio that silicone elastomer described in the present embodiment counts 90:10--95:5 by weight by component A and B component is mixed with, and wherein the raw material of component A with parts by weight is: nano silicon 3-9, the silicone resin 1.5-4.5 containing active group of the polysiloxane 18-24 of vinyl, surface treatment and activation, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70; The raw material of B component with parts by weight is: platinum group catalyst 0.03-0.3, dimethylbenzene 5-10.
Organosilicone elastic body thickness described in the present embodiment is 0.03-0.5mm.
The preparation method of the organosilicon compound glass feeding bottle described in the present embodiment is as follows:
(1) preparation of component A: by weight, will stir for subsequent use containing nano silicon 3-9, the silicone resin 1.5-4.5 containing active group of the polysiloxane 18-24 of vinyl, surface treatment and activation, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70;
(2) preparation of B component: by weight, is placed in clean container by platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 and is uniformly mixed for subsequent use;
(3) component A and B group are counted by weight the ratio mixing of 90:10--95:5, and vacuum get rid of bubble, then by prepare mixed solution spraying or dip-coating in clean glass feeding bottle surface, baking-curing, wherein storing temperature is 140-180 DEG C, and baking time is 10-30min.
Above, understand specific embodiments of the invention in detail, but these examples are only illustrate, be not limit claims, the technology recorded in claims comprises carries out the technology after various distortion, change to above illustrative particular instantiation.
Be below the common non-processor glass feeding bottle in the present invention and market, liquid silica gel coated glass feeding bottle, use caking agent and liquid silica gel coated glass feeding bottle and the contrast of organosilicon compound glass feeding bottle in performance and manufacturing process, comparing result is as follows:
* test specification: height empty bottle drops result in distance 1.4 meters, cement flooring.(if filled with fluid is tested, and internal liquid blocks glass cullet in matcoveredn glass feeding bottle and, with the separation of protective layer, do not embody the bonding strength of glass with protective layer)
As can be seen from above comparative result, property indices of the present invention is all better than original technical products.
Claims (6)
1. a silicone elastomer, it is characterized in that, this organosilicone elastic shape is two composition curing type rubber, and the ratio being counted 90:10--95:5 by component A and B component is by weight mixed with, and wherein A, B component are by being prepared from by the raw material of following parts by weight respectively:
Component A: vinyl polysiloxane 18-24, the nano silicon 3-9 of surface treatment and activation, containing the silicone resin 1.5-4.5 of active group, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70;
B component: platinum group catalyst 0.03-0.3, dimethylbenzene 5-10.
2. silicone elastomer according to claim 1, is characterized in that, the described silicone resin containing active group comprises dialkyl polydimethylsiloxane.
3. silicone elastomer according to claim 1, is characterized in that, described rate controlling substance comprises 3-methyl isophthalic acid-butine-3-alcohol, 1-ethynylcyclohexanol.
4. silicone elastomer according to claim 1, is characterized in that, described platinum group catalyst comprises platinum-1,3-divinyl tetramethyl disiloxane, platinum-1,3-dimethyl-1,3-phenylbenzene-1,3-divinyl disiloxane.
5. silicone elastomer according to claim 1, its preparation method comprises the following steps:
(1) preparation of component A: by weight, by the polysiloxane 18-24 containing vinyl, the nano silicon 3-9 of surface treatment and activation, containing the silicone resin 1.5-4.5 of active group, containing hydrogen silicone oil linking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70 stirs for subsequent use;
(2) preparation of B component: by weight, by platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 is placed in clean container and is uniformly mixed for subsequent use;
(3) component A and B group are counted by weight the ratio mixing of 90:10--95:5, and vacuum gets rid of bubble, under the condition of 140-180 DEG C, baking-curing 10-30min, can obtain silicone elastomer.
6. prepare organosilicon compound glass feeding bottle (1) with the silicone elastomer described in the arbitrary claim of claim 1-5, it is characterized in that, by prepare A, B component mixed solution spraying or dip-coating in the surface of clean glass feeding bottle body (2), baking-curing, wherein storing temperature is 140-180 DEG C, baking time is 10-30min, can obtain the organosilicon compound glass feeding bottle (1) comprising glass feeding bottle body (2) and silicone elastomer (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510107819.2A CN104610755B (en) | 2014-03-13 | 2015-03-11 | A kind of elastomer silicone |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2014201128667 | 2014-03-13 | ||
| CN201420112866 | 2014-03-13 | ||
| CN201510107819.2A CN104610755B (en) | 2014-03-13 | 2015-03-11 | A kind of elastomer silicone |
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| Publication Number | Publication Date |
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| CN104610755A true CN104610755A (en) | 2015-05-13 |
| CN104610755B CN104610755B (en) | 2017-03-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510107819.2A Active CN104610755B (en) | 2014-03-13 | 2015-03-11 | A kind of elastomer silicone |
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| Country | Link |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238064A (en) * | 2015-09-29 | 2016-01-13 | 广东标美硅氟新材料有限公司 | Organosilicon material, preparation method thereof, and application method thereof in 3D printing |
| CN109437587A (en) * | 2018-12-29 | 2019-03-08 | 贵州威顿晶磷电子材料股份有限公司 | It is a kind of for holding the film plating process of electronic chemical product quartz source bottle |
| CN109504282A (en) * | 2018-12-05 | 2019-03-22 | 湖南松井新材料股份有限公司 | A kind of anti-pollution type hand-feeling coating and its preparation method and application |
| CN109502986A (en) * | 2019-01-30 | 2019-03-22 | 东莞市希贝实业有限公司 | A kind of surface sheath preparation method, system and the container of glass container |
| WO2019095468A1 (en) * | 2017-11-16 | 2019-05-23 | 刘展标 | Glass/ceramic container and method for manufacturing same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102512327A (en) * | 2011-12-15 | 2012-06-27 | 佘庆琛 | Safe silica gel glass feeding bottle and production process thereof |
| CN203075234U (en) * | 2013-01-21 | 2013-07-24 | 王丽霞 | Safe liquid silicone rubber glass bottle |
| CN103214856A (en) * | 2013-04-13 | 2013-07-24 | 甘春丽 | Dipping-molded silicon rubber product and preparation method thereof |
-
2015
- 2015-03-11 CN CN201510107819.2A patent/CN104610755B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102512327A (en) * | 2011-12-15 | 2012-06-27 | 佘庆琛 | Safe silica gel glass feeding bottle and production process thereof |
| CN203075234U (en) * | 2013-01-21 | 2013-07-24 | 王丽霞 | Safe liquid silicone rubber glass bottle |
| CN103214856A (en) * | 2013-04-13 | 2013-07-24 | 甘春丽 | Dipping-molded silicon rubber product and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238064A (en) * | 2015-09-29 | 2016-01-13 | 广东标美硅氟新材料有限公司 | Organosilicon material, preparation method thereof, and application method thereof in 3D printing |
| CN105238064B (en) * | 2015-09-29 | 2019-04-09 | 广东标美硅氟新材料有限公司 | A kind of organosilicon material and preparation method thereof and its method for being applied to 3D printing |
| WO2019095468A1 (en) * | 2017-11-16 | 2019-05-23 | 刘展标 | Glass/ceramic container and method for manufacturing same |
| CN109504282A (en) * | 2018-12-05 | 2019-03-22 | 湖南松井新材料股份有限公司 | A kind of anti-pollution type hand-feeling coating and its preparation method and application |
| CN109437587A (en) * | 2018-12-29 | 2019-03-08 | 贵州威顿晶磷电子材料股份有限公司 | It is a kind of for holding the film plating process of electronic chemical product quartz source bottle |
| CN109502986A (en) * | 2019-01-30 | 2019-03-22 | 东莞市希贝实业有限公司 | A kind of surface sheath preparation method, system and the container of glass container |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104610755B (en) | 2017-03-29 |
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Effective date of registration: 20180612 Address after: 518000 Shiling street, Longgang District, Shenzhen, Guangdong. No. 103, No. 1 floor, Longdong Industrial Park, Longgang. Patentee after: Shenzhen Chu Eagle New Material Co., Ltd. Address before: 518000 Longgang street, Longgang District, Shenzhen, Guangdong, No. 23, Longdong Tong Chang Road, Longgang Co-patentee before: Feng Deping Patentee before: Sheng Chunguang |
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