CN104403517A - High imitation electroplating silver powder paint and preparation method thereof - Google Patents

High imitation electroplating silver powder paint and preparation method thereof Download PDF

Info

Publication number
CN104403517A
CN104403517A CN201410633548.XA CN201410633548A CN104403517A CN 104403517 A CN104403517 A CN 104403517A CN 201410633548 A CN201410633548 A CN 201410633548A CN 104403517 A CN104403517 A CN 104403517A
Authority
CN
China
Prior art keywords
powder
powder coating
electrosilvering
silver powder
imitates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410633548.XA
Other languages
Chinese (zh)
Inventor
罗绵生
史中平
马会刚
杨小华
肖龙和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Kinte Industrial Co Ltd
Original Assignee
Guangzhou Kinte Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Kinte Industrial Co Ltd filed Critical Guangzhou Kinte Industrial Co Ltd
Priority to CN201410633548.XA priority Critical patent/CN104403517A/en
Publication of CN104403517A publication Critical patent/CN104403517A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/031Powdery paints characterised by particle size or shape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • C09D5/035Coloring agents, e.g. pigments
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high imitation electroplating silver powder paint. The paint comprises transparent paint basic powder and silver powder, and the transparent paint basic powder contains a silver powder directional arranging agent. The invention also discloses a binding preparation method of the powdery paint. The silver powder directional arranging agent is added into the transparent paint basic powder, then under the binding assistance of a binding machine, the silver powder migrates to the surface of melt powdery paint with high viscosity, the silver powder is well arranged under the effect of the directional arranging agent, and a reflective chromium-coated mirror metal-liked effect can be achieved on the surface of the coating.

Description

A kind of high imitative electrosilvering powder coating and preparation method thereof
Technical field
The present invention relates to a kind of powder coating, particularly relate to a kind of high imitative electrosilvering powder coating.Meanwhile, the invention still further relates to the preparation method of the imitative electrosilvering powder coating of this height.
Background technology
Powder coating has the characteristic such as performance, good decorative property, use safety that is energy-conservation, VOC free discharge, and domestic powder coating technology development in recent years rapidly.Powder coating is as decorative material, and plentiful along with what live, people are no longer limited to the requirement of powder coating coating single color.There is the binding powder coating of metal appearance, generally acknowledged it is art of powder coatings medium and high-grade goods by people, be subject to the favorable comment of the market segments such as household electrical appliances, furniture and automobile, slowly promote in every field and come.The coating that height wherein imitates electrosilvering powder coating has excellent mirror effect and beautiful outward appearance, extremely the pursuing of people.But current height imitates the coating gloss partially dark (< 100GU) of electrosilvering powder coating, and coating has dim spot pockety and shrinkage cavity, the metallic membrane effect of coatingsurface reflective chromium plating minute surface is unsatisfactory.
Summary of the invention
The object of this invention is to provide a kind of high imitative electrosilvering powder coating, this powder coating coating gloss > 100GU, create the metal effect of reflective picture chromium plating minute surface and beautiful appearance effect.
Another object of the present invention is to provide above-mentioned height to imitate the binding method of electrosilvering powder coating.
First object of the present invention is achieved through the following technical solutions: a kind of high imitative electrosilvering powder coating, comprises powder at the bottom of Clear paint and silver powder, wherein, align agent in powder at the bottom of described Clear paint containing silver powder.
Agent is aligned containing appropriate silver powder in powder at the bottom of Clear paint of the present invention, after at the bottom of Clear paint, powder and silver powder are bound, when hot setting, silver powder aligns agent and promotes that silver powder is to melting high viscosity powder coating surface transport, aligning under agent effect, obtaining good aligning, producing the metallic membrane of reflective picture chromium plating minute surface at coatingsurface, make coatingsurface gloss at more than 100GU, increase coating whiteness and metal sense.
Particularly, powder at the bottom of Clear paint of the present invention aligns agent by clear coat binder and silver powder and forms.Wherein, described clear coat binder is convention transparent powder coating, and its component comprises resin and auxiliary agent etc.
In the present invention, with powder coating total mass for Calculation Basis, the mass parts that described silver powder aligns agent is 0.5 ~ 1.5 part, preferably 0.8 ~ 1.2 part.Particularly, it is aldehyde ketone condensation resin that described silver powder aligns agent.Aldehyde ketone condensation resin can guarantee metal-powder mirror effect, can keep enough mechanical propertys and aesthetic appearance simultaneously.As one embodiment of the present of invention, described aldehyde ketone condensation resin is white odorless particle, fusing point 127 ~ 169 DEG C, fugitive constituent≤0.5%, the such as CATB-250 of the various trade mark, CTB-280 and K-100 etc., wherein preferred CATB-250, K-100.
In the present invention, with the total mass of clear coat binder for Calculation Basis, the mass parts of the resin in described clear coat binder is 50 ~ 95 parts, and it comprises the conventional resin of all kinds powder coating such as epoxy resin, vibrin, urethane resin and acrylic resin.Described auxiliary agent is conven-tional adjuvants used for powder coating, and its mass parts is 1 ~ 10 part, and it comprises one or more the mixing in flow agent, defoamer, st-yrax and ventilating agent etc.
Also solidifying agent can be comprised in clear coat binder of the present invention, this solidifying agent mass parts is 1 ~ 50 part, and it comprises the corresponding solidifying agent of all kinds powder coating such as epoxy resin, isocyanuric acid three-glycidyl ester (TGIC), amine curing agent and beta-hydroxy alkylamide (HAA).
In the present invention, the part by weight 100:0.003-100:0.015 of powder and silver powder at the bottom of described Clear paint, preferred 100:0.008.
Described silver powder is metallic leafing pigments.Particularly, described metallic leafing pigments is metallic aluminium pigment.Described metallic aluminium pigment is the floating type aluminium pigment of particle diameter 4-20 μm, comprises SCHLENK company Powdal 170XB, Powdal 130; Benda-Lutz company 2091,7080,2081 and ECKART company PC100, Chromal IV etc.
Second object of the present invention is achieved through the following technical solutions: the binding method of high imitative electrosilvering powder coating, comprises the following steps:
(1) take powder at the bottom of Clear paint in proportion and silver powder mixes, be placed in binding machine;
(2) in room temperature environment, pass into shielding gas in bonding machines and bind;
(3) powder completing nation fixed sieves, and obtains high imitative electrosilvering metal powder coating.
Rotating speed 400 ~ the 1000n/min of bonding machines in step of the present invention (2), rotation time arranges 3 ~ 7min.Preferred rotating speed 7000 ~ 8000n/min, rotation time arranges 4 ~ 6min, to guarantee that powder at the bottom of Clear paint fully mixes with silver powder in bonding machines equipment, silver powder is produced and aligns effect.
Embodiment
The present invention will be described to enumerate a part of specific examples below, be necessary to herein means out be following specific embodiment only for the invention will be further described, do not represent limiting the scope of the invention.Some nonessential amendments that other people make according to the present invention and adjustment still belong to protection scope of the present invention.
In following examples, bonding machines adopts German HENSCHEL company MB350 model bonding machines group.Rotating speed 400 ~ the 1000n/min of bonding machines in step of the present invention (2), rotation time arranges 3 ~ 7min.Preferred rotating speed 7000 ~ 8000n/min, rotation time arranges 4 ~ 6min, to guarantee that powder at the bottom of powder fully mixes with silver powder in bonding machines equipment, silver powder is produced and aligns effect.
It is aldehyde ketone condensation resin that silver powder aligns agent.Aldehyde ketone condensation resin can guarantee metal-powder mirror effect, can keep enough mechanical propertys and aesthetic appearance simultaneously.As one embodiment of the present of invention, described aldehyde ketone condensation resin is white odorless particle, fusing point 127 ~ 169 DEG C, fugitive constituent≤0.5%, the such as CATB-250 of the various trade mark, CTB-280 and K-100 etc., wherein preferred CATB-250, K-100.
Auxiliary agent is conven-tional adjuvants used for powder coating, comprises one or more the mixing in flow agent, st-yrax, ventilating agent etc.
Silver powder is metallic leafing pigments.Particularly, described metallic leafing pigments is metallic aluminium pigment.Described metallic aluminium pigment is the floating type aluminium pigment of particle diameter 4-20 μm, comprises SCHLENK company Powdal 170XB, Powdal 130; Benda-Lutz company 2091,7080,2081 and ECKART company PC100, Chromal IV etc.
Vibrin NH3307, Guangzhou Qing Tian Resins Corporation produces.
Vibrin SJ4B, Anhui Shenjian New Material Co., Ltd. produces.
Vibrin P5086, Hangzhou Zhong Fa Industrial Co., Ltd. produces.
Epoxy resin R304 mitsui petrochemical industry is produced
The kind floating Chemical Manufacture in epoxy resin E-12 (604) Mount Huang
embodiment 1
Component and weight:
Vibrin P5086 50 parts
Epoxy resin E-12 (604) 50 parts
Flow agent 1.3 parts
St-yrax 0.6 part
K-100 0.8 part
Powder preparation at the bottom of Clear paint:
A () takes vibrin P5086, epoxy resin E-12 (604), flow agent, st-yrax and K-100 in proportion, be placed in compounding jar, fully mixing also broken 1 ~ 10 minute.
B the material after () fragmentation enters twin screw extruder and extrudes; Forcing machine heating and temperature control is at 80 ~ 120 DEG C.
(c) extrude after material be ground into through compressing tablet, cooling, pulverizer the powder that particle diameter (equivalent grain size D50) is 30 ~ 45 um, then screening after namely obtain powder at the bottom of Clear paint.
binding method:
(1) by powder at the bottom of Clear paint and the pre-mixing of metallic leafing pigments Benda-Lutz company 2091, part by weight 100:0.003 ~ 100:0.015, preferred 100:0.008.Take and mix, add in bonding machines.
(2) in room temperature environment, pass into shielding gas in bonding machines and bind.Arrange bonding machines parameter, rotating speed arranges 400-1000n/min, preferably 700 ~ 800 n/min, set of time 5min.
(3) after nation completes surely, gained powder sieves, and obtains high imitative electrosilvering powder coating.
Take out high imitative electrosilvering powder coating, spray plate with electrostatic gun, after baking, both obtain the metal effect that film coated surface produces reflective picture chromium plating minute surface.
embodiment 2
Component and weight:
Vibrin NH3307 93 parts
TGIC 7 parts
Flow agent 1.3 parts
St-yrax 0.6 part
CATB-250 0.8 part
Powder preparation at the bottom of Clear paint:
A () takes vibrin NH3307, TGIC, flow agent, st-yrax and CATB-250 in proportion, be placed in compounding jar, fully mixing also broken 1 ~ 10 minute.
B the material after () fragmentation enters twin screw extruder and extrudes; Forcing machine heating and temperature control is at 80 ~ 120 DEG C.
(c) extrude after material be ground into through compressing tablet, cooling, pulverizer the powder that particle diameter (equivalent grain size D50) is 30 ~ 45 um, then screening after namely obtain powder at the bottom of Clear paint.
nation determines method:
(1) by powder at the bottom of Clear paint and metallic leafing pigments ECKART company Chromal IV pre-mixing, part by weight 100:0.003 ~ 100:0.015, preferred 100:0.008.Take and mix, add in bonding machines.
(2) in room temperature environment, pass into shielding gas in bonding machines and bind.Arrange bonding machines parameter, rotating speed arranges 400-1000n/min, preferably 700 ~ 800 n/min, set of time 5min.
(3) after nation completes surely, gained powder sieves, and obtains high imitative electrosilvering powder coating.
Take out high imitative electrosilvering powder coating, spray plate with electrostatic gun, after baking, both obtain the metal effect that film coated surface produces reflective picture chromium plating minute surface.
embodiment 3
Component and weight are:
Vibrin SJ4B 95 parts
Hydroxyalkyl amide (Primid) 5 parts
Flow agent 1.3 parts
St-yrax 0.6 part
CATB-250 0.8 part
Powder preparation at the bottom of Clear paint:
A () takes vibrin SJ4B, hydroxyalkyl amide, flow agent, st-yrax and CATB-250 in proportion, be placed in compounding jar, fully mixing also broken 1 ~ 10 minute.
B the material after () fragmentation enters twin screw extruder and extrudes; Forcing machine heating and temperature control is at 80 ~ 120 DEG C.
(c) extrude after material be ground into through compressing tablet, cooling, pulverizer the powder that particle diameter (equivalent grain size D50) is 30 ~ 45 um, then screening after namely obtain powder at the bottom of Clear paint.
nation determines method:
(1) by powder at the bottom of Clear paint and metallic leafing pigments SCHLENK company Powdal 170XB pre-mixing, part by weight 100:0.003 ~ 100:0.015, preferred 100:0.008.Take and mix, add in bonding machines.
(2) in room temperature environment, pass into shielding gas in bonding machines and bind.Arrange bonding machines parameter, rotating speed arranges 400-1000n/min, preferably 700 ~ 800 n/min, set of time 5min.
(3) after nation completes surely, gained powder sieves, and obtains high imitative electrosilvering powder coating.
Take out high imitative electrosilvering powder coating, spray plate with electrostatic gun, after baking, both obtain the metal effect that film coated surface produces reflective picture chromium plating minute surface.
embodiment 4
Component and weight are:
Vibrin P5086 50 parts
Epoxy resin R304 50 parts
Flow agent 1.3 parts
St-yrax 0.6 part
CTB-280 0.9 part
Powder preparation at the bottom of Clear paint:
A () takes vibrin P5086, epoxy resin R304, flow agent, st-yrax and CTB-280 in proportion, be placed in compounding jar, fully mixing also broken 1 ~ 10 minute.
B the material after () fragmentation enters twin screw extruder and extrudes; Forcing machine heating and temperature control is at 80 ~ 120 DEG C.
(c) extrude after material be ground into through compressing tablet, cooling, pulverizer the powder that particle diameter (equivalent grain size D50) is 30 ~ 45 um, then screening after namely obtain powder at the bottom of Clear paint.
nation determines method:
(1) by powder at the bottom of Clear paint and the pre-mixing of metallic leafing pigments Benda-Lutz company 2091, part by weight 100:0.003 ~ 100:0.015, preferred 100:0.008.Take and mix, add in bonding machines.
(2) in room temperature environment, pass into shielding gas in bonding machines and bind.Arrange bonding machines parameter, rotating speed arranges 400-1000n/min, preferably 700 ~ 800 n/min, set of time 5min.
(3) after nation completes surely, gained powder sieves, and obtains high imitative electrosilvering powder coating.
Take out high imitative electrosilvering powder coating, spray plate with electrostatic gun, after baking, both obtain the metal effect that film coated surface produces reflective picture chromium plating minute surface.
 
test item:
Test item Inspecting standard or method Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Gloss (60 DEG C) GB/T 9754 ≥100GU ≥100GU ≥100GU ≥100GU
Outward appearance / Mirror effect Mirror effect Mirror effect Mirror effect
Sticking power GB/T 9286 0 grade 0 grade 0 grade 0 grade
Powder utilization / 82% 82% 82% 82%
Shock resistance (50kgcm) GB/T 1732 Positive and negatively to pass through Positive and negatively to pass through Positive and negatively to pass through Positive and negatively to pass through
Bending GB/T 1731 2mm 2mm 2mm 2mm
In above-described embodiment 1 to 4, silver powder also can adopt the metal of different company to float Silver pigments, can add the mixture of one or more when testing, and produces the mirror metal effect of different-effect.

Claims (10)

1. a high imitative electrosilvering powder coating, comprises powder at the bottom of Clear paint and silver powder, it is characterized in that, aligns agent in powder at the bottom of described Clear paint containing silver powder.
2. height according to claim 1 imitates electrosilvering powder coating, it is characterized in that, powder at the bottom of described Clear paint aligns agent by clear coat binder and silver powder and forms.
3. height according to claim 1 imitates electrosilvering powder coating, it is characterized in that, described clear coat binder is convention transparent powder coating, and its component comprises resin, auxiliary agent and solidifying agent.
4. height according to claim 3 imitates electrosilvering powder coating, it is characterized in that, with the total mass of clear coat binder for Calculation Basis, described resin is usual resins used for powder coating, and its mass parts is 50 ~ 95 parts; Described auxiliary agent is conven-tional adjuvants used for powder coating, and its mass parts is 1 ~ 10 part; The mass parts of described solidifying agent is 1 ~ 50 part.
5. the height according to any one of claim 1 ~ 4 imitates electrosilvering powder coating, it is characterized in that, with powder coating total mass for Calculation Basis, it is 0.5 ~ 1.5 part that described silver powder aligns the mass parts of agent in powder coating.
6. height according to claim 5 imitates electrosilvering powder coating, it is characterized in that, it is aldehyde ketone condensation resin that described silver powder aligns agent.
7. height according to claim 6 imitates electrosilvering powder coating, it is characterized in that, the fusing point of described aldehyde ketone condensation resin 127 ~ 169 DEG C, fugitive constituent≤0.5%.
8. height according to claim 5 imitates electrosilvering powder coating, it is characterized in that, the part by weight 100:0.003-100:0.015 of powder and silver powder at the bottom of described Clear paint; Described silver powder is metallic leafing pigments; Described metallic leafing pigments is metallic aluminium pigment; Described metallic aluminium pigment is the floating type aluminium pigment of particle diameter 4 ~ 20 μm.
9. the height described in any one of claim 1 ~ 8 imitates the binding method of electrosilvering powder coating, it is characterized in that, comprises the following steps:
(1) take powder at the bottom of Clear paint in proportion and silver powder mixes, be placed in binding machine;
(2) in room temperature environment, pass into shielding gas in bonding machines and bind;
(3) powder completing nation fixed sieves, and obtains high imitative electrosilvering metal powder coating.
10. height according to claim 9 imitates the binding method of electrosilvering powder coating, it is characterized in that, rotating speed 400 ~ the 1000n/min of bonding machines in described step (2), rotation time arranges 3 ~ 7min, to guarantee that powder at the bottom of Clear paint fully mixes with silver powder in bonding machines equipment, silver powder is produced and aligns effect.
CN201410633548.XA 2014-11-12 2014-11-12 High imitation electroplating silver powder paint and preparation method thereof Pending CN104403517A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410633548.XA CN104403517A (en) 2014-11-12 2014-11-12 High imitation electroplating silver powder paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410633548.XA CN104403517A (en) 2014-11-12 2014-11-12 High imitation electroplating silver powder paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN104403517A true CN104403517A (en) 2015-03-11

Family

ID=52641191

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410633548.XA Pending CN104403517A (en) 2014-11-12 2014-11-12 High imitation electroplating silver powder paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104403517A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877539A (en) * 2015-06-08 2015-09-02 山东朗法博粉末涂装科技有限公司 Metal bonding powder coating with mirror-like silver effect as well as preparation method and application thereof
CN105176331A (en) * 2015-09-25 2015-12-23 科威嘉粉末涂料(天津)有限公司 Acrylic acid and silicon-aluminum composite high-heat-dissipation powder coating for engine
CN106085153A (en) * 2016-07-16 2016-11-09 芜湖市四捍粉末涂料有限公司 A kind of formula of mixed type flash of light argentum powder and preparation method thereof
CN106085154A (en) * 2016-07-16 2016-11-09 芜湖市四捍粉末涂料有限公司 A kind of formula of high glaze minute surface argentum powder and preparation method thereof
CN106243838A (en) * 2015-09-18 2016-12-21 廊坊立邦涂料有限公司 A kind of electrosilvering coating composition, preparation method and applications
CN106381014A (en) * 2016-08-31 2017-02-08 苏州翰晨商贸有限公司 Grey flash silver powder coating
CN106497328A (en) * 2016-10-28 2017-03-15 福建万安实业集团有限公司 A kind of additional type electrosilvering powdery paints
CN106519922A (en) * 2016-10-28 2017-03-22 福建万安实业集团有限公司 High-levelling silver-flashing powder coating and preparation method thereof
CN107892865A (en) * 2017-11-15 2018-04-10 广州擎天材料科技有限公司 A kind of automobile aluminum wheel hub bottom surface unification electrosilvering special bottom powder coating and preparation method thereof
CN108329806A (en) * 2018-02-12 2018-07-27 浙江华彩新材料有限公司 Anti-corrosive powder paint and preparation method with plating mirror effect and application
CN108467663A (en) * 2018-05-08 2018-08-31 浙江绿环新材料科技有限公司 A kind of Novel imitation plating powder preparation method for coating
CN109401566A (en) * 2018-09-28 2019-03-01 上海国丽粉体涂料有限公司 The imitative plating powdery paints of one kind, preparation method and imitative electroplated coating
CN109897505A (en) * 2019-03-27 2019-06-18 佛山市顺德区千之彩实业有限公司 A kind of double powdery paints and preparation method thereof thoroughly
CN110028881A (en) * 2019-04-18 2019-07-19 佛山市南海嘉多彩粉末涂料有限公司 A kind of double coating paints disguise high chroma weather-resistant powder paint and preparation method thereof
CN113122103A (en) * 2019-12-30 2021-07-16 苏州青田新材料有限公司 Imitation electroplating powder coating and preparation method thereof
CN114163904A (en) * 2021-12-13 2022-03-11 安徽江淮汽车集团股份有限公司 Preparation method and coating process of light truck compartment scintillation powder free of light shading
CN115232540A (en) * 2022-08-03 2022-10-25 珑彩环保材料(苏州)有限公司 High-imitation electroplated silver metal powder coating and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102775887A (en) * 2012-08-23 2012-11-14 广东华江粉末科技有限公司 Weather-resistant metal type powder coating for aluminum profiles and preparation method thereof
CN103160181A (en) * 2013-02-22 2013-06-19 安徽华辉塑业科技有限公司 Pearl-lustre powder coating and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102775887A (en) * 2012-08-23 2012-11-14 广东华江粉末科技有限公司 Weather-resistant metal type powder coating for aluminum profiles and preparation method thereof
CN103160181A (en) * 2013-02-22 2013-06-19 安徽华辉塑业科技有限公司 Pearl-lustre powder coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
许井全等: ""粉末涂料的邦定技术与金属颜料"", 《第十二次全国环氧树脂应用技术学术交流会论文集》 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877539A (en) * 2015-06-08 2015-09-02 山东朗法博粉末涂装科技有限公司 Metal bonding powder coating with mirror-like silver effect as well as preparation method and application thereof
CN106243838B (en) * 2015-09-18 2019-09-10 廊坊立邦涂料有限公司 A kind of electrosilvering coating composition, preparation method and applications
CN106243838A (en) * 2015-09-18 2016-12-21 廊坊立邦涂料有限公司 A kind of electrosilvering coating composition, preparation method and applications
CN105176331A (en) * 2015-09-25 2015-12-23 科威嘉粉末涂料(天津)有限公司 Acrylic acid and silicon-aluminum composite high-heat-dissipation powder coating for engine
CN106085153A (en) * 2016-07-16 2016-11-09 芜湖市四捍粉末涂料有限公司 A kind of formula of mixed type flash of light argentum powder and preparation method thereof
CN106085154A (en) * 2016-07-16 2016-11-09 芜湖市四捍粉末涂料有限公司 A kind of formula of high glaze minute surface argentum powder and preparation method thereof
CN106381014A (en) * 2016-08-31 2017-02-08 苏州翰晨商贸有限公司 Grey flash silver powder coating
CN106497328A (en) * 2016-10-28 2017-03-15 福建万安实业集团有限公司 A kind of additional type electrosilvering powdery paints
CN106519922A (en) * 2016-10-28 2017-03-22 福建万安实业集团有限公司 High-levelling silver-flashing powder coating and preparation method thereof
CN107892865A (en) * 2017-11-15 2018-04-10 广州擎天材料科技有限公司 A kind of automobile aluminum wheel hub bottom surface unification electrosilvering special bottom powder coating and preparation method thereof
CN108329806A (en) * 2018-02-12 2018-07-27 浙江华彩新材料有限公司 Anti-corrosive powder paint and preparation method with plating mirror effect and application
CN108467663A (en) * 2018-05-08 2018-08-31 浙江绿环新材料科技有限公司 A kind of Novel imitation plating powder preparation method for coating
CN109401566A (en) * 2018-09-28 2019-03-01 上海国丽粉体涂料有限公司 The imitative plating powdery paints of one kind, preparation method and imitative electroplated coating
CN109897505A (en) * 2019-03-27 2019-06-18 佛山市顺德区千之彩实业有限公司 A kind of double powdery paints and preparation method thereof thoroughly
CN110028881A (en) * 2019-04-18 2019-07-19 佛山市南海嘉多彩粉末涂料有限公司 A kind of double coating paints disguise high chroma weather-resistant powder paint and preparation method thereof
CN113122103A (en) * 2019-12-30 2021-07-16 苏州青田新材料有限公司 Imitation electroplating powder coating and preparation method thereof
CN114163904A (en) * 2021-12-13 2022-03-11 安徽江淮汽车集团股份有限公司 Preparation method and coating process of light truck compartment scintillation powder free of light shading
CN115232540A (en) * 2022-08-03 2022-10-25 珑彩环保材料(苏州)有限公司 High-imitation electroplated silver metal powder coating and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN104403517A (en) High imitation electroplating silver powder paint and preparation method thereof
CN105273583B (en) A kind of aluminium dedicated weather-proof Pearlescent powder paint and preparation method thereof
CN101157816A (en) Indoor decorative metal powdery paints
CN103483988A (en) Boiling-endurable sand-ripple powder paint for coating corners of aluminum section and preparation method thereof
CN104119784A (en) Epoxy/ polyester mixed powder coating
CN104479518A (en) Heat resisting powder coating
CN101608085A (en) Weather-resisting powder coating
CN104231872A (en) Anti-adhesion powder coating for wooden transfer
CN103265874A (en) High-toughness powder coating specially used for security door
CN103483942A (en) Perfluorocarbon powder paint with texture effect and preparation method thereof
CN101157819A (en) Outdoor decorative metal powdery paints
CN103965735A (en) Fast curing automobile balance part powder coating and production method thereof
CN101012328A (en) PVC resin particle for producing wallpaper and preparing method thereof
CN105440911A (en) Low temperature crosslinked high molecular composite material used for MDF sheet material, and preparation method thereof
CN104877539A (en) Metal bonding powder coating with mirror-like silver effect as well as preparation method and application thereof
CN105802116A (en) Spraying-free high-metal-gloss transparent ABS material and preparation method
CN101215442A (en) Weather-resisting powder coating composition
CN103756525A (en) Thermosetting powder coating and preparation method thereof
CN108531009A (en) A kind of valve plate resistant hydrophobic coating material of insulating powder in use and preparation method thereof
CN107858082A (en) A kind of metal powder coating and preparation method thereof
CN105111899A (en) Metallic outdoor pattern powder coating and producing method thereof
CN104231871A (en) High-adhesion powder coating
CN100528991C (en) Flash powder paint
CN109337529A (en) A kind of super-durable stereo metal wire-drawing effect coating and its production method
CN104559691B (en) Polymer composite for heat transfer printing low-temperature crosslinking and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150311

RJ01 Rejection of invention patent application after publication