CN104538134A - Thermistor slurry - Google Patents

Thermistor slurry Download PDF

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Publication number
CN104538134A
CN104538134A CN201410826209.3A CN201410826209A CN104538134A CN 104538134 A CN104538134 A CN 104538134A CN 201410826209 A CN201410826209 A CN 201410826209A CN 104538134 A CN104538134 A CN 104538134A
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CN
China
Prior art keywords
parts
microcrystalline glass
powder
coupling agent
epoxy resin
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Pending
Application number
CN201410826209.3A
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Chinese (zh)
Inventor
吴国民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU LIANMAO ELECTRONIC TECHNOLOGY Co Ltd
Original Assignee
CHANGSHU LIANMAO ELECTRONIC TECHNOLOGY Co Ltd
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Application filed by CHANGSHU LIANMAO ELECTRONIC TECHNOLOGY Co Ltd filed Critical CHANGSHU LIANMAO ELECTRONIC TECHNOLOGY Co Ltd
Priority to CN201410826209.3A priority Critical patent/CN104538134A/en
Publication of CN104538134A publication Critical patent/CN104538134A/en
Pending legal-status Critical Current

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Abstract

The invention discloses thermistor slurry which is prepared from the following components in parts by weight: 6-10 parts of a barium-containing flame-retardant temperature-resistant macromolecular polymer, 1-5 parts of copper and gold composite powder, 0.5-1 part of tributyl citrate, 0.5-1 part of cellulose nitrate, 30-35 parts of o-methyl novolac epoxy resin, 4-6 parts of a coupling agent, 20-30 parts of linear phenolic resin, 5-10 parts of lanthanum oxide microcrystalline glass powder, 5-10 parts of bismuth oxide microcrystalline glass powder and 1-5 parts of aluminum oxide. The thermistor slurry disclosed by the invention not only realizes the compound functions of flame retardance, heat resistance, aging resistance, heat radiation resistance, environmental protection and the like, but also can be used for improving the stability of the system.

Description

A kind of Thermistor
Technical field
The present invention relates to electronic applications, be specifically related to a kind of Thermistor.
Background technology
A kind of conventional electric component during resistance, application is extensive, such as be used in integrated circuit, chip, but along with developing rapidly of integrated circuit and chip, current resistance also exists shortcomings, can not meet integrated needs, resistance slurry becomes the direction addressed this problem.
As the main component of resistance slurry, be usually made up of glass composition, electric conducting material, organic carrier, comprising glass composition is in order to adjusting resistance value and the cementability increasing slurry.On substrate after printed resistor slurry, by sintering, form thickness and be about the thick-film resistor of 5-20um, and, in this kind of resistance slurry, ruthenium-oxide and plumbous ru oxide usually can be used as electric conducting material, lead oxide class glass etc. can be used as glass.
In recent years, inquire into environmental problem just energetically, just advancing and get rid of the harmful substances such as plumbous from electronic unit.Above-mentioned resistance slurry is no exception, is carrying out unleaded research.
As resistance slurry unleaded in one of problem, particularly in high-resistance resistance slurry, such as there is taking into account of temperature characterisitic and voltage endurance, such as, TCR is being regulated, when former state is applied in without lead composition, owing to comparing with plumbous constituents by by being added on the metal oxide used in existing plumbous quasi-resistance slurry, the resistance value variation caused because voltage applies is comparatively large, so result is just difficult to realize taking into account of TCR and STOL.
Summary of the invention
Goal of the invention: for above-mentioned prior art Problems existing and deficiency, the object of this invention is to provide a kind of Thermistor.
Technical scheme: the invention discloses a kind of Thermistor, described formula presses mass fraction: the fire-retardant heatproof high molecule polymer 6-10 of baric element; Copper gold composite powder 1-5; Tributyl citrate 0.5-1; NC Nitroncellulose 0.5-1; O-cresol formaldehyde epoxy resin 30-35; Coupling agent 4-6; Linear phenolic resin 20-30; Lanthana microcrystalline glass in series powder 5-10; Bismuth oxide microcrystalline glass in series powder 5-10; Aluminium oxide 1-5.
As further optimization of the present invention, formula of the present invention presses mass fraction: the fire-retardant heatproof high molecule polymer 6 of baric element; Copper gold composite powder 1; Tributyl citrate 0.5; NC Nitroncellulose 0.5; O-cresol formaldehyde epoxy resin 30; Coupling agent 4; Linear phenolic resin 20; Lanthana microcrystalline glass in series powder 5; Bismuth oxide microcrystalline glass in series powder 5; Aluminium oxide 1.
As further optimization of the present invention, formula of the present invention presses mass fraction: the fire-retardant heatproof high molecule polymer 10 of baric element; Copper gold composite powder 5; Tributyl citrate 1; NC Nitroncellulose 1; O-cresol formaldehyde epoxy resin 35; Coupling agent 6; Linear phenolic resin 30; Lanthana microcrystalline glass in series powder 10; Bismuth oxide microcrystalline glass in series powder 10; Aluminium oxide 5.
As further optimization of the present invention, formula of the present invention presses mass fraction: the fire-retardant heatproof high molecule polymer 8 of baric element; Copper gold composite powder 3; Tributyl citrate 0.8; NC Nitroncellulose 0.8; O-cresol formaldehyde epoxy resin 33; Coupling agent 5; Linear phenolic resin 23; Lanthana microcrystalline glass in series powder 8; Bismuth oxide microcrystalline glass in series powder 13; Aluminium oxide 3.
Beneficial effect: resistance slurry of the present invention, there is the characteristic of low-temperature setting, applied at elevated temperature, printing and wettability good, with the strong adhesion of base material, the present invention not only achieves the complex functions such as fire-retardant, heat-resisting, anti-aging, thermal radiation, environmental protection, and improves the stability of system, thermal radiation usefulness is excellent, caloric value is large, and heat resistance is good, and energy-saving effect is remarkable.The resistance prepared by the present invention is through test analysis, and display resistive performance is good, and the method technological requirement is simple, low cost of manufacture.
Embodiment
The present invention is illustrated further below in conjunction with embodiment.
Embodiment 1:
The formula of a kind of Thermistor of the present embodiment presses mass fraction: the fire-retardant heatproof high molecule polymer 6 of baric element; Copper gold composite powder 1; Tributyl citrate 0.5; NC Nitroncellulose 0.5; O-cresol formaldehyde epoxy resin 30; Coupling agent 4; Linear phenolic resin 20; Lanthana microcrystalline glass in series powder 5; Bismuth oxide microcrystalline glass in series powder 5; Aluminium oxide 1.
Resistance prepared by the present embodiment is through test analysis, and display resistive performance is good.
Embodiment 2:
The formula of a kind of Thermistor of the present embodiment presses mass fraction: the fire-retardant heatproof high molecule polymer 10 of baric element; Copper gold composite powder 5; Tributyl citrate 1; NC Nitroncellulose 1; O-cresol formaldehyde epoxy resin 35; Coupling agent 6; Linear phenolic resin 30; Lanthana microcrystalline glass in series powder 10; Bismuth oxide microcrystalline glass in series powder 10; Aluminium oxide 5.
Resistance prepared by the present embodiment is through test analysis, and display resistive performance is good.
Embodiment 3:
The formula of a kind of Thermistor of the present embodiment presses mass fraction: the fire-retardant heatproof high molecule polymer 8 of baric element; Copper gold composite powder 3; Tributyl citrate 0.8; NC Nitroncellulose 0.8; O-cresol formaldehyde epoxy resin 33; Coupling agent 5; Linear phenolic resin 23; Lanthana microcrystalline glass in series powder 8; Bismuth oxide microcrystalline glass in series powder 13; Aluminium oxide 3.
Resistance prepared by the present embodiment is through test analysis, and display resistive performance is good.
The invention discloses a kind of Thermistor, described formula presses mass fraction: the fire-retardant heatproof high molecule polymer 6-10 of baric element; Copper gold composite powder 1-5; Tributyl citrate 0.5-1; NC Nitroncellulose 0.5-1; O-cresol formaldehyde epoxy resin 30-35; Coupling agent 4-6; Linear phenolic resin 20-30; Lanthana microcrystalline glass in series powder 5-10; Bismuth oxide microcrystalline glass in series powder 5-10; Aluminium oxide 1-5.The present invention not only achieves the complex functions such as fire-retardant, heat-resisting, anti-aging, thermal radiation, environmental protection, and improves the stability of system.

Claims (4)

1. a Thermistor, is characterized in that: described formula is by mass fraction: the fire-retardant heatproof high molecule polymer 6-10 of baric element; Copper gold composite powder 1-5; Tributyl citrate 0.5-1; NC Nitroncellulose 0.5-1; O-cresol formaldehyde epoxy resin 30-35; Coupling agent 4-6; Linear phenolic resin 20-30; Lanthana microcrystalline glass in series powder 5-10; Bismuth oxide microcrystalline glass in series powder 5-10; Aluminium oxide 1-5.
2. a kind of Thermistor according to claim 1, is characterized in that: described formula is by mass fraction: the fire-retardant heatproof high molecule polymer 6 of baric element; Copper gold composite powder 1; Tributyl citrate 0.5; NC Nitroncellulose 0.5; O-cresol formaldehyde epoxy resin 30; Coupling agent 4; Linear phenolic resin 20; Lanthana microcrystalline glass in series powder 5; Bismuth oxide microcrystalline glass in series powder 5; Aluminium oxide 1.
3. a kind of Thermistor according to claim 1, is characterized in that: described formula is by mass fraction: the fire-retardant heatproof high molecule polymer 10 of baric element; Copper gold composite powder 5; Tributyl citrate 1; NC Nitroncellulose 1; O-cresol formaldehyde epoxy resin 35; Coupling agent 6; Linear phenolic resin 30; Lanthana microcrystalline glass in series powder 10; Bismuth oxide microcrystalline glass in series powder 10; Aluminium oxide 5.
4. a kind of Thermistor according to claim 1, is characterized in that: described formula is by mass fraction: the fire-retardant heatproof high molecule polymer 8 of baric element; Copper gold composite powder 3; Tributyl citrate 0.8; NC Nitroncellulose 0.8; O-cresol formaldehyde epoxy resin 33; Coupling agent 5; Linear phenolic resin 23; Lanthana microcrystalline glass in series powder 8; Bismuth oxide microcrystalline glass in series powder 13; Aluminium oxide 3.
CN201410826209.3A 2014-12-26 2014-12-26 Thermistor slurry Pending CN104538134A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410826209.3A CN104538134A (en) 2014-12-26 2014-12-26 Thermistor slurry

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410826209.3A CN104538134A (en) 2014-12-26 2014-12-26 Thermistor slurry

Publications (1)

Publication Number Publication Date
CN104538134A true CN104538134A (en) 2015-04-22

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Family Applications (1)

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CN201410826209.3A Pending CN104538134A (en) 2014-12-26 2014-12-26 Thermistor slurry

Country Status (1)

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CN (1) CN104538134A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519306A (en) * 2009-02-24 2009-09-02 上海大学 Method for preparing high curie temperature leadless PTCR ceramic
CN101735561A (en) * 2008-11-25 2010-06-16 西安宏星电子浆料科技有限责任公司 Electrothermal organic power resistance slurry for heater
CN102522169A (en) * 2011-12-07 2012-06-27 华中科技大学 Termination electrode for multilayer sheet-type temperature-sensitive ceramic resistor and preparation method thereof
CN103295707A (en) * 2013-03-01 2013-09-11 广东丹邦科技有限公司 Carbon rubber embedded resistance paste and preparation method of carbon rubber embedded resistance material
CN104150880A (en) * 2014-06-27 2014-11-19 句容市博远电子有限公司 Manganese-cobalt-copper thermistor material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735561A (en) * 2008-11-25 2010-06-16 西安宏星电子浆料科技有限责任公司 Electrothermal organic power resistance slurry for heater
CN101519306A (en) * 2009-02-24 2009-09-02 上海大学 Method for preparing high curie temperature leadless PTCR ceramic
CN102522169A (en) * 2011-12-07 2012-06-27 华中科技大学 Termination electrode for multilayer sheet-type temperature-sensitive ceramic resistor and preparation method thereof
CN103295707A (en) * 2013-03-01 2013-09-11 广东丹邦科技有限公司 Carbon rubber embedded resistance paste and preparation method of carbon rubber embedded resistance material
CN104150880A (en) * 2014-06-27 2014-11-19 句容市博远电子有限公司 Manganese-cobalt-copper thermistor material

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Application publication date: 20150422

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