CN104479743B - A kind of rubbish plasma gasification stove with vapor as gasifying medium - Google Patents

A kind of rubbish plasma gasification stove with vapor as gasifying medium Download PDF

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Publication number
CN104479743B
CN104479743B CN201410744809.5A CN201410744809A CN104479743B CN 104479743 B CN104479743 B CN 104479743B CN 201410744809 A CN201410744809 A CN 201410744809A CN 104479743 B CN104479743 B CN 104479743B
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China
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room
gasification
water
rubbish
temperature
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CN104479743A (en
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王希
李宏
张春飞
谢斐
王晓亮
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Dongfang Electric Corp
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Dongfang Electric Corp
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/80Other features with arrangements for preheating the blast or the water vapour
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/123Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C10J2300/1238Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687Integration of gasification processes with another plant or parts within the plant with steam generation

Abstract

The invention discloses a kind of rubbish plasma gasification stove with vapor as gasifying medium, there is room with the high-temperature vapor of bottom in the refuse gasification room including top, refuse gasification room and high-temperature vapor occur to be provided with spaced water-cooled chimney arch between room, and refuse gasification room and high-temperature vapor room and separated by water-cooled chimney arch occur;There is the inwall of room circumferentially two plasma torch in the high-temperature vapor, using low temperature vapor as plasma torch working gas;, using steam plasma body gasification rubbish, for gasification reaction provides high temperature, a high-energy environment, the material rate of heat addition is fast, and reaction rate is fast, with treatment effeciency very high, moreover it is possible to which some reactions that can not occur under common gasification condition occur for the present invention.

Description

A kind of rubbish plasma gasification stove with vapor as gasifying medium
Technical field
The present invention relates to the gasification process equipment of municipal refuse, particularly plant rubbish with vapor as gasifying medium etc. from Daughter gasification furnace.
Background technology
Current China domestic waste harmless treatment facility is based on sanitary landfills, supplemented by compost and burning.Rubbish Fill the last selection that garbage disposal is acknowledged as due to taking big quantity space and polluted underground water, and compost high cost, Fertilizer efficiency is low, product marketability is poor, there is potential safety hazard, and development is still limited.Burning disposal can to a certain extent realize rubbish Minimizing, innoxious, resource integrated treatment, in terms of environmental protection and the utilization of resources have obvious advantage, thus Obtain developing faster at home.However, directly burn cause that flue gas is exceeded, foul smell disturbs residents, and burning process is easily produced The secondary pollution such as bioxin and heavy metal, causes the fear of resident, and its neighbour for bringing topic of taking refuge can not look down upon.Therefore, hair is burned Electricity moves ahead in dispute always, and the substitute technology for developing waste incineration and generating electricity is imperative.
Plasma gasification technology originates from the sixties in 20th century earliest, the heat resistanceheat resistant experiment that U.S. NASA carries out material with it, Start the seventies for metallurgical and material heat treatment industry, the eighties, the solid waste such as start to process medical science, started in recent years Attempt for processing city and industrial refuse.Different from traditional waste incineration mode, plasma gasification technology almost can be by rubbish Rubbish 100% is converted into recyclable byproduct, and organic matter therein is converted into clean fuel gas(Mainly CO and H2), can be direct Burning or the fuels and chemicals for being refined into greater degree, and the harmless glassy state slag cooling that inorganic matter melting is produced After can be used as construction material, be most potential waste incineration so as to realize real rubbish processing to be harmless and resource application A kind of substitute technology.With the constantly improve of plasma generator technology(It is long lifespan, stable)With plasma consumable The continuous decline of electricity, China's domestic waste is converted into the ripe of the energy using plasma gasification technology.
However, the existing most using plasma torch of rubbish plasma gasification stove carries out direct High Temperature Gas to rubbish Change, up to 7000 DEG C of plasma is produced by arc discharge, so that rubbish is thoroughly pyrolyzed, such as United States Patent (USP) of Hans Kalt The US005280757A and tall United States Patent (USP) US005634414A of Karma, arc-plasma is unique thermal source, without utilization Rubbish calorific value, energy ezpenditure in itself is high, and plasma torch consumption rate causes to run into up to the 30%-45% of its electricity generation ability Originally greatly increase, add plasma torch power limited, it is difficult to which expansion scale realizes commercial applications.Further, since merely entering Electric energy, by plasma jet direct gasification rubbish, makes gasification temperature field in furnace and flow field very uneven, prevents rubbish from complete Entirely by high-temperature process, so that bringing bigger problem to Solid state fermentation containing harmful substances such as bioxin in waste residue.
Meanwhile, the gasifying agent that refuse gasification is used is usually air, oxygen-enriched or vapor, when with air as gasifying agent, Due to there are a large amount of N2 compositions not reacted, the N2 contents in synthesis gas can be caused higher, H2/ CO ratios decline, synthesis Gas calorific value is relatively low and unstable, it is difficult to meet follow-up industrial utilization;When with it is oxygen-enriched for gasifying agent when, although synthesis can be reduced N2 contents in gas, improve synthesis gas quality, but need to set up the larger air-separating plant of bulky and energy consumption, so will Increase the cost of whole equipment for gasification;And the steam gasification of routine needs key equipment steam generator, due in rubbish Coke requires temperature higher with the reaction of vapor, therefore the temperature of only vapor reaches more than 700 DEG C, and gasification result is More satisfactory, this proposes requirement higher to steam generator performance.Under normal circumstances, because steam gasification is difficult to reach Temperature higher, therefore gas yield is relatively low, gasification result is poor, and industrial less application, is mainly used in experiment at present Study room.
The content of the invention
It is an object of the invention to provide a kind of rubbish plasma gasification stove with vapor as gasifying medium, using low temperature Vapor(150℃-250℃)As the working gas of plasma torch, while from a part of vapor of gasification furnace lateral leadin, I.e. using vapor as refuse gasification medium, the vapor after being heated through plasma torch, mean temperature is up to 5000 DEG C, with Conventional steam gasification is compared, and the gasification of steam plasma body provides high temperature, a high-energy environment for gasification reaction, and material adds Hot speed is fast, and reaction rate is fast, there is treatment effeciency very high, moreover it is possible to which occur that some can not occur under common gasification condition is anti- Should, and it is more uniformly distributed rubbish flow field thermo parameters method by high-temperature vapor indirect gasification garbage energy;While rubbish plasma Part calorific value reduction power consumption of the body gasification furnace using waste in itself, from a certain amount of air of gasification furnace lateral leadin(Excess air Coefficient is less than 0.3), so as to avoid air during existing rubbish plasma direct gasification from being only used as plasma torch working gas Into gasification furnace(Excess air coefficient is less than 0.02), make the reduction of plasma torch energy consumption, the operation of rubbish plasma gasification Cost reduction.
Technical scheme is as follows:
A kind of rubbish plasma gasification stove with vapor as gasifying medium, it is characterised in that:Rubbish including top Vaporizer occurs room, to be provided between refuse gasification room and high-temperature vapor generation room and be spaced with the high-temperature vapor of bottom Water-cooled chimney arch, there is room and separates by water-cooled chimney arch in refuse gasification room and high-temperature vapor;There is room in the high-temperature vapor Inwall circumferentially two plasma torch, are in α angles between two plasma torch, and α is 120 ° -150 °;Using water at low temperature Steam(150℃-250℃)As the working gas of plasma torch.
The inwall of the gasification furnace is cast with refractory material.
The refuse gasification ceiling portion is provided with dog-house, and side higher position is provided with syngas outlet, and side lower is provided with Air supply opening.
One end of the water-cooled chimney arch is water inlet, and the other end is delivery port.
The main body of water-cooled chimney arch is steel pipe, and water is introduced from side water inlet, the cross arrangement in gasification furnace, by cooling water Heat is taken away in Bottomhole pressure, chimney arch is cooled down, so as to extend the service life of chimney arch, maintenance cost is reduced.
The bottom that the high-temperature vapor occurs room is slag notch, and side is provided with vapor import, vapor import and water The delivery port connection of black furnace arch, becomes high-temperature vapor, so as to as rubbish by plasma torch again by the water that chimney arch is heated Gasifying medium.Volume and size reduction after refuse gasification, the waste residue of formation fall into the high-temperature water of bottom by the gap of chimney arch There is room in steam, contain the pollutants such as bioxin in waste residue at high temperature and further decompose completely, then by the deslagging of bottom Mouth discharge, so as to realize the thorough harmless treatment of waste residue, without landfill, can be used as building materials.
There is a part of vapor of room lateral leadin from high-temperature vapor, i.e., using vapor as refuse gasification medium, Vapor after being heated through plasma torch, mean temperature is up to 5000 DEG C, travels up to refuse gasification room so that rubbish Pyrolytic gasification, makes the flow field in refuse gasification room be more uniformly distributed with temperature field by vapor indirectly heat garbage energy.While rubbish Rubbish vaporizer air supply opening introduces portion of air(Excess air coefficient is less than 0.3), make rubbish that partial oxidation to occur at high temperature Reaction, so as to using itself calorific value of a part of rubbish, reduce plasma power consumption.
Operating method of the invention is:
Rubbish is put into the refuse gasification room on top from dog-house, the heap on the water-cooled chimney arch of arrangement at regular intervals The certain height of product, starts the plasma torch that bottom high-temperature vapor occurs room, produces steady temperature, while by water from water-cooled It is passed through in fire grate;Water enters high-temperature vapor generation room after being preheated in water-cooled chimney arch after, the high temperature that stabilization is flowed up is formed Vapor, raises rubbish temperature, and pyrolytic gasification occurs;Meanwhile, blast a certain amount of excess air system from the air supply opening on top Air of the number less than 0.3, makes rubbish realize partial oxidation, using a part of itself calorific value, reduces the plasma power consumption of bottom, The synthesis gas of generation is drawn from the syngas outlet on top, can be used as heat supply or generating, and waste residue is by bottom after refuse gasification There is room and fall into bottom slag discharge in high-temperature vapor, the thorough harmless treatment of waste residue is realized at high temperature.
Beneficial effects of the present invention are as follows:
(1)Using steam plasma body gasification rubbish, for gasification reaction provides high temperature, a high-energy environment, material adds Hot speed is fast, and reaction rate is fast, there is treatment effeciency very high, moreover it is possible to which occur that some can not occur under common gasification condition is anti- Should;
(2)A certain amount of air is passed through in refuse gasification room(Excess air coefficient is less than 0.3), can be using rubbish part heat There is partial oxidation in value, so as to reduce the power consumption of plasma torch, reduce the operating cost of rubbish plasma gasification;
(3)The high-temperature vapor indirect gasification rubbish of using plasma torch heating, can make the flow field in refuse gasification room It is more uniformly distributed with temperature field, makes rubbish completely by high-temperature process, the waste residue of generation occurs room and enters by the high-temperature vapor of bottom The treatment of one step, so that thoroughly being eliminated containing harmful substances such as bioxin in waste residue, the motlten metal of discharge is recyclable Recycle, and the inorganic matter for melting is similar to vitreous structure, experiment shows, it has not leachability, can be used as construction material;
(4)Tar composition is free of in steam plasma body gasification product, gasification burning quality is high, almost completely by H2And CO Composition, accounts for the 99% of gas component, is easy to gas further to process, and can be directly used for gas turbine power generation.And H2And CO Ratio, regulation can be reached by controlling the amount of steam and waste, the need for so can directly meeting some chemical syntheses. Such as synthesizing methanol, by H2It is the most suitable 2 to 1 to be controlled with the ratio of CO.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Wherein, reference is:There are room, 3 water-cooled chimney arch, 4 dog-houses, 5 synthesis in 1 refuse gasification room, 2 high-temperature vapors Gas is exported, 6 air supply openings, 7 slag notches, 8 plasma torch, 9 water inlets, 10 delivery ports, 11 vapor imports.
Specific embodiment
The present invention is to provide a kind of rubbish plasma gasification stove with vapor as gasifying medium, by the rubbish gas on top Change room 1 to be constituted with the high-temperature vapor generation room 2 of bottom, upper and lower two parts are separated by spaced water-cooled chimney arch 3, gasification furnace Inwall is cast with refractory material.
The top of refuse gasification room 1 is provided with dog-house 4, and side higher position has syngas outlet 5, and side lower is provided with supply Mouth 6;It is slag notch 7, side circumferentially two plasma torch 8, two plasma torch that high-temperature vapor occurs the bottom of room 2 It is in α angles between 8, α is 120 ° -150 °;It is 150 DEG C -250 DEG C of low temperature vapor as plasma torch 8 to use temperature Working gas, while there is a part of vapor of lateral leadin of room 2 from high-temperature vapor, i.e., using vapor as refuse gasification Medium, the vapor after being heated through plasma torch 8, mean temperature is up to 5000 DEG C, travel up to refuse gasification room 1 so as to Refuse pyrolysis is gasified, the flow field in refuse gasification room 1 is more uniformly distributed with temperature field by vapor indirectly heat garbage energy.
Meanwhile, rubbish vaporizer air supply opening 6 introduces portion of air(Excess air coefficient is less than 0.3), make rubbish in high temperature First portion oxidation reaction is issued, so as to using itself calorific value of a part of rubbish, reduce plasma power consumption.
The main body of water-cooled chimney arch 3 is steel pipe, and water is introduced from side water inlet 9, the cross arrangement in gasification furnace, by cooling water Heat is taken away in Bottomhole pressure, chimney arch is cooled down, so as to extend the service life of chimney arch, maintenance cost is reduced.Water-cooled chimney arch 3 goes out The mouth of a river 10 is connected with the vapor import 11 of bottom, and high-temperature vapor is become by plasma torch 8 again by the water that chimney arch is heated, So as to as the gasifying medium of rubbish.Volume and size reduction after refuse gasification, the waste residue of formation are fallen into by the gap of chimney arch The pollutants such as room 2, the bioxin for containing in waste residue at high temperature and further decompose completely in the high-temperature vapor of bottom, Ran Houtong there is The slag-drip opening discharge of bottom is crossed, so as to realize the thorough harmless treatment of waste residue, without landfill, can be used as building materials.
Operating method of the invention is:Rubbish is put into the refuse gasification room 1 on top from dog-house 4, it is certain having Certain height is piled up on the water-cooled chimney arch 3 of spacing arrangement, starts the plasma torch 8 that bottom high-temperature vapor occurs room 2, produced Raw constant high temperature, while water is passed through from water-cooled grate;Water enters high-temperature vapor and room occurs after being preheated in water-cooled chimney arch 3 After 2, the high-temperature vapor that stabilization is flowed up is formed, raise rubbish temperature, pyrolytic gasification occurs;Meanwhile, from the confession on top Gas port 6 blasts air of a certain amount of excess air coefficient less than 0.3, rubbish is realized partial oxidation, using a part itself Calorific value, reduces the plasma power consumption of bottom, and the synthesis gas of generation draws from the syngas outlet 5 on top, can be used as heat supply or Generate electricity, waste residue falls into bottom slag discharge by the high-temperature vapor generation room 2 of bottom after refuse gasification, and waste residue is realized at high temperature Thorough harmless treatment.

Claims (3)

1. a kind of rubbish plasma gasification stove with water vapour as gasifying medium, it is characterised in that:Rubbish gas including top Change room(1)There is room with the high-temperature water vapor of bottom(2), refuse gasification room(1)There is room with high-temperature water vapor(2)Between set There is spaced water-cooled chimney arch(3), water-cooled chimney arch(3)By refuse gasification room(1)There is room with high-temperature water vapor(2)Separate; There is room in the high-temperature water vapor(2)Inwall circumferentially two plasma torch(8), two plasma torch(8)Between In α angles, α is 120 ° -150 °;Plasma torch(8)Working gas be low temperature water vapour that temperature is 150 DEG C -250 DEG C;
The water-cooled chimney arch(3)Main body be steel pipe, water-cooled chimney arch(3)One end be water inlet(9), the other end is delivery port (10);
The refuse gasification room(1)Top is provided with the dog-house for garbage throwing(4), side higher position is provided with syngas outlet (5), side lower is provided with air supply opening(6);
There is room in the high-temperature water vapor(2)Bottom be slag notch(7), side is provided with water vapour import(11), water vapour enters Mouthful(11)With water-cooled chimney arch(3)Delivery port(10)Connection.
2. a kind of rubbish plasma gasification stove with water vapour as gasifying medium according to claim 1, its feature exists In:The inwall of the gasification furnace is cast with refractory material.
3. a kind of rubbish plasma gasification with water vapour as gasifying medium according to claim 1-2 any one Stove, it is characterised in that the course of work is:
By rubbish from dog-house(4)Put into the refuse gasification room on top(1)It is interior, in the water-cooled chimney arch of spread configuration(3)Upper heap Product, starts bottom high-temperature water vapor and room occurs(2)Plasma torch(8), steady temperature is produced, while by water from water-cooled grate In be passed through;Water is in water-cooled chimney arch(3)Enter high-temperature water vapor after middle preheating and room occurs(2)Afterwards, the height that stabilization is flowed up is formed Heated steam, raises rubbish temperature, and pyrolytic gasification occurs;Meanwhile, from the air supply opening on top(6)Blast a certain amount of excessive empty Air of the gas coefficient less than 0.3 realizes partial oxidation for rubbish, the syngas outlet of the synthesis gas of generation from top(5)Draw Go out, can be used as heat supply or generating, waste residue occurs room by the high-temperature water vapor of bottom after refuse gasification(2)Fall into bottom deslagging Mouthful, the thorough harmless treatment of waste residue is realized at high temperature.
CN201410744809.5A 2014-12-09 2014-12-09 A kind of rubbish plasma gasification stove with vapor as gasifying medium Active CN104479743B (en)

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CN105423308A (en) * 2015-11-08 2016-03-23 广东工业大学 Petroleum coke assisted refuse disposal system combining microwave drying and plasma gasification
CN105542862B (en) * 2016-03-07 2018-03-16 衢州迪升工业设计有限公司 A kind of plasma gasification device
CN108518684B (en) * 2018-04-13 2019-06-04 湖北中道环保科技股份有限公司 Rural garbage processing low temperature pyrogenation processing unit
CN108753363A (en) * 2018-06-26 2018-11-06 加拿大艾浦莱斯有限公司 Solid-state dangerous waste gasifies and ashing all-in-one oven
CN112708473B (en) * 2019-10-25 2023-04-07 中国石油化工股份有限公司 Gasification device and gasification method for producing synthesis gas by co-gasification of multiple materials and coal
CN111586954B (en) * 2020-06-08 2022-09-09 江苏帕斯玛环境科技有限公司 Method for generating water vapor plasma
CN112708464A (en) * 2020-12-23 2021-04-27 合肥中科远望环保科技有限公司 Device for treating organic solid-containing waste by two-section type gasification melting furnace
CN113528188A (en) * 2021-08-27 2021-10-22 上海中川国宇环境有限公司 Novel plasma gasification furnace and operation process thereof

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