CN104479502A - Water-base anticorrosive coating - Google Patents

Water-base anticorrosive coating Download PDF

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Publication number
CN104479502A
CN104479502A CN201410850446.3A CN201410850446A CN104479502A CN 104479502 A CN104479502 A CN 104479502A CN 201410850446 A CN201410850446 A CN 201410850446A CN 104479502 A CN104479502 A CN 104479502A
Authority
CN
China
Prior art keywords
parts
water
anticorrosive paint
based anticorrosive
anticorrosive coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410850446.3A
Other languages
Chinese (zh)
Inventor
张新良
王春华
赵虹
章伟杰
李文卫
王鹏飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGYIN TIANBANG PAINT Ltd BY SHARE Ltd
Original Assignee
JIANGYIN TIANBANG PAINT Ltd BY SHARE Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGYIN TIANBANG PAINT Ltd BY SHARE Ltd filed Critical JIANGYIN TIANBANG PAINT Ltd BY SHARE Ltd
Priority to CN201410850446.3A priority Critical patent/CN104479502A/en
Publication of CN104479502A publication Critical patent/CN104479502A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45Heterocyclic compounds having sulfur in the ring
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/327Aluminium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/328Phosphates of heavy metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to water-base anticorrosive coating which is prepared from the following raw materials in parts by weight: 100 to 200 parts of BH-620 water dispersible epoxy resin, 10 to 20 parts of zinc phosphate, 10 to 20 parts of aluminium phosphate, 1 to 5 parts of a BZ-1250 superfine talcum powder, 1 to 10 parts of R-930 titanium dioxide, and 1 to 10 parts of a corrosion-resistant additive. The water-base anticorrosive coating provided by the invention has a better corrosion-resistant effect and has a wide prospect in industrial application.

Description

A kind of water-based anticorrosive paint
Technical field
The present invention relates to paint field, specifically, the present invention relates to a kind of water-based anticorrosive paint.
Background technology
Steel Structure Work is made as main structure with steel, is one of modern main building construction types.The annual steel output in the whole world, more than 1,000,000,000 tons, is estimated about to be equivalent to 30% of annual production because corroding the steel equipment scrapped every year, and wherein about 1/3 permanently owing to reclaiming to lost, the financial loss brought is up to trillion dollars.Suffer except atomospheric corrosion except a large amount of steel construction is in open air, the erosion that the hardware in seashore periphery and Chemical Manufacture is subject to the corrosive mediums such as acid, alkali, salt is particularly serious.This protection against corrosion not only needing a large amount of financial resources of input and manpower to carry out perennially is safeguarded, and also has potential potential safety hazard.
With regard to present scientific and technical storage, to set about solving etching problem from steel construction itself very unrealistic for one speech, generally stainlessly involves great expense, and price is several times to tens times of the common high-quality steel of same specification, and work-ing life is limited.Then mainly there is insufficient strength in other corrosion resistant material, work-ing life is limited, less economical series of problems of Denging, and adopt paint spraying to be most widely used general, the most effective, the most economic means to prevent metallic corrosion.Again because the organic volatile in solvent based coating is to the pollution of air.So development long service life, cheap, safety non-toxic, energy-conserving and environment-protective, easy construction, novel aqueous steel structure protective system applied widely are very necessary.
Summary of the invention
The object of the present invention is to provide a kind of water-based anticorrosive paint.
In order to realize object of the present invention, the invention provides a kind of water-based anticorrosive paint, be made up of the raw material of following weight part: BH-620 aqueous dispersion type epoxy resin 100-200 part, zinc phosphate 10-20 part, aluminum phosphate 10-20 part, BZ-1250 superfine talcum powder 1-5 part, R-930 titanium dioxide 1-10 part and anti-corrosive aids 1-10 part.
Preferably, water-based anticorrosive paint of the present invention is made up of the raw material of following weight part: BH-620 aqueous dispersion type epoxy resin 150 parts, zinc phosphate 15 parts, aluminum phosphate 10 parts, BZ-1250 superfine talcum powder 2 parts, R-930 titanium dioxide 6 parts and anti-corrosive aids 2 parts.
More preferably, described anti-corrosive aids is 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride.
Most preferably, described water-based anticorrosive paint can make whitewash.
Water-based anticorrosive paint of the present invention has good preservative effect, and industrial application has broad prospects.
Embodiment
Below by way of the description of embodiment, the invention will be further described, but this is not limitation of the present invention, those skilled in the art are according to basic thought of the present invention, various amendment or improvement can be made, but only otherwise depart from basic thought of the present invention, all within the scope of the present invention.
Embodiment 1
Take zinc phosphate 15 grams, aluminum phosphate 10 grams, adding 200ml concentration is in the ammoniacal liquor of 2 % by weight, 12h is stirred under the high speed dispersion of 2500r/min, then with 1000 object filtering nets, above-mentioned mixed solution is filtered, BH-620 aqueous dispersion type epoxy resin 150 grams is added in filtrate, BZ-1250 superfine talcum powder 2 grams, R-930 titanium dioxide 6 grams and 4, 5, 6, 7-tetramethylene sulfide also [3, 2-C] pyridine hydrochloride 2 grams, stir under 500r/min and then use sand mill sand milling in 20 minutes, fineness is detected with Hegman grind gage, below sand milling to 50 μm, filter through 200 mesh filter screens, pack and obtain coating finished product.
Embodiment 2
Prepare water-based anticorrosive paint according to the mode identical with embodiment 1, difference is not use 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride.
Experimental example
Determine acid resistance according to GB/T 9274-88 standard gauge location survey, determine alkali resistance according to GB 9265-88 standard gauge location survey, measure resistance to salt water according to GB 1763-79 standard regulation.
The acid resistance of the coating in embodiment 1, alkali resistance and resistance to salt water are all without exception at 1200 hours, and the acid resistance of the coating of embodiment 2, alkali resistance and resistance to salt water are all without exception at 480 hours.Both compare has significant difference (P < 0.05).This illustrate, anti-corrosive aids add the preservative effect greatly enhancing coating.

Claims (4)

1. a water-based anticorrosive paint, it is characterized in that, be made up of the raw material of following weight part: BH-620 aqueous dispersion type epoxy resin 100-200 part, zinc phosphate 10-20 part, aluminum phosphate 10-20 part, BZ-1250 superfine talcum powder 1-5 part, R-930 titanium dioxide 1-10 part and anti-corrosive aids 1-10 part.
2. water-based anticorrosive paint according to claim 1, it is characterized in that, be made up of the raw material of following weight part: BH-620 aqueous dispersion type epoxy resin 150 parts, zinc phosphate 15 parts, aluminum phosphate 10 parts, BZ-1250 superfine talcum powder 2 parts, R-930 titanium dioxide 6 parts and anti-corrosive aids 2 parts.
3. water-based anticorrosive paint according to claim 2, is characterized in that, described anti-corrosive aids is 4,5,6,7-tetramethylene sulfide also [3,2-C] pyridine hydrochloride.
4. water-based anticorrosive paint according to claim 3, is characterized in that, described water-based anticorrosive paint can make whitewash.
CN201410850446.3A 2014-12-31 2014-12-31 Water-base anticorrosive coating Pending CN104479502A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410850446.3A CN104479502A (en) 2014-12-31 2014-12-31 Water-base anticorrosive coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410850446.3A CN104479502A (en) 2014-12-31 2014-12-31 Water-base anticorrosive coating

Publications (1)

Publication Number Publication Date
CN104479502A true CN104479502A (en) 2015-04-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410850446.3A Pending CN104479502A (en) 2014-12-31 2014-12-31 Water-base anticorrosive coating

Country Status (1)

Country Link
CN (1) CN104479502A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105504951A (en) * 2015-12-30 2016-04-20 王丽萍 Environment-friendly coating additive
CN106497323A (en) * 2016-10-21 2017-03-15 过冬 A kind of non-solvent epoxy pipeline coating and preparation method thereof
CN106811005A (en) * 2017-02-03 2017-06-09 安徽华晟涂料有限公司 A kind of anticorrosion water-soluble coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1452624A (en) * 2000-07-06 2003-10-29 三共株式会社 Hydropyridine deriv. acid addition salts
CN101230228A (en) * 2007-01-26 2008-07-30 深圳市海川实业股份有限公司 Single-component aqueous epoxy medium temperature curing rust-inhibiting paint
CN101591499A (en) * 2009-05-21 2009-12-02 浙江天女集团制漆有限公司 Heavy sizing aqueous heavy anti-corrosion paint and production method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1452624A (en) * 2000-07-06 2003-10-29 三共株式会社 Hydropyridine deriv. acid addition salts
CN101230228A (en) * 2007-01-26 2008-07-30 深圳市海川实业股份有限公司 Single-component aqueous epoxy medium temperature curing rust-inhibiting paint
CN101591499A (en) * 2009-05-21 2009-12-02 浙江天女集团制漆有限公司 Heavy sizing aqueous heavy anti-corrosion paint and production method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘秉智等: "4,5,6,7-四氢噻吩并[3,2-c]吡啶的合成研究", 《科学技术与工程》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105504951A (en) * 2015-12-30 2016-04-20 王丽萍 Environment-friendly coating additive
CN106497323A (en) * 2016-10-21 2017-03-15 过冬 A kind of non-solvent epoxy pipeline coating and preparation method thereof
CN106811005A (en) * 2017-02-03 2017-06-09 安徽华晟涂料有限公司 A kind of anticorrosion water-soluble coating and preparation method thereof

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Application publication date: 20150401