CN104540842B - 制备硫化碱土金属十二烷基酚盐的方法 - Google Patents

制备硫化碱土金属十二烷基酚盐的方法 Download PDF

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Publication number
CN104540842B
CN104540842B CN201380018084.5A CN201380018084A CN104540842B CN 104540842 B CN104540842 B CN 104540842B CN 201380018084 A CN201380018084 A CN 201380018084A CN 104540842 B CN104540842 B CN 104540842B
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Prior art keywords
dodecylphenol
amount
product
pddp
sulfur
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Chinese (zh)
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CN104540842A (zh
Inventor
G·M·沃克
R·L·索尔比
J·P·罗斯基
R·L·帕森斯
C·L·弗兰德
A·格兰吉
C·J·科利
M·G·法赫米
J·佩雷拉
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Lubrizol Corp
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Lubrizol Corp
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G99/00—Subject matter not provided for in other groups of this subclass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/02—Sulfurised compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028—Overbased salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/52—Base number [TBN]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380018084.5A 2012-02-08 2013-02-06 制备硫化碱土金属十二烷基酚盐的方法 Active CN104540842B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261596286P 2012-02-08 2012-02-08
US61/596,286 2012-02-08
PCT/US2013/024877 WO2013119623A1 (en) 2012-02-08 2013-02-06 Method of preparing a sulfurized alkaline earth metal dodecylphenate

Publications (2)

Publication Number Publication Date
CN104540842A CN104540842A (zh) 2015-04-22
CN104540842B true CN104540842B (zh) 2017-09-22

Family

ID=47739511

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380018084.5A Active CN104540842B (zh) 2012-02-08 2013-02-06 制备硫化碱土金属十二烷基酚盐的方法

Country Status (7)

Country Link
US (1) US9617496B2 (https=)
EP (1) EP2812340B1 (https=)
CN (1) CN104540842B (https=)
CA (1) CA2863950C (https=)
IN (1) IN2014DN07290A (https=)
SG (2) SG10201607435RA (https=)
WO (1) WO2013119623A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201506250XA (en) 2013-02-11 2015-09-29 Lubrizol Corp Bridged alkaline earth metal alkylphenates
CA2944879A1 (en) * 2014-04-04 2015-10-08 The Lubrizol Corporation Method for preparing a sulfurized alkaline earth metal dodecylphenate
EP3212749B1 (en) 2014-10-31 2023-04-19 The Lubrizol Corporation Marine diesel lubricating composition
CN108473900B (zh) 2015-12-15 2021-10-26 路博润公司 用于润滑组合物的硫化儿茶酚酯清净剂
SG10202012640RA (en) 2016-06-17 2021-01-28 Lubrizol Corp Lubricating compositions
SG11201810337PA (en) 2016-06-17 2018-12-28 Lubrizol Corp Lubricating compositions
WO2017218657A2 (en) 2016-06-17 2017-12-21 The Lubrizol Corporation Polyisobutylene-substituted phenol, derivatives thereof, and lubricating compositions containing the polyisobutylene-substituted phenol and its derivatives
SG11201810334SA (en) 2016-06-17 2018-12-28 Lubrizol Corp Lubricating compositions
US10260019B2 (en) 2016-06-30 2019-04-16 The Lubrizol Corporation Hydroxyaromatic succinimide detergents for lubricating compositions
US12454656B2 (en) 2022-04-27 2025-10-28 Afton Chemical Corporation Additives with high sulfurization for lubricating oil compositions

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100661A (zh) * 1986-01-14 1987-12-23 阿莫科公司 改进的酚盐产品及其工艺方法
CN87108239A (zh) * 1986-11-29 1988-06-15 Bp化学有限公司 碱土金属烃基酚盐及其磁化衍生物，它们的制备和应用
CN1048231A (zh) * 1989-06-23 1991-01-02 宇宙石油株式会社 高碱性硫化碱土金属酚盐型洗涤剂的生产方法
EP0601721A2 (en) * 1992-12-07 1994-06-15 Ethyl Petroleum Additives, Inc. Process for preparing overbased phenates
CN1106383A (zh) * 1993-08-25 1995-08-09 株式会社宇宙总合研究所 高碱性硫化碱土金属酚盐及其制备方法
WO2013059173A1 (en) * 2011-10-20 2013-04-25 The Lubrizol Corporation Bridged alkylphenol compounds

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2501731A (en) 1946-10-14 1950-03-28 Union Oil Co Modified lubricating oil
US2680096A (en) 1951-02-12 1954-06-01 California Research Corp Process for preparing sulfurized polyvalent metal phenates
US2616911A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes formed by use of sulfonic promoters
US2616925A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes formed by use of thiophosphoric promoters
US2616905A (en) 1952-03-13 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes and methods of making same
US2777874A (en) 1952-11-03 1957-01-15 Lubrizol Corp Metal complexes and methods of making same
US3036971A (en) 1958-12-24 1962-05-29 Socony Mobil Oil Co Inc Lubricating oils containing carbonated basic sulfurized calcium phenates
DE1248643B (de) 1959-03-30 1967-08-31 The Lubrizol Corporation, Cleveland, Ohio (V. St. A.) Verfahren zur Herstellung von öllöslichen aeylierten Aminen
US3488284A (en) 1959-12-10 1970-01-06 Lubrizol Corp Organic metal compositions and methods of preparing same
US3282835A (en) 1963-02-12 1966-11-01 Lubrizol Corp Carbonated bright stock sulfonates and lubricants containing them
US3381022A (en) 1963-04-23 1968-04-30 Lubrizol Corp Polymerized olefin substituted succinic acid esters
US3320162A (en) 1964-05-22 1967-05-16 Phillips Petroleum Co Increasing the base number of calcium petroleum sulfonate
US3318809A (en) 1965-07-13 1967-05-09 Bray Oil Co Counter current carbonation process
GB1105217A (en) 1965-10-05 1968-03-06 Lubrizol Corp Process for preparing basic metal phenates
US3365396A (en) 1965-12-28 1968-01-23 Texaco Inc Overbased calcium sulfonate
US3384585A (en) 1966-08-29 1968-05-21 Phillips Petroleum Co Overbasing lube oil additives
US3464970A (en) 1967-03-13 1969-09-02 Maruzen Oil Co Ltd Process for preparing over-based sulfurized calcium phenates
US3634515A (en) 1968-11-08 1972-01-11 Standard Oil Co Alkylene polyamide formaldehyde
US3629109A (en) 1968-12-19 1971-12-21 Lubrizol Corp Basic magnesium salts processes and lubricants and fuels containing the same
US4234435A (en) 1979-02-23 1980-11-18 The Lubrizol Corporation Novel carboxylic acid acylating agents, derivatives thereof, concentrate and lubricant compositions containing the same, and processes for their preparation
US4285822A (en) 1979-06-28 1981-08-25 Chevron Research Company Process for preparing a sulfurized molybdenum-containing composition and lubricating oil containing the composition
US4594378A (en) 1985-03-25 1986-06-10 The Lubrizol Corporation Polymeric compositions, oil compositions containing said polymeric compositions, transmission fluids and hydraulic fluids
GB8531626D0 (en) 1985-12-23 1986-02-05 Shell Int Research Grease composition
US5024773A (en) 1986-10-21 1991-06-18 Chevron Research Company Methods for preparing, group II metal overbased sulfurized alkylphenols
US6310011B1 (en) 1994-10-17 2001-10-30 The Lubrizol Corporation Overbased metal salts useful as additives for fuels and lubricants
EP0954517B1 (en) 1997-11-13 2003-02-05 Lubrizol Adibis Holdings (Uk) Limited Salicyclic calixarenes and their use as lubricant additives
EP1254100A1 (en) 2000-02-07 2002-11-06 Bp Oil International Limited Calixarenes and their use as lubricant additives
US6310009B1 (en) 2000-04-03 2001-10-30 The Lubrizol Corporation Lubricating oil compositions containing saligenin derivatives
US6569818B2 (en) 2000-06-02 2003-05-27 Chevron Oronite Company, Llc Lubricating oil composition
ATE292667T1 (de) 2001-11-05 2005-04-15 Lubrizol Corp Schmiermittelzusammensetzung mit verbesserter brennstoffersparnis
US7651987B2 (en) 2004-10-12 2010-01-26 The Lubrizol Corporation Tartaric acid derivatives as fuel economy improvers and antiwear agents in crankcase oils and preparation thereof
CN101151353A (zh) 2005-03-28 2008-03-26 卢布里佐尔公司 钛化合物和络合物作为润滑剂中的添加剂
US7335711B2 (en) 2005-08-17 2008-02-26 Fina Technology, Inc. Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins
US7435709B2 (en) 2005-09-01 2008-10-14 Chevron Oronite Company Llc Linear alkylphenol derived detergent substantially free of endocrine disruptive chemicals
ES2655116T3 (es) 2006-09-19 2018-02-16 Infineum International Limited Una composición de aceite lubricante
US8207380B2 (en) 2007-04-27 2012-06-26 Chevron Oronite LLC Alkylated hydroxyaromatic compound substantially free of endocrine disruptive chemicals and method of making the same
JP2010528156A (ja) 2007-05-24 2010-08-19 ザ ルブリゾル コーポレイション ヒドロキシポリカルボン酸誘導体に基づく無灰の磨耗防止剤およびモリブデン化合物を含有する潤滑組成物
US7943796B2 (en) 2008-07-31 2011-05-17 Chevron Oronise Company LLC Lubricating oil additive and lubricating oil composition containing same
US20120172265A1 (en) 2008-12-09 2012-07-05 The Lubrizol Corporation Lubricating Composition Containing a Compound Derived from a Hydroxy-carboxylic Acid
US8486877B2 (en) 2009-11-18 2013-07-16 Chevron Oronite Company Llc Alkylated hydroxyaromatic compound substantially free of endocrine disruptive chemicals
US8580717B2 (en) 2009-11-24 2013-11-12 Chevron Oronite Company Llc Process for making an overbased, sulfurized salt of an alkylated hydroxyaromatic compound
US8183192B2 (en) 2010-02-03 2012-05-22 Chevron Oronite Company Llc Lubricating oil additive and lubricating oil composition containing same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100661A (zh) * 1986-01-14 1987-12-23 阿莫科公司 改进的酚盐产品及其工艺方法
CN87108239A (zh) * 1986-11-29 1988-06-15 Bp化学有限公司 碱土金属烃基酚盐及其磁化衍生物，它们的制备和应用
CN1048231A (zh) * 1989-06-23 1991-01-02 宇宙石油株式会社 高碱性硫化碱土金属酚盐型洗涤剂的生产方法
EP0601721A2 (en) * 1992-12-07 1994-06-15 Ethyl Petroleum Additives, Inc. Process for preparing overbased phenates
CN1106383A (zh) * 1993-08-25 1995-08-09 株式会社宇宙总合研究所 高碱性硫化碱土金属酚盐及其制备方法
WO2013059173A1 (en) * 2011-10-20 2013-04-25 The Lubrizol Corporation Bridged alkylphenol compounds

Also Published As

Publication number Publication date
IN2014DN07290A (https=) 2015-04-24
SG10201607435RA (en) 2016-10-28
WO2013119623A1 (en) 2013-08-15
EP2812340A1 (en) 2014-12-17
US9617496B2 (en) 2017-04-11
SG11201404656RA (en) 2014-09-26
CN104540842A (zh) 2015-04-22
EP2812340B1 (en) 2018-08-29
CA2863950A1 (en) 2013-08-15
CA2863950C (en) 2022-06-07
US20150045269A1 (en) 2015-02-12

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