CN104530758A - Heterocyclic disperse dye and preparation method thereof - Google Patents
Heterocyclic disperse dye and preparation method thereof Download PDFInfo
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- CN104530758A CN104530758A CN201410786286.0A CN201410786286A CN104530758A CN 104530758 A CN104530758 A CN 104530758A CN 201410786286 A CN201410786286 A CN 201410786286A CN 104530758 A CN104530758 A CN 104530758A
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Abstract
The invention discloses a heterocyclic disperse dye and a preparation method thereof. The heterocyclic disperse dye is characterized by being prepared from the following raw materials in parts by weight: 100-110 parts of a heterocyclic dyeing material, 1-2 parts of octaphenyl polyoxyethyiene, 1-2 parts of sodium citrate, 2-3 parts of carboxymethylcellulose, 130-150 parts of deionized water, 1-2 parts of polyethylene glycol, a penetrant JFC1-2, 1-2 parts of N-vinyl pyrrolidone, 3-4 parts of acrylic ester, 1-2 parts of sodium sulfate, a crosslinking agent TAC1-2, 0.5-1 part of zinc stearate, 1-2 parts of carboxymethyl chitosan, 0.3-0.6 part of organosiloxane, and 3-5 parts of an additive. The disperse dye prepared by the invention has the advantages of high washing firmness, high hydrophobicity, good sublimation resistance, and good leveling property, and also has the advantages of good fixation rate, improving property, and environmental friendliness, simple process, and convenience in operation.
Description
Technical field
The present invention relates to dispersed dye and Application Areas thereof, particularly a kind of heterocyclic type dispersed dye and preparation method thereof.
Background technology
China is dyestuff output big country, but most of production commercial city is confined in the production of primary raw material and primary chemical, in later stage fine processing technique etc., still have certain distance with world lead level.For this reason, country lists commercialization of dyes processing technology in " encouraging foreign investment industry catalogue ", this reprocessing plant has low stain, high profit return property, hi-tech, and its Commissioning Technique will play to domestic dye industry the effect of drawing high, and promote domesticly to carry out upgrading of industries.
Dispersed dye are the water-soluble lower nonionic dyes of a class.The earliest for the dyeing of cellulose acetate fibre, be called cellulose acetate dye.Along with the development of synthon, polyamide fibre, terylene occur in succession, especially terylene, high owing to having permutation degree, the characteristics such as fiber gap is few, and hydrophobicity is strong, and will make swelling of fiber having under carrier or high temperature, thermosol, dyestuff just can enter fiber and upper dye.Therefore, new requirement is proposed to dyestuff, namely require the dyestuff with better hydrophobicity and certain dispersiveness and resistance to distillation etc.Heterocyclic type dyestuff has bright-colored, tinctorial strength, dyeing firmly fixed height, along with the raising of people's living standard, also more and more higher to the environmental requirement of textile product, the present invention, according to this situation, is carried out homogeneous blending realized people to coloured light needed for dyestuff, power part and firmly demand by accurate proportioning.
Summary of the invention
The object of this invention is to provide a kind of heterocyclic type dispersed dye and preparation method thereof and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of heterocyclic type dispersed dye and preparation method thereof, are made up of the raw material of following weight part: heterocyclic type dyeing raw material 100-110, polyoxyethylene octylphenol ether 1-2, Sodium Citrate 1-2, carboxymethyl cellulose 2-3, deionized water 130-150, polyoxyethylene glycol 1-2, penetrating agent JFC 1-2, N-vinylpyridine network alkane ketone 1-2, acrylate 3-4, Sodium sulfate anhydrous.min(99) 1-2, linking agent TAC1-2, Zinic stearas 0.5-1, cm-chitosan 1-2, organo-siloxane 0.3-0.6, auxiliary agent 3-5;
Described auxiliary agent is made up of the raw material of following weight part: Sudan Gum-arabic 3-4, two lauryl alcohol ester 1-2, leveling agent d A2-3, lemon oil 3-4, geranial 1-2, methyl amyl alcohol 1-2, tripoly phosphate sodium STPP 1-2, octadecylisocyanate 3-5, trolamine 0.2-0.5, alkylphenol polyoxyethylene 2-3, sodium sulphite anhydrous 99.3 1-2, deionized water 10-15; Alkylphenol polyoxyethylene is added in deionized water by preparation method, is heated to 60-70 ° of C, then adds methyl amyl alcohol, tripoly phosphate sodium STPP, octadecylisocyanate, leveling agent d A form clear viscous liquid after stirring; Lemon oil, geranial, Sudan Gum-arabic, two lauryl alcohol ester are mixed and heated to 60-80 ° of C, are added to after stirring in the liquid of above-mentioned clear viscous and stir 15-20 minute under 800-1200 rev/min, then add all the other surplus materialss and stir.
A kind of heterocyclic type dispersed dye of the present invention and preparation method thereof, be made up of following concrete steps:
(1) by deionized water, organo-siloxane, carboxymethyl cellulose, polyoxyethylene glycol, cm-chitosan mixing, slowly be heated to 50-60 ° of C while stirring, reaction 0.5-1 hour, then add Zinic stearas, acrylate, auxiliary agent continuation stirring reaction 1-2 hour;
(2) reaction terminates to add heterocyclic type dyeing raw material, Sodium Citrate, linking agent TAC in backward step (1), continues to be warming up to 80-85 ° of C, and insulation reaction 0.5-1 hour;
(3) all the other remaining materials are mixed in the reaction product being added to step (2), after being uniformly mixed, be added to ground leaching filtrate in sand mill.
Advantage of the present invention is: disperse dye washing firmness prepared by the present invention is high, and hydrophobicity is strong, and resistance to sublimability is good, good level-dyeing property, also has good degree of fixation, enhancing and the feature of environmental protection, and technique is simple, easy to operate.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of heterocyclic type dispersed dye and preparation method thereof, are made up of the raw material of following weight part (kilogram): heterocyclic type dyeing raw material 100, polyoxyethylene octylphenol ether 1, Sodium Citrate 1, carboxymethyl cellulose 2, deionized water 140, polyoxyethylene glycol 2, penetrating agent JFC 1, N-vinylpyridine network alkane ketone 2, acrylate 3, Sodium sulfate anhydrous.min(99) 1, linking agent TAC2, Zinic stearas 0.6, cm-chitosan 1, organo-siloxane 0.5, auxiliary agent 4;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): Sudan Gum-arabic 4, two lauryl alcohol ester 1, leveling agent d A3, lemon oil 3, geranial 1, methyl amyl alcohol 1, tripoly phosphate sodium STPP 2, octadecylisocyanate 4, trolamine 0.3, alkylphenol polyoxyethylene 2, sodium sulphite anhydrous 99.3 2, deionized water 15; Alkylphenol polyoxyethylene is added in deionized water by preparation method, is heated to 60-70 ° of C, then adds methyl amyl alcohol, tripoly phosphate sodium STPP, octadecylisocyanate, leveling agent d A form clear viscous liquid after stirring; Lemon oil, geranial, Sudan Gum-arabic, two lauryl alcohol ester are mixed and heated to 60-80 ° of C, are added to after stirring in the liquid of above-mentioned clear viscous and stir 15-20 minute under 800-1200 rev/min, then add all the other surplus materialss and stir.
A kind of heterocyclic type dispersed dye of the present invention and preparation method thereof, be made up of following concrete steps:
(1) by deionized water, organo-siloxane, carboxymethyl cellulose, polyoxyethylene glycol, cm-chitosan mixing, slowly be heated to 50-60 ° of C while stirring, reaction 0.5-1 hour, then add Zinic stearas, acrylate, auxiliary agent continuation stirring reaction 1-2 hour;
(2) reaction terminates to add heterocyclic type dyeing raw material, Sodium Citrate, linking agent TAC in backward step (1), continues to be warming up to 80-85 ° of C, and insulation reaction 0.5-1 hour;
(3) all the other remaining materials are mixed in the reaction product being added to step (2), after being uniformly mixed, be added to ground leaching filtrate in sand mill.
Through inspection, dyestuff washing fastness of the present invention is 4 grades, and crock fastness is 5 grades, and sublimation fastness (180 ° of C) is 4 grades, and light fastness is 7 grades.
Claims (2)
1. heterocyclic type dispersed dye and preparation method thereof, it is characterized in that, be made up of the raw material of following weight part: heterocyclic type dyeing raw material 100-110, polyoxyethylene octylphenol ether 1-2, Sodium Citrate 1-2, carboxymethyl cellulose 2-3, deionized water 130-150, polyoxyethylene glycol 1-2, penetrating agent JFC 1-2, N-vinylpyridine network alkane ketone 1-2, acrylate 3-4, Sodium sulfate anhydrous.min(99) 1-2, linking agent TAC1-2, Zinic stearas 0.5-1, cm-chitosan 1-2, organo-siloxane 0.3-0.6, auxiliary agent 3-5;
Described auxiliary agent is made up of the raw material of following weight part: Sudan Gum-arabic 3-4, two lauryl alcohol ester 1-2, leveling agent d A2-3, lemon oil 3-4, geranial 1-2, methyl amyl alcohol 1-2, tripoly phosphate sodium STPP 1-2, octadecylisocyanate 3-5, trolamine 0.2-0.5, alkylphenol polyoxyethylene 2-3, sodium sulphite anhydrous 99.3 1-2, deionized water 10-15; Alkylphenol polyoxyethylene is added in deionized water by preparation method, is heated to 60-70 ° of C, then adds methyl amyl alcohol, tripoly phosphate sodium STPP, octadecylisocyanate, leveling agent d A form clear viscous liquid after stirring; Lemon oil, geranial, Sudan Gum-arabic, two lauryl alcohol ester are mixed and heated to 60-80 ° of C, are added to after stirring in the liquid of above-mentioned clear viscous and stir 15-20 minute under 800-1200 rev/min, then add all the other surplus materialss and stir.
2. a kind of heterocyclic type dispersed dye according to claim 1 and preparation method thereof, is characterized in that, be made up of following concrete steps:
(1) by deionized water, organo-siloxane, carboxymethyl cellulose, polyoxyethylene glycol, cm-chitosan mixing, slowly be heated to 50-60 ° of C while stirring, reaction 0.5-1 hour, then add Zinic stearas, acrylate, auxiliary agent continuation stirring reaction 1-2 hour;
(2) reaction terminates to add heterocyclic type dyeing raw material, Sodium Citrate, linking agent TAC in backward step (1), continues to be warming up to 80-85 ° of C, and insulation reaction 0.5-1 hour;
(3) all the other remaining materials are mixed in the reaction product being added to step (2), after being uniformly mixed, be added to ground leaching filtrate in sand mill.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153749A (en) * | 2015-09-18 | 2015-12-16 | 太仓市国峰纺织印染有限责任公司 | Preparation method of novel polyester fiber dyeing composition |
| CN107780243A (en) * | 2016-08-30 | 2018-03-09 | 江苏吉华化工有限公司 | A kind of preparation method of high-performance polyetheretherketonefiber fiber product disperse dyes system |
| CN107793791A (en) * | 2016-08-30 | 2018-03-13 | 江苏吉华化工有限公司 | A kind of preparation method of automatically cleaning disperse dyes |
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| US4812143A (en) * | 1986-12-22 | 1989-03-14 | Cassella Aktiengesellschaft | Liquid formulations of disperse dyestuffs containing inorganic oxides or silicates for dyeing textile materials |
| CN101676488A (en) * | 2008-09-16 | 2010-03-24 | 朱樑 | Pulp-shaped dispersed dyes used in fabrics printing and dyeing |
| CN102051069A (en) * | 2010-10-24 | 2011-05-11 | 绍兴文理学院 | Nonionic disperse system liquid-shaped disperse dye and preparation method thereof |
| WO2012064859A2 (en) * | 2010-11-12 | 2012-05-18 | Invista Technologies S.Ar.L. | Aqueous dispersion of dye, stain-blocker, and fluorochemical and its use in the manufacture of carpet |
| CN102504595A (en) * | 2011-11-15 | 2012-06-20 | 东营安诺其纺织材料有限公司 | Azo dye composition, preparation method thereof and use method thereof |
| CN102838897A (en) * | 2012-09-26 | 2012-12-26 | 长胜纺织科技发展(上海)有限公司 | Disperse dye ink for cold transfer printing and application method thereof |
| CN103497589A (en) * | 2013-10-10 | 2014-01-08 | 鲁继烈 | Aqueous disperse dye ink-jet printing ink |
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2014
- 2014-12-18 CN CN201410786286.0A patent/CN104530758A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4812143A (en) * | 1986-12-22 | 1989-03-14 | Cassella Aktiengesellschaft | Liquid formulations of disperse dyestuffs containing inorganic oxides or silicates for dyeing textile materials |
| CN101676488A (en) * | 2008-09-16 | 2010-03-24 | 朱樑 | Pulp-shaped dispersed dyes used in fabrics printing and dyeing |
| CN102051069A (en) * | 2010-10-24 | 2011-05-11 | 绍兴文理学院 | Nonionic disperse system liquid-shaped disperse dye and preparation method thereof |
| WO2012064859A2 (en) * | 2010-11-12 | 2012-05-18 | Invista Technologies S.Ar.L. | Aqueous dispersion of dye, stain-blocker, and fluorochemical and its use in the manufacture of carpet |
| CN102504595A (en) * | 2011-11-15 | 2012-06-20 | 东营安诺其纺织材料有限公司 | Azo dye composition, preparation method thereof and use method thereof |
| CN102838897A (en) * | 2012-09-26 | 2012-12-26 | 长胜纺织科技发展(上海)有限公司 | Disperse dye ink for cold transfer printing and application method thereof |
| CN103497589A (en) * | 2013-10-10 | 2014-01-08 | 鲁继烈 | Aqueous disperse dye ink-jet printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153749A (en) * | 2015-09-18 | 2015-12-16 | 太仓市国峰纺织印染有限责任公司 | Preparation method of novel polyester fiber dyeing composition |
| CN107780243A (en) * | 2016-08-30 | 2018-03-09 | 江苏吉华化工有限公司 | A kind of preparation method of high-performance polyetheretherketonefiber fiber product disperse dyes system |
| CN107793791A (en) * | 2016-08-30 | 2018-03-13 | 江苏吉华化工有限公司 | A kind of preparation method of automatically cleaning disperse dyes |
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