CN104610755B - A kind of elastomer silicone - Google Patents

A kind of elastomer silicone Download PDF

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Publication number
CN104610755B
CN104610755B CN201510107819.2A CN201510107819A CN104610755B CN 104610755 B CN104610755 B CN 104610755B CN 201510107819 A CN201510107819 A CN 201510107819A CN 104610755 B CN104610755 B CN 104610755B
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component
feeding bottle
elastomer silicone
glass feeding
weight
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CN104610755A (en
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盛春光
冯德平
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Shenzhen Chu Eagle New Material Co., Ltd.
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盛春光
冯德平
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Abstract

The present invention relates to a kind of elastomer silicone, and the compound glass feeding bottle prepared with the elastomer silicone, elastomer silicone protective layer cementability is good, with glass feeding bottle body being integrally formed property structure.Simple production process reliability of the present invention, the eager to do well in everything degree of the elastomer silicone protective layer transparency is high and does not separate with vitreous surface, and fragment can be made in glass breaking to be retained in inside protective layer not spluttering, and security is good.

Description

A kind of elastomer silicone
Technical field
The present invention relates to the technical field of elastomer silicone, and in particular to be that one kind can be used to prepare compound glass milk The elastomer silicone of bottle.
Background technology
At present, the feeding bottle material sold on market is mainly two kinds of plastic and glass.Wherein, the feeding bottle of plastic material is main It is made up of PC (poly- carbon fiber) material, that is, the space glass material being commonly called as.Which has light weight, high, the inexpensive advantage of toughness.But Its high temperature resistance is not good, and easily aging.The characteristics of feeding bottle of glass quality has good stability, easy cleaning, and high temperature repeatedly Sterilization will not also reduce its quality.But Glass breadks easily, can especially infant works the mischief to user.And due in fact good Good heat carrier, easily scalds one's hand when the liquid of heat is loaded, and experience is not good.
CN102512327A announces a kind of " safe silica gel glass feeding bottle and its production technology ", and which is on glass feeding bottle body Silicone spray protective coating, and there is glass silicon knot adhesion coating in the glass feeding bottle body and silica gel protected painting interlayer, and make Toluene level up to 80~90% in standby glass silicon knot adhesion coating, and production process is more complicated.
Based on the problem above of glass feeding bottle, solve in the urgent need to a kind of new method and mode.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of simple structure, diaphragm is single component High strength elastic body, with glass feeding bottle bonding firmly, easy construction simple and stable, health are hand-held to be not easy to skid, even if broken Diaphragm surface unseparated safe silicone glass composite nursing bottle is sticked to afterwards still.
To solve above-mentioned technical problem, the technical solution used in the present invention is:
A kind of organosilicon compound glass feeding bottle is manufactured, it is organic with glass feeding bottle body and glass feeding bottle body outer surface Silicone elastomer, elastomer silicone have unitary structure with glass feeding bottle body, and the organosilicone elastic shape solidifies for double-component Type rubber, is calculated as 90 by weight by component A and B component:10--95:5 ratio is mixed with, and wherein component A raw material includes Vinyl polysiloxane, the nano silicon of surface treatment and activation, the silicones containing active group, containing hydrogen silicone oil crosslinking Agent, rate controlling substance, dimethylbenzene, B component raw material include platinum group catalyst, dimethylbenzene.
In the elastomer silicone of the glass feeding bottle, the raw material of component A is calculated as by weight:The polysiloxanes 18- of vinyl 24th, surface treatment and the nano silicon 3-9 for activating, the silicones 1.5-4.5 containing active group, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70.
In elastomer silicone, the raw material of the raw material of B component B component by weight is calculated as by weight:Platinum group catalyst 0.03-0.3, dimethylbenzene 5-10.
Described organosilicon compound glass feeding bottle, its preparation method are comprised the following steps:
(1) preparation of component A:By weight, by the polysiloxanes 18-24 containing vinyl, surface treatment and activation Nano silicon 3-9, the silicones 1.5-4.5 containing active group, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70 stir standby;
(2) preparation of B component:By weight, platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 are placed in into clean container In be uniformly mixed it is standby;
(3) component A and B groups are calculated as into 90 by weight:10--95:5 ratio mixing, and vacuum excludes bubble, then The mixed liquor for preparing is sprayed or dip-coating is in clean glass feeding bottle surface, baking-curing, wherein baking temperature are 140-180 DEG C, baking time is 10-30min.
The present invention increases the ratio of tackifier in the organosilicon materials proportioning, so as to improve the bonding to base material Property.Make it have adhesion strong, solidification is convenient, to base material non-corrosiveness, the characteristics of chemical property is more stable.
Further, described organosilicone elastic body thickness is 0.03-0.5mm.
Description of the drawings
One embodiment of the present of invention is shown in the drawings, Fig. 1 represents the entirety of organosilicon compound glass feeding bottle of the present invention Cut-away view, wherein:(1) it is organosilicon compound glass feeding bottle, (2) are glass feeding bottle body, (3) are in bottle body outer surface Elastomer silicone.
Specific embodiment
Hereinafter, the preferred embodiment of the present invention is illustrated.In addition, beyond item specifically mentioned in this specification The present invention enforcement necessary to item, can setting as the those skilled in the art based on the prior art in this area Count item to understand.The present invention can be combined based on the technology general knowledge of content disclosed in this specification and this area and come real Apply.
With reference to the accompanying drawings shown in 1, organosilicon compound glass feeding bottle (1) described in the present embodiment includes glass feeding bottle body (2) and in the elastomer silicone (3) of bottle body outer surface
Elastomer silicone described in the present embodiment is calculated as 90 by weight by component A and B component:10--95:5 ratio It is mixed with, the raw material of wherein component A is in parts by weight:The polysiloxanes 18-24 of vinyl, surface treatment and receiving of activating Rice silica 3-9, the silicones 1.5-4.5 containing active group, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03- 0.15th, dimethylbenzene 55-70;The raw material of B component is in parts by weight:Platinum group catalyst 0.03-0.3, dimethylbenzene 5-10.
Organosilicone elastic body thickness described in the present embodiment is 0.03-0.5mm.
The preparation method of the organosilicon compound glass feeding bottle described in the present embodiment is as follows:
(1) preparation of component A:By weight, by the polysiloxanes 18-24 containing vinyl, surface treatment and activation Nano silicon 3-9, the silicones 1.5-4.5 containing active group, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70 stir standby;
(2) preparation of B component:By weight, platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 are placed in into clean container In be uniformly mixed it is standby;
(3) component A and B groups are calculated as into 90 by weight:10--95:5 ratio mixing, and vacuum excludes bubble, then The mixed liquor for preparing is sprayed or dip-coating is in clean glass feeding bottle surface, baking-curing, wherein baking temperature are 140-180 DEG C, baking time is 10-30min.
More than, the specific embodiment of the present invention is described in detail by, but, these examples are only illustrated, and are not right Claims are defined, and the technology described in claims includes that the particular instantiation illustrated to more than carries out various changes Technology after shape, change.
The following is the present invention with market it is common without process glass feeding bottle, liquid silica gel coating glass feeding bottle, use bonding agent With the contrast of liquid silica gel coating glass feeding bottle and organosilicon compound glass feeding bottle in performance and manufacturing process, comparing result It is as follows:
* test specification:Result is being dropped apart from 1.4 meters of cement flooring height empty bottle.(if liquid testing is filled, it is internal Liquid blocks separation of the cullet with protective layer in matcoveredn glass feeding bottle, and the bonding for not embodying glass with protective layer is strong Degree)
The property indices that the present invention be can be seen that from above comparative result are superior to original technology product.

Claims (3)

1. a kind of elastomer silicone, it is characterised in that the organosilicone elastic shape is double-component curing type rubber, by component A and B Component is calculated as 90 by weight:10--95:5 ratio is mixed with, and wherein A, B component are by respectively by the original of following weight portion meter Material is prepared from:
Component A:Vinyl polysiloxane 18-24, surface treatment and the nano silicon 3-9 for activating, the silicon containing active group Resin 1.5-4.5, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03-0.15, dimethylbenzene 55-70;
B component:Platinum group catalyst 0.03-0.3, dimethylbenzene 5-10;The silicones containing active group includes dihydroxy poly- two Methylsiloxane;The rate controlling substance includes 3- methyl isophthalic acids-butine -3- alcohol, 1- ethynylcyclohexanols;The platinum group catalyst Including platinum -1,3- divinyl tetramethyl disiloxanes, platinum -1,3- dimethyl -1,3- diphenyl -1, two silica of 3- divinyl Alkane.
2. elastomer silicone according to claim 1, its preparation method are comprised the following steps:
(1) preparation of component A:By weight, by the nanometer of the polysiloxanes 18-24 containing vinyl, surface treatment and activation Silica 3-9, the silicones 1.5-4.5 containing active group, containing hydrogen silicone oil crosslinking agent 1.5-4.5, rate controlling substance 0.03- 0.15, dimethylbenzene 55-70 stirs standby;
(2) preparation of B component:By weight, by platinum group catalyst 0.03-0.3, dimethylbenzene 5-10 is placed in clean container and stirs Mix be well mixed it is standby;
(3) component A and B groups are calculated as into 90 by weight:10--95:5 ratio mixing, and vacuum excludes bubble, in 140-180 Under conditions of DEG C, baking-curing 10-30min, you can obtain elastomer silicone.
3. with the elastomer silicone described in claim 1-2 any claim preparing organosilicon compound glass feeding bottle (1), Characterized in that, by the A for preparing, the spraying of B component mixed liquor or dip-coating in the surface of clean glass feeding bottle body (2), baking Solidification, wherein baking temperature are 140-180 DEG C, and baking time is 10-30min, you can obtain including glass feeding bottle body (2) and Organosilicon compound glass feeding bottle (1) of elastomer silicone (3).
CN201510107819.2A 2014-03-13 2015-03-11 A kind of elastomer silicone Active CN104610755B (en)

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CN2014201128667 2014-03-13
CN201420112866 2014-03-13
CN201510107819.2A CN104610755B (en) 2014-03-13 2015-03-11 A kind of elastomer silicone

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238064B (en) * 2015-09-29 2019-04-09 广东标美硅氟新材料有限公司 A kind of organosilicon material and preparation method thereof and its method for being applied to 3D printing
WO2019095468A1 (en) * 2017-11-16 2019-05-23 刘展标 Glass/ceramic container and method for manufacturing same
CN109504282A (en) * 2018-12-05 2019-03-22 湖南松井新材料股份有限公司 A kind of anti-pollution type hand-feeling coating and its preparation method and application
CN109437587A (en) * 2018-12-29 2019-03-08 贵州威顿晶磷电子材料股份有限公司 It is a kind of for holding the film plating process of electronic chemical product quartz source bottle
CN109502986A (en) * 2019-01-30 2019-03-22 东莞市希贝实业有限公司 A kind of surface sheath preparation method, system and the container of glass container

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102512327A (en) * 2011-12-15 2012-06-27 佘庆琛 Safe silica gel glass feeding bottle and production process thereof
CN203075234U (en) * 2013-01-21 2013-07-24 王丽霞 Safe liquid silicone rubber glass bottle
CN103214856B (en) * 2013-04-13 2016-01-20 甘春丽 Molded silastic product of a kind of leaching and preparation method thereof

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Effective date of registration: 20180612

Address after: 518000 Shiling street, Longgang District, Shenzhen, Guangdong. No. 103, No. 1 floor, Longdong Industrial Park, Longgang.

Patentee after: Shenzhen Chu Eagle New Material Co., Ltd.

Address before: 518000 Longgang street, Longgang District, Shenzhen, Guangdong, No. 23, Longdong Tong Chang Road, Longgang

Co-patentee before: Feng Deping

Patentee before: Sheng Chunguang

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