Leak the detection method of chlorine alarm warning function
Technical field
The present invention relates to the field of the nuclear power water factory plant maintenance safety inspection in nuclear power station maintenance process, more particularly to inspection
Check the method for leaking chlorine alarm warning function that electric water factory used during chlorination.
Background technology
Nuclear power is carried out disinfection with water using chlorination in nuclear power water factory, because chlorine is hypertoxic gas, therefore in chlorination
Chlorine leakage warning device-leakage chlorine alarm is provided with equipment, the alarm principle of leakage chlorine alarm is by leaking chlorine sensor
Chlorine content in probe detection air, then feeds back to alarm, and alarm is sent by warning device.And once leak chlorine alarm and go out
Existing failure, during warning function cisco unity malfunction, once leakage too high, the influence that may result in chlorine content in factory building occurs for chlorine
Staff's is healthy, occurs chlorine poisoning event.Therefore, the season of nuclear power water factory in repair and maintenance project, leaks chlorine report
Alert instrument warning function is detected as pressure and must survey project.
Because chlorine is nuclear power to be entered with water using bottled chlorine as chlorine gas source in toxic gas, therefore nuclear power water factory
Row sterilization, chlorine cylinder was used after one month (summer) to three months (winter), and the chlorine in chlorine cylinder is not enough to support chlorination to set
Standby normal work, but now still have remaining chlorine in bottle.In conventional operating process, staff can change bottled chlorine
When, the chlorine cylinder removed is placed near the leakage chlorine sensor probe of Lou chlorine alarm, remaining chlorine in bottle is freely expanded
Shed and, so as to detect whether the warning function of Lou chlorine alarm is normal.However, when making to be detected in this way, work
Make personnel need to leakage chlorine alarm near be operated, without obvious phenomenon determine chlorine whether out of chlorine cylinder loss comes out,
Process of the test is not accurate enough, and staff is placed oneself in the midst of in the higher environment of chlorine gas concentration, chlorine poisoning phenomenon easily occurs.
The content of the invention
When detecting whether leakage chlorine alarm warning function is normal to solve prior art, the process of the test brought is not accurate enough
The problem of being easily poisoned with staff, the present invention proposes a kind of detection method for leaking chlorine alarm warning function, the detection method
Comprise the following steps:
(1) preparation
Check wiring and the energization situation of leakage chlorine alarm, it is ensured that leakage chlorine alarm is in holding state, and adjusts reset
Button, opens the chlorine detection function of leakage chlorine alarm;
(2) checkout procedure
Ammoniacal liquor is contained in open-top receptacle, and the open-top receptacle is placed on to the leakage chlorine sensor probe of Lou chlorine alarm
Near, then open-top receptacle is gently rocked, ammonia is escaped, white cigarette shape material whether is produced near observation leakage chlorine sensor probe;
If there are a large amount of white cigarettes to produce near the leakage chlorine sensor probe for leaking chlorine alarm, and leak chlorine alarm and never sent out from on-test
Go out alarm, then illustrate that the chlorine in chlorination equipment has been leaked, leakage chlorine alarm warning function breaks down, and reaction equation is
8NH3+3Cl2=6NH4Cl+N2↑;If not occurring a large amount of white cigarettes during leak detection, staff need to using reagent sodium hypochlorite and
Whether watery hydrochloric acid reaction generation chlorine is normal with the warning function for detecting Lou chlorine alarm, and reaction equation is:NaClO+2HCl
=NaCl+H2O+Cl2↑;
(3) agent treatment
After leakage chlorine alarm warning function detection terminates, discharged after reaction reagent is diluted.
The warning function for leaking chlorine alarm is detected using the detection method of present invention leakage chlorine alarm warning function
When, whether normal, and reaction has higher controllability if can be quickly detected Lou chlorine alarm, reagent starts reaction just at once
Produce chlorine so that detection process can be completed in very short time, and testing result is more accurate.
Preferably, during the leak detection, the time that ammoniacal liquor is exposed in factory building is 3s~10s (second).Ammoniacal liquor is opened light
Light rock can produce ammonia, and ammonia is toxic gas, and exposure in atmosphere can be to the healthy of neighbouring staff for a long time
Produce high risks.Meanwhile, the reaction speed of ammonia and chlorine quickly, if there is chlorine leakage in factory building, connects in ammonia with chlorine
Within tactile 1s, ammonia will generate white cigarette shape material ammonium chloride with chlorine reaction at once, and reaction is acutely and reacting phenomenon is easily seen
Examine, reaction result is waited without time-consuming.
Preferably, the sodium hypochlorite used in checkout procedure is that concentration range is molten in 4%~8% sodium hypochlorite
Liquid.When liquor natrii hypochloritis's concentration is too low, the course of reaction of liquor natrii hypochloritis and hydrochloric acid is more slow, the amount of chlorine produced compared with
It is low, it is impossible to the detecting concentration scope of the leakage chlorine sensor probe of leakage chlorine alarm is reached in moment, one section of reagent reacting is needed to wait for
Time can complete detection, but staff's supervisory instrument nearby is needed during due to experiment, and suction chlorine can be right for a long time
The body of staff produces injury, or even triggers poisoning.The excessive concentration of sodium hypochlorite can cause reaction excessively acute again
It is strong, produce amount of chlorine excessive, although detecting step can be quickly completed, but because reagent concentration is higher, after detecting step terminates
Reagent still can the sustained response long period, staff after diluting reaction during reagent still can suction part chlorine, to work
Considerable influence can be produced by making the personal safety of personnel.
Further, the concentration of the liquor natrii hypochloritis is 6%.Sodium hypochlorite using sodium hypochlorite content 6%
Solution during the course of the reaction, the leakage chlorine sensor probe detection of leakage chlorine alarm enough can be produced in time as reaction reagent
After the completion of the chlorine gas concentration arrived, and detection, the dilution work of reagent is relatively easy to.
Further, the volume of the liquor natrii hypochloritis used in checkout procedure is 3mL~5mL.Only need 3mL~5mL dense
The liquor natrii hypochloritis 4%~8% is spent, is reacted with watery hydrochloric acid, obtained chlorine is enough by the leakage chlorine of leakage chlorine alarm
Sensor probe is detected.
Preferably, the concentration range of the watery hydrochloric acid is 8%~15%.The watery hydrochloric acid reacted with liquor natrii hypochloritis
Excess is needed, this causes course of reaction more rapidly and sufficiently.
Further, the concentration of the watery hydrochloric acid is 12%.Concentration is relatively easy to for 12% watery hydrochloric acid preparation, and in examination
Chlorine can be comparatively fast produced in agent course of reaction, it is to avoid the peace caused by the chlorine that staff's long-time haptoreaction is produced
Full problem.
Preferably, the volume for the watery hydrochloric acid used in checkout procedure is 3mL~5mL.The chlorine that reaction reagent is obtained only is used
Whether there is obstacle in the warning function of detection leakage chlorine alarm, therefore, as long as the amount for the chlorine that reaction is produced can be by leakage chlorine
The leakage chlorine sensor probe of alarm is detected, and the amount of reaction reagent is without excessive.
Preferably, the volume for the water of diluting reaction reagent is more than 100 times of reaction reagent volume.More than hundred times waters
After being diluted to reaction reagent, reagent will not continue to react after detection terminates, and can pass through the pumping equipments such as sewer
Naturally drain, environment or water quality will not be impacted.
Use the detection method of present invention leakage chlorine alarm warning function so that the warning function of leakage chlorine alarm was detected
Journey is more quick, accurate, and reaction reagent is readily available, and course of reaction is more rapid, and detection can be completed within a short period of time,
So that the time that staff is exposed under chlorine gas environment greatly shortens, the person peace of staff has largely been ensured
Entirely.
Embodiment
Embodiment 1:
A kind of detection method for leaking chlorine alarm warning function, the detection method comprises the following steps:
(1) preparation
Check wiring and the energization situation of leakage chlorine alarm, it is ensured that leakage chlorine alarm is in holding state, and adjusts reset
Button, opens the chlorine detection function of leakage chlorine alarm;
(2) checkout procedure
Ammoniacal liquor is contained in open-top receptacle, and the open-top receptacle is placed on to the leakage chlorine sensor probe of Lou chlorine alarm
Near, then open-top receptacle 5s is gently rocked, so that the ammonia in ammoniacal liquor is fully escaped, reaction equation isWhite cigarette shape material whether is produced near observation leakage chlorine sensor probe;If leaking chlorine alarm
There are a large amount of white cigarettes to produce near leakage chlorine sensor probe, and leak chlorine alarm and alarm is never sent from on-test, then illustrate
Chlorine in chlorination equipment has been revealed, and leakage chlorine alarm warning function breaks down, and reaction equation is 8NH3+3Cl2=
6NH4Cl+N2↑;If not occurring a large amount of white cigarettes during leak detection, staff need to use concentration for 6% liquor natrii hypochloritis
3mL, reaction reagent is made with concentration for 12% watery hydrochloric acid 3mL, after both reagents are mixed reaction generation chlorine with
Whether detection leakage chlorine alarm warning function is normal, and reaction equation is:NaClO+2HCl=NaCl+H2O+Cl2↑;If now leaking
Chlorine alarm does not send alarm yet, then illustrates that obstacle occurs in the warning function of the leakage chlorine alarm;If leakage chlorine alarm sends police
Report, then illustrate that the warning function of the leakage chlorine alarm is normal;
(3) agent treatment
After leakage chlorine alarm warning function detection terminates, after reaction reagent plus 1L water are diluted by sewer certainly
So discharge.
Embodiment 2:
A kind of detection method for leaking chlorine alarm warning function, the detection method comprises the following steps:
(1) preparation
Check wiring and the energization situation of leakage chlorine alarm, it is ensured that leakage chlorine alarm is in holding state, and adjusts reset
Button, opens the chlorine detection function of leakage chlorine alarm;
(2) checkout procedure
Ammoniacal liquor is contained in open-top receptacle, and the open-top receptacle is placed on to the leakage chlorine sensor probe of Lou chlorine alarm
Near, then open-top receptacle 3s is gently rocked, so that the ammonia in ammoniacal liquor is fully escaped, reaction equation isWhite cigarette shape material whether is produced near observation leakage chlorine sensor probe;If leaking chlorine alarm
There are a large amount of white cigarettes to produce near leakage chlorine sensor probe, and leak chlorine alarm and alarm is never sent from on-test, then illustrate
Chlorine in chlorination equipment has been revealed, and leakage chlorine alarm warning function breaks down, and reaction equation is 8NH3+3Cl2=
6NH4Cl+N2↑;If not occurring a large amount of white cigarettes during leak detection, staff need to use concentration for 8% liquor natrii hypochloritis
3mL, reaction reagent is made with concentration for 8% watery hydrochloric acid 5mL, and reaction generates chlorine to examine after both reagents are mixed
Leaking hunting, whether chlorine alarm warning function is normal, and reaction equation is:NaClO+2HCl=NaCl+H2O+Cl2↑;If now leaking chlorine
Alarm does not send alarm yet, then illustrates that obstacle occurs in the warning function of the leakage chlorine alarm;If leakage chlorine alarm sends alarm,
Then illustrate that the warning function of the leakage chlorine alarm is normal;
(3) agent treatment
After leakage chlorine alarm warning function detection terminates, after reaction reagent plus 1L water are diluted by sewer certainly
So discharge.
Embodiment 3:
A kind of detection method for leaking chlorine alarm warning function, the detection method comprises the following steps:
(1) preparation
Check wiring and the energization situation of leakage chlorine alarm, it is ensured that leakage chlorine alarm is in holding state, and adjusts reset
Button, opens the chlorine detection function of leakage chlorine alarm;
(2) checkout procedure
Ammoniacal liquor is contained in open-top receptacle, and the open-top receptacle is placed on to the leakage chlorine sensor probe of Lou chlorine alarm
Near, then open-top receptacle 10s is gently rocked, so that the ammonia in ammoniacal liquor is fully escaped, reaction equation isWhite cigarette shape material whether is produced near observation leakage chlorine sensor probe;If leaking chlorine alarm
There are a large amount of white cigarettes to produce near leakage chlorine sensor probe, and leak chlorine alarm and alarm is never sent from on-test, then illustrate
Chlorine in chlorination equipment has been revealed, and leakage chlorine alarm warning function breaks down, and reaction equation is 8NH3+3Cl2=
6NH4Cl+N2↑;If not occurring a large amount of white cigarettes during leak detection, staff need to use concentration for 4% liquor natrii hypochloritis
5mL, reaction reagent is made with concentration for 15% watery hydrochloric acid 3mL, after both reagents are mixed reaction generation chlorine with
Whether detection leakage chlorine alarm warning function is normal, and reaction equation is:NaClO+2HCl=NaCl+H2O+Cl2↑;If now leaking
Chlorine alarm does not send alarm yet, then illustrates that obstacle occurs in the warning function of the leakage chlorine alarm;If leakage chlorine alarm sends police
Report, then illustrate that the warning function of the leakage chlorine alarm is normal;
(3) agent treatment
After leakage chlorine alarm warning function detection terminates, after reaction reagent plus 1L water are diluted by sewer certainly
So discharge.
The leakage chlorine of chlorination equipment in nuclear power water is alarmed using the detection method of present invention leakage chlorine alarm warning function
The warning function of instrument detected, whether normal, and reaction has higher controllability, makes if being enough quickly detected Lou chlorine alarm
Obtaining detection process can complete in very short time, and testing result is more accurate.Also reducing staff simultaneously and being exposed to has
Time in chlorine gas environment, it is ensured that staff's is healthy.