CN104497847B - One can temperature induced color changing waterborne UV coating and preparation method thereof - Google Patents

One can temperature induced color changing waterborne UV coating and preparation method thereof Download PDF

Info

Publication number
CN104497847B
CN104497847B CN201410853924.6A CN201410853924A CN104497847B CN 104497847 B CN104497847 B CN 104497847B CN 201410853924 A CN201410853924 A CN 201410853924A CN 104497847 B CN104497847 B CN 104497847B
Authority
CN
China
Prior art keywords
coating
temperature
waterborne
agent
changing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410853924.6A
Other languages
Chinese (zh)
Other versions
CN104497847A (en
Inventor
陈梦茹
李国鼐
许自成
刘磊
张卫宝
张忠良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG UVCHEM SPECIAL COATINGS CO Ltd
Original Assignee
ZHEJIANG UVCHEM SPECIAL COATINGS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG UVCHEM SPECIAL COATINGS CO Ltd filed Critical ZHEJIANG UVCHEM SPECIAL COATINGS CO Ltd
Priority to CN201410853924.6A priority Critical patent/CN104497847B/en
Publication of CN104497847A publication Critical patent/CN104497847A/en
Application granted granted Critical
Publication of CN104497847B publication Critical patent/CN104497847B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/26—Thermosensitive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

The invention discloses one can temperature induced color changing waterborne UV coating, by mass percentage, consist of: water-base resin 30～60%, reactive diluent 5～25%, light trigger 1～5%, temperature-sensing color-changing material 0.5～10%, moistening flatting agent 0.05～1%, thickening agent 0.05～2%, emulsifying agent 0.1～5%, defoamer 0.1～2%, coalescents 0～8% and deionized water 25～60%.The invention also discloses described can the preparation method of temperature induced color changing waterborne UV coating.The invention provides one can temperature induced color changing waterborne UV coating, it is not necessary to previously prepared microcapsule, and preparation technology is simple, convenient, more conducively large-scale industrial production.

Description

One can temperature induced color changing waterborne UV coating and preparation method thereof
Technical field
The present invention relates to the technical field of coating, particularly relating to one can temperature induced color changing waterborne UV coating and construction party thereof Method.
Background technology
Along with people's attention to environmental conservation, it is the most perfect that environmental protection is made laws, and performs increasingly stringent, promotes greatly The development and application of waterborne UV coating.Waterborne UV coating has not only acted on that UV coating is energy-efficient, the environmental protection and economy suitability is strong Advantage, also replaces to water, Ke Yiji by the oil-based solvent with penetrating odor in UV coating and amount of activated diluent Big degree ground reduces VOC emission, alleviates the pollution to air and human injury.
Temperature induced color changing coating is the new special coating that a kind of coating color changes along with surface temperature change.Necessarily Within the temperature range of, it may appear that a certain color changes, and thus can determine that the instruction temperature of this coating.Different according to temperature, can divide For low temperature variable color (10 DEG C), feel variable color (30 DEG C), high-temperature discoloration (80 DEG C).Be widely used in drinking water glass at present, temperature becomes Mobile phone shell, novel toy, temperature become the incrustation of all types of plastic goods such as Blowing drum, artware.
The Chinese patent literature of Publication No. CN103603229A disclose a kind of can the coating of temperature induced color changing, containing forming sediment Powder, microcapsule, rheology water-retaining agent, latex, resistance to hydrated agent, lubricant, dispersant, interfacial agent and can be in temperature induced color changing capsule One or more, the solid content of described coating is 20～30%, and described temperature induced color changing capsule accounts for the 0.997 of whole coating quality ～2.997 ‰.
And for example the Chinese patent literature of Publication No. CN104130633A discloses one to have reversibility photochromic Aqueous inner wall paint, uses reversible photoreception microcapsule aqueous liquid dispersion, 5040 dispersants, 2,2,4-trimethyl-1,3-pentanediol Mono isobutyrate, polyacrylic ester thickener, 2-amino-2-methyl-1-propanol, calcium carbonate, Kaolin, mica powder, octyl phenol Polyoxyethylene ether, titanium dioxide, 705 type EVA emulsions, AGITAN-208 type defoamer, Kazon, 2-hydroxyl-4-n-octyloxy hexichol The raw materials such as ketone, UV-1300 type ultraviolet absorber and water are compounding to be formed.
Existing can be in temperature induced color changing or photochromic coating, off-color material all joins coating with the form of microcapsule Other component in, this is owing to off-color material is the most sensitive to the effect of ambient impurities, with other component of building coating mix During conjunction, its discoloration meeting serious loss, therefore, is all to use micro-capsule package technology first to prepare microcapsule in prior art, Mix with other component again and prepare allochroic paint.
Aforesaid way well solves the problem that off-color material is easily affected by ambient impurities, but needs previously prepared micro-glue Capsule, adds production procedure, improves production cost.
Summary of the invention
The invention provides one can temperature induced color changing waterborne UV coating, it is not necessary to previously prepared microcapsule, preparation technology is simple, Convenient, more conducively large-scale industrial production.
One can temperature induced color changing waterborne UV coating, by mass percentage, consist of: water-base resin 30～60%, activity Diluent 5～25%, light trigger 1～5%, temperature-sensing color-changing material 0.5～10%, moistening flatting agent 0.05～1%, thickening agent 0.05～2%, emulsifying agent 0.1～5%, defoamer 0.1～2%, coalescents 0～8% and deionized water 25～60%.
As preferably, described water-base resin is selected from aqueous polyurethane acrylate emulsion, aqueous polyurethane acrylate At least one in dispersion, waterborne, polycarbonate acrylate, waterborne epoxy acrylate.Due to watersoluble polyurethane acrylic acid Ester has excellent stability and comprehensive mechanical property, more preferably aqueous polyurethane acrylate emulsion, aqueous polyurethane third Olefin(e) acid ester dispersion.
As preferably, described reactive diluent is lived selected from esters of acrylic acid reactive diluent, ethoxyquin esters of acrylic acid At least one in property diluent, the third propylene oxide esters of gallic acid reactive diluent.More preferably ethoxyquin esters of acrylic acid activity Diluent or the third propylene oxide esters of gallic acid reactive diluent.
As preferably, described light trigger is selected from water solublity cracking type free radical photo-initiation, water solublity hydrogen-abstraction certainly By at least one in base light trigger.
As preferably, described temperature-sensing color-changing material is selected from triaryl methane Phthalide type, indoline Phthalide type, fluorane type, fen At least one in thiazine type dye, more preferably triaryl methane Phthalide type or indoline Phthalide type.
As preferably, described moistening flatting agent is selected from silicone, polyacrylate, the moistening flatting agent of fluorinated In at least one；More preferably polyacrylate moistening flatting agent.
At least one in cellulose ether, polyacrylate, association thickener of described thickening agent；More preferably Association thickener.
Described emulsifying agent is in carboxylic acid type, sulfonate type, sulfate type, phosphate type, polyether-type emulsifying agent At least one.
Described defoamer is selected from poly organo siloxane and/or polyethers defoamer；More preferably polysiloxane Class defoamer.
Described coalescents is selected from ethanol, ethylene glycol, propylene glycol, butanediol, diethylene glycol ether, diethylene glycol fourth At least one in ether, DAA, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether.
As preferably, by mass percentage, described can the consisting of of temperature induced color changing waterborne UV coating: water-base resin 40 ～60%, reactive diluent 5～15%, light trigger 1～5%, temperature-sensing color-changing material 1.0～2.0%, moistening flatting agent 0.05 ～1%, thickening agent 0.05～2%, emulsifying agent 1～5%, defoamer 0.1～2%, coalescents 0～5% and deionized water 25～40%.
Further preferably, described water-base resin is aqueous urethane acrylate dispersoid and watersoluble polyurethane acrylic acid Ester emulsion, the mass ratio of aqueous urethane acrylate dispersoid and aqueous polyurethane acrylate emulsion is 1:1～1.5.
Described temperature-sensing color-changing material be the trade mark be the three of 350C or 312C (Dongguan City thousand becomes Chemical Industry Science Co., Ltd) Virtue methane Phthalide type temperature-sensing color-changing material,
Or for the indoline Phthalide type heat discoloration material that the trade mark is TM01 (Dongguan City thousand becomes Chemical Industry Science Co., Ltd) Material；
Described reactive diluent is ethoxyquin tetramethylol methane tetraacrylate；
Described light trigger is 2-hydroxyl-4-(2-hydroxy ethoxy)-2-methyl phenyl ketone；
Described moistening flatting agent is Tego KL245 or Tego260；Thickening agent is BYK-425, BYK-428 or BYK- 420, emulsifying agent is Hypermer A70 or Hypermer B-246SF, and defoamer is BYK-093, BYK-1730 or BYK-011, Coalescents is propylene glycol monomethyl ether or DAA.
The invention discloses described can the preparation method of temperature induced color changing waterborne UV coating, comprise the following steps:
(1) by light trigger, coalescents and reactive diluent mix, under 500～1000r/min stir 5～ 10min, dissolves mix homogeneously；
(2) under agitation, add water-base resin, under 500～1000r/min, continue stirring 10～15min to mixed Close uniformly, add deionized water, defoamer, emulsifying agent, moistening flatting agent, thickening agent and temperature-sensing color-changing material, 1000～ Disperse 0.5～1h under 3000r/min, filter, discharging, obtain described can temperature induced color changing waterborne UV coating.
Compared with prior art, present invention have the advantage that
The present invention can not only have water paint and UV coating environmental protection, energy saving economy by temperature induced color changing waterborne UV coating Etc. advantage, and its paint film color can vary with temperature and change, and ornamental strong, paint stability is good simultaneously.ABS, PC, PS, Having adhesive force, hardness and the good patience of excellence on all kinds of base materials such as PETG and water transfer, coating color is with temperature simultaneously Degree change is sensitive, good reversibility；
The present invention uses specific preparation and construction technology simple, meets wanting of current development environmental protection sustainable development Ask, have broad application prospects and be worth.
Detailed description of the invention
Embodiment 1～8
According to table 1 below, the weight proportion shown in 2, prepare respectively can temperature induced color changing waterborne UV coating, concrete preparation flow As follows:
(1) light trigger, coalescents, reactive diluent are added sequentially in stirred tank, 500～1000r/min Stir 5～10min under rotating speed, dissolve mix homogeneously.
(2) under agitation, in stirred tank, add aqueous UV resin, under 500～1000r/min rotating speeds, stir 10 ～15min.To be mixed uniformly after, be sequentially added into deionized water, defoamer, emulsifying agent, moistening flatting agent, thickening agent and temperature-sensitive Off-color material, dispersion 0.5～1h under 1000～3000r/min rotating speeds, filtration, discharging, obtain temperature induced color changing waterborne UV coating.
Table 1
Table 2
The construction technology of above-mentioned coating is as follows:
Plastic rubber substrate sprays after above-mentioned coating, 60 DEG C of bakings 4～10min, UV energy be 400～ 1200mJ/cm2Lower solidification, coating prepared by each embodiment the performance test results on plastic cement ABS and PC base material is respectively such as table 3 Shown in table 4:
Table 3
Table 4

Claims (3)

1. one kind can temperature induced color changing waterborne UV coating, it is characterised in that by mass percentage, consist of: water-base resin 30～ 60%, reactive diluent 5～25%, light trigger 1～5%, temperature-sensing color-changing material 0.5～10%, moistening flatting agent 0.05～ 1%, thickening agent 0.05～2%, emulsifying agent 0.1～5%, defoamer 0.1～2%, coalescents 0～8% and deionized water 25～60%；
Described water-base resin is aqueous urethane acrylate dispersoid and aqueous polyurethane acrylate emulsion, the poly-ammonia of aqueous The mass ratio of ester acrylate dispersoid and aqueous polyurethane acrylate emulsion is 1:1～1.5；
Described temperature-sensing color-changing material be the trade mark be the triaryl methane Phthalide type temperature-sensing color-changing material of 350C or 312C, or be board It number it is the indoline Phthalide type temperature-sensing color-changing material of TM01；
Described reactive diluent is ethoxyquin tetramethylol methane tetraacrylate；
Described light trigger is 2-hydroxyl-4-(2-hydroxy ethoxy)-2-methyl phenyl ketone；
Described moistening flatting agent is Tego KL245 or Tego260, and thickening agent is BYK-425, BYK-428 or BYK-420, breast Agent is Hypermer A70 or Hypermer B-246SF, and defoamer is BYK-093, BYK-1730 or BYK-011, and film forming helps Agent is propylene glycol monomethyl ether or DAA.
The most according to claim 1 can temperature induced color changing waterborne UV coating, it is characterised in that by mass percentage, described Can the consisting of of temperature induced color changing waterborne UV coating: water-base resin 40～60%, reactive diluent 5～15%, light trigger 1～ 5%, temperature-sensing color-changing material 1.0～2.0%, moistening flatting agent 0.05～1%, thickening agent 0.05～2%, emulsifying agent 1～5%, Defoamer 0.1～2%, coalescents 0～5% and deionized water 25～40%.
3. one kind according to claim 1 can the preparation method of temperature induced color changing waterborne UV coating, it is characterised in that include with Lower step:
(1) light trigger, coalescents and reactive diluent being mixed, under 500～1000r/min, stirring 5～10min, molten Solve mix homogeneously；
(2) under agitation, add water-base resin, under 500～1000r/min, continue stirring 10～15min to mixing all Even, add deionized water, defoamer, emulsifying agent, moistening flatting agent, thickening agent and temperature-sensing color-changing material, 1000～3000r/ Disperse 0.5～1h under min, filter, discharging, obtain described can temperature induced color changing waterborne UV coating.
CN201410853924.6A 2014-12-31 2014-12-31 One can temperature induced color changing waterborne UV coating and preparation method thereof Active CN104497847B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410853924.6A CN104497847B (en) 2014-12-31 2014-12-31 One can temperature induced color changing waterborne UV coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410853924.6A CN104497847B (en) 2014-12-31 2014-12-31 One can temperature induced color changing waterborne UV coating and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104497847A CN104497847A (en) 2015-04-08
CN104497847B true CN104497847B (en) 2016-11-30

Family

ID=52939308

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410853924.6A Active CN104497847B (en) 2014-12-31 2014-12-31 One can temperature induced color changing waterborne UV coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104497847B (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104963216A (en) * 2015-06-17 2015-10-07 广东溢达纺织有限公司 Thermochromic rope head, raw materials thereof and preparation method of thermochromic rope head
CN105111928B (en) * 2015-08-12 2018-03-16 江苏省电力公司泰州供电公司 A kind of special reversible thermocoating of high-temperature-resisting transformer pile crown and preparation method thereof
CN105753373A (en) * 2015-11-09 2016-07-13 派丽(上海)管理有限公司 Iridescent joint filling plaster
CN106833297A (en) * 2016-12-15 2017-06-13 滁州市自然空间建材有限公司 A kind of temperature-sensing color-changing material of applied metal door and window accessory and preparation method thereof
CN107201117B (en) * 2017-06-12 2019-10-18 星空男孩(杭州)科技有限公司 A kind of temperature sensing paint and its preparation process
CN107841234A (en) * 2017-11-20 2018-03-27 广东华兹卜新材料科技有限公司 A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof
CN108560267B (en) * 2018-03-21 2021-03-19 兰州科天水性高分子材料有限公司 Aqueous temperature-sensitive color-changing printing treating agent for synthetic leather and preparation method and application thereof
CN109468878B (en) * 2018-09-27 2022-03-01 上海烟草集团有限责任公司 Photochromic cigarette package
CN109575789B (en) * 2018-12-26 2021-02-09 广东百川化工有限公司 Method and equipment for manufacturing water-based LEDUV photocureable coating
CN109880509A (en) * 2019-01-29 2019-06-14 张家港康得新光电材料有限公司 Aqueous allochroic paint and its painting membrane product
CN110183956A (en) * 2019-06-27 2019-08-30 东莞大宝化工制品有限公司 A kind of waterborne UV coating and preparation method thereof suitable for plastic curtain blade
CN110564216A (en) * 2019-09-30 2019-12-13 湖北中烟工业有限责任公司 Energy-storage time-delay temperature-change printing ink for cigarette packaging and application thereof
CN111440496B (en) * 2020-04-20 2022-03-22 湖南松井新材料股份有限公司 Water-based UV silver powder coating and preparation method and application thereof
CN111363400B (en) * 2020-04-29 2022-09-02 卡秀万辉(无锡)高新材料有限公司 Aqueous one-coating baking-free silver ultraviolet curing coating and preparation method thereof
CN111808516B (en) * 2020-07-01 2022-02-18 中国科学院福建物质结构研究所 Washable ultraviolet-curable waterborne polyurethane resin and preparation method and application thereof
CN112852200B (en) * 2020-12-31 2022-04-15 广州市科涵实业有限责任公司 Photochromic coating, photochromic coating prepared from same and preparation method of photochromic coating
CN113717631B (en) * 2021-01-27 2022-10-04 浙江佑谦特种材料有限公司 Water-based UV coating and preparation method and application thereof
CN112980232A (en) * 2021-02-22 2021-06-18 苏州兴禾源复合材料有限公司 Coating formula of color-changing steel plate
CN114958188B (en) * 2022-05-31 2023-06-06 书香门地集团股份有限公司 Thermochromic water-based UV paint and preparation method thereof
CN115197640A (en) * 2022-08-19 2022-10-18 长虹美菱股份有限公司 Thermochromic material and preparation method thereof
CN115820124A (en) * 2022-12-12 2023-03-21 湖州市南浔区绿色家居产业研究院 Quick-drying process of water-based UV coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0116584B1 (en) * 1982-07-30 1990-06-13 RAYCHEM CORPORATION (a Delaware corporation) Thermochromic composition
CN103205183A (en) * 2012-01-12 2013-07-17 郭文迅 Tasteless and nontoxic aqueous ultraviolet-curable coating and preparation method thereof
CN103992736A (en) * 2014-06-04 2014-08-20 广东汇龙涂料有限公司 Water-based ultraviolet (UV) light curing transparent wood coating for base coloring of woodware and application process of wood coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0116584B1 (en) * 1982-07-30 1990-06-13 RAYCHEM CORPORATION (a Delaware corporation) Thermochromic composition
CN103205183A (en) * 2012-01-12 2013-07-17 郭文迅 Tasteless and nontoxic aqueous ultraviolet-curable coating and preparation method thereof
CN103992736A (en) * 2014-06-04 2014-08-20 广东汇龙涂料有限公司 Water-based ultraviolet (UV) light curing transparent wood coating for base coloring of woodware and application process of wood coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
热致可逆变色涂料的发展;孙文秀等;《现代涂料与涂装》;20090331;第12卷(第3期);第24-27页 *

Also Published As

Publication number Publication date
CN104497847A (en) 2015-04-08

Similar Documents

Publication Publication Date Title
CN104497847B (en) One can temperature induced color changing waterborne UV coating and preparation method thereof
CN102585691B (en) Ultraviolet-cured hydrophilic coating composition and preparation method thereof
CN110078867B (en) Core-shell pure acrylic emulsion for exterior wall coating and preparation method and application thereof
CN104592815B (en) Alkali-resistant primer and preparation method thereof
CN104212288A (en) Water-based colourful building coating and preparation method thereof
CN109852158B (en) Wetting-free waterproof slurry and preparation method thereof
CN103709885A (en) Water-based environment-friendly modified alkyd wood paint
CN104673080A (en) Antistatic water-borne UV coating
CN104031516A (en) Water-based glass winebottle baking varnish and preparation method thereof
CN110698930A (en) Long-acting high-weather-resistance self-cleaning water-based multicolor paint and preparation method thereof
CN102993883A (en) Acrylic ester waterproof paint
CN103421425B (en) A kind of spackling
CN102676009B (en) Anionic ecological multicolour paint and preparation method thereof
CN107022267A (en) A kind of water paint and preparation method thereof
CN106810973A (en) A kind of aqueous one-component coating and preparation method thereof
CN104448117A (en) Water-based organic/inorganic hybrid acrylate emulsion and preparation method thereof
CN111548715A (en) Preparation method and application of high-light-transmission anti-yellowing plastic coating
CN105647322A (en) Environment-friendly interior wall coating
CN104789057A (en) Colored organic fluorine-modified styrene-acrylic waterproof paint and preparation method thereof
CN106349842B (en) A kind of terpene resin modification thermoplastic acrylic acid resin quick-drying paint and preparation method thereof
CN104031472B (en) A kind of water-based anodized aluminium packaging composite film chromatograph ink
CN102975507B (en) Preparation method and obtained product of water transfer printing fictile
CN104356291A (en) Method for synthesizing aqueous hydroxyl polyacrylate dispersoid
CN106608717A (en) Thick knife-coated sand-textured building paint and preparation method thereof
CN104497654A (en) Water-based low-VOC (volatile organic compound) environment-friendly paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant