CN104559693A - Powder coating for electrical oil heater - Google Patents
Powder coating for electrical oil heater Download PDFInfo
- Publication number
- CN104559693A CN104559693A CN201410847852.4A CN201410847852A CN104559693A CN 104559693 A CN104559693 A CN 104559693A CN 201410847852 A CN201410847852 A CN 201410847852A CN 104559693 A CN104559693 A CN 104559693A
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- CN
- China
- Prior art keywords
- powder coating
- agent
- oil
- parts
- electric heating
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a powder coating for an electrical oil heater. The powder coating comprises the following components in parts by weight: 300+/-10 parts of saturated polyester resin with the acid value of 72-78 mgKOH/g, 300+/-5 parts of epoxy resin with the epoxy equivalent of 710-875 g/eq, 350+/-5 parts of barium sulfate, 40+/-1 parts of an assistant and 10+/-1 parts of pigment, wherein the assistant is a mixture of a leveler, a degasser, a yellowing-resistant agent, wax powder and a charging additive; the charging additive is a polar fatty acid ester charging additive and comprises a short-chain fatty acid ester charging additive and a long-chain fatty acid ester charging additive. The components are premixed and extruded by an extruder at 90-105 DEG C to form sheets and then the sheets are ground and screened to obtain heat-resistant powder. The powder coating does not contain toxic raw materials, is suitable for spraying the surface of a special member which is relatively high in use temperature and complex in structure and is provided with a plurality of included angles, is simple in production process and use method, nontoxic, free of environmental pollution, low in cost and remarkable in economic and social benefits.
Description
Technical field
The present invention relates to chemical powder paint field, particularly relate to a kind of electric heating installation using oil as medium powder coating.
Background technology
Powder coating be one not containing solvent, 100% solid powdery coating, has solvent-free, pollution-free, recyclable, environmental protection, the saving energy and resource, reduces labor intensity and film physical strength high.According to the environment for use of the device of institute's application, as the electrical equipment used under hot conditions, there is higher requirement to the resistance toheat of powder coating.In addition, some of them steel and iron member surface, complex structure, angle are dark, the how upper powder difficulty of groove, therefore higher requirement is had to the powder coating of such device of application, and ordinary powder coating is complicated at spray structure, angle is dark, there will be spraying and do not go up or spray non-uniform phenomenon during the many component of groove.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of for being sprayed on that use temperature is higher and structure is more complicated, the electric heating installation using oil as medium powder coating of many angles, many grooves.
For this reason, technical scheme of the present invention is as follows:
A kind of electric heating installation using oil as medium powder coating, be made up of the component of following weight parts:
Wherein, the saturated polyester resin of described vibrin to be acid number be 72 ~ 78mgKOH/g, the epoxy resin of described epoxy resin to be epoxy equivalent (weight) be 710 ~ 875g/eq.
Described growth agent is polarity fatty acid ester growth agent, comprise short-chain aliphatic ester class growth agent and long chain fatty acid ester class growth agent, and the two weight ratio is 3 ~ 5:5 ~ 7.Two kinds of growth agents are by used in combination with certain proportion, and increase upper powder amount when being conducive to powder paint, overcome electrostatic shielding, even if element structure is complicated, angle dark, groove is many also evenly can go up powder, and without electrostatic shielding phenomenon.
Described auxiliary agent is the mixture of flow agent, air release agent, wax powder, anti-yellowing dose and growth agent.
Preferably, the weight ratio of described flow agent, air release agent, wax powder, anti-yellowing dose and growth agent is 2:1:1:2:2.
Preferably, described flow agent is acrylate flow agent.
Preferably, described wax powder is polytetrafluoro class wax powder.
Preferably, described air release agent is st-yrax.
Preferably, described anti-yellowing dose is anti-yellowing dose of phosphorous acid esters.
In described auxiliary agent, there is one to flow and drying and forming-film process after the interpolation of flow agent makes this powder paint, then progressively form smooth, smooth, a uniform film; Described air release agent makes the gas in coating process in application ground be easy to effusion, and the powder coating like this after solidification is smooth bright and clean, eliminates holiday; Described wax powder makes hand feel and drape after powder coating and their application; Described anti-yellowing dose add can suppress film yellowing effectively, also can stable reproduction in hot environment even if make film color be in for a long time.
Barium sulfate in described powder coating component is conducive to this powder coating as filler increases the scratch resistant effect of hardness when powder film forming.
Described pigment is the high-carbon black pigment MA100 that Mitsubishi pigment company limited produces, and this pigment plays to hide and increases gorgeous effect in formula.
This electric heating installation using oil as medium is simple by powder coating preparation technology, and by each component pre-mixing taken according to formula, the time is 4 ~ 6 minutes, extrudes in flakes at 90 ~ 105 DEG C of forcing machines, finally pulverizes and sieves and namely obtains described electric heating installation using oil as medium powder coating.
The powder average particle size of described powder coating is about 30 ~ 40um.
In the R&D process to this electric heating installation using oil as medium powder coating, when selected vibrin and epoxy resin type or charging capacity are slightly different, great performance difference will be produced.Therefore, contriver carries out test of many times through the various ingredients content proportioning of producing different company, obtains the formula of this electric heating installation using oil as medium powder coating.
This electric heating installation using oil as medium is simple by powder coating using method, when spraying device, after powder is put into fluidizing bucket, can start spraying with electrostatic power unit device.
The present invention selects suitable material, electric heating installation using oil as medium powder coating is obtained after being aided with corresponding additive mixing, this powder coating is not containing toxogen material, be applicable to spraying use temperature higher, the special component surface of complex structure, many angles simultaneously, and production technique and using method are simply, nontoxic non-environmental-pollution, cost is low, and economic and social benefit is remarkable.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described, but the present invention is not only confined to following examples.
In the following embodiments, described vibrin is the 5086 type vibrin that Hangzhou Zhong Fa company limited produces; The 04T type epoxy resin that described epoxy resin adopts Anhui Heng Yuan company limited to produce; Described acrylate flow agent is the 896 type flow agents that moral modest (Shanghai) Chemical Co., Ltd. provides; The polytetrafluoro micronization wax powder that described polytetrafluoro class wax powder provides for Qingdao Economic development company limited; The st-yrax that described air release agent provides for Ningbo South Sea Company; Anti-yellowing dose of described phosphorous acid esters are anti-yellowing dose of the A005 type that Guangzhou Tian Long company limited produces; The A012 type long chain fatty acid ester class growth agent that described growth agent provides for Hefei Ketai Co. Ltd. and A016 type short-chain aliphatic ester class growth agent; The high-carbon black pigment MA100 that described pigment adopts Mitsubishi pigment company limited to produce.
Embodiment 1
Adopt formula as follows:
Embodiment 2
Adopt formula as follows:
Embodiment 3
Adopt formula as follows:
By the above-mentioned formula composition each component of accurate weighing respectively, be placed in high-speed mixer mixing 4 ~ 6 minutes, extrude in flakes in an extruder at 90 ~ 105 DEG C of temperature condition, grind as median size is at the powder granule of 30-40um with powder coating pulverizing mill afterwards, powder sieves by thing as qualified product with 180 eye mesh screens.
The powder coating produced by above-mentioned production technique adopts high pressure electrostatic painting voltage to be 30 ~ 70kv, and average film thickness is 60 ~ 80um, and condition of cure is high temperature 180 DEG C solidification 20 minutes.
Main film performance is as follows:
Guang Ze≤90 degree;
Chong Ji≤± 50kg.cm;
Sticking power≤1 grade;
Salt spray resistance line place in 500 hours: unidirectional corrosion≤2.0 ㎜, uncrossed district: without exception;
Resistance to subtractive: 5wt%NaOH 168h is without exception;
Acid resistance: 3wt%HCl 240h is without exception.
According to the electric heating installation using oil as medium powder coating and their application of preparation of filling a prescription in embodiment 1 ~ 3 after electric heating installation using oil as medium, plate face is level and smooth without tangerine line, and evenly, at angle or groove all without electrostatic shielding phenomenon, soft brightness is high, no sag phenomenon for upper powder.Simultaneously, tested by the resistance toheat of German BKY CV light splitting color difference meter to coating, color after toasting 24h by this thermotolerance powder coating at 180 DEG C of temperature with baking before powder coating color carry out chromatism test, test result: powder coating colour-change is little, value of chromatism △ E is between 0.5 ~ 0.8, namely high temperature also can not affect the quality of paint spraying at collector surface for a long time, has good resistance toheat.
Visible, this electric heating installation using oil as medium powder coating resistance toheat is good, and simultaneously the performance such as shock resistance, sticking power, upper powder effect all meets the requirements.Higher than ordinary powder coating angle powder utilization, overcome electrostatic shielding phenomenon, electrical equipment ground is played to the effect of protection simultaneously.
Claims (6)
1. an electric heating installation using oil as medium powder coating, is characterized in that, is mixed with forms by the component of following weight parts:
Wherein, the saturated polyester resin of described vibrin to be acid number be 72 ~ 78mgKOH/g; The epoxy resin of described epoxy resin to be epoxy equivalent (weight) be 710 ~ 875g/eq, and the two weight ratio 1:1; Described auxiliary agent is the mixture of flow agent, air release agent, wax powder, anti-yellowing dose and growth agent; Described growth agent is polarity fatty acid ester growth agent, comprise short-chain aliphatic ester class growth agent and long chain fatty acid ester class growth agent, and the two weight ratio is 3 ~ 5:5 ~ 7.
2. electric heating installation using oil as medium powder coating according to claim 1, is characterized in that, the weight ratio of described flow agent, air release agent, wax powder, anti-yellowing dose and growth agent is 2:1:1:2:2.
3. electric heating installation using oil as medium powder coating according to claim 1 or 2, is characterized in that, described flow agent is acrylate flow agent.
4. electric heating installation using oil as medium powder coating according to claim 1 and 2, is characterized in that, described wax powder is polytetrafluoro class wax powder.
5. electric heating installation using oil as medium powder coating according to claim 1 and 2, is characterized in that, described air release agent is st-yrax.
6. electric heating installation using oil as medium powder coating according to claim 1 and 2, is characterized in that, described anti-yellowing dose is anti-yellowing dose of phosphorous acid esters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410847852.4A CN104559693A (en) | 2014-12-31 | 2014-12-31 | Powder coating for electrical oil heater |
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CN201410847852.4A CN104559693A (en) | 2014-12-31 | 2014-12-31 | Powder coating for electrical oil heater |
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CN104559693A true CN104559693A (en) | 2015-04-29 |
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CN201410847852.4A Pending CN104559693A (en) | 2014-12-31 | 2014-12-31 | Powder coating for electrical oil heater |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110804329A (en) * | 2019-11-29 | 2020-02-18 | 老虎表面技术新材料(清远)有限公司 | Powder coating facilitating powdering and resisting solidification and sliding and application thereof |
CN111218141A (en) * | 2019-11-29 | 2020-06-02 | 老虎表面技术新材料(清远)有限公司 | A energizer, powder coating and automobile wheel hub for powder coating |
CN113930130A (en) * | 2021-11-04 | 2022-01-14 | 淮安凯佳粉末涂料有限公司 | Thermosetting powder coating |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US20060115665A1 (en) * | 2004-12-01 | 2006-06-01 | Helene Bolm | Powder coating composition for coating surfaces of heat-sensitive substrates |
CN103319973A (en) * | 2013-06-06 | 2013-09-25 | 浙江华彩化工有限公司 | Smokeless odorless powder paint used in electric oil heater |
CN103709909A (en) * | 2013-12-19 | 2014-04-09 | 安徽神剑新材料股份有限公司 | Powder paint applied to medium-density fiberboard, and preparation method and application thereof |
CN104087135A (en) * | 2014-07-04 | 2014-10-08 | 蒋炳 | Spraying powder used for household appliance evaporator and preparation method thereof |
-
2014
- 2014-12-31 CN CN201410847852.4A patent/CN104559693A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060115665A1 (en) * | 2004-12-01 | 2006-06-01 | Helene Bolm | Powder coating composition for coating surfaces of heat-sensitive substrates |
CN103319973A (en) * | 2013-06-06 | 2013-09-25 | 浙江华彩化工有限公司 | Smokeless odorless powder paint used in electric oil heater |
CN103709909A (en) * | 2013-12-19 | 2014-04-09 | 安徽神剑新材料股份有限公司 | Powder paint applied to medium-density fiberboard, and preparation method and application thereof |
CN104087135A (en) * | 2014-07-04 | 2014-10-08 | 蒋炳 | Spraying powder used for household appliance evaporator and preparation method thereof |
Non-Patent Citations (1)
Title |
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南仁植: "《粉末涂料与涂装技术》", 31 August 2008 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110804329A (en) * | 2019-11-29 | 2020-02-18 | 老虎表面技术新材料(清远)有限公司 | Powder coating facilitating powdering and resisting solidification and sliding and application thereof |
CN111218141A (en) * | 2019-11-29 | 2020-06-02 | 老虎表面技术新材料(清远)有限公司 | A energizer, powder coating and automobile wheel hub for powder coating |
CN110804329B (en) * | 2019-11-29 | 2022-08-30 | 老虎表面技术新材料(清远)有限公司 | Powder coating facilitating powdering and resisting solidification and sliding and application thereof |
CN113930130A (en) * | 2021-11-04 | 2022-01-14 | 淮安凯佳粉末涂料有限公司 | Thermosetting powder coating |
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