CN104560441B - A kind of aqua type crude oil pollution place surface cleaning agent - Google Patents
A kind of aqua type crude oil pollution place surface cleaning agent Download PDFInfo
- Publication number
- CN104560441B CN104560441B CN201410805355.8A CN201410805355A CN104560441B CN 104560441 B CN104560441 B CN 104560441B CN 201410805355 A CN201410805355 A CN 201410805355A CN 104560441 B CN104560441 B CN 104560441B
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- crude oil
- water
- surface cleaning
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The present invention relates to cleaning agent field, more particularly to a kind of aqua type crude oil pollution place surface cleaning agent.Cleaning agent by weight percentage, 2 12% surfactants, 1.5 7.3% auxiliary agents, surplus is water.Detergent for crude petroleum of the present invention is directed to petroleum crude oil greasy dirt, have the advantages that it is safe and environment-friendly, reduce labor intensity, reduce and clean cost, easy to use.The detergent for crude petroleum of the present invention has a wide range of application, mainly for the various surfaces of oil pollution, the equipment surface of such as petrochemical plant, the car body surface of transport vehicle, cement road surface are cleaned, it can also be cleaned in offshore platform deck, cabin, and the seabeach pollution cleaning that marine oil spill is caused.
Description
Technical field
The present invention relates to cleaning agent field, more particularly to a kind of aqua type crude oil pollution place surface cleaning agent.
Background technology
At present, the cleaning agent species both at home and abroad for crude oil washing/COW is more, but basic point three kinds：Leaning solvent, water
Fundamental mode cleaning agent and two-phase cleaning agent agent.Leaning solvent and two-phase cleaning agent agent contain solvent composition, and pollution is big, dangerous
Height, the murder by poisoning to operating personnel is big.Cleaning performance and environment-friendly side of the existing aqua type cleaning agent to crude oil pollution surface
Face generally there are certain shortcoming, and price is higher.Based on sustainable development idea, for petrochemical industry, pipeline road leakage, sea
The cleaning on the crude oil pollution place surface that oil etc. is caused is permeated with, efficient, environment-friendly, reasonable price cleaning agent is for oil phase
Close industry or even China's cleaning industry is all significant.
The content of the invention
Present invention aims to solve the deficiencies of the prior art, and provides a kind of a kind of aqua type crude oil pollution place surface clean
Agent.
To achieve the above object, the technical solution adopted by the present invention is：
A kind of aqua type crude oil pollution place surface cleaning agent, cleaning agent by weight percentage, 2-12% surface-actives
Agent, 1.5-7.3% auxiliary agents, surplus is water.
The surfactant is neopelex and aliphatic acid polyethenoxy (9) ester.
The auxiliary agent is disodium ethylene diamine tetraacetate, sodium citrate, sodium carbonate, sodium carboxymethylcellulose, natrium nitrosum, sweet
Oil.
The surface cleaning agent preferred component is：By weight percentage, 0.2%-1% sodium citrates, 0.5%-2% ten
Dialkyl benzene sulfonic acids sodium, 2%-10% aliphatic acid polyethenoxies (9) ester, 1%-2% sodium carbonate, 0-0.3% carboxymethyl celluloses
Sodium, 0%-1% natrium nitrosums and 0.5%-2% glycerine, surplus is water.
The water be meet People's Republic of China (PRC) standards for drinking water quality GB5749-2006 drinking water, river,
Fresh water lake lake water or deionized water.
Surfactant and auxiliary agent described in a kind of preparation method of aqua type crude oil pollution place surface cleaning agent are in proportion
In the water for being dissolved in 60 DEG C -90 DEG C, stir to transparent stable homogeneous state, be cooled to and produce cleaning agent at room temperature.
Advantage for present invention：
The water base detergent for crude petroleum of the present invention is the cleaning for high concentration crude oil pollution place, and cleaning agent is in contaminated site
The various surfaces such as metal surface, frosting, cement surface, the road surface of presence have significant cleaning performance, and have simultaneously
Antirust and slow releasing function.Easy volatile solvent is free of in cleaning agent raw material selection of the present invention, using efficient, environmentally friendly, degradable table
Face activating agent and auxiliary agent, reduce the harm to environment and human body.Specifically,
(1) specific aim
Detergent for crude petroleum in development using crude oil greasy dirt as cleaning object, all experiments are deployed with crude oil pollution, institute
With the cleaning for the various oil pollutions that are particularly suitable for use in.
(2) broad spectrum activity
Cleaning test and improvement are carried out to different surfaces in development, on metal surface, frosting, cement surface, road
The various surfaces such as face show excellent clean effect.
(3) security
Without volatile solvent, safety is non-explosive.
(4) stability
Prepare and can use various fresh water when diluting：Running water, lake water, underground water etc., and can use through complexing agent
Treated seawater dilution, performance is stable, at normal temperatures with good clean effect.
(5) feature of environmental protection
Added auxiliary agent is not phosphorous, small to environmental disturbances without not degradable organic matter without heavy metal element, drop
Solution is fast.
(6) rust-preventing characteristic and anti-corrosive properties
It is low to metal erosion, and with certain antirust ability.
Embodiment
Water base detergent for crude petroleum is synthesized, for original using water as solvent by the way of surfactant compound addition auxiliary agent
The various surfaces of oily pollution are cleaned, with good removal effect.
Embodiment
Preparation method：
Recorded by the correlation in table 1 by sodium citrate, neopelex, aliphatic acid polyethenoxy (9) ester, carbonic acid
Sodium, sodium carboxymethylcellulose, natrium nitrosum and glycerine are dissolved in 65 DEG C of water, are stirred and are then cooled at room temperature, produce
Cleaning agent.
The Application Example of table 1
Cleaning agent in above-described embodiment 1 is prepared using deionized water, and it is diluted in practical operation, using go from
Sub- water is diluted to 3 times.The cleaning agent is under uniform state to stainless steel surface greasy dirt average removal rate up to 99.3%.
Cleaning agent in above-described embodiment 2 is prepared using running water, is diluted in practical operation, using running water,
Lake water, river are diluted to 3 times.The cleaning agent is under uniform state to stainless steel surfaces greasy dirt average removal rate up to 96.7%.
Cleaning agent in above-described embodiment 3 is prepared using the underground water of the higher water hardness, is diluted in practical operation,
3 times are diluted to using various fresh water.The cleaning agent is under uniform state to stainless steel surfaces greasy dirt average removal rate up to 94.7%.
Cleaning agent in above-described embodiment 4 is prepared using deionized water, and it is applied to non-metallic material surface crude oil greasy dirt
Cleaning, the cleaning agent under uniform state to frosting greasy dirt average removal rate up to 96.1%, cement surface greasy dirt is averaged
Clearance is up to 78.6%, and road pavement oily waste degradation effect substantially, can make road surface recover background color.
Cleaning agent in above-described embodiment 5 is prepared using deionized water, is diluted in practical operation, using various light
Water is diluted to 3 times.Its metal surface crude oil washing/COW that is particularly suitable for use in, has derusting, antirust concurrently, alleviates corrosiveness.This is clear
Lotion meets the cleaning of JBT 4323.1-1999 water-base metals under uniform state to the antirust and corrosion inhibition on No. 45 carbon steel surfaces
Agent standard, to the clearance of surface of steel plate greasy dirt up to 94.9% when being diluted using deionized water.
The computational methods of all kinds of surface and oil contaminant clearances are in above-described embodiment：
The greasy dirt amount that clearance (the %)=cleaning agent is washed down/dirty amount of initial painting oiling
Measured for the initial greasy dirt amount that dirt is measured and cleaning agent is washed down of refueling that applies in surface by weight method.
Detergent for crude petroleum prepared by above-described embodiment is directed to petroleum crude oil greasy dirt, with it is safe and environment-friendly, lighten one's labor it is strong
Degree, reduction cleaning cost, advantage easy to use.The detergent for crude petroleum application clean range of above-mentioned preparation is wide, mainly for stone
The various surfaces of oily pollution, such as the equipment surface of petrochemical plant, the car body surface of transport vehicle, cement road surface are carried out clearly
Wash, can also be cleaned in offshore platform deck, cabin, and the seabeach pollution cleaning that marine oil spill is caused.
Above-mentioned cleaning agent is specifically useful in the petroleum-polluted machinery of oil plant, vehicle, building, road surface, using spray
The cleaning means such as giant, steam cleaner are spilt, soaked or coordinated, tiny particle can be formed simultaneously by emulsified crude oil rapidly
It is dissolved in detergent for crude petroleum, prevents that crude oil from depositing and absorption forms secondary pollution.For the pollution based on petroleum hydrocarbon, water
Base detergent for crude petroleum can also play good effect, such as the industrial oil pollution of mechanical surface, using immersion, sprinkling, punching
The mode such as washing effectively and can suppress, and not damage mechanical part.For accidents such as marine oil spills, using spray water base
The mode of oily cleaning agent, can carry out emulsion dispersion to crude oil in the very first time, reduce the dirt that crude oil is caused to ocean, land etc.
Dye.
Claims (3)
1. a kind of aqua type crude oil pollution place surface cleaning agent, it is characterised in that：Surface cleaning agent by weight percentage,
0.2%-1% sodium citrates, 0.5%-2% neopelexes, 2%-10% aliphatic acid polyethenoxies (9) ester, 1%-
2% sodium carbonate, 0-0.3% sodium carboxymethylcelluloses, 0%-1% natrium nitrosums and 0.5%-2% glycerine, surplus is water.
2. aqua type crude oil pollution place surface cleaning agent according to claim 1, it is characterised in that：The water is to meet
People's Republic of China (PRC) standards for drinking water quality GB5749-2006 drinking water or deionized water.
3. a kind of preparation method of the aqua type crude oil pollution place surface cleaning agent described in claim 1, it is characterised in that：Institute
State sodium citrate, neopelex, aliphatic acid polyethenoxy (9) ester, sodium carbonate, sodium carboxymethylcellulose, nitrous acid
Sodium and glycerine are dissolved in 60 DEG C -90 DEG C of water in proportion, stir to transparent stable homogeneous state, are cooled to and produce cleaning at room temperature
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410805355.8A CN104560441B (en) | 2014-12-22 | 2014-12-22 | A kind of aqua type crude oil pollution place surface cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410805355.8A CN104560441B (en) | 2014-12-22 | 2014-12-22 | A kind of aqua type crude oil pollution place surface cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104560441A CN104560441A (en) | 2015-04-29 |
| CN104560441B true CN104560441B (en) | 2017-10-20 |
Family
ID=53077525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410805355.8A Active CN104560441B (en) | 2014-12-22 | 2014-12-22 | A kind of aqua type crude oil pollution place surface cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104560441B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105695184A (en) * | 2016-01-13 | 2016-06-22 | 重庆中渝市政环卫有限责任公司解放碑分公司 | Heavy oil contamination road surface cleaning agent and preparation method |
| CN105524736A (en) * | 2016-01-18 | 2016-04-27 | 重庆中渝市政环卫有限责任公司解放碑分公司 | Nondestructive efficient detergent and preparation method therefor |
| CN106047516B (en) * | 2016-05-25 | 2018-12-21 | 青岛中孚达环境科技开发有限公司 | Environment-friendly type oil sludge and sand cleansing composition and preparation method thereof |
| CN108070466A (en) * | 2017-12-21 | 2018-05-25 | 大庆吉益来科技有限公司 | A kind of oil field oil sludge cleaning agent and preparation method |
| CN111334378A (en) * | 2018-12-19 | 2020-06-26 | 深圳市天正隆科技有限公司 | Cleaning agent, preparation, use and cleaning system for oil drilling platform |
| CN110846146A (en) * | 2019-11-26 | 2020-02-28 | 江苏华路建设工程有限公司 | Road oil stain cleaning solution |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000071661A1 (en) * | 1999-05-21 | 2000-11-30 | Reckitt Benckiser Inc. | Low residue aqueous hard surface cleaning compositions particularly adapted for cleaning glass and glossy hard surfaces |
| CN1844342A (en) * | 2006-04-10 | 2006-10-11 | 中国海洋石油总公司 | Heavy oil cleaning agent |
-
2014
- 2014-12-22 CN CN201410805355.8A patent/CN104560441B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000071661A1 (en) * | 1999-05-21 | 2000-11-30 | Reckitt Benckiser Inc. | Low residue aqueous hard surface cleaning compositions particularly adapted for cleaning glass and glossy hard surfaces |
| CN1844342A (en) * | 2006-04-10 | 2006-10-11 | 中国海洋石油总公司 | Heavy oil cleaning agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104560441A (en) | 2015-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104560441B (en) | A kind of aqua type crude oil pollution place surface cleaning agent | |
| CN105696008B (en) | A kind of hardware products ultrasonic wave water-base cleaning liquid and preparation method thereof | |
| CN110982642B (en) | Neutral silicone oil silicone grease cleaning agent and preparation method and application thereof | |
| MX2012013928A (en) | Use of eco-friendly microemulsions in oil cleaning applications. | |
| CN104313622A (en) | Normal-temperature water-based non-phosphorus rust-proof cleaning agent for heavy oil | |
| CN104694946A (en) | Phosphorus-free degreaser | |
| CN106350260B (en) | Water-based microemulsion rubber print cleaning agent for aircraft carrier runways | |
| CN105623890A (en) | Efficient and environmentally friendly industrial heavy oil stain cleaning agent | |
| CN104087433A (en) | Greasy dirt scavenger | |
| US7384902B2 (en) | Metal brightener and surface cleaner | |
| CN107858191A (en) | One kind derusting lubrication aerosol and preparation method thereof | |
| CN104878404A (en) | Emulsion-type antirust cleaning agent and preparation method thereof | |
| CA2503018A1 (en) | Cleaning compositions for oil-gas wells, well lines, casings, equipment, storage tanks, etc., and method of use | |
| CN111304665A (en) | Rust removing and preventing agent | |
| CN104005033A (en) | Anti-corrosion rust remover and preparation method thereof | |
| CN105220160B (en) | A kind of stirred tank rust-proofing method | |
| CN101440495A (en) | Environment protection type rapid strong oil-removing rust-removing agent | |
| US9561531B2 (en) | Composition and method for hydrocarbon and lipid degradation and dispersal | |
| CN114457344A (en) | Water-based cleaning agent for cleaning offshore oil well pipe column and preparation method thereof | |
| CN104098951B (en) | A kind of five metals detergent for ink and preparation method thereof | |
| CN108003717B (en) | Nano-scale dispersed long-acting water-based antirust liquid and preparation method thereof | |
| CN102876481A (en) | Grease dirt cleaning agent | |
| CA2977259A1 (en) | Composition and method for hydrocarbon and lipid degradation and dispersal | |
| CN103642300A (en) | Car-washing water for printing | |
| CN112980601B (en) | Heavy oil pollution oil pipeline cleaning agent and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |