CN104593667B - Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels and production method - Google Patents

Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels and production method Download PDF

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CN104593667B
CN104593667B CN201410481630.5A CN201410481630A CN104593667B CN 104593667 B CN104593667 B CN 104593667B CN 201410481630 A CN201410481630 A CN 201410481630A CN 104593667 B CN104593667 B CN 104593667B
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steel
alloying
1200mpa
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quenched
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CN104593667A (en
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张帆
吴杰
徐志
周新龙
罗国华
刘婳
王媛
龙莉
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Wuhan Iron and Steel Co Ltd
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Wuhan Iron and Steel Group Corp
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium

Abstract

Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels, its component and wt% are:C:0.30~0.50 %, Si:0.40~0.60 %, Mn:1.2~1.5 %, P≤0.015 %, S≤0.015 %, N:0.03~0.05 %, B:0.01~0.02 %, Al:0.01~0.03 %, V:0.1~0.15 %;Technique:Smelt and be casting continuously to form base;Square billet is heated;It is rolled into bar steel;Water cooling;Entering hole after bundling carries out slow cooling to room temperature.The present invention using BN be mingled with can significantly improve cutting rolled steel performance and on mechanical property without influence the characteristics of and research and develop.Its compared with resulfurizing series free cutting steel, with more preferable mechanical property;Compared with lead series free cutting steel, with the more preferable feature of environmental protection;With rare metal series free-cutting steel ratio, with lower production cost, market application foreground is wide;Using vanadium micro-alloying, hot-rolled steel plate state property can reach:Tensile strength >=1200MPa, yield strength >=850MPa, elongation percentage A >=15%, contraction percentage of area Z >=20% have excellent cutting ability concurrently.

Description

Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels and production method
Technical field
The present invention relates to a kind of automatic steel and production method, vanadium micro-alloying BN systems Rel >=1200MPa is specifically belonged to Non-quenched and tempered free machining steel and production method.
Background technology
Non-hardened and tempered steel is that microalloy element is added in medium carbon steel(V, Ti, Nb etc.), by controlled rolling and controlled cooling, give full play to steel Middle carbon(Nitrogen)Compound refined crystalline strengthening and precipitation enhancement, structural alloy steel or carbon structural steels can be obtained without modifier treatment The steel grade of the mechanical property reached after modifier treatment.Due to saving quenching and temper, non-hardened and tempered steel has production efficiency The advantages of height, low energy resource consumption, low production cost, extensive use is obtained in fields such as automobile makings, for manufacturing bent axle, connecting The strength members such as bar, knuckle, front-axle beam.
With the development of economic society, the index such as vehicle safety, stability and energy consumption more and more attracts attention, and adopts High intensity non-hardened and tempered steel is used, vehicle safety and reliability can be effectively improved, reduce automotive dead weight, reducing energy consumption and pollution row Put, therefore along with automotive light weight technology, non-hardened and tempered steel is gradually towards high intensity(Tensile strength >=1000MPa)Direction is developed.
Relative to emerging increasing material manufacturing(3D printing), tradition machinery is manufactured to be needed by multiple machining, and data show Show that parts machining expense accounts for more than the 40% of its manufacturing cost, thus select eligible and free machining material energy Significantly improve production efficiency, reduce production cost.Modern manufacturing industry such as auto industry, more with Digit Control Machine Tool as machining center, machine The automation of bed, precise treatment and high efficiency are to the cutting ability requirement more and more higher of material, but some important spare parts are again simultaneously Mechanical property very high is needed, this requires steel while having intensity higher and good cutting ability the two contradictions concurrently Body, that is, need a kind of automatic steel of high intensity.
Automatic steel is by addition Cutting free element in steel(S, Pd, Bi etc.), using Cutting free element in itself or shape Into compound improve the steel grade of cutting ability, often improve cutting ability to sacrifice mother metal mechanical property as cost.
Lead treated steel is not because mechanical property, heat treatment performance, cold and hot working performance and welding performance be by the shadow of leading Ring, and cutting ability(Cutter life, chip treatability, machined surface finish etc.)Excellent the characteristics of, obtain extensive use.But by In lead to environment and harm greatly, therefore the developed country such as European Union and the U.S. to the production containing Pd automatic steels, using and Recovery is strictly limited, it is contemplated that being the developing direction of automatic steel without Pdization.The automatic steels such as sulphur system, bismuth system are often See without Pd automatic steels, but its production or application face various problems:Sulphur higher, oxygen content, meeting in resulfurizing series free cutting steel Reduce purity of steel, severe exacerbation steel mechanics performance;Se(Selenium)、Te(Hoof)、Bi(Bismuth)Help to improve Deng rare element The cutting ability of steel and will not significantly deteriorate steel mechanics performance, but cannot large-scale application because costly.
Through retrieval, Chinese Patent Application No. is the document of CN02809296.1, discloses a kind of mechanical structure sulfur-bearing easy Cutting Steel, its chemical constituent percentage by weight is, C:0.10-0.55%, Si:0.05-1.00%, Mn:0.30-2.50%, P:≤ 0.15%, S:0.050-0.350%, Al:> 0.010% to≤0.020%, Nb:0.015-0.200%, O: 0.0015-0.0150%, N:≤ 0.02%;Also contain % by weight:Selected from V:0.03-0.50%, Ti:0.02-0.20% And Zr:At least one in 0.01-0.20%.Also Chinese Patent Application No. is the document of CN02808349.0, discloses and contains Sulphur automatic steel, its chemical constituent percentage by weight is, C:0.03-0.20%, Si:0.35% or less (including 0%), Mn: 0.30-2.00%, P:0.01-0.15%, S:0.35-0.65%, O:0.0100-0.0250%, N:0.020% or more It is few, Al:0.005% or less (including 0%), Nb:0.02-0.20%, also includes:V:0.05-0.50% and/or Ti: 0.02 to 0.20%, and the remainder being made up of Fe and inevitable impurity.Above-mentioned two patent document is present not Foot:Two patent is resulfurizing series free cutting steel, and controlling of production process is complicated and mechanical property is difficult to ensure, and this two special Noble metal Nb contents are higher in profit(Reach as high as 0.2%), thus production cost is high, mechanical property is relatively low.
China Patent Publication No. is the document of CN101338393B, discloses a kind of automobile connecting bar high intensity non-tempering easy Cutting Steel, its chemical composition includes(Percentage by weight):0.30-0.40% C, 0.50-0.70% Si, 0.80-1.20% Mn, no P, 0.030-0.060% S, 0.010-0.040% Al, 0.10-0.40% Cr, 0.10-0.30% V more than 0.040%, 0.010-0.015% N, its balance of iron and are inevitably mingled with.Its deficiency for existing:It still falls within resulfurizing series free cutting steel, It is expected that by being mingled with to improve cutting rolled steel performance, but the document for guarantee mechanical property to addition S generations MnS in steel By the control of S contents in very low scope(0.030-0.060%)So that the steel grade cutting ability is poor, and mechanical property is relatively low, It is difficult to meet the processing request of modern machine.
The invention belongs to BN type automatic steels, its cutting ability is similar with Pd series free-cutting steels and is significantly better than sulphur system and easily cuts Steel is cut, and BN is mingled with harmless to steel mechanics performance so that steel grade of the present invention can be provided simultaneously with preferable cutting ability and mechanics Performance.
The present invention, be mingled with using BN can significantly improve cutting rolled steel performance and on mechanical property without influence the characteristics of, use Vanadium micro-alloying, develops the non-hardened and tempered steel that a kind of intensity is high and cutting ability is excellent, to meet automotive light weight technology and lathe certainly The demand of dynamicization, precise treatment and high-efficiency reform.
The content of the invention
The present invention is in view of the shortcomings of the prior art, there is provided a kind of tensile strength >=1200MPa, yield strength >=850MPa, Elongation percentage A >=15%, contraction percentage of area Z >=20% simultaneously have the non-hardened and tempered steel of excellent cutting ability concurrently, and cost is relatively low, can meet vapour Car lightweight and the vanadium micro-alloying BN systems Rel >=1200MPa Micro Alloyings of Machinery Tool Automation, precise treatment and high-efficiency reform demand Automatic steel and production method.
Realize the measure of above-mentioned purpose:
Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels, its component and weight percent content are:C: 0.30~0.50 %, Si:0.40~0.60 %, Mn:1.2~1.5 %, P≤0.015 %, S≤0.015 %, N:0.03~0.05 %、B:0.01~0.02 %, Al:0.01~0.03 %, V:0.1~0.15 %, remaining is Fe and inevitable impurity.
Preferably:Its component and weight percent content are further:C:0.41~048 %, Si:0.41~0.57 %、Mn:1.25~1.47%, P≤0.015 %, S≤0.015 %, N:0.037~0.048 %, B:0.015~0.02 %, Al: 0.018~0.028 %, V:0.12~0.15 %.
Vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels, its component and weight percent content are:C: 0.30~0.50%, Si:0.40~0.60%, Mn:1.2~1.5%, P≤0.015%, S≤0.015%, N:0.03~0.05%, B: 0.01~0.02%, Al:0.01~0.03%, V:0.04~0.08%, Ti:0.02~0.04%, remaining is for Fe and inevitably Impurity.
Preferably:The weight percent content of C is:0.35~0.45%.
Preferably:The weight percent content of B is:0.015~0.020%.
Preferably:The weight percent content of N is:0.040~0.050%.
Preferably:The weight percent content of V is 0.051~0.070%.
Preferably:The weight percent content of Ti is 0.020~0.030%.
The method of production vanadium micro-alloying BN system Rel >=1200MPa non-quenched and tempered free machining steels, its step:
1)Smelt and be casting continuously to form base;
2)Square billet is heated, it is 1150~1250 DEG C, 120~150min of soaking time to control heating-up temperature;
3)It is rolled into bar steel:Control roughing start rolling temperature is at 1100~1200 DEG C;Control finish rolling finishing temperature 750~ 850℃;
4)Water cooling is carried out, 300~500 DEG C are cooled in the case where cooling velocity is 20~120 DEG C/min;
5)Entering hole after bundling carries out slow cooling, is cooled to room temperature.
The effect of each element and master operation in the present invention
C:High strength non-quenched and tempered free machining steel need to keep certain intensity and hardness, and the hardness of matrix steel is depending on carbon containing Amount.Too high carbon content can make the increase of steel medium pearlite ratio, make steel partially hard, be unfavorable for machining;Too low carbon content meeting Causing ratio of ferrite in steel increases, and steel low-intensity reduction, toughness increases, and steel is partially soft, it is difficult to meet the requirement of high intensity and same Sample is unfavorable for machining.Therefore, carbon content of the present invention is designed as 0.30~0.50%;C is preferably 0.41~048% or 0.35 ~0.45%.
Si:The main intensity that steel is improved with solution strengthening form, but too high silicone content can deteriorate the cold deformation ability of steel, And its deoxidation products has a higher hardness, working angles Cutter wear is serious, thus silicone content of the present invention be designed as 0.40~ 0.60%, it is therefore preferable to 0.41~0.57 %.
Mn:In ferrite, the solution strengthening effect of Mn is only second to P and Si, can improve steel strength, and will not show When writing the deformability for deteriorating steel, but content less than 0.80%, its reinforcing DeGrain;Mn can also be pressed from both sides with S reaction generations MnS Miscellaneous raising cutting rolled steel performance, and can prevent from causing hot short low melting point FeS to be separated out in crystal boundary, at the same MnS be mingled with can be with It is mingled with forming core core as BN, reduces BN and be mingled with this free energy of jeep needed for precipitation, increases BN and be mingled with precipitation quantity, so as to improve The cutting ability of steel.Therefore, manganese content of the present invention is designed as 1.2~1.5%, it is therefore preferable to 1.25~1.47%.
P:P can reinforced ferrite phase, but P is harmful element for steel performance, require in theory its content it is more low more It is good, just can guarantee that the performance of steel of the present invention.
S:Sulphur is mingled with the MnS that manganese can be formed and can be mingled with forming core core as BN in steel, improves BN and is mingled with nucleation rate, increases BN is mingled with quantity in steel, but excessive MnS is mingled with the anisotropy that can increase steel performance, the application of serious limitation steel.
N:N and B reactions generation is conducive to the BN for improving cutting ability to be favorably mingled with steel, and by V(C、N)Generation reality Existing vanadium micro-alloying improves the purpose of steel strength, therefore appropriate N content is needed in steel, if but N content is excessive, steel can be deteriorated Material mechanical property simultaneously reduces the rate of steel products produced to steel ingots.Therefore, nitrogen content of the present invention is designed as 0.03~0.05%, it is therefore preferable to 00.037 ~0.048 % or 0.040~0.050%.
B:The addition of B is mingled with to form BN, to improve cutting rolled steel performance.B content is too low in steel, it is difficult to which generation is enough The BN of amount is mingled with, too high, easily deteriorates steel toughness and is unfavorable for steel popularization and application.Therefore B content of the present invention is designed as 0.01~0.02 %, it is therefore preferable to 0.015~0.02 %.
Al:Aluminium is added in steel as deoxidier, and a certain amount of aluminium may advantageously facilitate the precipitation that BN is mingled with, but excess Al meetings Influence steel mechanics performance, reduces cutting rolled steel performance.Therefore, aluminium content of the present invention is designed as 0.01~0.03%, it is therefore preferable to 0.018~0.028 %.
V:Added as the micro alloying element for improving steel strength, vanadium solid solubility temperature in austenite is relatively low, but diffusion Speed is fast, and in heating and soaking stage, sediment is dissolved, and dissolved state is kept during hot-working, and when then cooling down Intergranular precipitation is separated out increases the intensity of steel, but excessive vanadium can increase smelting cost and the further reinforcing effect to steel is failed to understand It is aobvious.Therefore, content of vanadium of the present invention is designed as 0.1~0.15%, it is therefore preferable to 0.12~0.15%;0.04 is designed as when content of vanadium~ 0.08%, it is therefore preferable to 0.051~0.070%.
Ti:Added as the micro alloying element for improving steel strength, the carbonitride intergranular precipitation of titanium is separated out and can refined Crystal grain, making the intensity of steel increases, but excessive titanium can increase smelting difficulty.Therefore, Ti content of the present invention be designed as 0.02~ 0.04%, it is therefore preferable to 0.02~0.03%.
The present invention compared with prior art, its be mingled with using BN can significantly improve cutting rolled steel performance and to mechanical property without The characteristics of influence, develop a kind of BN type automatic steels of intensity Micro Alloying high.Its compared with resulfurizing series free cutting steel, with more preferable Mechanical property;Compared with lead series free cutting steel, with the more preferable feature of environmental protection;With rare metal series free-cutting steel ratio, with more Low production cost, market application foreground is wide;Using vanadium micro-alloying, rolled performance reaches:Tensile strength >= 1200MPa, yield strength >=850MPa, elongation percentage A >=15%, contraction percentage of area Z >=20% have excellent cutting ability concurrently.
Brief description of the drawings
The distribution map of BN in Fig. 1 steel of the present invention(200X);
Fig. 2 is steel chip-breaking performance situation map of the present invention;
Fig. 3 is the chip-breaking performance situation map of the steel grade of comparative example 1.
Specific embodiment
The present invention is described in detail below:
Table 1 is the comparative example of various embodiments of the present invention and comparative example;
Table 2 is the main technologic parameters list of various embodiments of the present invention and comparative example;
Table 3 is various embodiments of the present invention and comparative example mechanics and cutting ability detection case list.
Various embodiments of the present invention are produced according to following steps:
1)Smelt and be casting continuously to form base;
2)Square billet is heated, it is 1150~1250 DEG C, 120~150min of soaking time to control heating-up temperature;
3)It is rolled into bar steel:Control roughing start rolling temperature is at 1100~1200 DEG C;Control finish rolling finishing temperature 750~ 850℃;
4)Water cooling is carried out, 300~500 DEG C are cooled in the case where cooling velocity is 20~120 DEG C/min;
5)Entering hole after bundling carries out slow cooling, is cooled to room temperature.
The comparative example of the various embodiments of the present invention of table 1 and comparative example(wt%)
Embodiment C Si Mn P S N B Al V Ti
1 0.30 0.42 1.5 0.010 0.010 0.035 0.010 0.015 0.10 -
2 0.32 0.40 1.2 0.004 0.008 0.030 0.012 0.014 0.12 -
3 0.45 0.50 1.2 0.005 0.004 0.045 0.020 0.020 0.14 -
4 0.50 0.55 1.3 0.015 0.003 0.042 0.015 0.010 0.11 -
5 0.42 0.60 1.4 0.008 0.015 0.044 0.018 0.022 0.15 -
6 0.48 0.48 1.5 0.001 0.001 0.050 0.016 0.030 0.13 -
7 0.42 0.44 1.3 0.008 0.005 0.042 0.015 0.020 0.14 -
8 0.44 0.46 1.4 0.008 0.015 0.048 0.016 0.022 0.13 -
9 0.46 0.42 1.3 0.004 0.008 0.046 0.020 0.025 0.15 -
10 0.48 0.48 1.5 0.003 0.001 0.035 0.018 0.020 0.14 -
11 0.35 0.50 1.2 0.005 0.008 0.033 0.019 0.015 0.15 -
12 0.45 0.56 1.5 0.001 0.008 0.036 0.015 0.022 0.12 -
Comparative example 1 0.35 0.50 1.3 0.015 0.25 0.010 - 0.010 0.20 -
Comparative example 2 0.45 0.51 1.4 0.010 0.33 0.020 - 0.015 0.22 -
Comparative example 3 0.48 0.55 1.3 0.012 0.35 0.015 - 0.020 0.30 -
13 0.30 0.45 1.5 0.009 0.008 0.036 0.011 0.015 0.040 0.020
14 0.34 0.40 1.2 0.004 0.008 0.030 0.012 0.014 0.050 0.030
15 0.46 0.50 1.2 0.005 0.004 0.045 0.020 0.020 0.080 0.035
16 0.50 0.55 1.3 0.015 0.003 0.042 0.010 0.010 0.060 0.040
17 0.42 0.60 1.4 0.008 0.015 0.044 0.018 0.022 0.070 0.025
18 0.48 0.48 1.5 0.001 0.001 0.050 0.016 0.030 0.075 0.038
19 0.35 0.42 1.3 0.002 0.009 0.035 0.012 0.012 0.057 0.022
20 0.37 0.45 1.2 0.007 0.004 0.044 0.017 0.018 0.064 0.024
21 0.42 0.52 1.4 0.008 0.005 0.050 0.018 0.024 0.062 0.022
22 0.44 0.50 1.5 0.005 0.015 0.042 0.019 0.027 0.067 0.032
23 0.32 0.55 1.3 0.004 0.008 0.043 0.018 0.023 0.054 0.037
24 0.38 0.57 1.2 0.004 0.001 0.047 0.015 0.015 0.055 0.035
Comparative example 4 0.35 0.50 1.3 0.015 0.010 0.024 - 0.01 0.070 0.030
Comparative example 5 0.45 0.51 1.4 0.010 0.013 0.020 - 0.015 0.050 0.040
Comparative example 6 0.48 0.55 1.3 0.012 0.015 0.025 - 0.020 0.080 0.020
The main technologic parameters list of the various embodiments of the present invention of table 2 and comparative example
The various embodiments of the present invention of table 3 and comparative example mechanics and cutting ability detection case list
The cutting ability of steel grade is tested in table 3, using unified machining condition:Stepless speed regulation horizontal lathe, geometric parameter Consistent hard alloy cutter, cutting test specimen is Ф 100mm × 300mm bars, and under the conditions of cutting fluid is not used, the amount of feeding is 0.2mm/r, cutting depth is 1mm, and cutting speed is 200m/min, and tool flank wear sets for the turnery processing time of 0.3mm It is set to cutter life.
As known from Table 3, mechanical property of the present invention meets:Tensile strength >=1200MPa, yield strength >=850MPa, extension Rate A >=15%, contraction percentage of area Z >=20%, and cutter life significantly improves, chip-breaking performance is excellent, and steel surface is bright and clean after cutting Degree is high.The demand of automotive light weight technology is fully met, and the need of Machinery Tool Automation, precise treatment and high-efficiency reform can be well adapted to Ask.
Above-described embodiment is only most preferably to enumerate, and is not the restriction to embodiments of the present invention.

Claims (4)

1. vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels, its component and weight percent content are:C: 0.30~0.50%, Si:0.40~0.60%, Mn:1.2~1.5%, P≤0.015%, S≤0.015%, N:0.03~0.05%, B: 0.01~0.02%, Al:0.01~0.03%, V:0.04~0.08%, Ti:0.02~0.04%, remaining is for Fe and inevitably Impurity.
2. vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels as claimed in claim 1, it is characterised in that:V Weight percent content be 0.051~0.070%.
3. vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels as claimed in claim 1, it is characterised in that:Ti Weight percent content be 0.020~0.030%.
4. the side of one of claim 1 to 3 described vanadium micro-alloying BN systems Rel >=1200MPa non-quenched and tempered free machining steels is produced Method, its step:
1)Smelt and be casting continuously to form base;
2)To heating strand, it is 1150~1250 DEG C, 120~150min of soaking time to control heating-up temperature;
3)It is rolled into bar steel:Control roughing start rolling temperature is at 1100~1200 DEG C;Control finish rolling finishing temperature is at 750~850 DEG C;
4)Water cooling is carried out, 300~500 DEG C are cooled in the case where cooling velocity is 20~120 DEG C/min;
5)Entering hole after bundling carries out slow cooling, is cooled to room temperature.
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