CN104556698A - Smoke yellow crystal bead blank and preparation method thereof - Google Patents
Smoke yellow crystal bead blank and preparation method thereof Download PDFInfo
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- CN104556698A CN104556698A CN201510003680.7A CN201510003680A CN104556698A CN 104556698 A CN104556698 A CN 104556698A CN 201510003680 A CN201510003680 A CN 201510003680A CN 104556698 A CN104556698 A CN 104556698A
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Abstract
The invention discloses a smoke yellow crystal bead blank and a preparation method thereof. The smoke yellow crystal bead blank is prepared from the following components in parts by weight: 90-165 parts of quartz sands, 11-19 parts of zinc oxide, 28-53 parts of sodium carbonate, 15-30 parts of potassium carbonate, 5-17 parts of boric acid, 3-5 parts of calcium carbonate,0.8-3.2 parts of aluminum hydroxide, 1-2 parts of table salt, 2-5 parts of antimonous oxide, 0.1-2 parts of potassium nitrate, 0.01-0.15 part of sodium selenite, 0.001-0.003 part of ferrous sulfide, 0.1-0.8 part of samarium oxide and 0.9-2.2 parts of nickel oxide. When the smoke yellow crystal bead blank is prepared, a lot of cerous compounds are not used, colors of selenium and compounds of selenium are fixed in secondary finishing, and the bead blank is adjusted to smoke yellow by virtue of compounds of samarium and nickel. Lead-containing raw materials are not used, and the bead blank has the advantages of good glossiness, bright color, orderliness, no chromatic aberration and patterns, high yield, no lead and pollution, and good production benefit.
Description
Technical field
The present invention relates to a kind of cigarette yellow crystal pearl embryo and preparation method thereof.
Background technology
Cigarette yellow crystal pearl embryo is used to the work in-process preparing cigarette yellow crystal product, existing cigarette yellow crystal pearl embryo technique adopts crucible manufacture, there is aberration, color is uneven, have decorative pattern, unstable product quality, production efficiency is low, be not suitable for continuous production in enormous quantities, and cause environmental pollution by coal burning.And the rare-earth oxidation erbium of the consumption costliness had in existing technical recipe, but some selenium powders are painted unstable, the lead compound containing contaminate environment had.
Summary of the invention
It is good that technical problem to be solved by this invention is to provide a kind of color reproduction, and solid colour no color differnece, without decorative pattern, constant product quality, production efficiency is high, can be applicable to the cigarette yellow crystal pearl embryo of the production operation of continuous tank furnace.
For solving the problem, the present invention is achieved through the following technical solutions: a kind of cigarette yellow crystal pearl embryo, and this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 90-165 part, zinc oxide 11-19 part, soda ash 28-53 part, salt of wormwood 15-30 part, boric acid 5-17 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.15 part, Iron sulfuret 0.001-0.003 part, Samarium trioxide 0.1-0.8 part and nickel oxide 0.9-2.2 part.
Another technical problem to be solved by this invention is to provide a kind of preparation method of cigarette yellow crystal pearl embryo,
The present invention is achieved through the following technical solutions: the preparation process of described cigarette yellow crystal pearl embryo is as follows:
1) extract quartz sand 90-165 part, zinc oxide 11-19 part, soda ash 28-53 part, salt of wormwood 15-30 part, boric acid 5-17 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.15 part, Iron sulfuret 0.001-0.003 part, Samarium trioxide 0.1-0.8 part and nickel oxide 0.9-2.2 part by weight ratio to mix;
2) the cigarette yellow crystal pearl embryo raw material mixed is carried out granulation by tablets press;
3) granular cigarette yellow crystal pearl embryo raw material will be made put into glass quartz tank furnace and found, and when founding, keep weak oxide atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into cigarette yellow crystal pearl embryo after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, cigarette yellow crystal pearl embryo without decorative pattern.
Further, described in the preparation process 3 of cigarette yellow crystal pearl embryo, when founding, temperature controls at 1320 DEG C-1380 DEG C.
Further, described in the preparation process 4 of cigarette yellow crystal pearl embryo, cooling temperature controls at 800 DEG C-1000 DEG C.
The beneficial effect of cigarette yellow crystal pearl embryo of the present invention is: the compound not adopting a large amount of ceriums time prepared by described cigarette yellow crystal pearl embryo, fixes the painted of methyl seleninic acid, and be adjusted to cigarette yellow by the compound of samarium and nickel in secondary integer; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, unleaded pollution-free, the advantage that productivity effect is good.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
A kind of cigarette yellow crystal pearl embryo of the present invention, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 150 parts, 15 parts, zinc oxide, soda ash 32 parts, 21 parts, salt of wormwood, boric acid 12 parts, 3.9 parts, calcium carbonate, 1.5 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.3 parts, 0.9 part, saltpetre, Sodium Selenite 0.03 part, Iron sulfuret 0.001 part, Samarium trioxide 0.6 part and nickel oxide 1 part.
The preparation process of described cigarette yellow crystal pearl embryo is as follows:
1) extract quartz sand 150 parts, 15 parts, zinc oxide, soda ash 32 parts, 21 parts, salt of wormwood, boric acid 12 parts, 3.9 parts, calcium carbonate, 1.5 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.3 parts, 0.9 part, saltpetre, Sodium Selenite 0.03 part, Iron sulfuret 0.001 part, Samarium trioxide 0.6 part and nickel oxide 1 part by weight ratio to mix;
2) the cigarette yellow crystal pearl embryo raw material mixed is carried out granulation by tablets press;
3) will make granular cigarette yellow crystal pearl embryo raw material to put into glass quartz tank furnace and found, keep weak oxide atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1320 DEG C-1380 DEG C;
4) crystal solution is molded into cigarette yellow crystal pearl embryo after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, cigarette yellow crystal pearl embryo without decorative pattern.
Embodiment 2
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 165 parts, 19 parts, zinc oxide, soda ash 53 parts, 30 parts, salt of wormwood, boric acid 17 parts, 5 parts, calcium carbonate, 3.2 parts, aluminium hydroxide, salt 2 parts, antimonous oxide 5 parts, 2 parts, saltpetre, Sodium Selenite 0.15 part, Iron sulfuret 0.003 part, Samarium trioxide 0.8 part and nickel oxide 2.2 parts.
Embodiment 3
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 90 parts, 11 parts, zinc oxide, soda ash 28 parts, 15 parts, salt of wormwood, boric acid 5 parts, 3 parts, calcium carbonate, 0.8 part, aluminium hydroxide, salt 1 part, antimonous oxide 2 parts, 0.1 part, saltpetre, Sodium Selenite 0.01 part, Iron sulfuret 0.001 part, Samarium trioxide 0.1 part and nickel oxide 0.9 part.
Embodiment 4
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 100 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 7 parts, 3.6 parts, calcium carbonate, 1.1 parts, aluminium hydroxide, salt 1.3 parts, antimonous oxide 2.8 parts, 0.9 part, saltpetre, Sodium Selenite 0.07 part, Iron sulfuret 0.0019 part, Samarium trioxide 0.4 part and nickel oxide 1.2 parts.
Embodiment 5
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 155 parts, 17 parts, zinc oxide, soda ash 49 parts, 27 parts, salt of wormwood, boric acid 16 parts, 4.7 parts, calcium carbonate, 3.1 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 4.4 parts, 1.6 parts, saltpetre, Sodium Selenite 0.13 part, Iron sulfuret 0.0025 part, Samarium trioxide 0.6 part and nickel oxide 2 parts.
Embodiment 6
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 120 parts, 15 parts, zinc oxide, soda ash 36 parts, 25 parts, salt of wormwood, boric acid 13 parts, 4 parts, calcium carbonate, 2 parts, aluminium hydroxide, salt 1.4 parts, antimonous oxide 3 parts, 0.8 part, saltpetre, Sodium Selenite 0.1 part, Iron sulfuret 0.002 part, Samarium trioxide 0.4 part and nickel oxide 1.5 parts.
Embodiment 7
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 130 parts, 12 parts, zinc oxide, soda ash 43 parts, 18 parts, salt of wormwood, boric acid 9 parts, 3.9 parts, calcium carbonate, 2.3 parts, aluminium hydroxide, salt 1.7 parts, antimonous oxide 2.9 parts, 1.1 parts, saltpetre, Sodium Selenite 0.11 part, Iron sulfuret 0.0021 part, Samarium trioxide 0.3 part and nickel oxide 1.3 parts.
Embodiment 8
Its difference from Example 1 is, this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 125 parts, 16 parts, zinc oxide, soda ash 40 parts, 23 parts, salt of wormwood, boric acid 14 parts, 4.4 parts, calcium carbonate, 2.6 parts, aluminium hydroxide, salt 1.2 parts, antimonous oxide 4.2 parts, 1.3 parts, saltpetre, Sodium Selenite 0.05 part, Iron sulfuret 0.002 part, Samarium trioxide 0.5 part and nickel oxide 1.7 parts.
The present invention is not limited to above-mentioned preferred forms, anyone other any or akin products identical with the present invention drawn under enlightenment of the present invention, all drops within protection scope of the present invention.
Claims (4)
1. a cigarette yellow crystal pearl embryo, is characterized in that: this cigarette yellow crystal pearl embryo is made up of following weight composition: quartz sand 90-165 part, zinc oxide 11-19 part, soda ash 28-53 part, salt of wormwood 15-30 part, boric acid 5-17 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.15 part, Iron sulfuret 0.001-0.003 part, Samarium trioxide 0.1-0.8 part and nickel oxide 0.9-2.2 part.
2. prepare a preparation method for cigarette yellow crystal pearl embryo according to claim 1, it is characterized in that: the method comprises the following steps:
1) extract quartz sand 90-165 part, zinc oxide 11-19 part, soda ash 28-53 part, salt of wormwood 15-30 part, boric acid 5-17 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.15 part, Iron sulfuret 0.001-0.003 part, Samarium trioxide 0.1-0.8 part and nickel oxide 0.9-2.2 part by weight ratio to mix;
2) the cigarette yellow crystal pearl embryo raw material mixed is carried out granulation by tablets press;
3) granular cigarette yellow crystal pearl embryo raw material will be made put into glass quartz tank furnace and found, and when founding, keep weak oxide atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into cigarette yellow crystal pearl embryo after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, cigarette yellow crystal pearl embryo without decorative pattern.
3. cigarette yellow crystal pearl embryo preparation method according to claim 2, is characterized in that: described in the preparation process 3 of cigarette yellow crystal pearl embryo, when founding, temperature controls at 1320 DEG C-1380 DEG C.
4. cigarette yellow crystal pearl embryo preparation method according to claim 2, is characterized in that: described in the preparation process 4 of cigarette yellow crystal pearl embryo, cooling temperature controls at 800 DEG C-1000 DEG C.
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| CN201510003680.7A CN104556698B (en) | 2015-01-06 | 2015-01-06 | A kind of cigarette yellow crystal pearl embryo and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105859136A (en) * | 2016-06-15 | 2016-08-17 | 浙江伟兴水晶有限公司 | Amber crystal bead blank and preparation method thereof |
| CN106082653A (en) * | 2016-06-15 | 2016-11-09 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of pale yellow color and preparation method thereof |
| CN106430956A (en) * | 2016-08-29 | 2017-02-22 | 浙江伟兴水晶有限公司 | Lemon yellow crystal bead blank and preparation method thereof |
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2015
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| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105859136A (en) * | 2016-06-15 | 2016-08-17 | 浙江伟兴水晶有限公司 | Amber crystal bead blank and preparation method thereof |
| CN106082653A (en) * | 2016-06-15 | 2016-11-09 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of pale yellow color and preparation method thereof |
| CN106082653B (en) * | 2016-06-15 | 2018-05-08 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of pale yellow color and preparation method thereof |
| CN106430956A (en) * | 2016-08-29 | 2017-02-22 | 浙江伟兴水晶有限公司 | Lemon yellow crystal bead blank and preparation method thereof |
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| CN104556698B (en) | 2016-03-23 |
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Effective date of registration: 20220301 Address after: 321000 No. 668, Xuecheng East Road, Hanxiang Industrial Park, Tangya Town, Jindong District, Jinhua City, Zhejiang Province Patentee after: Zhejiang xinweixing crystal Co.,Ltd. Address before: 321000 Jindong comprehensive development park, Jinhua City, Zhejiang Province Patentee before: ZHEJIANG WEIXING CRYSTAL Co.,Ltd. |
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