CN104530809A - Anticorrosive additives for water-based anticorrosive paint - Google Patents
Anticorrosive additives for water-based anticorrosive paint Download PDFInfo
- Publication number
- CN104530809A CN104530809A CN201410850448.2A CN201410850448A CN104530809A CN 104530809 A CN104530809 A CN 104530809A CN 201410850448 A CN201410850448 A CN 201410850448A CN 104530809 A CN104530809 A CN 104530809A
- Authority
- CN
- China
- Prior art keywords
- water
- anticorrosive
- anticorrosive paint
- additives
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Provided is anticorrosive additives for water-based anticorrosive paint. The invention relates to the use of 4, 5, 6, 7- tetrahydrothiophene and [3, 2 - C] pyridine hydrochloride which are used as the anticorrosive additives for the water-based anticorrosive paint. The water-based anticorrosive paint has a better anticorrosive effect and wide prospect in the industrial application.
Description
Technical field
The present invention relates to paint field, specifically, the present invention relates to a kind of water-based anticorrosive paint anti-corrosive aids.
Background technology
Steel Structure Work is made as main structure with steel, is one of modern main building construction types.The annual steel output in the whole world, more than 1,000,000,000 tons, is estimated about to be equivalent to 30% of annual production because corroding the steel equipment scrapped every year, and wherein about 1/3 permanently owing to reclaiming to lost, the financial loss brought is up to trillion dollars.Suffer except atomospheric corrosion except a large amount of steel construction is in open air, the erosion that the hardware in seashore periphery and Chemical Manufacture is subject to the corrosive mediums such as acid, alkali, salt is particularly serious.This protection against corrosion not only needing a large amount of financial resources of input and manpower to carry out perennially is safeguarded, and also has potential potential safety hazard.
With regard to present scientific and technical storage, to set about solving etching problem from steel construction itself very unrealistic for one speech, generally stainlessly involves great expense, and price is several times to tens times of the common high-quality steel of same specification, and work-ing life is limited.Then mainly there is insufficient strength in other corrosion resistant material, work-ing life is limited, less economical series of problems of Denging, and adopt paint spraying to be most widely used general, the most effective, the most economic means to prevent metallic corrosion.Again because the organic volatile in solvent based coating is to the pollution of air.So development long service life, cheap, safety non-toxic, energy-conserving and environment-protective, easy construction, novel aqueous steel structure protective system applied widely are very necessary.
Summary of the invention
The object of the present invention is to provide a kind of water-based anticorrosive paint anti-corrosive aids.
In order to realize object of the present invention, the invention provides 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride be used as the purposes in water-based anticorrosive paint anti-corrosive aids.
Preferably, described water-based anticorrosive paint can make whitewash.
Water-based anticorrosive paint of the present invention has good preservative effect, and industrial application has broad prospects.
Embodiment
Below by way of the description of embodiment, the invention will be further described, but this is not limitation of the present invention, those skilled in the art are according to basic thought of the present invention, various amendment or improvement can be made, but only otherwise depart from basic thought of the present invention, all within the scope of the present invention.
Embodiment 1
Take zinc phosphate 15 grams, aluminum phosphate 10 grams, adding 200ml concentration is in the ammoniacal liquor of 2 % by weight, 12h is stirred under the high speed dispersion of 2500r/min, then with 1000 object filtering nets, above-mentioned mixed solution is filtered, BH-620 aqueous dispersion type epoxy resin 150 grams is added in filtrate, BZ-1250 superfine talcum powder 2 grams, R-930 titanium dioxide 6 grams and 4, 5, 6, 7-tetramethylene sulfide also [3, 2-C] pyridine hydrochloride 2 grams stirs and then uses sand mill sand milling in 20 minutes under 500r/min, fineness is detected with Hegman grind gage, below sand milling to 50 μm, filter through 200 mesh filter screens, pack and obtain coating finished product.
Embodiment 2
Prepare water-based anticorrosive paint according to the mode identical with embodiment 1, difference is not use 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride.
Experimental example
Determine acid resistance according to GB/T 9274-88 standard gauge location survey, determine alkali resistance according to GB 9265-88 standard gauge location survey, measure resistance to salt water according to GB 1763-79 standard regulation.
The acid resistance of the coating in embodiment 1, alkali resistance and resistance to salt water are all without exception at 1200 hours, and the acid resistance of the coating of embodiment 2, alkali resistance and resistance to salt water are all without exception at 480 hours.Both compare has significant difference (P < 0.05).This illustrate, 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride add the preservative effect greatly enhancing coating.
Claims (2)
1.4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride is being used as the purposes in water-based anticorrosive paint anti-corrosive aids.
2. purposes according to claim 1, is characterized in that, described water-based anticorrosive paint can make whitewash.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410850448.2A CN104530809A (en) | 2014-12-31 | 2014-12-31 | Anticorrosive additives for water-based anticorrosive paint |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410850448.2A CN104530809A (en) | 2014-12-31 | 2014-12-31 | Anticorrosive additives for water-based anticorrosive paint |
Publications (1)
Publication Number | Publication Date |
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CN104530809A true CN104530809A (en) | 2015-04-22 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201410850448.2A Pending CN104530809A (en) | 2014-12-31 | 2014-12-31 | Anticorrosive additives for water-based anticorrosive paint |
Country Status (1)
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CN (1) | CN104530809A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105419438A (en) * | 2015-12-30 | 2016-03-23 | 李栋军 | Novel paint auxiliary agent |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1965710A1 (en) * | 1968-12-31 | 1970-07-16 | Union Carbide Corp | Condensed pyridones, process for their preparation and their uses |
-
2014
- 2014-12-31 CN CN201410850448.2A patent/CN104530809A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1965710A1 (en) * | 1968-12-31 | 1970-07-16 | Union Carbide Corp | Condensed pyridones, process for their preparation and their uses |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105419438A (en) * | 2015-12-30 | 2016-03-23 | 李栋军 | Novel paint auxiliary agent |
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Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |