CN104559789A - Water-in-water sand-containing multicolor paint and manufacturing method thereof - Google Patents
Water-in-water sand-containing multicolor paint and manufacturing method thereof Download PDFInfo
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- CN104559789A CN104559789A CN201510036064.1A CN201510036064A CN104559789A CN 104559789 A CN104559789 A CN 104559789A CN 201510036064 A CN201510036064 A CN 201510036064A CN 104559789 A CN104559789 A CN 104559789A
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- Prior art keywords
- water
- sand
- preparation
- color lacquer
- sand mold
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
Abstract
The invention discloses a water-in-water sand-containing multicolor paint and a manufacturing method thereof. The water-in-water sand-containing multicolor paint is prepared by mixing a multicolor paint, a sand preparation and a magnesium silicate solution, wherein the multicolor paint is composed of water, a film forming material, a pigment paste, an inorganic filler and an additive; and the sand preparation is composed of water, quartz sand, a surfactant, polymer microspheres, a polyphosphate chelator and a hydrophobic modified block copolymer. Compared with the prior art, the decorative effect of the multicolor paint can achieve the same effect as the granite burnt surface, and the paint has the advantages of high stability, proper suspensibility and excellent decorative effect and is convenient to use.
Description
Technical field
The present invention relates to paint field, in particular a kind of water-water is containing sand mold multi-color lacquer and preparation method thereof.
Background technology
Grouan face of burning is the normally stone material decorative effect that can reach, and the texture of bright-colored color colorful for water-water and sand grains is combined, can create the paradoxical effect that grouan burns face.Its gordian technique will solve containing the permanent suspension of the color grain of sand in system and compatibility problems.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of water-water containing sand mold multi-color lacquer and preparation method thereof.
The present invention is achieved by the following technical solutions: a kind of water-water is containing sand mold multi-color lacquer, it is characterized in that: water-water is become with magnesosilicate solution mixing system by colorful colored paint, sand preparation containing sand mold multi-color lacquer, and colorful colored paint is made up of according to weight percent following component:
Sand preparation is made up of according to weight percent following component:
The mass ratio of colorful colored paint and sand preparation is 3:1 ~ 1:1, and polyphosphoric acid salt sequestrant is through organically-modified polyphosphoric acid salt sequestrant.
As further improvement of these options, the polymer microballoon including the hollow structure of rare gas element that polymer microballoon selects Eka Chemicals (Suzhou) company limited to produce.
As further improvement of these options, polyethylene oxide alkyl ethers selected by tensio-active agent, and the HLB value of polyethylene oxide alkyl ethers is 9 ~ 15.
As further improvement of these options, quartz sand adopts 80-200 object white quartz sand.
Present invention also offers a kind of method making above-mentioned water-water and contain sand mold multi-color lacquer, it is characterized in that step is as follows:
Step one: the preparation of colorful colored paint, takes mineral filler and additive by proportioning, in water, adds film forming matter after grinding distribution, adds color paste toning again, obtain colorful colored paint after stirring paint;
Step 2: the preparation of sand preparation, adds polymer microballoon, hydrophobically modified segmented copolymer, polyphosphoric acid salt sequestrant, quartz sand and tensio-active agent by proportioning in water, obtains sand preparation after fully stirring;
Step 3: join paint and make a little, after the sand preparation that colorful colored paint step one obtained and step 2 obtain is mixed in proportion, makes a little in magnesosilicate solution, then adds the emulsion that film forming matter and water forms and obtain water-water containing sand mold multi-color lacquer.
As further improvement of these options, also comprise step 4, water-water step 3 obtained is adjusted to 7-10 containing the pH value buffer reagent of sand mold multi-color lacquer.
The present invention has the following advantages compared to existing technology: decorative effect can reach the equivalent effect that grouan burns face, paint vehicle good stability, and the suspension of paint vehicle is suitable, easy to use, and decorative effect is excellent.
Embodiment
Elaborate to embodiments of the invention below, the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
A kind of water-water is become with magnesosilicate solution mixing system by colorful colored paint, sand preparation containing sand mold multi-color lacquer, and colorful colored paint is made up of according to weight percent following component:
Sand preparation is made up of according to weight percent following component:
The mass ratio of colorful colored paint and sand preparation is 3:1, and polyphosphoric acid salt sequestrant is through organically-modified polyphosphoric acid salt sequestrant.
By adding sand preparation, utilizing the quartz sand in sand preparation to be combined with the bright-colored color of colorful colored paint, the paradoxical effect that grouan burns face can be createed.But after being doped with quartz sand in the suspended particle that colorful colored paint is formed, density increases greatly, cause sedimentation very serious, cannot service requirements be met.In order to address this problem, we add polymer microballoon in sand preparation, and containing rare gas element in polymer microballoon, its density is very low, can reduce the density containing the colorful suspended particle of sand after interpolation, can realize suspending in the solution.In actual applications, we find that inorganic quartz sand is with the problem that there is consistency between organic polymer microballoon, can because the diffusing phenomenon of colorful particle occurs two-phase laminated flow after the water-water configured is long placed in containing sand multi-color lacquer.Add polyphosphoric acid salt sequestrant etc. and effectively can solve problems, because polyphosphoric acid salt can carry out chelating with sand surface, hydrophobically modified segmented copolymer is with the easier affinity of polymer microballoon, like this through organically-modified polyphosphoric acid salt with hydrophobically modified segmented copolymer in conjunction with time, just greatly strengthen inorganic sand with the consistency of polymer microballoon and bonding force, simultaneously owing to having carried out hydrophobically modified to segmented copolymer, make to make the suspended particle formed a little and there is water tolerance, can not dissolve at short notice, thus ensure the effect of multi-color lacquer.
The polymer microballoon including the hollow structure of rare gas element that polymer microballoon selects Eka Chemicals (Suzhou) company limited to produce.The diameter of microballoon is 20 μm, and it is scattered in multi-color lacquer, and does not affect outward appearance and the result of use of multi-color lacquer, adds a small amount of microballoon and namely can reach service requirements.
Polyethylene oxide alkyl ethers selected by tensio-active agent, and the HLB value of polyethylene oxide alkyl ethers is 9 ~ 15.
Quartz sand adopts 80-200 object white quartz sand.Can be good at the effect of imitating baked wheaten cake face by the quartz sand adding this kind of size, use white quartz sand to mix colours very easily.
Embodiment 2
A kind of water-water is become with magnesosilicate solution mixing system by colorful colored paint, sand preparation containing sand mold multi-color lacquer, and colorful colored paint is made up of according to weight percent following component:
Sand preparation is made up of according to weight percent following component:
The mass ratio of colorful colored paint and sand preparation is 2:1, and polyphosphoric acid salt sequestrant is through organically-modified polyphosphoric acid salt sequestrant.
By adding sand preparation, utilizing the quartz sand in sand preparation to be combined with the bright-colored color of colorful colored paint, the paradoxical effect that grouan burns face can be createed.But after being doped with quartz sand in the suspended particle that colorful colored paint is formed, density increases greatly, cause sedimentation very serious, cannot service requirements be met.In order to address this problem, we add polymer microballoon in sand preparation, and containing rare gas element in polymer microballoon, its density is very low, can reduce the density containing the colorful suspended particle of sand after interpolation, can realize suspending in the solution.In actual applications, we find that inorganic quartz sand is with the problem that there is consistency between organic polymer microballoon, can because the diffusing phenomenon of colorful particle occurs two-phase laminated flow after the water-water configured is long placed in containing sand multi-color lacquer.Add polyphosphoric acid salt sequestrant etc. and effectively can solve problems, because polyphosphoric acid salt can carry out chelating with sand surface, hydrophobically modified segmented copolymer is with the easier affinity of polymer microballoon, like this through organically-modified polyphosphoric acid salt with hydrophobically modified segmented copolymer in conjunction with time, just greatly strengthen inorganic sand with the consistency of polymer microballoon and bonding force simultaneously owing to having carried out hydrophobically modified to segmented copolymer, make to make the suspended particle formed a little and there is water tolerance, can not dissolve at short notice, thus ensure the effect of multi-color lacquer.
The polymer microballoon including the hollow structure of rare gas element that polymer microballoon selects Eka Chemicals (Suzhou) company limited to produce.The diameter of microballoon is 20 μm, and it is scattered in multi-color lacquer, and does not affect outward appearance and the result of use of multi-color lacquer, adds a small amount of microballoon and namely can reach service requirements.
Polyethylene oxide alkyl ethers selected by tensio-active agent, and the HLB value of polyethylene oxide alkyl ethers is 9 ~ 15.
Quartz sand adopts 80-200 object white quartz sand.Can be good at the effect of imitating baked wheaten cake face by the quartz sand adding this kind of size, use white quartz sand to mix colours very easily.
Embodiment 3
A kind of water-water is become with magnesosilicate solution mixing system by colorful colored paint, sand preparation containing sand mold multi-color lacquer, and colorful colored paint is made up of according to weight percent following component:
Sand preparation is made up of according to weight percent following component:
The mass ratio of colorful colored paint and sand preparation is 1:1, and polyphosphoric acid salt sequestrant is through organically-modified polyphosphoric acid salt sequestrant.
By adding sand preparation, utilizing the quartz sand in sand preparation to be combined with the bright-colored color of colorful colored paint, the paradoxical effect that grouan burns face can be createed.But after being doped with quartz sand in the suspended particle that colorful colored paint is formed, density increases greatly, cause sedimentation very serious, cannot service requirements be met.In order to address this problem, we add polymer microballoon in sand preparation, and containing rare gas element in polymer microballoon, its density is very low, can reduce the density containing the colorful suspended particle of sand after interpolation, can realize suspending in the solution.In actual applications, we find that inorganic quartz sand is with the problem that there is consistency between organic polymer microballoon, can because the diffusing phenomenon of colorful particle occurs two-phase laminated flow after the water-water configured is long placed in containing sand multi-color lacquer.Add polyphosphoric acid salt sequestrant etc. and effectively can solve problems, because polyphosphoric acid salt can carry out chelating with sand surface, hydrophobically modified segmented copolymer is with the easier affinity of polymer microballoon, like this through organically-modified polyphosphoric acid salt with hydrophobically modified segmented copolymer in conjunction with time, just greatly strengthen inorganic sand with the consistency of polymer microballoon and bonding force simultaneously owing to having carried out hydrophobically modified to segmented copolymer, make to make the suspended particle formed a little and there is water tolerance, can not dissolve at short notice, thus ensure the effect of multi-color lacquer.
The polymer microballoon including the hollow structure of rare gas element that polymer microballoon selects Eka Chemicals (Suzhou) company limited to produce.The diameter of microballoon is 20 μm, and it is scattered in multi-color lacquer, and does not affect outward appearance and the result of use of multi-color lacquer, adds a small amount of microballoon and namely can reach service requirements.
Polyethylene oxide alkyl ethers selected by tensio-active agent, and the HLB value of polyethylene oxide alkyl ethers is 9 ~ 15.
Quartz sand adopts 80-200 object white quartz sand.Can be good at the effect of imitating baked wheaten cake face by the quartz sand adding this kind of size, use white quartz sand to mix colours very easily.
Embodiment 4
Make the method for water-water containing sand mold multi-color lacquer, its step is as follows:
Step one: the preparation of colorful colored paint, takes mineral filler and additive by proportioning, in water, adds film forming matter after grinding distribution, adds color paste toning again, obtain colorful colored paint after stirring paint;
Step 2: the preparation of sand preparation, adds polymer microballoon, hydrophobically modified segmented copolymer, polyphosphoric acid salt sequestrant, quartz sand and tensio-active agent by proportioning in water, obtains sand preparation after fully stirring;
Step 3: join paint and make a little, after the sand preparation that colorful colored paint step one obtained and step 2 obtain is mixed in proportion, makes a little in magnesosilicate solution, then adds the emulsion that film forming matter and water forms and obtain water-water containing sand mold multi-color lacquer.
Step 4: water-water step 3 obtained is adjusted to 7-10 containing the pH value buffer reagent of sand mold multi-color lacquer.The pH value of this scope contributes to ensureing that the stable of polyphosphoric acid salt makes it better play a role, and weakly alkaline environment can help anticorrosion with coat simultaneously.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (7)
1. water-water is containing a sand mold multi-color lacquer, it is characterized in that: described water-water is become with magnesosilicate solution mixing system by colorful colored paint, sand preparation containing sand mold multi-color lacquer, and described colorful colored paint is made up of according to weight percent following component:
Described sand preparation is made up of according to weight percent following component:
The mass ratio of described colorful colored paint and sand preparation is 3:1 ~ 1:1, and described polyphosphoric acid salt sequestrant is through organically-modified polyphosphoric acid salt sequestrant.
2. a kind of water-water, containing sand mold multi-color lacquer, is characterized in that: the polymer microballoon including the hollow structure of rare gas element that described polymer microballoon selects Eka Chemicals (Suzhou) company limited to produce as claimed in claim 1.
3. a kind of water-water is containing sand mold multi-color lacquer as claimed in claim 1, and it is characterized in that: polyethylene oxide alkyl ethers selected by described tensio-active agent, the HLB value of described polyethylene oxide alkyl ethers is 9 ~ 15.
4. a kind of water-water, containing sand mold multi-color lacquer, is characterized in that as claimed in claim 1: described quartz sand adopts 80-200 object white quartz sand.
5. a kind of water-water, containing sand mold multi-color lacquer, is characterized in that as claimed in claim 1: described a kind of water-water is 7 ~ 10 containing the pH value of sand mold multi-color lacquer.
6. make a kind of water-water as claimed in claim 1 and, containing a method for sand mold multi-color lacquer, it is characterized in that step is as follows:
Step one: the preparation of colorful colored paint, takes mineral filler and additive by proportioning, in water, adds film forming matter after grinding distribution, adds color paste toning again, obtain colorful colored paint after stirring paint;
Step 2: the preparation of sand preparation, adds polymer microballoon, hydrophobically modified segmented copolymer, polyphosphoric acid salt sequestrant, quartz sand and tensio-active agent by proportioning in water, obtains sand preparation after fully stirring;
Step 3: join paint and make a little, after the sand preparation that colorful colored paint step one obtained and step 2 obtain is mixed in proportion, makes a little in magnesosilicate solution, then adds the emulsion that film forming matter and water forms and obtain water-water containing sand mold multi-color lacquer.
7. make the method for a kind of water-water containing sand mold multi-color lacquer as claimed in claim 6, it is characterized in that: also comprise step 4, water-water step 3 obtained is adjusted to 7-10 containing the pH value buffer reagent of sand mold multi-color lacquer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510036064.1A CN104559789B (en) | 2015-01-23 | 2015-01-23 | A kind of water-water is containing sand mold multi-color lacquer and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510036064.1A CN104559789B (en) | 2015-01-23 | 2015-01-23 | A kind of water-water is containing sand mold multi-color lacquer and preparation method thereof |
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| CN104559789A true CN104559789A (en) | 2015-04-29 |
| CN104559789B CN104559789B (en) | 2016-02-10 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860590A (en) * | 2016-04-05 | 2016-08-17 | 江苏海明斯新材料科技有限公司 | Preparation method of modified hectorite for water-in-water multicolor paint protecting adhesives |
| CN115820028A (en) * | 2021-09-28 | 2023-03-21 | 立邦涂料（中国）有限公司 | Expandable hollow microsphere, novel hollow material and application of novel hollow material in sand-containing stone-like coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010006987A1 (en) * | 2008-07-16 | 2010-01-21 | Hossein Maleki | Siliceous building material mixture |
| CN102181196A (en) * | 2011-01-24 | 2011-09-14 | 张兴艺 | Water-in-water colorful stone simulated paint |
| CN104231818A (en) * | 2014-08-29 | 2014-12-24 | 亚士漆(上海)有限公司 | Water-in-water colored sand wall texture coating and preparation method thereof |
| CN104250499A (en) * | 2013-06-28 | 2014-12-31 | 上海墙特节能材料有限公司 | Rough granite-simulative water-in-water colorful textural paint and preparation method thereof |
-
2015
- 2015-01-23 CN CN201510036064.1A patent/CN104559789B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010006987A1 (en) * | 2008-07-16 | 2010-01-21 | Hossein Maleki | Siliceous building material mixture |
| CN102181196A (en) * | 2011-01-24 | 2011-09-14 | 张兴艺 | Water-in-water colorful stone simulated paint |
| CN104250499A (en) * | 2013-06-28 | 2014-12-31 | 上海墙特节能材料有限公司 | Rough granite-simulative water-in-water colorful textural paint and preparation method thereof |
| CN104231818A (en) * | 2014-08-29 | 2014-12-24 | 亚士漆(上海)有限公司 | Water-in-water colored sand wall texture coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860590A (en) * | 2016-04-05 | 2016-08-17 | 江苏海明斯新材料科技有限公司 | Preparation method of modified hectorite for water-in-water multicolor paint protecting adhesives |
| CN115820028A (en) * | 2021-09-28 | 2023-03-21 | 立邦涂料（中国）有限公司 | Expandable hollow microsphere, novel hollow material and application of novel hollow material in sand-containing stone-like coating |
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| Publication number | Publication date |
|---|---|
| CN104559789B (en) | 2016-02-10 |
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Denomination of invention: Water-in-water sand-containing multicolor paint and manufacturing method thereof Effective date of registration: 20180330 Granted publication date: 20160210 Pledgee: Anhui Changfeng Keyuan village bank Limited by Share Ltd Pledgor: ANHUI BENJIAMIN PAINT CO., LTD. Registration number: 2018340000092 |