CN104538471A - Multi-layer packaging material used for solar module and preparation technology and device thereof - Google Patents

Multi-layer packaging material used for solar module and preparation technology and device thereof Download PDF

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Publication number
CN104538471A
CN104538471A CN201410768490.XA CN201410768490A CN104538471A CN 104538471 A CN104538471 A CN 104538471A CN 201410768490 A CN201410768490 A CN 201410768490A CN 104538471 A CN104538471 A CN 104538471A
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CN
China
Prior art keywords
poe
top layer
eva
layer
micelle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410768490.XA
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Chinese (zh)
Inventor
赵世界
陈勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGZHOU JIUHE NEW ENERGY Co Ltd
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CHANGZHOU JIUHE NEW ENERGY Co Ltd
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Priority to CN201410768490.XA priority Critical patent/CN104538471A/en
Publication of CN104538471A publication Critical patent/CN104538471A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552Fatigue strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/12Photovoltaic modules
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention discloses a multi-layer packaging material used for a solar module. The multi-layer packaging material is composed of a POE surface layer A, an EVA core layer B and a POE surface layer C in sequence. The POE surface layer A is an adhesive film, and is made of ethylene and POE colloidal particles, and the surface of the POE surface layer A makes contact with a solar battery piece. The EVA core layer B is made of EVA polymers and performance additives. The POE surface layer C is an adhesive film, and is made of ethylene and POE colloidal particles, and the surface of the POE surface layer A makes contact with a back board in the solar module. The ageing-resistant performance of the material is high.

Description

A kind of multilayer encapsulation material for solar energy module, its preparation technology and equipment
Technical field
The present invention relates to a kind of multilayer encapsulation material for solar energy module, its preparation technology and equipment.
Background technology
Along with the development of China's photovoltaic industry, require more and more higher to the serviceability of encapsulating material in solar module.Use single ethene-vinyl acetate (EVA) polymer can not satisfy the demand in resistance to ultraviolet and hydrothermal aging performance as the base material of encapsulating material.And the multilayer encapsulation adhesive film material adopting the micelle of unlike material to obtain is owing to remaining the superperformance of single stack package glued membrane, compensate for again the defect of each single variety glued membrane, form a kind of new composite encapsulating material.Thus more single packaging adhesive film has better physical and mechanical properties.Different materials, by reasonable combination, under the prerequisite ensureing presentation quality, can save high-quality raw material, reduces the production cost of packaging adhesive film, therefore, has vast potential for future development.
For the production of multilayer material, the past adopts shaping different material respectively to carry out laminate adhesive or prolong the conventional methods such as extrusion sheet-superimposed lamination realizing multiple stratification.This technique is still used at present, and its shortcoming is that operation is many, investment is large, production efficiency is low.
In order to address these problems, Abroad in Recent Years has developed the new technology that coetrusion produces multilayer material.This method is that the extruder (the large I of specification is identical, also can be different) with more than two, simultaneously to a coextrusion die head feed, makes two or more meltings cut into slices and extrudes from common extrusion simultaneously and form overall technology.Owing to having small investment, the advantage such as technological process is short, occupation area of equipment is little, sustainable, High-efficient Production.Therefore, very large development is obtained abroad.The production that there are multilayer material in some industrial flourishing countries as U.S., method, West Germany, Japan, Italy etc., still has larger development from now on.
Summary of the invention
the problem that invention will solve
One object of the present invention is to overcome deficiency of the prior art, provides a kind of multilayer encapsulation material for solar energy module, its preparation technology and equipment.
for the scheme of dealing with problems
For a multilayer encapsulation material for solar energy module, be made up of POE top layer A, EVA sandwich layer B and POE top layer C successively,
Described POE top layer A is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer A surface contacts with solar battery sheet;
Described EVA sandwich layer B is made up of ethene-vinyl acetate (EVA) polymer and modified additive;
Described POE top layer C is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer C surface contacts with the backboard in solar energy module.
Preferably, the described multilayer encapsulation material for solar energy module,
Described POE top layer A, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described EVA sandwich layer B, is prepared from by following raw material by weight:
EVA micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described POE top layer C, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part.
The present invention provides a kind of technique preparing the described multilayer encapsulation material for solar energy module simultaneously, comprises the steps:
(1) described raw material is mixed through batch mixer;
(2) the raw materials compound of POE top layer A is dropped in the first screw extruder, the raw materials compound of EVA sandwich layer B is dropped in the second screw extruder, the raw materials compound of POE top layer C is dropped in three-screw extruder, at 90 DEG C through plasticizing, entered in co-extrusion modling head by connector and extrude, respectively by three-roll press-polishing unit, cool cold roller, hauling machine, cutter, finished product crimping device, carry out roll-in, cooling, stretching, traction, shearing, rolling make.
The present invention provides a kind of simultaneously and prepares the process equipment turning light packaging adhesive film, comprise connect successively screw extruder, connector, co-extrusion modling head, three-roll press-polishing unit, cool cold roller, hauling machine, cutter, finished product crimping device.POE is the block copolymer of ethene and octene, and the flexible chain coiled structure of octene and the ethylene chain of crystallization, as crosslinking points, have excellent toughness and good processing characteristics.There is no unsaturated double-bond in POE structure, therefore it has excellent weather resistance and good mobility, contributes to the dispersion effect improving filler.In order to improve the ageing-resistant performance of assembly, this patent adopts three-layer co-extruded technology to produce a kind of novel encapsulating material.
the effect of invention
1, technique provided by the invention, reduces production cost, improves production efficiency, also assures that the sustainability of production simultaneously.
2, encapsulating material provided by the invention, improves the physical and mechanical properties of product on the one hand, ensure that the superperformance of sandwich layer EVA adhesive film, on the other hand, save high-quality raw material, reduced production cost, also improve the wet and heat ageing resistant performance of solar components and anti-PID performance simultaneously.
Accompanying drawing explanation
Fig. 1 is process equipment flowage structure schematic diagram;
Fig. 2 is the structure composition schematic diagram of multilayer encapsulation material;
Fig. 3 is solar energy module structural representation.
1-screw extruder; 2-connector; 3-co-extrusion modling head, 4-three-roll press-polishing unit; 5-cools cold roller; 6-pulling equipment; 7-shear; 8-finished product crimping device; 10-solar cell layer; 20-POE top layer A; 30-EVA sandwich layer B; 40-POE top layer C; 50-backsheet layer.
Embodiment
Various exemplary embodiment of the present invention, characteristic sum aspect is described in detail below with reference to embodiment.In order to better the present invention is described, in embodiment hereafter, give numerous details.It will be appreciated by those skilled in the art that do not have these details, the present invention can implement equally.In other example, known method, means, material are not described in detail, so that highlight purport of the present invention.
Fig. 1 is process equipment flowage structure schematic diagram.The screw extruder 1 connected successively, connector 2, co-extrusion modling head 3, three-roll press-polishing unit 4, cool cold roller 5, hauling machine 6, cutter 7, finished product crimping device 8.Screw extruder 1 can be provided with one, also can be set to three.
Described POE top layer A, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described EVA sandwich layer B, is prepared from by following raw material by weight:
EVA micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described POE top layer C, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part.
Just the raw materials compound of POE top layer A drops in the first screw extruder, the raw materials compound of EVA sandwich layer B is dropped in the second screw extruder, the raw materials compound of POE top layer C is dropped in three-screw extruder, at 90 DEG C through plasticizing, entered in co-extrusion modling head 3 by connector 2 and extrude, respectively by three-roll press-polishing unit 4, cool cold roller 5, hauling machine 6, cutter 7, finished product crimping device 8, carry out roll-in, cooling, stretching, traction, shearing, rolling make.
Fig. 2 is the structure composition schematic diagram of multilayer encapsulation material.POE is the block copolymer of ethene and octene, and the flexible chain coiled structure of octene and the ethylene chain of crystallization, as crosslinking points, have excellent toughness and good processing characteristics.There is no unsaturated double-bond in POE structure, therefore it has excellent weather resistance and good mobility, contributes to the dispersion effect improving filler.
Fig. 3 is solar energy module structural representation.In order to improve the ageing-resistant performance of assembly, described POE top layer A20 is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer A20 surface contacts with solar cell layer 10; Described EVA sandwich layer B30 is made up of ethene-vinyl acetate (EVA) polymer and modified additive; Described POE top layer C40 is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer C40 surface contacts with the backsheet layer 50 in solar energy module.
Three layers of encapsulating material that this patent adopts three-layer co-extruded technology obtained, improve the physical and mechanical properties of product on the one hand, ensure that the superperformance of sandwich layer EVA adhesive film, on the other hand, save high-quality raw material, reduce production cost, also improve the wet and heat ageing resistant performance of solar components and anti-PID performance simultaneously.
Although describe the present invention with reference to above execution mode, it should be understood that and the invention is not restricted to disclosed execution mode.The scope of appended claims should make an explanation in the most wide in range scope, to contain all modification, equivalent structure and function.

Claims (4)

1. for a multilayer encapsulation material for solar energy module, it is characterized in that, be made up of POE top layer A, EVA sandwich layer B and POE top layer C successively,
Described POE top layer A is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer A surface contacts with solar battery sheet;
Described EVA sandwich layer B is made up of ethene-vinyl acetate (EVA) polymer and modified additive;
Described POE top layer C is glued membrane, is made up of ethene and octene block copolymer (POE) micelle, and described POE top layer C surface contacts with the backboard in solar energy module.
2. the multilayer encapsulation material for solar energy module according to claim 1, is characterized in that,
Described POE top layer A, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described EVA sandwich layer B, is prepared from by following raw material by weight:
EVA micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part;
Described POE top layer C, is prepared from by following raw material by weight:
POE micelle: 100 parts, crosslinking agent: 0.1-5 part, coupling agent: 0.1-1 part, antioxidant: 0.01-0.5 part, ultra-violet absorber: 0.1-1 part.
3. prepare a technique for the multilayer encapsulation material for solar energy module as described in any one of claim 1 to 2, it is characterized in that, comprise the steps:
(1) described raw material is mixed through batch mixer;
(2) the raw materials compound of POE top layer A is dropped in the first screw extruder, the raw materials compound of EVA sandwich layer B is dropped in the second screw extruder, the raw materials compound of POE top layer C is dropped in three-screw extruder, at 90 DEG C through plasticizing, entered in co-extrusion modling head by connector and extrude, respectively by three-roll press-polishing unit, cool cold roller, hauling machine, cutter, finished product crimping device, carry out roll-in, cooling, stretching, traction, shearing, rolling make.
4. the process equipment for the multilayer encapsulation material for the preparation of solar energy module as claimed in claim 3, it is characterized in that, comprise connect successively screw extruder, connector, co-extrusion modling head, three-roll press-polishing unit, cool cold roller, hauling machine, cutter and finished product crimping device.
CN201410768490.XA 2014-12-12 2014-12-12 Multi-layer packaging material used for solar module and preparation technology and device thereof Pending CN104538471A (en)

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Application Number Priority Date Filing Date Title
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105802521A (en) * 2016-04-12 2016-07-27 赛特瑞太阳能(苏州)有限公司 POE (polyolefin elastomer) composite adhesive film
CN105882094A (en) * 2016-04-06 2016-08-24 广东东立新材料科技有限公司 Solar panel high-temperature-resistant anti-ultraviolet self-adhesive film
CN109294455A (en) * 2018-09-04 2019-02-01 江苏鹿山光电科技有限公司 A kind of solar energy composite package glue film used for packing material and preparation method thereof
CN109401059A (en) * 2018-11-14 2019-03-01 安徽兆拓新能源科技有限公司 A kind of solar cell package film and preparation method thereof
CN109536053A (en) * 2018-11-26 2019-03-29 广州市隆创新材料有限公司 Hot-melt optical adhesive film with multilayer structure and preparation method thereof
CN109553911A (en) * 2018-11-30 2019-04-02 苏州度辰新材料有限公司 A kind of non-fluorine Ageing-resistant film for solar energy backboard and the solar energy backboard being made from it
CN112201719A (en) * 2020-09-29 2021-01-08 浙江晶科能源有限公司 Adhesive film structure and photovoltaic module
CN114805868A (en) * 2022-04-06 2022-07-29 浙江中聚材料有限公司 Polyolefin fiber reinforced layer and application thereof in solar cell adhesive film
US11695089B2 (en) 2019-12-31 2023-07-04 Industrial Technology Research Institute Solar cell modules

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CN103229312A (en) * 2010-11-30 2013-07-31 三菱树脂株式会社 Laminate for solar cell and solar cell module produced using same
CN203639397U (en) * 2013-10-22 2014-06-11 杭州福斯特光伏材料股份有限公司 Photovoltaic module packaging adhesive film with double-layer structure
CN103895304A (en) * 2012-12-28 2014-07-02 苏州度辰新材料有限公司 Solar energy back panel and preparation method thereof
CN204011452U (en) * 2014-09-09 2014-12-10 常州斯威克光伏新材料有限公司 A kind of single-side embossing packaging adhesive film for solar cell

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Publication number Priority date Publication date Assignee Title
CN103229312A (en) * 2010-11-30 2013-07-31 三菱树脂株式会社 Laminate for solar cell and solar cell module produced using same
CN103895304A (en) * 2012-12-28 2014-07-02 苏州度辰新材料有限公司 Solar energy back panel and preparation method thereof
CN203639397U (en) * 2013-10-22 2014-06-11 杭州福斯特光伏材料股份有限公司 Photovoltaic module packaging adhesive film with double-layer structure
CN204011452U (en) * 2014-09-09 2014-12-10 常州斯威克光伏新材料有限公司 A kind of single-side embossing packaging adhesive film for solar cell

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105882094A (en) * 2016-04-06 2016-08-24 广东东立新材料科技有限公司 Solar panel high-temperature-resistant anti-ultraviolet self-adhesive film
CN105882094B (en) * 2016-04-06 2018-02-16 广东东立新材料科技有限公司 Solar panels high-temperature-resistant ultraviolet-resistant self-adhesive film
CN105802521A (en) * 2016-04-12 2016-07-27 赛特瑞太阳能(苏州)有限公司 POE (polyolefin elastomer) composite adhesive film
CN109294455B (en) * 2018-09-04 2021-11-23 江苏鹿山新材料有限公司 Composite packaging adhesive film for solar packaging material and preparation method thereof
CN109294455A (en) * 2018-09-04 2019-02-01 江苏鹿山光电科技有限公司 A kind of solar energy composite package glue film used for packing material and preparation method thereof
CN109401059A (en) * 2018-11-14 2019-03-01 安徽兆拓新能源科技有限公司 A kind of solar cell package film and preparation method thereof
CN109536053A (en) * 2018-11-26 2019-03-29 广州市隆创新材料有限公司 Hot-melt optical adhesive film with multilayer structure and preparation method thereof
CN109536053B (en) * 2018-11-26 2021-04-20 广州市隆创新材料有限公司 Hot-melt optical adhesive film with multilayer structure and preparation method thereof
CN109553911A (en) * 2018-11-30 2019-04-02 苏州度辰新材料有限公司 A kind of non-fluorine Ageing-resistant film for solar energy backboard and the solar energy backboard being made from it
US11695089B2 (en) 2019-12-31 2023-07-04 Industrial Technology Research Institute Solar cell modules
CN112201719A (en) * 2020-09-29 2021-01-08 浙江晶科能源有限公司 Adhesive film structure and photovoltaic module
CN112201719B (en) * 2020-09-29 2023-07-14 浙江晶科能源有限公司 Adhesive film structure and photovoltaic module
CN114805868A (en) * 2022-04-06 2022-07-29 浙江中聚材料有限公司 Polyolefin fiber reinforced layer and application thereof in solar cell adhesive film

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Application publication date: 20150422