CN104591907A

CN104591907A - Foliage fertilizer having bactericidal, disease treating and antiviral effects and production method of foliage fertilizer

Info

Publication number: CN104591907A
Application number: CN201510058133.9A
Authority: CN
Inventors: 张继方; 孟玉伟; 张政
Original assignee: Individual
Current assignee: Individual
Priority date: 2015-02-05
Filing date: 2015-02-05
Publication date: 2015-05-06

Abstract

The invention provides a foliage fertilizer having bactericidal, disease treating and antiviral effects and a production method of the foliage fertilizer. The foliage fertilizer is an insecticide fertilizer preparation formed by complexing copper sulfate pentahydrate, zinc sulfate monohydrate, food-grade ammonium bicarbonate or ammonium citrate, sodium tetraborate, purified water and triacontanol together. The antiviral advantage of zinc in complex state is skillfully combined with the mechanisms of killing fungi and bacteria of copper in complex state, and therefore, copper poisoning caused by the application of excessive copper ions can be effectively prevented; due to powerful combination, a synergistic effect is achieved; the foliage fertilizer is mild in physical and chemical properties, and the defects existing in the prior art are avoided; the foliage fertilizer has multiple effects and can be applied to multiple purposes, and the foliage fertilizer is capable of preventing various diseases caused by fungi and bacteria and also effectively inhibiting viral diseases, and also has the effects of supplementing micro-elements, sweetening and turning leaves into green; the foliage fertilizer can be applied to the foliage, and can also be applied to irrigating root soil and removing stem disease spots; in short, the foliage fertilizer is a quick-acting, non-toxic, residue-free and pollution-free environment-friendly preparation.

Description

A kind of have sterilization and to cure the disease the foliage fertilizer of antivirus action and production method

Technical field

The present invention relates to a kind of for the sterilization of agriculture industry of planting forest or fruit tress, cure the disease, antiviral, the foliage fertilizer production method of supplementary fertilizer volume increase again.

Background technology

Current agricultural sector structure adjustment, fruit tree, vegetables, melon and fruit and diversified economy crop area constantly expand.Various garden, Demonstration Garden, plant husbandry base plant large-area single variety for many years continuously, make various crop, the disease of each growth period is diversified, complicated, and bacterial disease and fungal disease and Disease occur simultaneously, and have the trend overweighting fungi, bacterial disease of Disease, what the output minimizing that it causes and quality declined suffers heavy losses.Traditional sterilant target face is narrow, and specificity is strong, needs several different agents and use, very easily produce antagonistic action, cause poisoning, again contaminate environment during integrated control.

Now in practice, for the diversified economy crops such as fruit tree, vegetables, melon and fruit, tobacco leaf, medicinal material leaf dressing and supplement micro-fertilizer of a great variety, formulation is diversified, amount of application increase, increased frequency; The multielement mixture of compound, chemical combination type, mix type, defines crop and lacks and all mend, lack east and mend west, by quantity not sufficient or higher.Also lack trace element with micro-fertilizer, trace uses poisoning a lot of examples.

In the actually operating of present crop pest control, there is sterilant in the overwhelming majority, sterilant, foliage fertilizer, growth regulator, auxiliary agent, synergistic agent blending once use, and mixes the phenomenon sprayed.During the dissimilar concentrated outburst of particularly disease, Bactericidal medicament mixed by the medicament of fungicidal, add the medicament controlling virus type disease, one is that working concentration is too high, cause the even whole strain of fallen flowers, fallen leaves, shedding withered dead, therefore the deformed fruit caused, the stripping of scar spot, surface contamination, quality decline, output minimizing are even had no harvest, and fruit tree also affect the production of Second Year; Two is the acid-basicity regardless of medicament, no matter formulation, do not consider the antagonism between element, sequestration, blindly or should acute mixing use, create a series of physics, chemical reaction as neutralization reaction, replacement(metathesis)reaction, cause liquid muddiness, precipitation, effective constituent reduce or lost efficacy; Not only do not reach diseases prevention, control the effect of worm supplementary fertilizer, and form poisoning, increase residual quantity, contaminate environment.

Summary of the invention

The object of this invention is to provide and a kind ofly have sterilization and to cure the disease the foliage fertilizer of antivirus action and production method, it is the fertile preparation of a kind of multielement complex state medicine, and function is many, effect is high, environmental friendliness, can effectively solve prior art Problems existing.

Realizing the technical scheme that the object of the invention adopts is: it is made up of the raw material of following mass parts: technical grade cupric sulfate pentahydrate 350-500 part of purity more than 98%, copper content more than 32%: purity more than 95%, technical grade Zinc Sulphate Monohydrate 300-400 part of Zn content more than 33%; Food grade ammonium bicarbonate or ammonium citrate 2000-3000 part that nitrogen content is greater than 17.3%; Technical grade sodium tetraborate 300-400 part of purity 95-98%, Boron contents more than 20%; Pure water or soft water 5000-6000 part; White flakes shape crystal triacontanol price quote or 98% high purity amine DA-6 20-40 part.

Production method of the present invention is:

1, at normal temperatures and pressures, after five aqueous sodium persulfates of aforementioned proportion, Zinc Sulphate Monohydrate were pulverized 40 mesh sieves, mix with the bicarbonate of ammonia of aforementioned proportion or ammonium citrate, with the hammer stirrer of plastics matter, fully rub and be stirred to pasty state;

2, the above-mentioned mashed prod obtained is transferred to rapidly in withstand voltage, reactor that closure is good that inner bag is ester plastic, at 25-40 ⁰close complex reaction 20-40 hour at the temperature of C, obtain A material;

3, at 30-80 ⁰in the pure water of the aforementioned proportion of C temperature or soft water, add the sodium tetraborate of aforementioned proportion and triacontanol price quote or 98% high purity amine DA-6, be stirred to and dissolve completely, obtain acid adjustment stable liquid;

4, obtained acid adjustment stable liquid joined in the above-mentioned A material reacted completely, after fully stirring, sealed reaction 10-20 hour, can obtain foliage fertilizer of the present invention.

Positively effect of the present invention is: the antiviral advantage of complex state zinc and the fungicidal of complex state copper and the mechanism of bacterium are combined cleverly, effectively prevent the copper poisoning that cupric ion uses excessive formation; Make again its combination among the strong ones, mutually short synergy; Its physicochemical character is gentle, does not use the disadvantage existing for prior art; Potion multiple-effect, potion is multiplex, both can prevent and treat the multiple diseases that fungus and bacterium causes, and can effectively face upward Disease processed again, and has supplementary micro-fertilizer of foliage fertilizer concurrently and increase sweet turn of green effect; Not only can blade face spraying, also can fill with pouring root soil, can smear by stem scab again; A kind of quick-acting, nontoxic, noresidue, free of contamination environmentally friendly preparation.

Embodiment

Embodiment one:

By the technical grade cupric sulfate pentahydrate (CuSO of the content 98% of 380 weight parts ₄5H ₂o) with the technical grade Zinc Sulphate Monohydrate (ZnSO of the content more than 95% of 325 weight parts ₄ .h ₂o) co-grinding, stand-by after crossing 40 mesh sieves; At normal temperatures and pressures, with the hammer stirrer of the first day of the lunar month material quality, the food grade ammonium bicarbonate of 2600 mass parts (edible raising agent nitrogenous more than 17.3%) is ground into Powdered, join again in the copper sulfate and zinc sulphate powder be pulverized and mixed and mix, fully rub stirring 20 minutes, in sky blue mashed prod;

Mashed prod, transfer to rapidly in reactor that inner bag is withstand voltage, the good seal of polyester the first day of the lunar month material or acid and alkali-resistance enamel, at 25-40 ⁰c temperature lower seal complex reaction 26-38 hour, obtains A material;

The soft water of 5000-6000 weight part is heated to 55 ⁰c, order adds the sodium tetraborate of 360 weight parts and the content of 40 weight parts is the amine DA-6 of 98%, fully stirs, and dissolves and obtains acid adjustment stable liquid; Obtained acid adjustment stable liquid be transferred in A material and fully stir, sealed reaction 10-20 hour, namely obtains I type preparation of the present invention, obtains blue solution, can pack, put in storage, use after precipitation, filtration.

Embodiment two:

By the technical grade copper sulfate (CuSO of the content 98% of 325 weight parts ₄5H ₂o) with the technical grade Zinc Sulphate Monohydrate (ZnSO of the content more than 95% of 380 weight parts ₄ .h ₂o) co-grinding, stand-by after crossing 40 mesh sieves; At normal temperatures and pressures, with the hammer stirrer of the first day of the lunar month material quality, the food grade ammonium bicarbonate of 2600 mass parts (edible raising agent nitrogenous more than 17.3%) is ground into Powdered, join again in the copper sulfate and zinc sulphate powder be pulverized and mixed and mix, fully rub stirring 20 minutes, in sky blue mashed prod;

The soft water of 5000-6000 weight part is heated to 55 ⁰c, order adds sodium tetraborate and the 20 weight part triacontanol price quotes (triacontanol price quote is white flakes shape crystal, first dissolves with ether or chloroform) of 360 weight parts, fully stirs, dissolves and obtain acid adjustment stable liquid; Obtained acid adjustment stable liquid be transferred in A material and fully stir, sealed reaction 10-20 hour, namely obtains II type preparation of the present invention, obtains blue solution, can pack, put in storage, use after precipitation, filtration.

Application Example one

I type preparation of the present invention, generally dilute 450-600 when using doubly, foliage-spray can be prevented and treated effectively; The microbial diseases of curing the disease such as fungi, bacterium and virus such as Peptic Ulcers, bacillary shot hole of leaf disease, anthrax, ring spot, shot hole, black soya bean disease, blight dis-ease, resin disease, leaf blight, withes broom, mosaic virus, watermelon virus disease, tobacco leaf virus disease, capsicum epidemic disease, virus.To seedling stage and growth rhizome portion disease in earlier stage, as damping-off, anthrax, samping off, drench with 500-600 times of liquid and execute or fill with root, Be very effective.And having effect of supplementary plant nitrogen and trace element zinc, copper, boron, it is obvious that removing jaundice turns green effect.

Application Example two;

II type preparation of the present invention, except having the sterilizing disease-preventing of I type preparation, supplementary nitrogen, ketone, zinc, boron, removing jaundice turns outside green function, to the flower leaf type virus disease of watermelon, capsicum, pimento, oranges and tangerines, grape, tobacco, the resistance of short wooden stake branch C-type virus C disease is remarkable, after spraying 500 times of liquid, can suppress symptom rapidly, sick leaf removing jaundice turns green, and young leaves is normal.

The present invention is through contriver over nearly 20 years, test with in a kind of watermelon, grape, oranges and tangerines, capsicum, eggplant, cowpea, balsam pear and tobacco leaf Different Crop at the watermelon of Henan, Xinjiang, Jiangxi, Guangdong, Guangxi different zones, muskmelon, cucumber, seed, application continue to optimize, meticulous, its use range and target more become expand.

Claims

1. there is sterilization to cure the disease the foliage fertilizer of antivirus action, it is characterized in that: it is made up of the raw material of following mass parts: technical grade cupric sulfate pentahydrate 350-500 part of purity more than 98%, copper content more than 32%: purity more than 95%, technical grade Zinc Sulphate Monohydrate 300-400 part of Zn content more than 33%; Food grade ammonium bicarbonate or ammonium citrate 2000-3000 part that nitrogen content is greater than 17.3%; Technical grade sodium tetraborate 300-400 part of purity 95-98%, Boron contents more than 20%; Pure water or soft water 5000-6000 part; Triacontanol price quote or 98% high purity amine DA-6 20-40 part.

2. have sterilization to cure the disease the foliage fertilizer of antivirus action, its production method is:

(1), at normal temperatures and pressures, after five aqueous sodium persulfates of aforementioned proportion, Zinc Sulphate Monohydrate were pulverized 40 mesh sieves, mix with the bicarbonate of ammonia of aforementioned proportion or ammonium citrate, with the hammer stirrer of plastics matter, fully rub and be stirred to pasty state;

(2), by the above-mentioned mashed prod obtained be transferred to rapidly in withstand voltage, reactor that closure is good that inner bag is ester plastic, at 25-40 ⁰close complex reaction 20-40 hour at C temperature, obtain A material;

(3), at 30-80 ⁰in the pure water of the aforementioned proportion of C temperature or soft water, add the sodium tetraborate of aforementioned proportion and triacontanol price quote or 98% high purity amine DA-6, be stirred to and dissolve completely, obtain acid adjustment stable liquid;

(4), by obtained acid adjustment stable liquid join in the above-mentioned A material reacted completely, after fully stirring, sealed reaction 10-20 hour, namely obtains foliage fertilizer of the present invention.