CN104525383A - Efficient floatation reagent for coal slime - Google Patents

Efficient floatation reagent for coal slime Download PDF

Info

Publication number
CN104525383A
CN104525383A CN201410845635.1A CN201410845635A CN104525383A CN 104525383 A CN104525383 A CN 104525383A CN 201410845635 A CN201410845635 A CN 201410845635A CN 104525383 A CN104525383 A CN 104525383A
Authority
CN
China
Prior art keywords
parts
hydrocarbon
coal slime
oil
coal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410845635.1A
Other languages
Chinese (zh)
Inventor
高建
李季
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huaibei Huaxing Industry & Trade Co Ltd
Original Assignee
Huaibei Huaxing Industry & Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huaibei Huaxing Industry & Trade Co Ltd filed Critical Huaibei Huaxing Industry & Trade Co Ltd
Priority to CN201410845635.1A priority Critical patent/CN104525383A/en
Publication of CN104525383A publication Critical patent/CN104525383A/en
Pending legal-status Critical Current

Links

Landscapes

  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)

Abstract

The invention relates to an efficient floatation reagent for coal slime. The reagent comprises, by weight, 70-90 parts of hydrocarbon oil, 15-30 parts of alcohol oil, 0.5-1.5 parts of catalysts and 0.5-1 part of regulators, and the reagent can be obtained by mixing the components and stirring the mixture for one hour at normal temperature. The reagent has the advantages that smell is light, irritation is avoided, foamability is high, selectivity is high, consumption is low, foam is rich and even, foaming effect is good, hydrophobicity of coal particles can be improved to the maximum, the difference between hydrophobicity of particle surfaces and hydrophobicity of impurity surfaces can be increased, clean coal yield can be increased by 3-5%, the size and motion state of bubbles in coal slurry can be changed, power consumption for air agitation of ore pulp can be reduced, a foam layer required by floatation can be formed on the surface of ore pulp, a product is stable in bubble densification, high in selectivity and high in reaction speed, and influence of temperature and PH value is avoided.

Description

A kind of coal slime the most efficient flotation reagents
Technical field
The present invention relates to Coal dressing technology industry, especially relate to a kind of coal slime the most efficient flotation reagents.
Background technology
Coal slime flotation is the difference utilizing coal and spoil Surface Physical Chemistry character, and can cross add specific floating agent method to expand the difference showing machine wetability between coal and spoil, thus realize a kind of slime separation technology that coal is separated with spoil.Why flotation can be widely used in slime separation, and important reason is that it controls floatation process neatly by floating agent, and effectively realizes coal according to the requirement of people and be separated with spoil, makes coal resources obtain comprehensive high-efficiency and utilizes.Floating agent can improve the character of gas in floatation system, liquid, gas three-phase, the Air Bubble Size of generation, quantity, life-span, liter is made to float speed etc. and meet flotation requirement, the effect of the surface nature of mineral, mineral and other materials and the character of ore pulp can also be adjusted, change can not float mineral into floating, enable floating mineral are better floating, and improving the selective of flotation and flotation speed, the quality of flotation effect, floating agent is important factor.At present, its consumption of the floating agent used in coal industry is high, and clean coal recovery is low, and smell weight is selective poor, and coal particle hydrophobicity is low.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of low consumption amount, clean coal recovery is high, smell is light, non-stimulated, foaming characteristic is strong, selective good, enter to wash that speed is fast, the uniform coal slime the most efficient flotation reagents of foaming abundancy.
The present invention solves the technical scheme that its technical problem takes: a kind of coal slime the most efficient flotation reagents, and it consists of by weight:
Hydrocarbon-type oil: 70 ~ 90 parts;
Alcohols oil: 15 ~ 30 parts;
Catalyst: 0.5 ~ 1.5 part;
Adjusting agent: 0.5 ~ 1 part;
Said components is mixed, stirs 1 hour at normal temperatures.
Concrete further, the hydrocarbon mixture that described hydrocarbon-type oil is made up of alkane, alkene, cycloalkane, aromatic hydrocarbon, polycyclic aromatic hydrocarbon.
Concrete further, the alcohol-based mixtures that described alcohols oil is made up of n-butanol, isobutanol, octanol.
Concrete further, described catalyst and adjusting agent change the surface nature of mineral and the feature of ore pulp, improves the selective of floatation process, accelerate and improve flotation conditions.
The invention has the beneficial effects as follows: after using above-mentioned medicament, there is taste light, non-stimulated, foaming characteristic is strong, selective good, consumption is few, the features such as foaming abundancy is even have good foaming effect, can maximize and improve coal particle hydrophobicity, increase particle surface and contaminant surface hydrophobic difference, existing basis is improved clean coal yield 3% ~ 5% percentage point, the size of bubble in coal slurry and motion state can be changed, reduce the power consumption to Aerated stirring in ore pulp, and the froth bed of flotation needs can be formed on mineral slurry level, and the bubble compactness of product is stablized, selective good, reaction speed is fast, do not affect by temperature and pH value.
Detailed description of the invention
The present invention will be described in detail below.
A kind of coal slime the most efficient flotation reagents, it consists of by weight:
Hydrocarbon-type oil: 70 ~ 90 parts; The hydrocarbon mixture that hydrocarbon-type oil is made up of alkane, alkene, cycloalkane, aromatic hydrocarbon, polycyclic aromatic hydrocarbon.
Alcohols oil: 15 ~ 30 parts; The alcohol-based mixtures that alcohols oil is made up of n-butanol, isobutanol, octanol.
Catalyst: 0.5 ~ 1.5 part;
Adjusting agent: 0.5 ~ 1 part; Catalyst and adjusting agent change the surface nature of mineral and the feature of ore pulp, improves the selective of floatation process, accelerate and improve flotation conditions.
Said components is mixed, stirs 1 hour at normal temperatures.
The first embodiment, by mass fraction, it consists of medicament:
Hydrocarbon-type oil: 70 parts;
Alcohols oil: 20 parts;
Catalyst: 0.5 part;
Adjusting agent: 0.5 part.
The second embodiment, by mass fraction, it consists of medicament:
Hydrocarbon-type oil: 75 parts;
Alcohols oil: 20 parts;
Catalyst: 1 part;
Adjusting agent: 0.5 part.
The third embodiment, by mass fraction, it consists of medicament:
Hydrocarbon-type oil: 80 parts;
Alcohols oil: 15 parts;
Catalyst: 1.5 parts;
Adjusting agent: 1 part.
Its compound method is allocated according to the above ratio at hydrocarbon-type oil, alcohols oil, catalyst, adjusting agent, with oil transfer pump, component sent into agitator tank mixing, then stir 1 hours under normal temperature, make it fully dissolve obtained product.
Selective good to coal of this kind of medicament, consumption is little, is 70 ~ 80% of conventional formulation; The rate of recovery is high, improves 3 ~ 5% than conventional formulation; There is taste light, non-stimulated, not by regional impact; Raw material are conveniently easily purchased, cost is low.
It is emphasized that, it is more than better implementation column of the present invention, not any type of restriction is done in appearance to invention, every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong to technical solution of the present invention.

Claims (7)

1. a coal slime the most efficient flotation reagents, is characterized in that, it consists of by weight:
Hydrocarbon-type oil: 70 ~ 90 parts;
Alcohols oil: 15 ~ 30 parts;
Catalyst: 0.5 ~ 1.5 part;
Adjusting agent: 0.5 ~ 1 part;
Said components is mixed, stirs 1 hour at normal temperatures.
2. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, the hydrocarbon mixture that described hydrocarbon-type oil is made up of alkane, alkene, cycloalkane, aromatic hydrocarbon, polycyclic aromatic hydrocarbon.
3. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, the alcohol-based mixtures that described alcohols oil is made up of n-butanol, isobutanol, octanol.
4. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, described catalyst and adjusting agent change the surface nature of mineral and the feature of ore pulp, improves the selective of floatation process, accelerate and improve flotation conditions.
5. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, by mass fraction, it consists of described medicament:
Hydrocarbon-type oil: 70 parts;
Alcohols oil: 20 parts;
Catalyst: 0.5 part;
Adjusting agent: 0.5 part.
6. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, by mass fraction, it consists of described medicament:
Hydrocarbon-type oil: 75 parts;
Alcohols oil: 20 parts;
Catalyst: 1 part;
Adjusting agent: 0.5 part.
7. coal slime the most efficient flotation reagents according to claim 1, is characterized in that, by mass fraction, it consists of described medicament:
Hydrocarbon-type oil: 80 parts;
Alcohols oil: 15 parts;
Catalyst: 1.5 parts;
Adjusting agent: 1 part.
CN201410845635.1A 2014-12-31 2014-12-31 Efficient floatation reagent for coal slime Pending CN104525383A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410845635.1A CN104525383A (en) 2014-12-31 2014-12-31 Efficient floatation reagent for coal slime

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410845635.1A CN104525383A (en) 2014-12-31 2014-12-31 Efficient floatation reagent for coal slime

Publications (1)

Publication Number Publication Date
CN104525383A true CN104525383A (en) 2015-04-22

Family

ID=52841115

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410845635.1A Pending CN104525383A (en) 2014-12-31 2014-12-31 Efficient floatation reagent for coal slime

Country Status (1)

Country Link
CN (1) CN104525383A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105728200A (en) * 2016-03-29 2016-07-06 江苏尧舜机械科技有限公司 Coal dressing composite reagent and preparing method thereof

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85106071A (en) * 1985-08-14 1986-01-10 轻工业部日用化学工业科学研究所 Oil-in-water emulsion used in flotation of coal slurry
CN85109744A (en) * 1984-11-20 1986-11-05 电源开发株式会社 Remove the preparation of the high solid concentration water coal slime of ash content
SU1510936A1 (en) * 1988-01-28 1989-09-30 Авдеевский Коксохимический Завод Им.50-Летия Ссср Reagent-modifier for flotation of coal slime
DE19835498A1 (en) * 1998-08-06 2000-02-10 Uvr Fia Gmbh Verfahrensentwick Production of intensively colored lapis lazuli for direct use as pigment involves multistage flotation, using long-chain amine as collector and neutral to alkaline conditions for removing mica and recovering and purifying lapis lazuli
CN101015820A (en) * 2007-03-02 2007-08-15 山西焦煤集团有限责任公司 Floatation method of difficult-to-float coal
CN102228871A (en) * 2011-06-08 2011-11-02 太原艾柯夫选煤技术有限公司 Coal slime pressurizing floating method
CN103041926A (en) * 2013-01-30 2013-04-17 唐山国华科技国际工程有限公司 Flotation process method of high-ash-content fine coal slime
CN103056033A (en) * 2013-01-25 2013-04-24 山东科技大学 Coal slime microemulsion collecting agent and preparation method thereof
CN103143449A (en) * 2013-02-28 2013-06-12 太原理工大学 Method for realizing flotation of coal slime with use of oxidized kerosene
CN103909021A (en) * 2014-04-04 2014-07-09 青岛科技大学 Microemulsion composite floatation agent for coal dressing and preparation method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109744A (en) * 1984-11-20 1986-11-05 电源开发株式会社 Remove the preparation of the high solid concentration water coal slime of ash content
CN85106071A (en) * 1985-08-14 1986-01-10 轻工业部日用化学工业科学研究所 Oil-in-water emulsion used in flotation of coal slurry
SU1510936A1 (en) * 1988-01-28 1989-09-30 Авдеевский Коксохимический Завод Им.50-Летия Ссср Reagent-modifier for flotation of coal slime
DE19835498A1 (en) * 1998-08-06 2000-02-10 Uvr Fia Gmbh Verfahrensentwick Production of intensively colored lapis lazuli for direct use as pigment involves multistage flotation, using long-chain amine as collector and neutral to alkaline conditions for removing mica and recovering and purifying lapis lazuli
CN101015820A (en) * 2007-03-02 2007-08-15 山西焦煤集团有限责任公司 Floatation method of difficult-to-float coal
CN102228871A (en) * 2011-06-08 2011-11-02 太原艾柯夫选煤技术有限公司 Coal slime pressurizing floating method
CN103056033A (en) * 2013-01-25 2013-04-24 山东科技大学 Coal slime microemulsion collecting agent and preparation method thereof
CN103041926A (en) * 2013-01-30 2013-04-17 唐山国华科技国际工程有限公司 Flotation process method of high-ash-content fine coal slime
CN103143449A (en) * 2013-02-28 2013-06-12 太原理工大学 Method for realizing flotation of coal slime with use of oxidized kerosene
CN103909021A (en) * 2014-04-04 2014-07-09 青岛科技大学 Microemulsion composite floatation agent for coal dressing and preparation method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄波: "《煤泥浮选技术》", 31 March 2012, 冶金工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105728200A (en) * 2016-03-29 2016-07-06 江苏尧舜机械科技有限公司 Coal dressing composite reagent and preparing method thereof

Similar Documents

Publication Publication Date Title
CN103909017B (en) Flotation process for silicon-calcium mixed collophanite containing organic carbon
CN105797868B (en) The beneficiation method of low-grade zinc oxide ore is recycled from lead-zinc ore floating tailing
RU2709877C1 (en) Method for flotation of coal, having low floatability
CN103962245B (en) A kind of complex floatation agent for coal preparation and preparation method thereof
AU2019289849B2 (en) Use of polyols for improving a process for reverse froth flotation of iron ore
CN102658242A (en) Mineral separation process of complex fluorite difficult to separate
CN101099946A (en) Collophanite floatation method
CN108380397A (en) A kind of recovery method of low concentration calcite type containing mica fluorite tailing
CN101428253A (en) Coal flotation agent and production method thereof
CN104607321A (en) Collophanite froth flotation collecting agent and preparation method thereof
CN105562215A (en) Novel coal dressing foaming agent and preparation method thereof
CN105583086A (en) Flotation column flotation method for flake graphite
CN101703965B (en) Bauxite column-type floatation method
CN106944263A (en) A kind of Collophane anti-floatation collector and its preparation method and application method
CN105344493B (en) A kind of direct flotation collecting agent of bauxite
CN105498980A (en) Rutile flotation collector composition and application thereof
CN103920596B (en) Collophanite combination flotation collector and preparation method and application thereof
CN108499743B (en) Combined inhibitor for inhibiting pumice stone minerals and using method thereof
CN107899753A (en) A kind of anion combined capturing and collecting agent of free-floride FLOTATION SEPARATION quartz and feldspar and preparation method and application
CN104525383A (en) Efficient floatation reagent for coal slime
CN103657875A (en) Medium-low-grade bauxite machine-column united separation process
CN106669977B (en) A kind of oxidized coal slime method for separating
CN107824341B (en) It is a kind of to improve difficult copper sulfide ore beneficiation and refer to calibration method
CN106076607A (en) A kind of two step desliming reverse floatation process processing high alumina-silica collophane
CN101507947A (en) Quartz sand flotation method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150422