CN106047516B - Environment-friendly type oil sludge and sand cleansing composition and preparation method thereof - Google Patents
Environment-friendly type oil sludge and sand cleansing composition and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
- C08B37/0012—Cyclodextrin [CD], e.g. cycle with 6 units (alpha), with 7 units (beta) and with 8 units (gamma), large-ring cyclodextrin or cycloamylose with 9 units or more; Derivatives thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The present invention relates to industrial cleaning agent fields, and in particular to a kind of oil sludge and sand cleansing composition and preparation method thereof.Environment-friendly type oil sludge and sand cleansing composition includes at least following components: nonionic surface active agent, perfluor modified polyether, fatty acid methyl ester ethoxylate sulfonate, water in parts by weight；Wherein, the nonionic surfactant includes at least sapn, tween, nonylphenol polyoxyethylene ether, alkyl glycosides；Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are (3~20): (1~15): (1~5): (0.01~0.1).
Description
Technical field
The present invention relates to industrial cleaning agent fields, and in particular to a kind of oil sludge and sand cleansing composition and preparation method thereof.
Background technique
With water flooding, sand production amount is higher and higher, and the pollution problem of oil-containing mud sand is increasingly severe, greasy filth
Sand has become the important pollution sources in oil field, it is necessary to take measures to carry out treatment and recycling to oil-containing mud sand early.
The oil sludge and sand in oil field is mainly derived from two aspects, first is that from drain sump, oil tank, sump oil in crude oil dehydration
The silt particle of the bottom deposits such as tank；Second is that the crude oil as caused by equipment perforation, operation, destruction is unrestrained.The complicated component of oil sludge and sand,
Oil content is high, and direct outlet will cause the pollution of ground environment.The oil-sand and fall that existing situation is each block station, multi-purpose station generates
Remaining greasy filth, which the methods of mainly uses air storage, sanitary landfills, paves the way, after ground crude oil recovery is disposed, and environmental pollution is tight
Weight, directly polluted surface water and groundwater.
Currently, handling oil sludge and sand by petroleum silt particle cleaning agent is more common method, but the processing temperature of oil sludge and sand
Degree is average, and at 80 DEG C, temperature is higher, and consume energy very big, higher cost, and petroleum silt particle oil content after treatment is average 1%
~5%, cleaning effect is also not ideal enough.
Therefore, be highly desirable to develop one kind to be handled at room temperature, and simultaneously being capable of cleaning effect with higher
The oil sludge and sand cleaning agent of rate.
Summary of the invention
In order to solve prior art problem, the present invention provides a kind of environment-friendly type oil sludge and sand cleansing composition, with parts by weight
Meter includes at least following components:
Wherein, the nonionic surfactant includes at least sapn, tween, nonylphenol polyoxyethylene ether, alkyl glycosides；
Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are (3~20): (1~15): (1~5): (0.01~
0.1)。
In a preferred embodiment, the environment-friendly type oil sludge and sand cleansing composition, it is described for Arlacel-20, department
Disk -40, Arlacel-60, any one in Arlacel-80.
In a preferred embodiment, the tween is Tween-20, in Tween-40, Tween-60, Tween-80
Any one.
In a preferred embodiment, the environment-friendly type oil sludge and sand cleansing composition, the polyoxyethylene nonyl phenyl second
Alkene ether is the mixture of TX-3 and TX-10.
In a preferred embodiment, the environment-friendly type oil sludge and sand cleansing composition, the TX-3 and TX-10's
Weight ratio are as follows: (50~200): (0.1~1).
In a preferred embodiment, the environment-friendly type oil sludge and sand cleansing composition further includes 1~5 parts by weight
Branched paraffin.
In a preferred embodiment, the environment-friendly type oil sludge and sand cleansing composition further includes 0.5~3 parts by weight
Cyclodextrin polymer.
In a preferred embodiment, the cyclodextrin polymer is the modified cyclodextrin polymer of graphene oxide.
The second aspect of the invention provides the preparation method of environment-friendly type oil sludge and sand cleansing composition:
(1) preparation of nonionic surface active agent:
The alkyl glycosides of the sapn of 3~20 parts by weight, 0.01~0.1 parts by weight is dissolved in distilled water, at 30 DEG C, with
The speed of 30~60r/min stirs to clarify, and adds the tween of 1~15 parts by weight, the polyoxyethylene nonyl phenyl second of 1~5 parts by weight
Alkene ether is stirred to clarify at 30~60 DEG C with the speed of 30~60r/min；
(2) environment-friendly type oil sludge and sand cleansing composition compounds:
By 15~50 parts by weight nonionic surface active agent, 1~20 parts by weight perfluor modified polyether, 0.1~5 parts by weight
The water of fatty acid methyl ester ethoxylate sulfonate, 5~35 parts by weight is stirred with the speed of 40~90r/min, to be mixed to equal
Stop stirring when even transparency liquid, stands at room temperature, cooling obtains oil sludge and sand cleaning agent.
The third aspect of the invention provide environment-friendly type oil sludge and sand cleansing composition petrochemical industry, auto industry,
The application of aerospace, building, weapons.
Specific embodiment
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily to understand
Bright content.Unless otherwise defined, all technologies used herein and scientific term have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... preparation " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this
Phrase will make claim closed, so that it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body,
It is only limited to element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end
Value and all integers and score in the range.
Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used to modify quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the acceptable modified part without will lead to the change of dependency basis this function close with the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measurement numerical value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges if not stated otherwise include all subranges contained therebetween.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component
(i.e. frequency of occurrence) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number
The element or component of form also include plural form, unless the obvious purport of the quantity refers to singular.
" polymer " means polymerizable compound prepared by the monomer by the identical or different type of polymerization.Generic term
" polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer by polymerization at least two different monomers preparation.Generic term " copolymer " includes
(it is general with term " terpolymer " for term " copolymer " (it is generally to refer to the polymer prepared by two kinds of different monomers)
To refer to the polymer prepared by three kinds of different monomers).It also includes the polymerization manufactured by polymerization four or more monomer
Object." blend " means that two or more polymer mixes the polymerization to be formed by physics or chemical method jointly
Object.
In order to solve prior art problem, the present invention provides a kind of environment-friendly type oil sludge and sand cleansing composition, with parts by weight
Meter includes at least following components:
Wherein, the nonionic surfactant includes at least sapn, tween, nonylphenol polyoxyethylene ether, alkyl glycosides；
Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are (3~20): (1~15): (1~5): (0.01~
0.1)。
Nonionic surface active agent
The main of oil sludge and sand cleaning agent in the present invention becomes nonionic surface active agent, the non-ionic surface active
Agent includes at least sapn, tween, nonylphenol polyoxyethylene ether, alkyl glycosides；
Sapn, also known as sorbitan fatty acid ester, anhydrous sorbitol are formed by ester from different higher fatty acids, from
From the point of view of from the viewpoint of cleaning effect, carbon atom number is 10~24, further preferably 12~18.Such as Arlacel-20 is laurel
Acid is formed by ester with anhydrous sorbitol；Arlacel-80 is that monoleate and anhydrous sorbitol are formed by ester.Its hydrophobic group is preferred
Beneficial effects of the present invention can be realized for alkyl, alkyl either straight chain or branch.
In a preferred embodiment, the sapn is Arlacel-20, in Arlacel-40, Arlacel-60, Arlacel-80
Any one or a few mixing.
In a kind of preferred embodiment, the sapn is Arlacel-80.
Tween, also known as sorbitan fatty acid ester polyoxyethylene ether.
In a preferred embodiment, the tween is Tween-20, in Tween-40, Tween-60, Tween-80
Any one.
In a kind of preferred embodiment, the tween is Tween-80.
Nonylphenol polyoxyethylene ether, with the non-ionic surface of nonyl phenol and ethylene oxide condensation reaction under the action of catalyst
Activating agent.
In a preferred embodiment, nonylphenol polyoxyethylene ether can selected from TX-3, TX-4, TX-6, TX-7,
Any one or a few mixing in TX-10, TX-15.
In a preferred embodiment, the nonylphenol polyoxyethylene ether is selected from the mixing of TX-3, TX-10.
In a preferred embodiment, the weight ratio of the TX-3 and TX-10 are as follows: (50~200): (0.1~1).
The present inventor is found surprisingly that, using TX-3 as main component, minimal amount of TX-10, which is added, can greatly be improved clearly
Wash efficiency.
In a kind of preferred embodiment, the TX-10 is sulfonation TX-10.
The preparation method of sulfonation TX-10 can be any one method well known in the art, and illustrative method can be as
Under:
The mixed gas for being 5% at the volumetric concentration of gaseous sulfur trioxide by sulfur trioxide and air conditioning, by gaseous mixture
Body is passed into the solution of TX-10, and controls n (TX-10): n (sulfur trioxide)=1:(0.1~0.3)；Sulfonation temperature be 20~
35 DEG C, sulfonation time is 1~3h, and sulfonation TX-10 can be obtained.
Alkyl glycosides, alkyl glycosides (APG) are to be obtained using fatty alcohol and glucose as raw material using catalysis acetalation technique
Product.Alkyl glycosides is obtained derived from the pure and mild glucose of natural fat of biomass resource by direct acetalation clean technologies
Environmentally protective class surfactant.
Alkyl glycosides in the present invention is not limited only to alkyl glycosides, further includes alkyl glycosides analog derivative.
The alkyl glycosides analog derivative that can be enumerated are as follows: alcohol ether glucoside, branched alkyl glycosides, short-chain alkyl glucosides, poly- alkane
Base glucosides, alkyl glycosides citrate, alkyl glycosides sulfosuccinate, alkyl glycosides tartrate etc..
For above-mentioned various surfactants, wherein sapn, tween, nonylphenol polyoxyethylene ether, the weight of alkyl glycosides
Than for (3~20): (1~15): (1~5): (0.01~0.1).
In a preferred embodiment, sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are
(8~16): (5~13): (1~4): (0.03~0.1).
In a kind of preferred embodiment, sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides
For 13:9:3:0.06.
Other than four kinds of above-mentioned surfactants, under the premise of not influencing cleaning effect of the present invention, can also include
Common nonionic surface active agent: polyethylene glycol type nonionic surfactant, polyol-based non-ionic surfactant；
Suitable nonionic surface active agent include polyoxyethylene ether, polyoxyethylene propylidene alkyl ether,
Polyoxyethylene phenyl ether and polyoxyethylene aliphatic ester.Particularly with for stability be preferably polyoxyethylene
Alkyl ether, polyoxyethylene propylidene alkyl ether and polyoxyethylene phenyl ether.Suitable example includes polyoxyethylene
Octyl Ether, polyoxyethylene nonyl ethers, polyoxyethylene certain herbaceous plants with big flowers base ether, polyoxyethylene propylidene certain herbaceous plants with big flowers base ether, the polyoxyethylene moon
Osmanthus base ether, polyoxyethylene propylidene lauryl ether, polyoxyethylene tridecyl ether, polyoxyethylene propylidene tridecyl
Ether, polyoxyethylene myristyl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene octyl
Phenyl ether, polyoxyethylene nonylplenyl ether and polyoxyethylene styrenated phenyl ether.
Perfluor modified polyether
In the present invention, perfluoropolyether is a kind of perfluoro-polymer compound, is only made of tri- kinds of elements of C, F, O in molecule,
Since fluorine atom has very strong electronegativity (bond energy is up to 418.4~502.08kJ/mo1), carbochain is most of by fluorine atom screen
It covers.
In the present invention, perfluoropolyether is prepared by perfluorinated monomer, according to polymerization and polymerized monomer
Difference, can aggregate into the perfluoropolyether of different molecular structures, and perfluoropolyether is divided into K-type, Y type, Z-type, four kinds of D type.Y type, Z-type
It is to utilize perfluoroepoxide for raw material, by made of anionic polymerisation, K-type, D type are passed through using perfluoroolefine as raw material
Photocatalysis polymerization.
The first is K-type perfluoropolyether, molecular structure are as follows:
K-type perfluoropolyether, using fluorine ion as catalyst in aprotic solvent, is polymerize using hexafluoropropylene oxide as raw material
Made of perfluorochemical, polymerization reaction equation is as follows:
Second is D type perfluoropolyether, molecular structural formula are as follows:
D type perfluoropolyether is to first pass through ring-opening polymerization at fluorine-containing oligomer, so using tetrafluoro oxetanes as monomer
Afterwards polymer is being fluorinated to obtain perfluoropolyether, specific reaction equation is as follows:
The third is Z-type perfluoropolyether, molecular structural formula are as follows:
4th kind is Y type perfluoropolyether, molecular structural formula are as follows:
In the present invention, any one perfluoropolyether can achieve beneficial effects of the present invention.
In a preferred embodiment, the perfluoropolyether K-type perfluoropolyether.
In the present invention, the perfluor modified polyether is 1~20 parts by weight；Preferably 5~18 parts by weight；More preferably 10 weights
Measure part.
Fatty acid methyl ester ethoxylate sulfonate
In the present invention, the fatty acid methyl ester ethoxylate sulfonate (FMES) is a kind of anionic type surface-active
Agent is obtained by non-ionic fatty acid methyl ester ethoxylate sulfonation.
In the present invention, the fatty acid methyl ester ethoxylate sulfonate is 0.1~5 parts by weight；Preferably 0.5~4 weight
Measure part；More preferably 3 parts by weight.
Branched paraffin
In the present invention, term " branched paraffin " is referred to and is connected between carbon atom with singly-bound, and branch or side are had in carbochain
The alkane of chain.
Contain 3-15 carbon atom for branched paraffin of the invention, specific example can enumerate for example: 2- methyl
Butane, neopentane, 2- methylpentane, 2,2- dimethylbutane, 2- methyl hexane, 2,2- dimethyl pentane, 2,2,3- trimethyl
Butane, 2- methyl heptane, 2,2- dimethylhexane, 2,2,3- trimethylpentane, 2,2,3,3- 4-methyl-butane, 2- methyl nonyl
Alkane, 2,2- dimethyl octane, 2,2,3- trimethylheptane, 2,2,3,3- tetramethyl hexane, 2,2,3,3,4- pentamethyl pentane, 2-
Methyldecane, 2,2- dimethylnonane, 2,2,3- trimethyl octane, 2,2,3,3- tetramethyl base heptane, 2,2,3,3,4- pentamethyl
Hexane, 2,2,3,3,4,4- hexamethyl pentane, 2- methylundecane, 2,2- dimethyl decane, 2,2,3- trimethyl nonane, 2,2,
3,3- tetramethyl octane, 2,2,3,3,4- five methylheptane, 2,2,3,3,4,4- hexamethyl hexane, 2- methyl dodecane, 2,2-
Dimethyl hendecane, 2,2,3- trimethyl decane, 2,2,3,3- tetramethyl nonane, 2,2,3,3,4- pentamethyl octane, 2,2,3,
3,4,4- pregnancy base heptane, seven methyl hexane of 2,2,3,3,4,4,5-, 2- methyltridec, 2,2- dimethyl dodecyl, 2,2,
3- norfarnesane, 2,2,3,3- tetramethyl decane, 2,2,3,3,4- pentamethyl nonane, 2,2,3,3,4,4- hexamethyl are pungent
Alkane, seven methyl heptane of 2,2,3,3,4,4,5-, 2,2,3,3,4,4,5,5- prestox hexane, 2- methyltetradecylphosphine, 2,2- diformazan
Base tridecane, 2,2,3- trimethyldodecane, 2,2,3,3- tetramethyl hendecane, 2,2,3,3,4- pentamethyl decane, 2,2,3,
3,4,4- hexamethyl nonane, seven methyloctane of 2,2,3,3,4,4,5-, 2,2,3,3,4,4,5,5- prestox heptane, 2,2,3,3,
Nine methyl hexane of 4,4,5,5,6-.
In a preferred embodiment, the branched paraffin contains 5-10 carbon atom, and specific example can arrange
It enumerates for example: 2,3- dimethyl pentane, 2,2,3- trimethylpentane, 2,3,4- trimethylpentane, 2,2- methyl hexane, 2,2,3,
5- tetramethyl hexane, 2- methyl heptane, 2- methylnonane, 2,2,3- trimethylheptane, 2,3,4- trimethylpentane, 3,4,4,5-
Tetramethyl base heptane, 2,2,7,7- tetramethyl octane, 2,2- dimethylnonane, 2,2,3- trimethyl octane.
In the present invention, the branched paraffin is 1~5 parts by weight；Preferably 1~3 parts by weight；More preferably 1 parts by weight.
Cyclodextrin polymer
Term " cyclodextrin polymer " is that cyclodextrin monomer is obtained by polymerization reaction.
Cyclodextrin monomer of the present invention is not particularly limited, and can be cyclodextrin, or cyclodextrine derivatives.
Heretofore described cyclodextrin and cyclodextrine derivatives such as, but not limited to, cyclodextrin such as alpha-cyclodextrin, β-ring
Dextrin and gamma-cyclodextrin；Cyclodextrine derivatives such as Dimethyl cyclodextrin, glucose cyclodextrin, 2- Hydroxyproply-α-cyclodextrin, 2,
Bis--O- methyl-alphacyclodextrin of 6-, 6-O- α-malt-base-alpha-cyclodextrin, 6-O- α-D- glucityl-alpha-cyclodextrin, six (2,3,
Tri--O- acetyl group of 6-)-alpha-cyclodextrin, six (2,3,6- tri--O- methyl)-alpha-cyclodextrins, six (6-O- tosyl)-α-rings
Dextrin, six (6- amino -6- deoxidation)-alpha-cyclodextrins, six (the bromo- 6- deoxidation of 2,3- acetyl group -6-)-alpha-cyclodextrins, six (2,3,6-
Three-O- octyls)-alpha-cyclodextrin, list (2-O- phosphoryl)-alpha-cyclodextrin, list [2, (3)-O- (carboxymethyl)]-alpha-cyclodextrin, eight
(6-O- t-butyldimethylsilyl)-alpha-cyclodextrin, succinyl-alpha-cyclodextrin, glucuronyl- glucityl-β-ring paste
Essence, seven (2,6- bis--O- methyl)-beta-cyclodextrins, seven (2,6- bis--O- ethyl)-beta-cyclodextrins, seven (6-O- sulfo group)-β-rings paste
Essence, seven (2,3- bis--O- acetyl group -6-O- sulfo group)-beta-cyclodextrins, seven (2,3- bis--O- methyl -6-O- sulfo group)-beta-cyclodextrins,
Seven (2,3,6- tri--O- acetyl group)-beta-cyclodextrins, seven (2,3,6- tri--O- benzoyl)-beta-cyclodextrins, seven (2,3,6- tri--
O- methyl)-beta-cyclodextrin, seven (bis--O- methyl of 3-O- acetyl group -2,6-)-beta-cyclodextrins, seven (2,3-O- acetyl group -6- are bromo-
6- deoxidation)-beta-cyclodextrin, 2- hydroxyethyl-β-cyclodextrin, hydroxypropyl-β-cyclodextrin, 2-HP-BETA-CD, (2- hydroxyl-
3-N, N, N- dimethylamino) propyl-beta-cyclodextrin, 6-O- α-malt sugar group-beta-cyclodextrin, methyl-B-cyclodextrin, six (6- ammonia
Base -6- deoxidation)-beta-cyclodextrin, bis- (6- nitrine -6- deoxidation)-beta-cyclodextrins, list (2-O- phosphoryl)-beta-cyclodextrin, six [6-
Deoxidation -6- (1- imidazole radicals)]-beta-cyclodextrin, single acetyl group-beta-cyclodextrin, triacetyl group-beta-cyclodextrin, monochloro triazine radical-β -
Cyclodextrin, 6-O- α-D- glucose group-beta-cyclodextrin, 6-O- α-D-Maltose group-beta-cyclodextrin, succinyl-beta-cyclodextrin, amber
Acyl-(2- hydroxypropyl)-beta-cyclodextrin, 2- carboxymethyl-beta-cyclodextrin, 2- carboxyethyl-beta-cyclodextrin, fourth group-beta-cyclodextrin, sulphur third
Group-beta-cyclodextrin, 6- monodeoxy -6- monoamine group-beta-cyclodextrin, silicyl [bis--O- second of (6-O- fert-butyidimethylsilyl) 2,3-
Acyl group]-beta-cyclodextrin, 2- ethoxy-gamma-cyclodextrin, 2- hydropropyl-y-cyclodextrin, butyl-gamma-cyclodextrin, 3A- amino-
3A- deoxidation-(2AS, 3AS)-gamma-cyclodextrin, mono- 2-O- (p-toluenesulfonyl)-gamma-cyclodextrin, mono- 6-O- are (to toluene sulphur
Acyl group)-gamma-cyclodextrin, mono- 6-O- mesitylene sulfonyl-gamma-cyclodextrin, eight (2,3,6- tri--O- methyl)-γ-rings paste
Essence, eight (2,6- bis--O- phenyl)-gamma-cyclodextrins, eight (6-O- t-butyldimethylsilyl)-gamma-cyclodextrins and eight (2,
3,6- tri--O- acetyl group)-gamma-cyclodextrin.These cyclodextrin can be used alone or are used in combination with it.Wherein, α-
Cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin and its derivative are preferred.From the point of view of cleaning efficiency consideration, particularly preferred β-ring paste
Essence and its derivative.
In one embodiment, the cyclodextrin polymer the preparation method is as follows:
A certain amount of β-cyclodextrin, isocyanates are added in 50ml dimethyl sulfoxide, electromagnetism stirs at 50~70 DEG C
Reaction is mixed, the reaction time is 5~8 hours.Acetone washing reaction system is used after reaction, and resulting reaction solid is successively used again
After boiling water, hot ethanol washing, in vacuum oven, at 60 DEG C dry 20 hours it is spare.
In a preferred embodiment, the cyclodextrin polymer is the modified cyclodextrin polymer of graphene oxide.
In one embodiment, the modified cyclodextrin polymer of the graphene oxide the preparation method is as follows:
It first disperses graphene oxide in deionized water, adds cyclodextrin polymer aqueous solution, be centrifuged after sonicated
Separation takes solid phase to dry to get the modified cyclodextrin polymer of graphene oxide.
In the present invention, the cyclodextrin polymer is 0.5~3 parts by weight；Preferably 0.5~2 parts by weight；More preferably 0.5 weight
Measure part.
It is other:
Various additives can be contained within the scope without prejudice to the object of the present invention.
Can be used as the specific example of additive, for example, preservative, essence, pH adjusting agent, viscosity modifier, moisturizer,
One of regulator, fungicide etc. are a variety of.
The second aspect of the invention provides the preparation method of environment-friendly type oil sludge and sand cleansing composition:
(1) preparation of nonionic surface active agent:
The alkyl glycosides of the sapn of 3~20 parts by weight, 0.01~0.1 parts by weight is dissolved in distilled water, at 30 DEG C, with
The speed of 30~60r/min stirs to clarify, and adds the tween of 1~15 parts by weight, the polyoxyethylene nonyl phenyl second of 1~5 parts by weight
Alkene ether is stirred to clarify at 30~60 DEG C with the speed of 30~60r/min；
(2) environment-friendly type oil sludge and sand cleansing composition compounds:
By 15~50 parts by weight nonionic surface active agent, 1~20 parts by weight perfluor modified polyether, 0.1~5 parts by weight
The water of fatty acid methyl ester ethoxylate sulfonate, 5~35 parts by weight is stirred with the speed of 40~90r/min, to be mixed to equal
Stop stirring when even transparency liquid, stands at room temperature, cooling obtains oil sludge and sand cleaning agent.
The third aspect of the invention provide environment-friendly type oil sludge and sand cleansing composition petrochemical industry, auto industry,
The application of aerospace, building, weapons.
Embodiment:
Embodiment 1: embodiments of the present invention 1 provide a kind of environment-friendly type oil sludge and sand cleansing composition, with weight
Part meter, includes at least following components:
Wherein, the nonionic surfactant includes at least sapn, tween, nonylphenol polyoxyethylene ether, alkyl glycosides；
Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are (3~20): (1~15): (1~5): (0.01~
0.1)。
Embodiment 2: identical as embodiment 1, difference is, the sapn is Arlacel-20, Arlacel-40, sapn-
60, any one in Arlacel-80.
Embodiment 3: identical as embodiment 1, difference is, the tween is Tween-20, Tween-40, tween-
60, any one in Tween-80.
Embodiment 4: identical as embodiment 1, difference is, the nonylphenol polyoxyethylene ether is TX-3 and TX-
10 mixture.
Embodiment 5: identical as embodiment 4, difference is, the weight ratio of the TX-3 and TX-10 are as follows: (50~
200): (0.1~1).
Embodiment 6: identical as embodiment 1, difference is that the environment-friendly type oil sludge and sand cleansing composition also wraps
Include the branched paraffin of 1~5 parts by weight.
Embodiment 7: identical as embodiment 1, difference is that the environment-friendly type oil sludge and sand cleansing composition also wraps
Include the cyclodextrin polymer of 0.5~3 parts by weight.
Embodiment 8: identical as embodiment 7, difference is, the cyclodextrin polymer is the modified polycyclic of graphene oxide
Dextrin.
Embodiment 9: embodiments of the present invention 9 provide the preparation method of environment-friendly type oil sludge and sand cleansing composition:
(1) preparation of nonionic surface active agent:
The alkyl glycosides of the sapn of 3~20 parts by weight, 0.01~0.1 parts by weight is dissolved in distilled water, at 30 DEG C, with
The speed of 30~60r/min stirs to clarify, and adds the tween of 1~15 parts by weight, the polyoxyethylene nonyl phenyl second of 1~5 parts by weight
Alkene ether is stirred to clarify at 30~60 DEG C with the speed of 30~60r/min；
(2) environment-friendly type oil sludge and sand cleansing composition compounds:
By 15~50 parts by weight nonionic surface active agent, 1~20 parts by weight perfluor modified polyether, 0.1~5 parts by weight
The water of fatty acid methyl ester ethoxylate sulfonate, 5~35 parts by weight is stirred with the speed of 40~90r/min, to be mixed to equal
Stop stirring when even transparency liquid, stands at room temperature, cooling obtains oil sludge and sand cleaning agent.
Embodiment 10: embodiments of the present invention 10 provide environment-friendly type oil sludge and sand cleansing composition in stone
The application of oiling work, auto industry, aerospace, building, weapons.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used
In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field
The some nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, and number used in following material is weight
Part.
Embodiment 1:
The embodiment of the present invention 1 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, TX-1, alkyl glycosides；Sapn-
80, Tween-80, TX-1, alkyl glycosides weight ratio be 3:15:1:0.01.
Preparation method:
(1) preparation of nonionic surface active agent:
The alkyl glycosides of the sapn of 3 parts by weight, 0.01 parts by weight is dissolved in distilled water, at 30 DEG C, with 30r/min's
Speed stirs to clarify, and the Tween-80 of 15 parts by weight, the TX-1 of 1 parts by weight is added, at 30~60 DEG C, with 40r/min's
Speed stirs to clarify；
(2) environment-friendly type oil sludge and sand cleansing composition compounds:
By 15 parts by weight nonionic surface active agent, 1 parts by weight perfluor modified polyether, 0.1 parts by weight fatty acid methyl ester
The water of ethoxylate sulfonates, 5 parts by weight is stirred with the speed of 40r/min, and when liquid to be mixed to homogeneous transparent stops stirring
It mixes, stands 2h at room temperature, cooling obtains oil sludge and sand cleaning agent.
Embodiment 2:
The embodiment of the present invention 2 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, TX-1, alkyl glycosides；Sapn-
80, Tween-80, TX-3, alkyl glycosides weight ratio be 20:1:5:0.1.
The preparation method is the same as that of Example 1, the difference lies in that the weight ratio between nonionic surfactant is different.
Embodiment 3:
The embodiment of the present invention 3 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, TX-3, alkyl glycosides；Sapn-
80, Tween-80, TX-3, alkyl glycosides weight ratio be 13:9:3:0.06.
The preparation method is the same as that of Example 1, the difference lies in that the weight ratio between nonionic surfactant is different.
Embodiment 4:
The embodiment of the present invention 4 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
3:TX-10=50:0.1), alkyl glycosides；Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are
13:9:3:0.06.
The preparation method is the same as that of Example 1, the difference lies in that the weight ratio between nonionic surfactant is different.
Embodiment 5:
The embodiment of the present invention 5 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
3:TX-10=200:0.1), alkyl glycosides；Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides
For 13:9:3:0.06.
Preparation method is the same as embodiment 4。
Embodiment 6:
The embodiment of the present invention 6 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
The weight ratio 100:1 of 3:TX-10), alkyl glycosides；Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether, alkyl glycosides weight
Amount is than being 13:9:3:0.06.The TX-10 is sulfonation TX-10.
The preparation method of sulfonation TX-10:
The mixed gas for being 5% at the volumetric concentration of gaseous sulfur trioxide by sulfur trioxide and air conditioning, by gaseous mixture
Body is passed into the solution of TX-10, and controls n (TX-10): n (sulfur trioxide)=1:0.1；Sulfonation temperature is 20 DEG C, when sulfonation
Between be 3h, sulfonation TX-10 can be obtained.
Preparation method is the same as embodiment 4。
Embodiment 7:
The embodiment of the present invention 7 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
3:TX-10=100:1), alkyl glycosides；Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are 13:9:3:
0.06。
Preparation method is the same as embodiment 4, the difference lies in that 3,4,4,5- tetramethyl heptan of 1 parts by weight are added in the step (2)
Alkane.
Embodiment 8:
The embodiment of the present invention 8 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
3:TX-10=100:1), alkyl glycosides；Sapn, tween, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are 13:9:3:
0.06。
The preparation method of cyclodextrin polymer:
6mmol β-cyclodextrin, 20mmol isocyanates are added in 50ml dimethyl sulfoxide, electromagnetism stirs at 70 DEG C
Reaction is mixed, the reaction time is 8 hours.Acetone washing reaction system is used after reaction, and resulting reaction solid is again successively with boiling
After water, hot ethanol washing, in vacuum oven, at 60 DEG C dry 20 hours it is spare.
Preparation method is the same as embodiment 7, the difference lies in that the cyclodextrin polymer of 0.5 parts by weight is added in step (2).
Embodiment 9:
The embodiment of the present invention 9 provides a kind of environment-friendly type oil sludge and sand cleansing composition and includes at least in parts by weight
Following components:
Wherein, the nonionic surfactant includes at least Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether (TX-
3:TX-10=100:1), alkyl glycosides；Arlacel-80, Tween-80, nonylphenol polyoxyethylene ether, the weight ratio of alkyl glycosides are
13:9:3:0.06.
The preparation method of the modified cyclodextrin polymer of graphene oxide
(1) preparation method of the preparation method of cyclodextrin polymer is the same as embodiment 8.
(2) it first disperses the graphene oxide of 0.01 parts by weight in 50ml deionized water, adds the poly- of 0.5 parts by weight
Cyclodextrin aqueous solution is centrifugated after sonicated, takes solid phase to dry to get the modified cyclodextrin polymer of graphene oxide.
Preparation method is the same as embodiment 8, change the difference lies in that cyclodextrin polymer is changed to graphene oxide in step (2)
Property cyclodextrin polymer.
Comparative example 1:
Oil sludge and sand cleaning agent, including following components:
Lignin-polyamines polyene of 70%~80% parts by weight；
The anhydrous sodium metasilicate of 7.5%~17.5% parts by weight；
The T-80 of 7.5%~17.5% parts by weight.
Preparation method:
By lignin-polyamines polyene 3g, then and be separately added into the anhydrous sodium metasilicate of 0.5g and the T-80 of 0.5g, by its point
It in the distilled water of 60ml and Jia Ru not stir evenly, be respectively formed petroleum silt particle cleaning agent.
Comparative example 2:
Oil sludge and sand cleaning agent, including following components:
The sorbitan mono-oleic acid ester of 10 parts by weight, the OP-15 of 30 parts by weight, the OP-40 of 20 parts by weight, 10 parts by weight
Ethylenediamine-lignosulfonate sodium, the T-80 of 3 parts by weight, the hydrogen peroxide of 3 parts by weight, the dodecyl sodium sulfate of 7 parts by weight, 13
The distilled water of parts by weight.
Preparation method:
10 parts of sorbitan mono-oleic acid esters, 30 parts of OP-15,20 parts of OP-40,10 parts of ethylenediamines-lignosulfonate sodium is taken to add
Enter into beaker, distilled water be added and starts to be stirred, temperature is controlled at 60 DEG C, it is to be mixed uniformly after successively plus auxiliary material, 3 parts of T-
80,7 parts of hydrogen peroxide, 7 parts of dodecyl sodium sulfates, 13 parts of distilled water, and continue to stir, when liquid to be mixed to homogeneous transparent, stop
It only stirs, stands at room temperature, is cooled into 1# petroleum silt particle cleaning agent.
Comparative example 3:
Oil sludge and sand cleaning agent, including following components:
The wetting agent of 20 parts by weight, the neopelex of 5 parts by weight, the op-10 of 15 parts by weight, 5 parts by weight
Sodium carbonate, part sodium metasilicate of 5 parts by weight, 20 parts by weight water.
Preparation method:
(1) synthesis of wetting agent:
The aqueous solution that sodium hydroxide is dissolved into 20% is spare；
Stearic acid is added to reaction kettle, heating stirring, constant temperature stirs when temperature rises to 120 DEG C, and diethanol amine is added, stirs
After mixing uniformly, it is slow added into 20% sodium hydrate aqueous solution, continues to stir 4h；Glacial acetic acid is added, stirs 20 minutes, it is naturally cold
It but is afterwards wetting agent；
(2) compounding of cleaning agent:
Sodium metasilicate and water are added to reaction kettle, stirring and dissolving sequentially adds wetting agent, dialkyl benzene sulfonic acids after dissolution completely
Sodium, op-10, sodium carbonate, after mixing evenly as product.
Comparative example 4:
Specific preparation step is with comparative example 6, the difference lies in that all Arlacel-80s of nonionic surfactant.
Comparative example 5:
Specific preparation step is with comparative example 6, the difference lies in that all Tween-80s of nonionic surfactant.
Comparative example 6:
Specific preparation step is with comparative example 6, the difference lies in that all TX-3 of nonionic surfactant.
Comparative example 7:
Specific preparation step is with comparative example 6, the difference lies in that all alkyl glycosides of nonionic surfactant.
Comparative example 8:
Specific preparation step is with comparative example 6, the difference lies in that the weight ratio of TX-3:TX-10 is 1:1.
Comparative example 9:
Specific preparation step is with comparative example 8, the difference lies in that 4,4,5- tetramethyl base heptanes are changed to normal heptane by 3.
Comparative example 10:
Specific preparation step is with comparative example 7, the difference lies in that cyclodextrin polymer is changed to cyclodextrin.
Performance evaluation:
1, at 60 DEG C, mud, the oil content of sand, oil recovery rate are tested.
Test method: taking 50g oil content is that 30% oil sludge and sand is put into the beaker of 500ml, and 60 DEG C are put into beaker
Water 200ml, then beaker is put into 60 DEG C of waters bath with thermostatic control, the oil sludge and sand of oil sludge and sand weight 0.1% is then added in beaker
Cleaning agent starts electric mixer (speed: 100 revs/min), and after stirring 15 minutes, 1 is stood in 60 DEG C of water bath with thermostatic control
Hour.Finally by beaker grease and silt particle separate, take beaker bottom silt particle carry out oil content, oil recovery rate detection,
Concrete outcome is shown in Table 1.
2, at 30 DEG C, mud, the oil content of sand, oil recovery rate are tested.
Test method: taking 50g oil content is that 30% oil sludge and sand is put into the beaker of 500ml, and 30 DEG C are put into beaker
Water 200ml, then beaker is put into 30 DEG C of waters bath with thermostatic control, the oil sludge and sand of oil sludge and sand weight 0.1% is then added in beaker
Cleaning agent starts electric mixer (speed: 100 revs/min), and after stirring 15 minutes, 1 is stood in 30 DEG C of water bath with thermostatic control
Hour.Finally by beaker grease and silt particle separate, take beaker bottom silt particle carry out oil content, oil recovery rate detection,
Concrete outcome is shown in Table 1.
1 performance evaluation of table
From table 1 it follows that the environment-friendly cleaning agent composition in the present invention, has preferable cleaning effect at 60 DEG C
Fruit, at 60 DEG C, the oil content of environment-friendly cleaning agent composition mud, sand shown in Examples 1 to 9 is below equal to 0.20%,
And oil recovery rate is higher, oil after the recovery can recycle.Meanwhile environment-friendly cleaning agent composition shown in embodiment 7~9
At 30 DEG C, still there is extraordinary cleaning efficiency, and oil recovery rate is higher, achieves essence for oil sludge and sand cleaning agent field
The progress of property, drops to 30 DEG C by 80 DEG C for cleaning temperature, greatly reduces energy consumption, cleaning condition is more mild.
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims
It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combined selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention
Feature exemplary selectional restriction.And the progress in science and technology will be formed language express it is inaccurate due to and not
The possible equivalent being presently considered or son replacement, and these variations should also be interpreted in the conceived case by appended
Claim covering.
Claims (6)
1. a kind of environment-friendly type oil sludge and sand cleansing composition, in parts by weight, which is characterized in that include at least following components:
1~20 parts by weight of perfluor modified polyether；
0.1~5 parts by weight of fatty acid methyl ester ethoxylate sulfonate；
5~35 parts by weight of water；
Wherein, the environment-friendly type oil sludge and sand cleansing composition further includes nonionic surfactant, TX-3 and sulfonation TX-10
Mixture；The nonionic surfactant, TX-3 and sulfonation TX-10 mixture total weight parts be 15~50 parts by weight；
The nonionic surfactant is selected from sapn, tween, alkyl glycosides；The sapn, tween, TX-3 and sulfonation TX-10 it is mixed
Close object, the weight ratio of alkyl glycosides is (3~20): (1~15): (1~5): (0.01~0.1)；
The sapn is Arlacel-20, Arlacel-40, Arlacel-60, any one or a few the mixing in Arlacel-80；
The tween is Tween-20, Tween-40, Tween-60, any one or a few the mixing in Tween-80；
The weight ratio of the TX-3 and sulfonation TX-10 are as follows: (50~200): (0.1~1).
2. environment-friendly type oil sludge and sand cleansing composition as described in claim 1, which is characterized in that the environment-friendly type oil sludge and sand cleaning
Agent composition further includes the branched paraffin of 1~5 parts by weight.
3. environment-friendly type oil sludge and sand cleansing composition as described in claim 1, which is characterized in that the environment-friendly type oil sludge and sand cleaning
Agent composition further includes the cyclodextrin polymer of 0.5~3 parts by weight.
4. environment-friendly type oil sludge and sand cleansing composition as claimed in claim 3, which is characterized in that the cyclodextrin polymer is oxidation stone
The modified cyclodextrin polymer of black alkene.
5. such as the preparation method of the described in any item environment-friendly type oil sludge and sand cleansing compositions of Claims 1 to 4, feature exists
In at least including the following steps:
(1) alkyl glycosides of the sapn of 3~20 parts by weight, 0.01~0.1 parts by weight is dissolved in distilled water, at 30 DEG C, with
The speed of 30~60 r/min stirs to clarify, and adds the tween of 1~15 parts by weight, the TX-3 of 1~5 parts by weight and sulfonation
The mixture of TX-10 is stirred with the speed of 30~60 r/min at 30~60 DEG C, obtains clear solution；
(2) by obtained clear solution, the perfluor modified polyether of 1~20 parts by weight, 0.1 in 15~50 parts by weight steps (1)
The water of the fatty acid methyl ester ethoxylate sulfonate of~5 parts by weight, 5~35 parts by weight, is stirred with the speed of 40~90 r/min
It mixes, stops stirring when the liquid to be mixed to homogeneous transparent, stand at room temperature, cooling obtains oil sludge and sand cleaning agent.
6. environment-friendly type oil sludge and sand cleansing composition as claimed in any one of claims 1 to 5 petrochemical industry, auto industry,
The application of aerospace, building, weapons.
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| CN106580235A (en) * | 2016-12-19 | 2017-04-26 | 东莞市广信知识产权服务有限公司 | Cleaning suite for light fixture |
| CN110643352A (en) * | 2018-12-14 | 2020-01-03 | 马鞍山微晶光电材料有限公司 | Red light quantum dot microcrystal composite master batch |
| CN110117141A (en) * | 2019-04-24 | 2019-08-13 | 广西博世科环保科技股份有限公司 | A kind of environment-friendly type oily sludge cleaning agent and its application method |
| CN113813929B (en) * | 2021-06-30 | 2023-10-24 | 盘锦富瑞达环保科技有限公司 | Preparation method of oil sludge treatment agent |
| CN113636739B (en) * | 2021-08-24 | 2023-11-21 | 山东理工大学 | Recycling treatment method of oil-containing sludge for rubber filling auxiliary agent |
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| CN102618396A (en) * | 2012-03-07 | 2012-08-01 | 东莞市安美润滑科技有限公司 | Mechanical equipment cleaning liquid |
| CN103357388A (en) * | 2013-08-05 | 2013-10-23 | 新乡医学院 | Preparation method for cyclodextrin- graphene microsphere used for water purification |
| CN104403818A (en) * | 2014-09-30 | 2015-03-11 | 中国石油天然气股份有限公司 | Petroleum mud sand cleaning compound |
| CN104560441A (en) * | 2014-12-22 | 2015-04-29 | 中国科学院烟台海岸带研究所 | Surface cleaning agent for water based crude oil pollution site |
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