CN104607650B - 作为新型试剂的零价金属与氢化物的稳定复合物 - Google Patents
作为新型试剂的零价金属与氢化物的稳定复合物 Download PDFInfo
- Publication number
- CN104607650B CN104607650B CN201410756518.8A CN201410756518A CN104607650B CN 104607650 B CN104607650 B CN 104607650B CN 201410756518 A CN201410756518 A CN 201410756518A CN 104607650 B CN104607650 B CN 104607650B
- Authority
- CN
- China
- Prior art keywords
- zero
- hydride
- metal
- complex
- valent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 111
- 239000002184 metal Substances 0.000 title claims abstract description 111
- 150000004678 hydrides Chemical class 0.000 title claims abstract description 73
- 150000001875 compounds Chemical class 0.000 title abstract description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 65
- 239000000203 mixture Substances 0.000 claims abstract description 63
- 238000000498 ball milling Methods 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract 6
- 238000000034 method Methods 0.000 claims description 44
- 238000009472 formulation Methods 0.000 claims description 43
- 239000011572 manganese Substances 0.000 claims description 32
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 27
- -1 metalloid hydrides Chemical class 0.000 claims description 24
- 229910052752 metalloid Inorganic materials 0.000 claims description 21
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 19
- 229910052748 manganese Inorganic materials 0.000 claims description 19
- 229910052718 tin Inorganic materials 0.000 claims description 19
- 239000012448 Lithium borohydride Substances 0.000 claims description 18
- 238000000026 X-ray photoelectron spectrum Methods 0.000 claims description 15
- 229910052987 metal hydride Inorganic materials 0.000 claims description 15
- 150000004681 metal hydrides Chemical class 0.000 claims description 15
- 229910001848 post-transition metal Inorganic materials 0.000 claims description 14
- 229910052723 transition metal Inorganic materials 0.000 claims description 14
- 150000003624 transition metals Chemical class 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 230000002194 synthesizing effect Effects 0.000 claims description 8
- 229910000619 316 stainless steel Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000003595 spectral effect Effects 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 16
- 150000002739 metals Chemical class 0.000 abstract description 14
- 238000003786 synthesis reaction Methods 0.000 abstract description 14
- 239000002082 metal nanoparticle Substances 0.000 abstract description 8
- 125000004429 atom Chemical group 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 10
- 229910052796 boron Inorganic materials 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000013459 approach Methods 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052706 scandium Inorganic materials 0.000 description 3
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052716 thallium Inorganic materials 0.000 description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910010082 LiAlH Inorganic materials 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009760 electrical discharge machining Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229910052699 polonium Inorganic materials 0.000 description 1
- HZEBHPIOVYHPMT-UHFFFAOYSA-N polonium atom Chemical compound [Po] HZEBHPIOVYHPMT-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000010942 self-nucleation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/02—Hydrides of transition elements; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
- C01B6/15—Metal borohydrides; Addition complexes thereof
- C01B6/19—Preparation from other compounds of boron
- C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Powder Metallurgy (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/046,081 | 2013-10-04 | ||
| US14/046,081 US8980219B1 (en) | 2013-10-04 | 2013-10-04 | Stable complexes of zero-valent metal and hydride as novel reagents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104607650A CN104607650A (zh) | 2015-05-13 |
| CN104607650B true CN104607650B (zh) | 2018-06-26 |
Family
ID=52632202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410756518.8A Active CN104607650B (zh) | 2013-10-04 | 2014-09-30 | 作为新型试剂的零价金属与氢化物的稳定复合物 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US8980219B1 (enExample) |
| JP (1) | JP6576027B2 (enExample) |
| CN (1) | CN104607650B (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9643254B2 (en) | 2013-10-04 | 2017-05-09 | Toyota Motor Engineering & Manufacturing North America, Inc. | Anionic reagent element complexes, their variations, and their uses |
| US9650248B2 (en) | 2013-10-04 | 2017-05-16 | Toyota Motor Engineering & Manufacturing North America, Inc. | Multi-element anionic reagent complexes |
| US9738536B2 (en) * | 2013-10-04 | 2017-08-22 | Toyota Motor Engineering & Manufacturing North America, Inc. | Allotrope-specific anionic element reagent complexes |
| US9796023B2 (en) | 2015-01-09 | 2017-10-24 | Toyota Motor Engineering & Manufacturing North America, Inc. | Synthesis of ferromagnetic manganese-bismuth nanoparticles using a manganese-based ligated anionic-element reagent complex (Mn-LAERC) and formation of bulk MnBi magnets therefrom |
| US9546192B2 (en) * | 2015-01-09 | 2017-01-17 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ligated anionic-element reagent complexes (LAERCs) as novel reagents |
| US10023595B2 (en) | 2015-01-09 | 2018-07-17 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ligated anionic-element reagent complexes as novel reagents formed with metal, metalloid, and non-metal elements |
| US10814397B2 (en) | 2016-03-21 | 2020-10-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Textured-crystal nanoparticles from ligated anionic element reagent complex |
| US11911995B2 (en) | 2016-09-22 | 2024-02-27 | Toyota Motor Engineering & Manufacturing North America, Inc. | Light weight composite of steel and aramid with fully penetrated reinforcement |
| US10774196B2 (en) | 2016-09-22 | 2020-09-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Light weight composite of steel and polymer |
| US9847157B1 (en) | 2016-09-23 | 2017-12-19 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ferromagnetic β-MnBi alloy |
| JP7245190B2 (ja) | 2019-03-21 | 2023-03-23 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ，インコーポレイティド | 非強化領域を有する織物カーボン繊維強化鋼マトリックス複合材料 |
| US11788175B2 (en) | 2019-03-21 | 2023-10-17 | Toyota Motor Engineering & Manufacturing North America, Inc. | Chemically bonded amorphous interface between phases in carbon fiber and steel composite |
| GB202019903D0 (en) * | 2020-12-16 | 2021-01-27 | Tokamak Energy Ltd | On the design of a composite hybride-metal to accommodate hydride decomposition |
| CN117069062A (zh) * | 2023-07-10 | 2023-11-17 | 中山大学 | 一种纳米钯氢化物及一类钯氢基合金态纳米材料的制备及其应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050217427A1 (en) | 2000-12-21 | 2005-10-06 | Suthersan Suthan S | Method of making and using nanoscale metal |
| US7041350B1 (en) * | 2002-08-30 | 2006-05-09 | The Coca-Cola Company | Polyester composition and articles with reduced acetaldehyde content and method using hydrogenation catalyst |
| AU2003902704A0 (en) * | 2003-05-29 | 2003-06-19 | Crc For Waste Management And Pollution Control Limited Of Unsw | Process for producing a nanoscale zero-valent metal |
| JP2006152376A (ja) * | 2004-11-29 | 2006-06-15 | Toyota Central Res & Dev Lab Inc | ナノ遷移金属粒子、その製造方法、およびナノ遷移金属粒子を複合化した水素吸蔵複合材料 |
| US20090264277A1 (en) | 2007-04-17 | 2009-10-22 | Dr. Rishi Raj | Picoscale catalysts for hydrogen catalysis |
| JP2011122202A (ja) | 2009-12-10 | 2011-06-23 | Central Glass Co Ltd | 水素発生用合金とその製造方法 |
| JP5206758B2 (ja) * | 2010-07-15 | 2013-06-12 | トヨタ自動車株式会社 | 負極材料、金属二次電池、および負極材料の製造方法 |
| EP2842667B1 (en) * | 2012-04-23 | 2017-11-22 | LG Chem, Ltd. | Method for producing core-shell particles |
-
2013
- 2013-10-04 US US14/046,081 patent/US8980219B1/en active Active
-
2014
- 2014-09-30 CN CN201410756518.8A patent/CN104607650B/zh active Active
- 2014-10-02 JP JP2014203808A patent/JP6576027B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US8980219B1 (en) | 2015-03-17 |
| JP6576027B2 (ja) | 2019-09-18 |
| JP2015074829A (ja) | 2015-04-20 |
| US20150098892A1 (en) | 2015-04-09 |
| CN104607650A (zh) | 2015-05-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104607650B (zh) | 作为新型试剂的零价金属与氢化物的稳定复合物 | |
| US9346676B2 (en) | Stable complexes of zero-valent metallic element and hydride as novel reagents | |
| US9216910B2 (en) | Stable complexes of multiple zero-valent metals and hydride as novel reagents | |
| US9260305B2 (en) | Stable complexes of zero-valent metallic element and hydride as novel reagents | |
| Liang et al. | Atomic arrangement engineering of metallic nanocrystals for energy-conversion electrocatalysis | |
| Jamil et al. | The role of nitrogen in transition-metal nitrides in electrochemical water splitting | |
| Lee et al. | High‐entropy nanomaterials for advanced electrocatalysis | |
| US9260312B2 (en) | Stable complexes of non-metal elements and hydride as novel reagents | |
| Jiang et al. | Multimetallic mesoporous spheres through surfactant‐directed synthesis | |
| US9281518B2 (en) | Metal nanoparticles synthesized via a novel reagent and application to electrochemical devices | |
| Zhang et al. | Remarkably improved hydrogen storage performance of MgH2 catalyzed by multivalence NbH x nanoparticles | |
| Tallapally et al. | Multivariate synthesis of tin phosphide nanoparticles: temperature, time, and ligand control of size, shape, and crystal structure | |
| Singh et al. | A critical review on amorphous–crystalline heterostructured electrocatalysts for efficient water splitting | |
| US9296043B2 (en) | Synthesis of metal nanoparticles | |
| JPWO2011027864A1 (ja) | 光還元触媒並びにそれを用いたアンモニアの合成方法および水中の窒素酸化物低減方法 | |
| Amakali et al. | Photocatalytic degradation of rhodamine B dye and hydrogen evolution by hydrothermally synthesized NaBH4—spiked ZnS nanostructures | |
| Ahmad et al. | Evolution of metal tellurides for energy storage/conversion: from synthesis to applications | |
| Jaśkaniec et al. | Solvent engineered synthesis of layered SnO for high-performance anodes | |
| Du et al. | Alloyed palladium-nickel hollow nanospheres with interatomic charge polarization for improved hydrolytic dehydrogenation of ammonia borane | |
| Mikhaylov et al. | Green synthesis of a nanocrystalline tin disulfide-reduced graphene oxide anode from ammonium peroxostannate: a highly stable sodium-ion battery anode | |
| Chang et al. | Synthesis of Cu/ZnO core/shell nanocomposites and their use as efficient photocatalysts | |
| Sun et al. | Synthesis of Ni–B compounds by high-pressure and high-temperature method | |
| Marimuthu et al. | Transition metal sulfide nanostructures: synthesis and application in metal-air batteries | |
| CN104934631B (zh) | 经由新型试剂合成的金属纳米颗粒及在电化学装置中的应用 | |
| US9278392B2 (en) | Synthesis of metal alloy nanoparticles via a new reagent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181019 Address after: Aichi Prefecture, Japan Patentee after: Toyota Motor Corp. Address before: American Kentucky Patentee before: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, Inc. |
|
| TR01 | Transfer of patent right |