CN104513550A - Environmentally friendly automobile priming paint - Google Patents
Environmentally friendly automobile priming paint Download PDFInfo
- Publication number
- CN104513550A CN104513550A CN201310456292.5A CN201310456292A CN104513550A CN 104513550 A CN104513550 A CN 104513550A CN 201310456292 A CN201310456292 A CN 201310456292A CN 104513550 A CN104513550 A CN 104513550A
- Authority
- CN
- China
- Prior art keywords
- environmentally friendly
- priming paint
- friendly vehicle
- aqueous acrylic
- acrylic emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an aqueous coating, and concretely relates to an environmentally friendly automobile priming paint. The environmentally friendly automobile priming paint comprises, by mass, 1-5% of mineral oil, 2-5% of 2,2,4-trimethyl-1,3-pentanediolmono(2-methylpropanoate), 0.5-3% of a thickening agent, 0.5-1% of an antiseptic, 0.5-1% of a coloring agent, 5-15% of a special assistant, 2-5% of a dispersant, 15-20% of a filler, 3-8% of modified polysiloxane, 40-60% of an aqueous propionic acid emulsion, and the balance of water.
Description
Technical field
The invention relates to water-borne coatings, particularly a kind of environmentally friendly vehicle priming paint.
Background technology
Along with the development of society, and the increase of the income of people, automobile is more and more come in the life of people, and people also constantly propose new requirement to automobile, and improvement idea; The effect requirements of spraying paint of car conour is more and more higher the most intuitively.This just requires that the priming paint of automobile will have good sticking power, with above in paint or finish paint can well coordinate, it also will possess the erosion etc. of good preservative property, rust-preventing characteristic, water tolerance, oil-proofness, chemicals-resistant, and its mechanical property such as glossiness, hardness also will be got well simultaneously.
Summary of the invention
The problem that the invention will solve is to provide a kind of environmentally friendly vehicle priming paint.
For solving the problems of the technologies described above, the technical scheme that the invention adopts is: a kind of environmentally friendly vehicle priming paint, and it has massfraction to be: mineral oil 1-5%, alcohol ester 12 2-5%, thickening material 0.5-3%, sanitas 0.5-1%, tinting material 0.5-1%, special auxiliary agent 5-15%, dispersion agent 2-5%, filler 15-20%, modified polyorganosiloxane 3-8%, water-based propionic acid emulsion 40-60%, water surplus composition.
Described water-based propionic acid emulsion is one or more in HD1092 self-cross linking type aqueous acrylic emulsion, HD2081 high adhesive force aqueous acrylic emulsion, HD2083 high rigidity aqueous acrylic emulsion, HD2538 strain indicating lacquer self-cross linking type aqueous acrylic emulsion.
Described special auxiliary agent is NeoCryl CX-100, NeoCryl CX-300 mono-kind or mixing.
Described mineral oil is cosmetic grade white oil.
Described dispersion agent is one or more in octadecanoic acid barium salt, polystyrene, polyacrylic acid, vinylformic acid-2-acrylamide-2-methyl propane sulfonic multipolymer.
Described sanitas is one or more in trichloro-butyl alcohol, propionic acid, thymol, Butyl Chemosept, borax.
Described octadecanoic acid barium salt can be used for dispersion agent, and can play good dissemination, chemical formula is as follows
Described HD1092 self-cross linking type aqueous acrylic emulsion is single-component, self-cross linking type, formaldehydeless acrylic ester emulsion.Be mainly used in the preparation of the water-borne coatings of chemical resistance reagent ability.HD1092 self-crosslinked acrylate emulsion has superior sharpness, low foam, crack resistance.
Described HD2081 high adhesive force aqueous acrylic emulsion is a moisture-proof, water-fast, corrosion resistant aqueous acrylic emulsion.The aqueous acrylic emulsion of HD2081 high adhesive force adopts resins synthesis technology, through well-designed, the high adhesive force of specific function and the group of water-repellancy can be also had to the monomer structure of UV stable, can make it in performance, greatly surmount common water borne ACRYLIC EMULSION product.
Described HD2538 strain indicating lacquer self-cross linking type aqueous acrylic emulsion resins synthesis technology, through well-designed, the application of water-based strain indicating lacquer has good decorate properties.It is that monomer composition and nucleocapsid structure may be controlled to film condition, and make water-based paint film at the successional decorative effect forming surface crack ensureing film forming simultaneously, it is widely used in the strain indicating lacquer decorative paint of aqueous metallic paint.
The advantage that the invention has and positively effect are: the vehicle paint base providing a kind of environmental protection, can increase car paint water tolerance, resistance to rust, resistance to preservative property, oil-proofness, chemicals-resistant erosion, increase glossiness, increase toughness, increase hardness.
Embodiment
Embodiment 1,2,3 is according to following formulated.Embodiment 1 special auxiliary agent selects NeoCryl CX-100; Embodiment 2 special auxiliary agent selects NeoCryl CX-300; Embodiment 3 special auxiliary agent selects NeoCryl CX-100, NeoCryl CX-300 to mix; Embodiment 1 water-based propionic acid emulsion elects HD1092 self-cross linking type aqueous acrylic emulsion as; Embodiment 2 water-based propionic acid emulsion elects HD2081 high adhesive force aqueous acrylic emulsion, HD2083 high rigidity aqueous acrylic emulsion as; Embodiment 3 water-based propionic acid emulsion elects HD2538 strain indicating lacquer self-cross linking type aqueous acrylic emulsion as.
Be mixed with embodiment 1,2,3, test index is in table 1, and test result is in table 2.
Table 1
| Project | Index |
| Material state in container | Answer foreign, without lump, easily stir into thick liquid |
| Viscosity (6# cup), s | ≤50 |
| Fineness, μm | ≤60 |
| Stability in storage, level, settleability | ≤6 |
| Stability in storage, level, skinning | ≤10 |
| Flash-point, DEG C | ≥26 |
| Color and outward appearance | Tone is indefinite, paint film is smooth, unglazed or zero diopter |
| Time of drying, h, does solid work | ≤24 |
| Time of drying, h, dries (120 ± 2 DEG C) | ≤1 |
| Pencil hardness | ≥B |
| Cupping is tested, mm | ≥5 |
| Specification is tested, level | 0 |
| Grinability, (20 times) | Easy polishing is not stained with sand paper |
| Oil-proofness, (48h) | Outward appearance is without considerable change |
| Petrol-resistance, (6h) | Non-foaming, wrinkle resistant, allow light discolouration |
| Water tolerance (168h) | Non-foaming, non-corrosive, allows light discolouration |
| Acid resistance (0.05mol/H 2SO 4In, 7h) | Non-foaming, non-corrosive |
| Alkali resistance (in 0.1mol/NaOH, 7h)) | Non-foaming, wrinkle resistant, allow light discolouration |
| Resistance to pyroxylin(e)finish | Do not stung, do not ooze red |
| Salt fog resistance, (168h) level | Outside the 2mm of line of cut side, pass through one-level |
| Humidity resistance, (96h) level | ≤1 |
Table 2
Claims (6)
1. an environmentally friendly vehicle priming paint, it is characterized in that, it has massfraction to be: mineral oil 1-5%, alcohol ester 12 2-5%, thickening material 0.5-3%, sanitas 0.5-1%, tinting material 0.5-1%, special auxiliary agent 5-15%, dispersion agent 2-5%, filler 15-20%, modified polyorganosiloxane 3-8%, water-based propionic acid emulsion 40-60%, water surplus composition.
2. a kind of environmentally friendly vehicle priming paint according to claim 1, is characterized in that: described water-based propionic acid emulsion is one or more in HD1092 self-cross linking type aqueous acrylic emulsion, HD2081 high adhesive force aqueous acrylic emulsion, HD2083 high rigidity aqueous acrylic emulsion, HD2538 strain indicating lacquer self-cross linking type aqueous acrylic emulsion.
3. a kind of environmentally friendly vehicle priming paint according to claim 1, is characterized in that: described special auxiliary agent is NeoCryl CX-100, NeoCryl CX-300 mono-kind or mixing.
4. a kind of environmentally friendly vehicle priming paint according to claim 1, is characterized in that: described mineral oil is cosmetic grade white oil.
5. a kind of environmentally friendly vehicle priming paint according to claim 1, is characterized in that: described dispersion agent is one or more in octadecanoic acid barium salt, polystyrene, polyacrylic acid, vinylformic acid-2-acrylamide-2-methyl propane sulfonic multipolymer.
6. a kind of environmentally friendly vehicle priming paint according to claim 1, is characterized in that: described sanitas is one or more in trichloro-butyl alcohol, propionic acid, thymol, Butyl Chemosept, borax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310456292.5A CN104513550A (en) | 2013-09-27 | 2013-09-27 | Environmentally friendly automobile priming paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310456292.5A CN104513550A (en) | 2013-09-27 | 2013-09-27 | Environmentally friendly automobile priming paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104513550A true CN104513550A (en) | 2015-04-15 |
Family
ID=52789433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310456292.5A Pending CN104513550A (en) | 2013-09-27 | 2013-09-27 | Environmentally friendly automobile priming paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104513550A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189583A (en) * | 2016-07-18 | 2016-12-07 | 成都拜迪新材料有限公司 | One is applied to 25 type passenger vehicle water based shop primer and preparation method thereof |
| CN106632907A (en) * | 2016-11-18 | 2017-05-10 | 陕西科技大学 | Modified casein/thymol/nano-ZnO composite antibacterial film prepared based on in-situ emulsion polymerization, and preparation method of composite antibacterial film |
| CN108003770A (en) * | 2017-12-11 | 2018-05-08 | 湖南太子化工涂料有限公司 | A kind of water-based crackle paint |
-
2013
- 2013-09-27 CN CN201310456292.5A patent/CN104513550A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189583A (en) * | 2016-07-18 | 2016-12-07 | 成都拜迪新材料有限公司 | One is applied to 25 type passenger vehicle water based shop primer and preparation method thereof |
| CN106632907A (en) * | 2016-11-18 | 2017-05-10 | 陕西科技大学 | Modified casein/thymol/nano-ZnO composite antibacterial film prepared based on in-situ emulsion polymerization, and preparation method of composite antibacterial film |
| CN108003770A (en) * | 2017-12-11 | 2018-05-08 | 湖南太子化工涂料有限公司 | A kind of water-based crackle paint |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150415 |
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| WD01 | Invention patent application deemed withdrawn after publication |