CN104530500A - Mildew-proof antibacterial shoe rubber and preparation process thereof - Google Patents
Mildew-proof antibacterial shoe rubber and preparation process thereof Download PDFInfo
- Publication number
- CN104530500A CN104530500A CN201410816398.6A CN201410816398A CN104530500A CN 104530500 A CN104530500 A CN 104530500A CN 201410816398 A CN201410816398 A CN 201410816398A CN 104530500 A CN104530500 A CN 104530500A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- antimildew
- agent
- antibacterial shoe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides mildew-proof antibacterial shoe rubber and a preparation process thereof. The rubber is prepared from the following raw materials in parts by mass: 100-150 parts of natural rubber, 50-70 parts of styrene-butadiene rubber, 20-50 parts of a filler, 5-7 parts of zinc oxide powder, 1-2 parts of stearic acid, 6-9 parts of an active agent DEG, 0.8-1.2 parts of an anti-aging agent SP, 0.8-1.0 part of an accelerant CZ/NS, 0.2-0.3 part of an accelerant TT/TS and 1.5-2.0 parts of sulfur. The mildew-proof antibacterial shoe rubber provided by the invention has relatively good mildew-proof, antibacterial and moisture-proof effects, and the service life of the rubber can be prolonged.
Description
Technical field
The present invention relates to material for shoes technical field, be specifically related to a kind of antimildew and antibacterial shoe rubber and preparation technology thereof.
Background technology
Shoe rubber material refers to the base material for the manufacture of conventional shoes, generally makes with natural rubber and styrene-butadiene rubber(SBR) or polybutadiene rubber.The footwear made with these elastomeric materials is in long-term transport, storage process, due to the unstable of previous fabrication processes and the change of follow-up artificial, physical environment, larger infringement, erosion can be caused to rubber footwear product, thus cause greatly reduce the work-ing life of product, cause damage to manufacturing enterprise.Thus, how to improve the performance of rubber footwear product, make it avoid producing unnecessary loss in lengthy warehousing, transportation, the product developing the problems such as the antimildew and antibacterial that fundamentally can solve rubber footwear product is moistureproof also just becomes the task of top priority.
Summary of the invention
The object of this invention is to provide a kind of antimildew and antibacterial shoe rubber, it has the moistureproof effect of good antimildew and antibacterial, can increase the service life.
In addition, another object of the present invention is to provide a kind of preparation technology of antimildew and antibacterial shoe rubber, and preparation process is simple, excellent product performance.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of antimildew and antibacterial shoe rubber, comprises the raw material of following mass parts: natural rubber 100 ~ 150 parts, 50 ~ 70 parts, styrene-butadiene rubber(SBR), weighting agent 20 ~ 50 parts, oxide powder and zinc 5 ~ 7 parts, stearic acid 1 ~ 2 part, promoting agent 6 ~ 9 parts, 0.8 ~ 1.2 part, anti-aging agent, promotor 1.0 ~ 1.3 parts, 1.5 ~ 2.0 parts, sulphur.
A preparation technology for antimildew and antibacterial shoe rubber, comprises the steps:
1) dnockout:
A) natural rubber, styrene-butadiene rubber(SBR) is mixing, temperature controls at 70 ~ 80 degree, and the time is 2 ~ 3 minutes;
B) add 65% of weighting agent total mass, all oxide powder and zinc, stearic acid, promoting agent and anti-aging agent, continue mixing, temperature controls at 90 ~ 100 degree, and the time is 2 ~ 3 minutes;
C) add remaining weighting agent and whole promotor, continue mixing, temperature controls at 110 ~ 130 degree, discharging after mixing 2 ~ 3 minutes, and leaves standstill 1 ~ 5 hour;
2) high temperature vulcanized: in compound prepared by step 1, add sulphur carry out sulfuration, temperature controls at 140 ~ 160 degree, sulfuration discharging after 4 ~ 6 minutes, and leaves standstill 3 ~ 8 hours.
According to above scheme, described weighting agent is White Carbon black.
According to above scheme, described promoting agent is Diethylene Glycol glycol ether (DEG).
According to above scheme, described anti-aging agent is styrenated phenol (SP).
According to above scheme, described promotor comprises N-cyclohexyl-2-benzothiazole sulfonamide (CZ), the N-tertiary butyl-2-benzothiazole sulfonamide (NS), tetramethyl-thiuram disulfide (TT), tetramethylthiuram monosulfide (TS), wherein N-cyclohexyl-2-benzothiazole sulfonamide (CZ) or the N-tertiary butyl-2-benzothiazole sulfonamide (NS) account for 0.8 ~ 1.0 part of total component, and tetramethyl-thiuram disulfide (TT) or tetramethylthiuram monosulfide (TS) account for 0.2 ~ 0.3 part of total component.
The invention has the beneficial effects as follows:
1) in preparation technology of the present invention, major ingredient rubber is mixed in advance, then add other batching respectively, each component can be made to mix, the reliable product quality of preparation;
2) the high temperature vulcanized standing toughness that can improve rubber major ingredient, extends the life-span of product;
3) the adding of multiple additives, make the present invention have mildew-resistant, antibacterial, moistureproof effect, be particularly suitable for being applied in footwear.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described.
embodiment 1:
A kind of antimildew and antibacterial shoe rubber, comprises the raw material of following mass parts: natural rubber 1200g, styrene-butadiene rubber(SBR) 600g, weighting agent 400g, oxide powder and zinc 60g, stearic acid 15g, promoting agent DEG 80g, antioxidant SP 11g, accelerant CZ 9g, promotor TS 2.5g, sulphur 18g.
A preparation technology for antimildew and antibacterial shoe rubber, comprises the steps:
1) dnockout:
A) natural rubber, styrene-butadiene rubber(SBR) is mixing, temperature controls at 75 degree, and the time is 2 minutes;
B) add 390g weighting agent, all oxide powder and zinc, stearic acid, promoting agent and anti-aging agent, continue mixing, temperature controls at 95 degree, and the time is 3 minutes;
C) add remaining weighting agent and whole promotor, continue mixing, temperature controls at 120 degree, discharging after mixing 2 minutes, and leaves standstill 0.8 hour;
2) high temperature vulcanized: in compound prepared by step 1, add sulphur carry out sulfuration, temperature controls at 150 degree, sulfuration discharging after 5 minutes, and leaves standstill 5 hours.
embodiment 2:
A kind of antimildew and antibacterial shoe rubber, comprises the raw material of following mass parts: natural rubber 1000g, styrene-butadiene rubber(SBR) 500g, weighting agent 200g, oxide powder and zinc 50g, stearic acid 10g, promoting agent DEG 60g, antioxidant SP 8.0g, accelerant CZ 8.0g, promotor TT 2.0g, sulphur 15g.
A preparation technology for antimildew and antibacterial shoe rubber, comprises the steps:
1) dnockout:
A) natural rubber, styrene-butadiene rubber(SBR) is mixing, temperature controls at 70 degree, and the time is 2 minutes;
B) add weighting agent 130g, all oxide powder and zinc, stearic acid, promoting agent and anti-aging agent, continue mixing, temperature controls at 90 degree, and the time is 2 minutes;
C) add remaining weighting agent and whole promotor, continue mixing, temperature controls at 130 degree, discharging after mixing 2 minutes, and leaves standstill 0.5 hour;
2) high temperature vulcanized: in compound prepared by step 1, add sulphur carry out sulfuration, temperature controls at 140 ~ 150 degree, sulfuration discharging after 4 minutes, and leaves standstill 2 hours.
embodiment 3:
A kind of antimildew and antibacterial shoe rubber, comprises the raw material of following mass parts: natural rubber 1500g, styrene-butadiene rubber(SBR) 700g, weighting agent 500g, oxide powder and zinc 70g, stearic acid 20g, promoting agent DEG 90g, antioxidant SP 12g, accelerator NS 10g, promotor TS 3g, sulphur 20g.
A preparation technology for antimildew and antibacterial shoe rubber, comprises the steps:
1) dnockout:
A) natural rubber, styrene-butadiene rubber(SBR) is mixing, temperature controls at 80 degree, and the time is 3 minutes;
B) add 455g weighting agent, all oxide powder and zinc, stearic acid, promoting agent and anti-aging agent, continue mixing, temperature controls at 100 degree, and the time is 3 minutes;
C) add remaining weighting agent and whole promotor, continue mixing, temperature controls at 110 degree, discharging after mixing 3 minutes, and leaves standstill 1 hour;
2) high temperature vulcanized: in compound prepared by step 1, add sulphur carry out sulfuration, temperature controls at 160 degree, sulfuration discharging after 6 minutes, and leaves standstill 8 hours.
Claims (6)
1. an antimildew and antibacterial shoe rubber, it is characterized in that, comprise the raw material of following mass parts: natural rubber 100 ~ 150 parts, 50 ~ 70 parts, styrene-butadiene rubber(SBR), weighting agent 20 ~ 50 parts, oxide powder and zinc 5 ~ 7 parts, stearic acid 1 ~ 2 part, promoting agent 6 ~ 9 parts, 0.8 ~ 1.2 part, anti-aging agent, promotor 1.0 ~ 1.3 parts, 1.5 ~ 2.0 parts, sulphur.
2. the preparation technology of antimildew and antibacterial shoe rubber according to claim 1, comprises the steps:
1) dnockout:
A) natural rubber, styrene-butadiene rubber(SBR) is mixing, temperature controls at 70 ~ 80 degree, and the time is 2 ~ 3 minutes;
B) add 65% of weighting agent total mass, all oxide powder and zinc, stearic acid, promoting agent and anti-aging agent, continue mixing, temperature controls at 90 ~ 100 degree, and the time is 2 ~ 3 minutes;
C) add remaining weighting agent and whole promotor, continue mixing, temperature controls at 110 ~ 130 degree, discharging after mixing 2 ~ 3 minutes, and leaves standstill 0.5 ~ 1 hour;
2) high temperature vulcanized: in compound prepared by step 1, add sulphur carry out sulfuration, temperature controls at 140 ~ 160 degree, sulfuration discharging after 4 ~ 6 minutes, and leaves standstill 2 ~ 8 hours.
3. antimildew and antibacterial shoe rubber according to claim 1, is characterized in that, described weighting agent is White Carbon black.
4. antimildew and antibacterial shoe rubber according to claim 1, is characterized in that, described promoting agent is Diethylene Glycol glycol ether.
5. antimildew and antibacterial shoe rubber according to claim 1, is characterized in that, described anti-aging agent is styrenated phenol.
6. antimildew and antibacterial shoe rubber according to claim 1, it is characterized in that, described promotor comprises N-cyclohexyl-2-benzothiazole sulfonamide, the N-tertiary butyl-2-benzothiazole sulfonamide, tetramethyl-thiuram disulfide, tetramethylthiuram monosulfide, wherein N-cyclohexyl-2-benzothiazole sulfonamide or the N-tertiary butyl-2-benzothiazole sulfonamide account for 0.8 ~ 1.0 part of total component, and tetramethyl-thiuram disulfide or tetramethylthiuram monosulfide account for 0.2 ~ 0.3 part of total component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410816398.6A CN104530500A (en) | 2014-12-25 | 2014-12-25 | Mildew-proof antibacterial shoe rubber and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410816398.6A CN104530500A (en) | 2014-12-25 | 2014-12-25 | Mildew-proof antibacterial shoe rubber and preparation process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104530500A true CN104530500A (en) | 2015-04-22 |
Family
ID=52846149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410816398.6A Pending CN104530500A (en) | 2014-12-25 | 2014-12-25 | Mildew-proof antibacterial shoe rubber and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104530500A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844862A (en) * | 2015-05-18 | 2015-08-19 | 上海扶联电梯配件有限公司 | Antibacterial rubber and preparing method thereof |
| CN107641230A (en) * | 2017-08-18 | 2018-01-30 | 西北矿冶研究院 | Sterilization mould-proof rubber floor manufactured by using acidized modified white ash |
| CN109135078A (en) * | 2018-09-13 | 2019-01-04 | 温州安宝乐鞋业科技有限公司 | Children's on-slip function shoes |
| CN109749138A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of antibacterial rubber material |
| CN116376126A (en) * | 2023-03-20 | 2023-07-04 | 界首市玉丰塑业有限公司 | Preparation method of rubber for antibacterial rubber shoes |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665591A (en) * | 2008-09-05 | 2010-03-10 | 江苏省派登鞋业有限公司 | Sole material for insulating labor protection shoes |
| CN101914227A (en) * | 2010-09-21 | 2010-12-15 | 际华三五三七制鞋有限责任公司 | Formula and preparation method of extinction type shoe rubber |
-
2014
- 2014-12-25 CN CN201410816398.6A patent/CN104530500A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665591A (en) * | 2008-09-05 | 2010-03-10 | 江苏省派登鞋业有限公司 | Sole material for insulating labor protection shoes |
| CN101914227A (en) * | 2010-09-21 | 2010-12-15 | 际华三五三七制鞋有限责任公司 | Formula and preparation method of extinction type shoe rubber |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844862A (en) * | 2015-05-18 | 2015-08-19 | 上海扶联电梯配件有限公司 | Antibacterial rubber and preparing method thereof |
| CN107641230A (en) * | 2017-08-18 | 2018-01-30 | 西北矿冶研究院 | Sterilization mould-proof rubber floor manufactured by using acidized modified white ash |
| CN107641230B (en) * | 2017-08-18 | 2020-02-28 | 西北矿冶研究院 | Sterilization mould-proof rubber floor manufactured by using acidized modified white ash |
| CN109749138A (en) * | 2017-11-02 | 2019-05-14 | 丹阳市贝尔特橡塑制品有限公司 | A kind of antibacterial rubber material |
| CN109135078A (en) * | 2018-09-13 | 2019-01-04 | 温州安宝乐鞋业科技有限公司 | Children's on-slip function shoes |
| CN109135078B (en) * | 2018-09-13 | 2020-12-29 | 浙江安宝乐科技有限公司 | Children's anti-slip functional shoes |
| CN116376126A (en) * | 2023-03-20 | 2023-07-04 | 界首市玉丰塑业有限公司 | Preparation method of rubber for antibacterial rubber shoes |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104530500A (en) | Mildew-proof antibacterial shoe rubber and preparation process thereof | |
| CN102093600B (en) | Wear-resisting sole material and preparation method thereof | |
| CN105778179A (en) | Rubber composition and application thereof | |
| CN102731848A (en) | Wear-resistant multiple-rubber-mixed rubber sealing ring | |
| CN102181083A (en) | Oil-resistant anti-slip rubber for soles and preparation method thereof | |
| CN112239573B (en) | Rubber composition for wear-resistant sole, vulcanized rubber, and preparation method and application thereof | |
| CN103589031A (en) | Antibacterial foamed rubber sole material | |
| JP5194729B2 (en) | Lead acid battery | |
| CN102731856A (en) | Butadiene rubber and chloroprene rubber mixed rubber sealing ring | |
| CN109836630A (en) | A kind of high-weatherability white rubber sole and preparation method thereof | |
| CN103205027A (en) | Rubber for shoe materials | |
| JP2008031433A (en) | Rubber composition for sidewall and pneumatic tire having sidewall using the same | |
| CN104371151A (en) | Calendered black rubber surround bar for flexing endurable liberation shoes as well as preparation method and application of calendered black rubber surround bar | |
| CN102020793A (en) | Heat-preservation folding-resistance vamp material and preparation method thereof | |
| CN105237824A (en) | Lightweight rain boot and making method thereof | |
| CN104371149A (en) | Rolled type black rubber surrounding bar rubber for wear-resisting liberation shoes as well as preparation method and application thereof | |
| CN103937048A (en) | Non-frosting rubber used for dark-color shoe sole and preparing method thereof | |
| CN105218886A (en) | At the bottom of the extremely cold-resistant high elasticity abrasion-proof glue of one | |
| CN107033401A (en) | A kind of military rubber fender of high-performance and preparation method thereof | |
| US20170130037A1 (en) | Rubber compound to produce tyres | |
| CN103980561A (en) | All-steel radial giant engineering tire sidewall filling rubber | |
| CN104311936A (en) | High-elasticity low-hardness synthetic rubber for color selector and preparation method thereof | |
| CN104356437A (en) | Calendering type leaf-yellow rubber foxing glue for liberation shoes, and preparation method and application thereof | |
| KR20130127755A (en) | Rubber composition styrene-butadiene based for outsole having excellent hardness change property | |
| US20150368445A1 (en) | Tyre high-stiffness compound |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |
|
| RJ01 | Rejection of invention patent application after publication |