CN104529552B - Ceramic glaze is formed the method for crocodile skin scale appearance effect - Google Patents
Ceramic glaze is formed the method for crocodile skin scale appearance effect Download PDFInfo
- Publication number
- CN104529552B CN104529552B CN201410726235.9A CN201410726235A CN104529552B CN 104529552 B CN104529552 B CN 104529552B CN 201410726235 A CN201410726235 A CN 201410726235A CN 104529552 B CN104529552 B CN 104529552B
- Authority
- CN
- China
- Prior art keywords
- wingdale
- clay
- quartz
- talcum
- glaze layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 14
- 241000270722 Crocodylidae Species 0.000 title claims abstract description 9
- LNNWVNGFPYWNQE-GMIGKAJZSA-N desomorphine Chemical compound C1C2=CC=C(O)C3=C2[C@]24CCN(C)[C@H]1[C@@H]2CCC[C@@H]4O3 LNNWVNGFPYWNQE-GMIGKAJZSA-N 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004927 clay Substances 0.000 claims abstract description 17
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010453 quartz Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 17
- 229910052623 talc Inorganic materials 0.000 claims abstract description 17
- 239000000454 talc Substances 0.000 claims abstract description 17
- 235000012222 talc Nutrition 0.000 claims abstract description 17
- 235000015895 biscuits Nutrition 0.000 claims abstract description 13
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 12
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 6
- 229910000389 calcium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000011010 calcium phosphates Nutrition 0.000 claims abstract description 6
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 6
- 229920000742 Cotton Polymers 0.000 claims abstract description 5
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 5
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007921 spray Substances 0.000 claims abstract description 5
- 239000006210 lotion Substances 0.000 claims abstract description 4
- 229910052656 albite Inorganic materials 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- WQEVDHBJGNOKKO-UHFFFAOYSA-K vanadic acid Chemical compound O[V](O)(O)=O WQEVDHBJGNOKKO-UHFFFAOYSA-K 0.000 claims description 3
- 239000010433 feldspar Substances 0.000 abstract 3
- -1 Wingdale Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The present invention discloses a kind of ceramic with crocodile skin scale appearance effect, comprise making biscuit, spray by ferric oxide, zirconium white, Vanadium Pentoxide in FLAKES, antimonous oxide, feldspar, clay, Wingdale, quartz, the first glaze layer that talcum is formed, paste the cotton gauze soaking perstearic acid lotion, soak by feldspar, clay, Wingdale, quartz, talcum, calcium phosphate, ferric oxide, with the second glaze layer of zirconium white composition, spraying is by cobalt oxide, nickel oxide, chromium sesquioxide, zirconium white, ferric oxide, Manganse Dioxide, feldspar, clay, Wingdale, quartz, 3rd glaze layer of talcum composition, roasting becomes finished product.
Description
Technical field
The present invention relates to the manufacture method of ceramic, on Ceramic glaze, specifically form the method for crocodile skin scale appearance effect.
Background technology
Domestic ceramics art ceramics is due to cosmetic requirement, various concavo-convex lines, plate, pattern or embossment is made on surface, existing method roughly two kinds, one forms concavo-convex lines, curved surface when making biscuit of ceramics, and this way lines are simple, lack natural sense, another kind is that sintering procedure transmutation in glaze paint is formed concavo-convex, but concavo-convex position occurs at random, can not carry out expecting and controlling, therefore can not form the ceramic with simulation crocodile skin scale appearance effect.
Summary of the invention
The object of the present invention is to provide a kind of ceramic with crocodile skin scale appearance effect.
The present invention includes following step:
A. ceramic biscuit is made;
B. the first glaze layer is sprayed, first glaze layer is by weight percentage by ferric oxide 5-8%, zirconium white 10-20%, Vanadium Pentoxide in FLAKES 6-12%, antimonous oxide 4-8%, albite or potassium felspar sand 10-15%, clay 10-20%, Wingdale 10-20%, quartz 8-15%, talcum 10-18% is formed, and the first glazed thickness is 0.05-0.1mm;
C. soak containing stearic acid 5-15% by cotton gauze, sodium hydroxide 1-3%, vanadic acid sodium 0.5-2%, surplus is dry after the lotion of water, is pasted onto on biscuit;
D. soak by weight percentage by albite or potassium felspar sand 12-18%, clay 15-25%, Wingdale 10-20%, quartz 8-15%, talcum 15-30%, calcium phosphate 10-20%, the second glaze layer that ferric oxide 1-3% and zirconium white 3-5% form, the second glazed thickness is 0.5-1mm;
E. spray by weight percentage by cobalt oxide 2-3%, nickel oxide 3-5%, chromium sesquioxide 3-5%, zirconium white 2-4%, ferric oxide 3-5%, Manganse Dioxide 3-5%, albite or potassium felspar sand 10-20%, clay 15-25%, Wingdale 10-20%, quartz 8-15%, the 3rd glaze layer that talcum 15-20% forms, the 3rd glazed thickness is 0.02-0.06mm;
F. roasting: intensification per hour 100-120 DEG C below 800 DEG C, 800-1200 DEG C of intensifications per hour 80-100 DEG C, 1200-1250 DEG C of insulations stopped heating after 20-60 minutes, and naturally cooling, becomes finished product.
Preferably: the first glaze layer mass percent consists of: ferric oxide 6%, zirconium white 14%, Vanadium Pentoxide in FLAKES 8%, antimonous oxide 6%, albite 12%, clay 15%, Wingdale 15%, quartz 10%, talcum 14%.
Preferably: the second glaze layer mass percent consists of: albite 15%, clay 20%, Wingdale 15%, quartz 10%, talcum 20%, calcium phosphate 14%, ferric oxide 2%, zirconium white 4%.
Preferably: the 3rd glaze layer mass percent consists of: cobalt oxide 2.5%, nickel oxide 3.5%, chromium sesquioxide 3.5%, zirconium white 2.5%, ferric oxide 4%, Manganse Dioxide 4%, albite 15%, clay 20%, Wingdale 15%, quartz 10%, talcum 18%.
The finished product that the present invention obtains is brownish black, has latticed gully, and be projection beyond gully, projection corner is round and smooth, and touch with hand and do not cut feel feel, the gully degree of depth about 0.5-1mm, gully color is slightly deeper than projection, has crocodile skin scale appearance effect.
Embodiment
Embodiment 1
Making ceramic biscuit, is diameter 15cm, the pen container totally 20 of height 20cm.
By weight percent:
Ferric oxide 6%, zirconium white 14%, Vanadium Pentoxide in FLAKES 8%, antimonous oxide 6%, albite 12%, clay 15%, Wingdale 15%, quartz 10%, the material ball milling of talcum 14%, cross 200 mesh sieves, the glaze slip of the furnishing solid content 50% that adds water, biscuit sprays glaze slip, become the first glaze layer, the first glazed thickness is about 0.08mm.
900ml water is heated to 80 DEG C, adds 20 grams of sodium hydroxide, vanadic acid sodium 10 grams, add 100 grams of stearic acid after dissolving, stir into paste, dry after cotton gauze being soaked lotion, paste coated by the biscuit executing the first glaze layer, cotton gauze is pasted onto on biscuit and forms square node, dry.
By weight percent: albite 15%, clay 20%, Wingdale 15%, quartz 10%, talcum 20%, calcium phosphate 14%, ferric oxide 2%, the material mixing grinding of zirconium white 4%, crosses 200 mesh sieves, add water and be made into second glaze slip of solid content 30wt%, take out after biscuit being immersed the second glaze slip and dry, take out after again immersing the second glaze slip and dry, repeatedly until the second glazed thickness is about 0.7mm.
By weight percent: cobalt oxide 2.5%, nickel oxide 3.5%, chromium sesquioxide 3.5%, zirconium white 2.5%, ferric oxide 4%, Manganse Dioxide 4%, albite 15%, clay 20%, Wingdale 15%, quartz 10%, the material mixing ball milling of talcum 18%, cross 200 mesh sieves, add water and be made into the 3rd glaze slip of solid content 45wt%, biscuit sprays the 3rd glaze slip, after dry, form the 3rd glaze layer of thickness 0.04mm.
Biscuit after glazing is put into kiln roasting, intensification per hour 100 DEG C below 800 DEG C, 800-1200 DEG C of intensifications per hour 80 DEG C, 1250 DEG C of insulations stopped heating after 0.5 hour, and naturally cooling, becomes finished product.
Finished product is brownish black, has latticed gully, and be projection beyond gully, projection corner is round and smooth, and touch with hand and do not cut feel feel, the gully degree of depth is about 0.7mm, and gully color is slightly deeper than projection, and even on projection have light arc colo(u)r streak, has crocodile skin scale appearance effect.
Claims (3)
1. on Ceramic glaze, form the method for crocodile skin scale appearance effect, it is characterized in that, comprise the steps:
A. ceramic biscuit is made;
B. the first glaze layer is sprayed, first glaze layer is by weight percentage by ferric oxide 5-8%, zirconium white 10-20%, Vanadium Pentoxide in FLAKES 6-12%, antimonous oxide 4-8%, albite or potassium felspar sand 10-15%, clay 10-20%, Wingdale 10-20%, quartz 8-15%, talcum 10-18% is formed, and the first glazed thickness is 0.05-0.1mm;
C. soak containing stearic acid 5-15% by cotton gauze, sodium hydroxide 1-3%, vanadic acid sodium 0.5-2%, surplus is dry after the lotion of water, is pasted onto on biscuit;
D. soak by weight percentage by albite or potassium felspar sand 12-18%, clay 15-25%, Wingdale 10-20%, quartz 8-15%, talcum 15-30%, calcium phosphate 10-20%, the second glaze layer that ferric oxide 1-3% and zirconium white 3-5% form, the second glazed thickness is 0.5-1mm;
E. spray by weight percentage by cobalt oxide 2-3%, nickel oxide 3-5%, chromium sesquioxide 3-5%, zirconium white 2-4%, ferric oxide 3-5%, Manganse Dioxide 3-5%, albite or potassium felspar sand 10-20%, clay 15-25%, Wingdale 10-20%, quartz 8-15%, the 3rd glaze layer that talcum 15-20% forms, the 3rd glazed thickness is 0.02-0.06mm;
F. roasting: intensification per hour 100-120 DEG C below 800 DEG C, 800-1200 DEG C of intensifications per hour 80-100 DEG C, 1200-1250 DEG C of insulations stopped heating after 20-60 minutes, and naturally cooling, becomes finished product.
2. method according to claim 1, it is characterized in that, described first glaze layer mass percent consists of: ferric oxide 6%, zirconium white 14%, Vanadium Pentoxide in FLAKES 8%, antimonous oxide 6%, albite 12%, clay 15%, Wingdale 15%, quartz 10%, talcum 14%.
3. method according to claim 1 or 2, is characterized in that, described second glaze layer mass percent consists of: albite 15%, clay 20%, Wingdale 15%, quartz 10%, talcum 20%, calcium phosphate 14%, ferric oxide 2%, zirconium white 4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410726235.9A CN104529552B (en) | 2014-12-04 | 2014-12-04 | Ceramic glaze is formed the method for crocodile skin scale appearance effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410726235.9A CN104529552B (en) | 2014-12-04 | 2014-12-04 | Ceramic glaze is formed the method for crocodile skin scale appearance effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104529552A CN104529552A (en) | 2015-04-22 |
| CN104529552B true CN104529552B (en) | 2016-04-20 |
Family
ID=52845239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410726235.9A Active CN104529552B (en) | 2014-12-04 | 2014-12-04 | Ceramic glaze is formed the method for crocodile skin scale appearance effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104529552B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109333784A (en) * | 2018-12-11 | 2019-02-15 | 广东皓明陶瓷科技有限公司 | A kind of silking glaze and silking glaze household porcelain production technique |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101439989B (en) * | 2008-12-09 | 2012-11-21 | 中国西电电气股份有限公司 | Raw material proportion of bice glaze and firing method thereof |
| CN102826872B (en) * | 2012-08-17 | 2014-01-15 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN103664231A (en) * | 2012-09-26 | 2014-03-26 | 邱伟 | Grayish blue glaze and firing method thereof |
-
2014
- 2014-12-04 CN CN201410726235.9A patent/CN104529552B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104529552A (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104130032B (en) | A kind of manufacture method of glazed tile and products thereof | |
| CN107793028A (en) | The local glaze embossment ceramic and preparation technology of once-firing | |
| CN104016719A (en) | Reactive crystalline glaze with sagging effect and preparation method of reactive crystalline glaze | |
| CN107344814A (en) | A kind of sheen brick cover-coat enamel and sheen brick | |
| CN109627052A (en) | A kind of Ceramic Tiles and preparation method thereof with three-dimensional decorative effect | |
| CN104446671B (en) | Ceramic glaze is formed the method for snakeskin scale appearance effect | |
| KR100908305B1 (en) | Crystalline Ceramics Manufacturing Method | |
| KR100884375B1 (en) | Manufacturing method of ocher interior and exterior materials using lacquer | |
| CN104529552B (en) | Ceramic glaze is formed the method for crocodile skin scale appearance effect | |
| CN106242290B (en) | Ferrimanganic rust glaze porcelain and its manufacture craft | |
| KR101348080B1 (en) | Process for preparing pottery with natural color and shape band | |
| CN102001866A (en) | Manufacturing method of ceramic imitating concavo-convex reticulation of sesame stone | |
| CN104909568B (en) | Ceramic with coffee crystal glaze layer on surface and preparation method therefor | |
| KR20030075855A (en) | High far-infrared emission glaze composition used for tile and tile using it | |
| CN102838386B (en) | Manufacturing method of glass-ceramic composite plate | |
| CN104446661B (en) | Ceramic glaze is formed the method for regular projection | |
| CN106365690B (en) | Bilayer reacts glaze modelled after an antique and preparation method thereof | |
| KR101692878B1 (en) | Manufacture method for ceramic | |
| CN108358448A (en) | A kind of application method of no ground-coat enamel low temperature furnace transmutation glaze | |
| CN106747673A (en) | Double-deck reaction glaze with strong melting property and preparation method thereof | |
| CN102161598A (en) | Method for manufacturing ceramic with convex and concave net grains of Indian red stone | |
| CN102001865B (en) | Method for manufacturing antique alabaster reticulate ceramics | |
| CN107915500A (en) | A kind of Ceramic Tiles with outstanding light effect | |
| CN110304828A (en) | A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect | |
| CN108975891A (en) | Ink-jet infiltration spends beautiful matter polished bricks and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zheng Qiurong Inventor after: Xing Jieqiang Inventor after: Lu Peijing Inventor before: Chen Chuchi Inventor before: Li Zhang |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160309 Address after: 515600 Chaoan City, Chaozhou Province Feng Tong Town, Feng Feng Road West Applicant after: GUANGDONG HAOMING CERAMIC TECHNOLOGY CO., LTD. Address before: 515041 Shantou high tech Zone, Guangdong science and Technology West Road, No. 6 6A02 Applicant before: GUANGDONG PROVINCE CERAMIC RESEARCH INSTITUTE |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for forming crocodile skin scale appearance effect on ceramic glaze Effective date of registration: 20211028 Granted publication date: 20160420 Pledgee: China Co. truction Bank Corp Chaozhou branch Pledgor: GUANGDONG HAOMING CERAMIC SCIENCE AND TECHNOLOGY Co.,Ltd. Registration number: Y2021980011504 |