CN104560446A - Environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather - Google Patents
Environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather Download PDFInfo
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- CN104560446A CN104560446A CN201310503941.2A CN201310503941A CN104560446A CN 104560446 A CN104560446 A CN 104560446A CN 201310503941 A CN201310503941 A CN 201310503941A CN 104560446 A CN104560446 A CN 104560446A
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Abstract
The invention discloses an environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather. The environment-friendly three-in-one preparation comprises the following main components: a surfactant (free of APEO), natural eucalyptus oil, turpentine (free of pyridines), cason and a solvent. Protection of ecological environment is facilitated; and the cleaning, sterilizing and deodorizing capacities are good.
Description
Technical field
The present invention relates to field of household chemical, in particular to a kind of environment-friendly type eider down washing and sterilizing deodorizing " three-in-one " preparation.
Background technology
Tensio-active agent is the important component in the preparation of eider down clean-out system compound.After tensio-active agent is water-soluble, according to whether generating ion and electrically, be divided into ionogenic surfactant and nonionogenic tenside.Commercially in eider down rinse product formula, many products contain polyoxyethylene alkylphenol ether (APEO), particularly polyoxyethylene nonylphenol ether (NPEO), because its decontamination cleansing power is strong, are widely used.World's alkylphenol polyoxyethylene (APEO) yearly consumption is 8.8 hundred million pounds, and wherein more than 80% is polyoxyethylene nonylphenol ether (NPEO).APEO can be summarized in following four aspects to ecological impact: toxicity, biological degradability, environmental hormone, produce harmful side product in process of production.
The toxicity of toxicity: NPEO9-10: LD50=1600mg/Kg; Be 42mg/L to the ECO50 of water flea; Be 50mg/L to the ECO50 of algae, show that NPEO is to Mammals and hydrobiological toxicity and to cancer, simultaneously similar to other non-ionic surfactants.
The degradation property of degradation rate: APEO is slow, and its biological degradation rate is 0%-9%.
Environmental hormone: APEO has similar female hormone effect, the chemical substance of the normal hormone secretion of energy harmful to human, i.e. said " female effect " and distortion.
By product: can harmful side product be produced in APEO production process, in APEO production process during the ethyleneoxide addition of alkylphenol, cause low polyoxyethylated ring structure to turn to dioxan (Isosorbide-5-Nitrae), i.e. dioxane due to the excess accumulation of oxyethane.Dioxan confirms as carcinogens.
Because APEO is studied the harm that environment is potential widely and proves.Some countries of Europe have formulated regulation limitations and have produced and use APEO.Specify in 2003/53/EC, as NP or NPEO content in fruit product or NP or the NPEO content in discharge are equal to or higher than 0.1% (weight ratio), this material just can not be for the production of.Outlet Europe limitation of APEO on eider down is no more than 100PPM. this is a huge challenge to eider down clean-out system industry in recent years.We should be paid attention to, then adopt some effective means and stop to produce and use containing the auxiliary agent of APEO, the key addressed this problem finds suitable tensio-active agent effectively to substitute APEO role and function in our cleaning and each procedure of arranging.
Down and Feather, wool, and silk is natural animal thiozell, people are used as the important source material of weaving and clothes.Wherein Down and Feather still has stench peculiar smell and a large amount of microorganism after surfactant wash.Therefore, prepare a kind of three-in-one " preparation, seem very necessary.
On Down and Feather reodorant market, some product pyridine compounds and their (2-picolines, 3-picoline and 2,6 lutidine) and polyoxyethylene alkylphenol ether (APEO) as the main component of reodorant or clean-out system, to ecological impact, there is destructiveness and disguise.Pyridine is moderate toxicity industrial chemicals, through multi-step chemical reaction, can do medicine or agricultural chemicals.But directly as feather deodorant, be great destruction to water resources and ecotope.Reason has: 1. pyridine mixes arbitrarily with water, containing pyridine waste water, not easily reclaims pyridine; 2. pyridine has moderate toxicity, remains in down jackets, harmful; 3. pyridine is very stable, and generally not oxidizable and biological degradation, does not measure pyridine COD containing pyridine waste water, is easy to " up to standard " discharge, harm hydrobiont.
Because APEO is studied the harm that environment is potential widely and proves.Some countries of Europe have formulated regulation limitations and have produced and use APEO.Specify in 2003/53/EC, as NP or NPEO content in fruit product or NP or the NPEO content in discharge are equal to or higher than 0.1% (weight ratio), this material just can not be for the production of.The limitation of outlet Europe APEO on eider down must not more than 100PPM in recent years, and this is a huge challenge to eider down cleaning reodorant industry.
Summary of the invention
The object of this invention is to provide one not containing polyoxyethylene alkylphenol ether (APEO), environment-friendly type eider down washing and sterilizing deodorizing " three-in-one " preparation not containing pyridines, main component is by tensio-active agent, natural organic-compound, Kathon CG and solvent composition.Wherein, natural organic-compound mainly eucalyptus oil and turps.
Tensio-active agent is fatty alcohol-polyoxyethylene ether (AEO-9), isomery ten polyoxyethylenated alcohol (E1009) mainly, Sodium dodecylbenzene sulfonate (EOS-9), these tensio-active agent biodegradabilities are better, and containing carcinogens, not containing heavy metal ion, can not work the mischief to HUMAN HEALTH.
Eucalyptus oil mainly forms: 1, 8-Cineole (more than 80%), amphene, phellandrene, Terpineol 350, geranyl alcohol, isovaleric aldehyde etc.Character: colourless or micro-yellow liquid.Also be with camphor smell somewhat in peculiar refrigerant spine folium eucalypti fragrance, be with a little medicine gas, have the refrigerant sense of peppery mouth, fragrance is strongly and not lasting.There are certain mildew-resistant and sterilization and anticorrosion effect.Water-soluble hardly, be dissolved in ethanol, dehydrated alcohol, oil & fat.Flash-point is 50 DEG C.Toxicology is according to GRAS FEMA2466.LD50>5.0g/kg (rabbit).
Turps is volatile terpene blend with aromatising flavour, has sterilization and mildew-proof function.LD50>5.7g/kg (rat oral); Also solvent can be worked as.
Kathon CG, i.e. chloro-2 methyl-4 isothiazoline-3-ketone and the MITs of 5-.
Safe, efficient, broad spectrum daily use chemicals product that Kathon CG product system generally acknowledges in the world limit the use of sanitas, external trade name " KATHON CG " (Kathon CG and KF88) its active part is isothiazolinone compounds, can effectively suppress and go out except mushroom and various microorganism.
Adding of a small amount of essence, Down and Feather is made to have light delicate fragrance.
A kind of environment-friendly type eider down washing and sterilizing deodorizing " three-in-one " preparation not containing APEO and pyridine of the present invention, its formula is:
Advantage of the present invention is exactly the protection being conducive to ecotope, detects, APEO:26.64mg/kg through the third-party institution, meets GB/T23322-2009, SN/T1850.2-2006, BESTSELLER chemical restriction requirement.
Further, the present invention has obvious washing and sterilizing deodorizing capability, detects, degree of cleaning (600mm), Oil and Fat Content (0.6%), oxygen-consumption (3.0mg/100g), smell 2 grades through the third-party institution.Meet GB/T14272-2011 individual event requirement.
Embodiment
Below by embodiment, the invention will be further described, instead of limitation of the present invention; Slightly do to change and production and sales to system component of the present invention or part by weight, all may be considered to infringement of the present invention.
Embodiment one, (being applicable to drake feather eider down)
Operation: in 100 kilograms of drake feather eider downs, add 1000 kg of water, 5 kilograms of " three-in-one " preparations, in 45 DEG C of stirring and washing 30 minutes, rinsing 16 times, water dumping, 120 DEG C of stirring and washing 30 minutes, dry, cooling and packaging.
Embodiment two, (being applicable to drake feather workprint)
Operation: in 100 kilograms of drake feather workprints, add 1000 kg of water, 4 kilograms of " three-in-one " preparations, in 45 DEG C of stirring and washing 30 minutes, rinsing 16 times, water dumping, 120 DEG C of oven dry, cooling and packing.
Embodiment three, (being applicable to drake feather staple)
Operation: in 100 kilograms of drake feather lousiness, add 1000 kg of water, 4 kilograms of " three-in-one " preparations, in 45 DEG C of stirring and washing 30 minutes, rinsing 16 times, water dumping, 120 DEG C of oven dry, cooling and packing.
Claims (2)
1. environment-friendly type eider down washing and sterilizing deodorizing " three-in-one " preparation, formula main component is tensio-active agent (not containing APEO), natural eucalyptus oil and turps (not containing pyridines), Kathon CG and solvent.
2., according to claim 1, the formula of environment-friendly type eider down washing and sterilizing deodorizing " three-in-one " preparation is:
Operation: in 100 kilograms of drake feather eider downs or workprint or lousiness, add 1000 kg of water, 4-5 kilogram of " three-in-one " preparation, in 45 DEG C of stirring and washing 30 minutes, clean 16 times, water dumping, 120 DEG C of oven dry, cools and pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310503941.2A CN104560446A (en) | 2013-10-24 | 2013-10-24 | Environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310503941.2A CN104560446A (en) | 2013-10-24 | 2013-10-24 | Environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather |
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| CN104560446A true CN104560446A (en) | 2015-04-29 |
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| CN201310503941.2A Pending CN104560446A (en) | 2013-10-24 | 2013-10-24 | Environment-friendly three-in-one preparation for cleaning, sterilizing and deodorizing down feather |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349280A (en) * | 2015-11-12 | 2016-02-24 | 安徽卓祥羽毛科技发展有限公司 | A detergent used for washing feather with water and a preparing method thereof |
| CN105368600A (en) * | 2015-11-12 | 2016-03-02 | 安徽卓祥羽毛科技发展有限公司 | Washing agent for raw feather and preparation method thereof |
| CN108485837A (en) * | 2018-05-03 | 2018-09-04 | 浙江工业职业技术学院 | A kind of bleaching cleaning and sterilization agent of efficient feather and its application process |
| CN114190389A (en) * | 2021-11-24 | 2022-03-18 | 山东志存科技有限公司 | Preparation method of special sterilizing and smell-removing agent for down feather |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102051276A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Down jacket cleaning agent |
| CN103351963A (en) * | 2013-07-01 | 2013-10-16 | 安徽华强羽绒有限公司 | Odor-eliminating eider down caring agent and preparation method thereof |
-
2013
- 2013-10-24 CN CN201310503941.2A patent/CN104560446A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051276A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Down jacket cleaning agent |
| CN103351963A (en) * | 2013-07-01 | 2013-10-16 | 安徽华强羽绒有限公司 | Odor-eliminating eider down caring agent and preparation method thereof |
Non-Patent Citations (1)
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| 郝新敏: "《医用纺织材料与防护服装》", 31 March 2008 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349280A (en) * | 2015-11-12 | 2016-02-24 | 安徽卓祥羽毛科技发展有限公司 | A detergent used for washing feather with water and a preparing method thereof |
| CN105368600A (en) * | 2015-11-12 | 2016-03-02 | 安徽卓祥羽毛科技发展有限公司 | Washing agent for raw feather and preparation method thereof |
| CN108485837A (en) * | 2018-05-03 | 2018-09-04 | 浙江工业职业技术学院 | A kind of bleaching cleaning and sterilization agent of efficient feather and its application process |
| CN108485837B (en) * | 2018-05-03 | 2020-12-18 | 浙江工业职业技术学院 | Efficient down feather bleaching and cleaning bactericide and application method thereof |
| CN114190389A (en) * | 2021-11-24 | 2022-03-18 | 山东志存科技有限公司 | Preparation method of special sterilizing and smell-removing agent for down feather |
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Application publication date: 20150429 |
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