CN104479519B - A kind of BDO aliphatic dicarboxylic acid ester paint preparation method - Google Patents
A kind of BDO aliphatic dicarboxylic acid ester paint preparation method Download PDFInfo
- Publication number
- CN104479519B CN104479519B CN201410741602.2A CN201410741602A CN104479519B CN 104479519 B CN104479519 B CN 104479519B CN 201410741602 A CN201410741602 A CN 201410741602A CN 104479519 B CN104479519 B CN 104479519B
- Authority
- CN
- China
- Prior art keywords
- parts
- aliphatic dicarboxylic
- dicarboxylic acid
- bdo
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 BDO aliphatic dicarboxylic acid ester Chemical class 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003973 paint Substances 0.000 title abstract description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 26
- WERYXYBDKMZEQL-UHFFFAOYSA-N 1,4-butanediol Substances OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 18
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940107816 ammonium iodide Drugs 0.000 claims abstract description 13
- 239000010425 asbestos Substances 0.000 claims abstract description 13
- 238000012986 modification Methods 0.000 claims abstract description 13
- 230000004048 modification Effects 0.000 claims abstract description 13
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 238000006253 efflorescence Methods 0.000 description 3
- 206010037844 rash Diseases 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of 1,4 butanediol aliphatic dicarboxylic acids ester paints, by following raw material mass mixture ratio: 1,4 butanediols 55 65 parts, aliphatic dicarboxylic acid 30 35 parts, dicyandiamide 35 parts, polyethers modification polysiloxanes 5 10 parts, 12 14 parts of acetone, ammonium iodide 5 10 parts, flake asbestos 10 15 parts, deionized water 45 50 parts.Preparation method comprises the following steps: Isosorbide-5-Nitrae butanediol, aliphatic dicarboxylic acid are added heating 150 180 DEG C in reactor and reacted 24 36 hours；Add polyethers modification polysiloxanes, acetone stirs, and reacts 58 hours at 70 80 DEG C；Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 37 hours, obtain coating.
Description
Technical field
The present invention relates to a kind of coating, a kind of BDO aliphatic dicarboxylic acid ester paint.
Background technology
Polyurethane paint i.e. polyurethanes paint.Its paint film is tough, and gloss is plentiful, and adhesive force is strong, water proof and wearable, corrosion resistance.It is widely used in high-class woodenware furniture it can also be used to metal surface.The problems such as its shortcoming mainly has wet to bubble, film efflorescence, as Polyester Paint, it equally exists the problem turned yellow.
Summary of the invention
For above-mentioned deficiency of the prior art, the invention provides a kind of moisture resistance, anti-efflorescence, invariant color, the BDO aliphatic dicarboxylic acid ester paint faded and preparation method.
The technical solution used in the present invention is: a kind of 1,4-butanediol aliphatic dicarboxylic acids ester paint, by following raw material mass mixture ratio: 1,4-butanediol 55-65 part, aliphatic dicarboxylic acid 30-35 part, dicyandiamide 3-5 part, polyethers modification polysiloxanes 5-10 part, acetone 12-14 part, ammonium iodide 5-10 part, flake asbestos 10-15 part, deionized water 45-50 part.
A kind of BDO aliphatic dicarboxylic acid ester paint preparation method, comprises the following steps:
BDO, aliphatic dicarboxylic acid are added heating 150-180 DEG C in reactor and react 24-36 hour；
Add polyethers modification polysiloxanes, acetone stirs, and reacts 5-8 hour at 70-80 DEG C；
Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 3-7 hour, obtain coating.
The polyester coating of the present invention, on the basis of traditional coating, uses polyethers modification polysiloxanes, acetone, ammonium iodide and flake asbestos to be effectively improved its moisture resistance, efflorescence and performance of fading, applied widely.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment one
A kind of 1,4-butanediol aliphatic dicarboxylic acids ester paint, by following raw material mass mixture ratio: BDO 65 parts, aliphatic dicarboxylic acid 35 parts, dicyandiamide 5 parts, polyethers modification polysiloxanes 10 parts, 14 parts of acetone, ammonium iodide 10 parts, flake asbestos 15 parts, deionized water 50 parts.
Preparation method comprises the following steps:
BDO, aliphatic dicarboxylic acid are added heating 180 DEG C in reactor and react 36 hours；
Add polyethers modification polysiloxanes, acetone stirs, and reacts 8 hours at 80 DEG C；
Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 7 hours, obtain coating.
Embodiment two
A kind of 1,4-butanediol aliphatic dicarboxylic acids ester paint, by following raw material mass mixture ratio: BDO 55 parts, aliphatic dicarboxylic acid 30 parts, dicyandiamide 3 parts, polyethers modification polysiloxanes 5 parts, 12 parts of acetone, ammonium iodide 5 parts, flake asbestos 10 parts, deionized water 45 parts.
Preparation method comprises the following steps:
BDO, aliphatic dicarboxylic acid are added heating 150 DEG C in reactor and react 24 hours；
Add polyethers modification polysiloxanes, acetone stirs, and reacts 5 hours at 70 DEG C；
Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 3 hours, obtain coating.
Embodiment three
A kind of 1,4-butanediol aliphatic dicarboxylic acids ester paint, by following raw material mass mixture ratio: BDO 60 parts, aliphatic dicarboxylic acid 33 parts, dicyandiamide 4 parts, polyethers modification polysiloxanes 6 parts, 13 parts of acetone, ammonium iodide 6 parts, flake asbestos 12 parts, deionized water 48 parts.
Preparation method comprises the following steps:
BDO, aliphatic dicarboxylic acid are added heating 160 DEG C in reactor and react 29 hours；
Add polyethers modification polysiloxanes, acetone stirs, and reacts 6 hours at 73 DEG C；
Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 5 hours, obtain coating.
Claims (1)
1. one kind 1,4-butanediol aliphatic dicarboxylic esters preparation method for coating, comprise the following steps: by following raw material mass mixture ratio: 1,4-butanediol 55-65 part, aliphatic dicarboxylic acid 30-35 part, dicyandiamide 3-5 part, polyethers modification polysiloxanes 5-10 part, acetone 12-14 part, ammonium iodide 5-10 part, flake asbestos 10-15 part, deionized water 45-50 part;
BDO, aliphatic dicarboxylic acid are added heating 150-180 DEG C in reactor and react 24-36 hour；
Add polyethers modification polysiloxanes, acetone stirs, and reacts 5-8 hour at 70-80 DEG C；
Finally in stirring, addition ammonium iodide, flake asbestos, deionized water stir 3-7 hour, obtain coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741602.2A CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741602.2A CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104479519A CN104479519A (en) | 2015-04-01 |
| CN104479519B true CN104479519B (en) | 2016-12-28 |
Family
ID=52754132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410741602.2A Active CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104479519B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4242052A1 (en) * | 1992-12-14 | 1994-06-16 | Hoechst Ag | Modified acidic polyesters and their use as hardeners in thermosetting binders |
| DE10033512A1 (en) * | 2000-07-11 | 2002-01-24 | Solutia Austria Gmbh Werndorf | Aliphatic low molecular weight polyester polyols, their preparation and use in high quality coating compositions |
| US6808821B2 (en) * | 2000-09-05 | 2004-10-26 | Dainippon Ink And Chemicals, Inc. | Unsaturated polyester resin composition |
| EP2228399B1 (en) * | 2007-12-27 | 2015-02-11 | Mitsubishi Chemical Corporation | Method for producing aliphatic polyester |
| JP2014133824A (en) * | 2013-01-10 | 2014-07-24 | Mitsubishi Chemicals Corp | Method for producing aliphatic polyester |
-
2014
- 2014-12-09 CN CN201410741602.2A patent/CN104479519B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104479519A (en) | 2015-04-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2020000919A1 (en) | Method for preparing flame-retardant, antibacterial, and waterborne polyurethane coating and adhesive | |
| CN103087626B (en) | A kind of UV varnish and preparation method thereof | |
| CN105153387A (en) | Polyurethane-amino resin modified waterborne alkyd resin and preparation and application thereof | |
| CN104327712A (en) | High-adhesion and wear-resistant engineering mechanical waterproof paint | |
| MX2017013038A (en) | Adjustable low gloss powder coating compositions. | |
| CN104263216A (en) | Wear-resistant anticorrosive paint with high toughness and adhesive force | |
| CN103694940A (en) | Method for preparing fast curing one-component water-based polyurethane adhesive | |
| CN104513575B (en) | A kind of preparation method of acrylic acid series anticorrosive paint | |
| CN112358773A (en) | Novel anticorrosive waterproof environment-friendly coating and preparation method thereof | |
| CN103059239A (en) | Phenolic resin and synthetic method thereof | |
| CN104479519B (en) | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method | |
| CN104479520B (en) | 1,4-butanediol aliphatic dicarboxylic ester coating and preparation method | |
| CN104177589A (en) | Flexible epoxy resin curing agent and synthesis method thereof | |
| CN107011769B (en) | A kind of solvent free corrosion prevention coating and its preparation method and application | |
| CN109293837A (en) | A kind of preparation method of adhesion promoter | |
| CN104845482A (en) | High-adhesion shock-resistant anti-corrosion mechanical paint | |
| CN107434950A (en) | A kind of colored steel coil coating polyurethane primer | |
| CN104327234B (en) | Preparation method of cationic waterborne polyurethane resin with high solid content | |
| CN103382317A (en) | Metal protection resin varnish | |
| JP2011168757A (en) | Method for producing iron rust-reducing water-based rustproofing coating | |
| CN105385317A (en) | Water-based alkyd resin stoving varnish for steel drum | |
| CN106634383A (en) | Epoxy modified acrylic resin emulsion aqueous anti-rust coating material | |
| CN106188949A (en) | A kind of liquid type rare earth complex heat stabilizer | |
| CN103881443A (en) | Environment-friendly antiseptic and anti-yellowing amino resin coating | |
| CN103709896A (en) | Flexible and antiseptic epoxy resin paint for copper sculptures |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160825 Address after: 225400 Jiangsu city of Taizhou province Taixing City Economic Development Zone Industrial Park East Road No. 18 Dai Wang Applicant after: Zhang Heqing Address before: 225400 Binjiang, Jiangsu, Taixing Town, Tongjiang Road, Applicant before: TAIXING HEQING MACHINERY FITTINGS FACTORY |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20161114 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Yukui Address before: 225400 Jiangsu city of Taizhou province Taixing City Economic Development Zone Industrial Park East Road No. 18 Dai Wang Applicant before: Zhang Heqing |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee after: Gu Yukui Address before: 266000 No. nine water East Road, Licang District, Qingdao, Shandong, 320 Patentee before: Gu Yukui |
|
| CP02 | Change in the address of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181106 Address after: 311200 Linjiang Industrial Park, Xiaoshan District, Hangzhou, Zhejiang (farm two) Patentee after: Hangzhou Sanlong New Material Co., Ltd. Address before: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee before: Gu Yukui |
|
| TR01 | Transfer of patent right |