CN105385317A - Water-based alkyd resin stoving varnish for steel drum - Google Patents
Water-based alkyd resin stoving varnish for steel drum Download PDFInfo
- Publication number
- CN105385317A CN105385317A CN201510828232.0A CN201510828232A CN105385317A CN 105385317 A CN105385317 A CN 105385317A CN 201510828232 A CN201510828232 A CN 201510828232A CN 105385317 A CN105385317 A CN 105385317A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- steel drum
- epichlorohydrin
- polyamsne
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based alkyd resin stoving varnish for a steel drum. The water-based alkyd resin stoving varnish is prepared from the following raw materials in parts by weight: 20 to 35 parts of water-based alkyd resin, 10 to 20 parts of water-based methylated amino resin, 5 to 15 parts of polyamide polyamine epichlorohydrin, 5 to 12 parts of water-based epoxy emulsion, 2 to 5 parts of styrene, 0.5 to 3.5 parts of vinyltriethoxysilane, 1 to 2 parts of N,N-dimethylethanolamine, 1 to 3 parts of monoethanolamine, 2 to 8 parts of phenylcarbinol, 1 to 3 parts of 2501 modified silane adhesive, 1 to 3 parts of iron oxide red, 2 to 5 parts of aluminium triphosphate, 15 to 30 parts of nano silicon dioxide, 10 to 20 parts of nano glass microbeads, 2 to 8 parts of calcium carbonate, 1 to 2 parts of emulsifier, 1 to 2 parts of dispersion agent, 1 to 2 parts of defoaming agent, 1 to 2 parts of flatting agent, 1 to 3 parts of mildewproof agent, 2 to 3 parts of water-based drier and 25 to 45 parts of water. The water-based alkyd resin stoving varnish for the steel drum is high in adhesive force, good in impact-resisting flexibility, excellent in corrosion resistance and high in glossiness.
Description
Technical field
The present invention relates to metal baking finish technical field, particularly relate to a kind of steel drum use Synolac baking vanish.
Background technology
Metal baking finish is as a kind of common industrial finish, be widely used in the industries such as machinofacture, electromechanics and five metals, at present for the growing growth in industrial paint market of steel drum, but the coating of steel drum mainly solvent based coating on the market, the volatilization of organic solvent brings pollution to environment, and along with the enhancing of people's environmental consciousness, the application of water-based stoving paint is increasingly extensive, but the snappiness of common water borne baking vanish, shock-resistant, sticking power and erosion resistance are general, can not meet high-level requirement.
Summary of the invention
A kind of steel drum use Synolac baking vanish, goods sticking power is high, and Impact-resistant flexible is good, excellent anti-corrosion performance, and glossiness is high.
A kind of steel drum use Synolac baking vanish that the present invention proposes, its raw material comprises by weight: aqueous alkide resin 20-35 part, water-based methyl-etherified aminoresin 10-20 part, Polyamide-Polyamsne-Epichlorohydrin 5-15 part, aqueous epoxy emulsion 5-12 part, vinylbenzene 2-5 part, vinyltriethoxysilane 0.5-3.5 part, N, N-dimethylethanolamine 1-2 part, monoethanolamine 1-3 part, phenylcarbinol 2-8 part, 2501 modified silane glue 1-3 parts, red iron oxide 1-3 part, aluminium triphosphate 2-5 part, nano silicon 15-30 part, nano-glass microballon 10-20 part, calcium carbonate 2-8 part, emulsifying agent 1-2 part, dispersion agent 1-2 part, defoamer 1-2 part, flow agent 1-2 part, mould inhibitor 1-3 part, water-based siccative 2-3 part, water 25-45 part.
Preferably, Polyamide-Polyamsne-Epichlorohydrin adopts following technique to prepare: by weight by 20-40 part poly hexamethylene adipamide diethylenetriamine, 50-80 part deionized water mixes, 10-16 part epoxy chloropropane is dripped under stirring at normal temperature state, after dropping terminates, be warming up to 60-70 DEG C with the speed of 1-4 DEG C/min under whipped state to continue to stir 20-40min, continue to add 1-5 part ethyl acrylate, 0.5-1 part benzoyl peroxide stirs, whipping temp is 80-95 DEG C, churning time is 5-15min, continuing to add 5-10 part concentration is that the hydrochloric acid of 0.5-4mol/L stirs, obtain Polyamide-Polyamsne-Epichlorohydrin.
Preferably, the weight ratio of aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion is 25-30:14-18:10-12:8-11.
Preferably, the weight ratio of Polyamide-Polyamsne-Epichlorohydrin, vinyltriethoxysilane is 10-12:1-2.6.
Preferably, the weight ratio of vinylbenzene, vinyltriethoxysilane, N, N-dimethylethanolamine, monoethanolamine is 3-4.5:1-2.6:1.2-1.6:2-2.5.
Preferably, the weight ratio of vinyltriethoxysilane, 2501 modified silane glue is 1-2.6:1.5-2.3.
Preferably, the weight ratio of red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate is 1.2-1.8:4-4.6:20-24:12-16:3-5.
Preferably, its raw material comprises by weight: aqueous alkide resin 25-30 part, water-based methyl-etherified aminoresin 14-18 part, Polyamide-Polyamsne-Epichlorohydrin 10-12 part, aqueous epoxy emulsion 8-11 part, vinylbenzene 3-4.5 part, vinyltriethoxysilane 1-2.6 part, N, N-dimethylethanolamine 1.2-1.6 part, monoethanolamine 2-2.5 part, phenylcarbinol 4-6 part, 2501 modified silane glue 1.5-2.3 parts, red iron oxide 1.2-1.8 part, aluminium triphosphate 4-4.6 part, nano silicon 20-24 part, nano-glass microballon 12-16 part, calcium carbonate 3-5 part, emulsifying agent 1.2-1.6 part, dispersion agent 1.4-1.8 part, defoamer 1.3-1.5 part, flow agent 1.2-1.6 part, mould inhibitor 2-2.5 part, water-based siccative 2-3 part, water 30-36 part.
A kind of steel drum use Synolac baking vanish that the present invention proposes adopts following technique to prepare: by aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion, vinylbenzene, vinyltriethoxysilane, phenylcarbinol, 2501 modified silane glue, red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate, emulsifying agent, dispersion agent, defoamer, flow agent, mould inhibitor mixes by proportioning, send in reactor and stir, whipping temp is 80-90 DEG C, churning time is 20-50h, be cooled to 65-70 DEG C and add N, N-dimethylethanolamine, monoethanolamine, water-based siccative stirs 40-80min, add water to stir, obtain steel drum use Synolac baking vanish.
In the present invention, by adopting aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion as filmogen, be equipped with vinylbenzene, N, N-dimethylethanolamine, monoethanolamine, goods sticking power is good, Impact-resistant flexible is good, excellent anti-corrosion performance, and glossiness is high.The Polyamide-Polyamsne-Epichlorohydrin adopting certain technique to prepare is water-soluble fabulous, and not release formaldehyde gas, with aqueous alkide resin, water-based methyl-etherified aminoresin, the consistency of aqueous epoxy emulsion is fabulous, goods are corrosion-resistant and adhesion performance is strong, and iron anode reacts in phosphate anion in aluminium triphosphate and steel drum, form the firm protective membrane based on tertiary iron phosphate, sticking power is good, antirust ability is very excellent, goods glossiness is high, with nano silicon, nano-glass microballon, calcium carbonate acts on further, goods sticking power and glossiness strengthen further, and Impact-resistant flexible is fabulous.
Vinyltriethoxysilane can interact with substrate interface, promote paint film and the interpenetrative reticulated structure of substrate interface, strengthen goods corrosion resistance nature, paint film adhesion is very excellent, interact with the 2501 modified silane glue added, 2501 modified silane glue can impel goods internal height to be cross-linked, and vinyltriethoxysilane and 2501 modified silane glue interact, goods Impact-resistant flexible, corrosion resistance nature are fabulous, and very excellent with the sticking power of ground; 2501 modified silane glue can be used as aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, the chain-transfer agent of aqueous epoxy emulsion effect and linking agent, with nano silicon, nano-glass microballon, calcium carbonate acting in conjunction, goods Impact-resistant flexible and corrosion resistance nature fabulous, and sticking power strengthens further.Above-mentioned steel drum use Synolac baking vanish has good sticking power, and Impact-resistant flexible is good, excellent anti-corrosion performance, pollution-free in coating process, and traditional solvent-borne type baking vanish can be replaced for steel drum.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of steel drum use Synolac baking vanish, its raw material comprises by weight: aqueous alkide resin 20 parts, 20 parts, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin 5 parts, aqueous epoxy emulsion 12 parts, vinylbenzene 2 parts, vinyltriethoxysilane 3.5 parts, N, N-dimethylethanolamine 1 part, monoethanolamine 3 parts, phenylcarbinol 2 parts, 2501 3 parts, modified silane glue, red iron oxide 1 part, aluminium triphosphate 5 parts, nano silicon 15 parts, nano-glass microballon 20 parts, 2 parts, calcium carbonate, emulsifying agent 2 parts, dispersion agent 1 part, defoamer 2 parts, flow agent 1 part, mould inhibitor 3 parts, water-based siccative 2 parts, 25 parts, water.
Embodiment 2
A kind of steel drum use Synolac baking vanish, its raw material comprises by weight: aqueous alkide resin 35 parts, water-based methyl-etherified aminoresin 10-2 part, Polyamide-Polyamsne-Epichlorohydrin 15 parts, aqueous epoxy emulsion 5 parts, vinylbenzene 5 parts, vinyltriethoxysilane 0.5 part, N, N-dimethylethanolamine 2 parts, monoethanolamine 1 part, phenylcarbinol 8 parts, 2501 1 part, modified silane glue, red iron oxide 3 parts, aluminium triphosphate 2 parts, nano silicon 30 parts, nano-glass microballon 10 parts, 8 parts, calcium carbonate, emulsifying agent 1 part, dispersion agent 2 parts, defoamer 1 part, flow agent 2 parts, mould inhibitor 1 part, water-based siccative 3 parts, 45 parts, water.
Embodiment 3
A kind of steel drum use Synolac baking vanish, its raw material comprises by weight: aqueous alkide resin 25 parts, 18 parts, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin 10 parts, aqueous epoxy emulsion 11 parts, vinylbenzene 3 parts, vinyltriethoxysilane 2.6 parts, N, N-dimethylethanolamine 1.2 parts, monoethanolamine 2.5 parts, phenylcarbinol 4 parts, 2501 2.3 parts, modified silane glue, red iron oxide 1.2 parts, aluminium triphosphate 4.6 parts, nano silicon 20 parts, nano-glass microballon 16 parts, 3 parts, calcium carbonate, emulsifying agent 1.6 parts, dispersion agent 1.4 parts, defoamer 1.5 parts, flow agent 1.2 parts, mould inhibitor 2.5 parts, water-based siccative 2.2 parts, 30 parts, water.
Polyamide-Polyamsne-Epichlorohydrin adopts following technique to prepare: 40 parts of poly hexamethylene adipamide diethylenetriamines, 50 parts of deionized waters are mixed by weight, 16 parts of epoxy chloropropane are dripped under stirring at normal temperature state, after dropping terminates, be warming up to 70 DEG C with the speed of 1 DEG C/min under whipped state to continue to stir 20min, continue to add 5 parts of ethyl acrylates, 0.5 part of benzoyl peroxide stirs, whipping temp is 95 DEG C, churning time is 5min, continuing to add 10 parts of concentration is that the hydrochloric acid of 0.5mol/L stirs, and obtains Polyamide-Polyamsne-Epichlorohydrin.
Steel drum use Synolac baking vanish adopts following technique to prepare: by aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion, vinylbenzene, vinyltriethoxysilane, phenylcarbinol, 2501 modified silane glue, red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate, emulsifying agent, dispersion agent, defoamer, flow agent, mould inhibitor mixes by proportioning, send in reactor and stir, whipping temp is 90 DEG C, churning time is 20h, be cooled to 70 DEG C and add N, N-dimethylethanolamine, monoethanolamine, water-based siccative stirs 40min, add water to stir, obtain steel drum use Synolac baking vanish.
Embodiment 4
A kind of steel drum use Synolac baking vanish, its raw material comprises by weight: aqueous alkide resin 30 parts, 14 parts, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin 12 parts, aqueous epoxy emulsion 8 parts, vinylbenzene 4.5 parts, vinyltriethoxysilane 1 part, N, N-dimethylethanolamine 1.6 parts, monoethanolamine 2 parts, phenylcarbinol 6 parts, 2501 1.5 parts, modified silane glue, red iron oxide 1.8 parts, aluminium triphosphate 4 parts, nano silicon 24 parts, nano-glass microballon 12 parts, 5 parts, calcium carbonate, emulsifying agent 1.2 parts, dispersion agent 1.8 parts, defoamer 1.3 parts, flow agent 1.6 parts, mould inhibitor 2 parts, water-based siccative 2.8 parts, 36 parts, water.
Polyamide-Polyamsne-Epichlorohydrin adopts following technique to prepare: 20 parts of poly hexamethylene adipamide diethylenetriamines, 80 parts of deionized waters are mixed by weight, 10 parts of epoxy chloropropane are dripped under stirring at normal temperature state, after dropping terminates, be warming up to 60 DEG C with the speed of 4 DEG C/min under whipped state to continue to stir 40min, continue to add 1 part of ethyl acrylate, 1 part of benzoyl peroxide stirs, whipping temp is 80 DEG C, churning time is 15min, continuing to add 5 parts of concentration is that the hydrochloric acid of 4mol/L stirs, and obtains Polyamide-Polyamsne-Epichlorohydrin.
Steel drum use Synolac baking vanish adopts following technique to prepare: by aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion, vinylbenzene, vinyltriethoxysilane, phenylcarbinol, 2501 modified silane glue, red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate, emulsifying agent, dispersion agent, defoamer, flow agent, mould inhibitor mixes by proportioning, send in reactor and stir, whipping temp is 80 DEG C, churning time is 50h, be cooled to 65 DEG C and add N, N-dimethylethanolamine, monoethanolamine, water-based siccative stirs 80min, add water to stir, obtain steel drum use Synolac baking vanish.
Embodiment 5
A kind of steel drum use Synolac baking vanish, its raw material comprises by weight: aqueous alkide resin 28 parts, 16 parts, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin 11.6 parts, aqueous epoxy emulsion 10.5 parts, vinylbenzene 4.1 parts, vinyltriethoxysilane 2.2 parts, N, N-dimethylethanolamine 1.4 parts, monoethanolamine 2.3 parts, phenylcarbinol 5.5 parts, 2501 2.1 parts, modified silane glue, red iron oxide 1.6 parts, aluminium triphosphate 4.2 parts, nano silicon 22 parts, nano-glass microballon 14 parts, 4.5 parts, calcium carbonate, emulsifying agent 1.4 parts, dispersion agent 1.6 parts, defoamer 1.4 parts, flow agent 1.35 parts, mould inhibitor 2.2 parts, water-based siccative 2.5 parts, 32 parts, water.
Polyamide-Polyamsne-Epichlorohydrin adopts following technique to prepare: 36 parts of poly hexamethylene adipamide diethylenetriamines, 75 parts of deionized waters are mixed by weight, 14 parts of epoxy chloropropane are dripped under stirring at normal temperature state, after dropping terminates, be warming up to 65 DEG C with the speed of 2.6 DEG C/min under whipped state to continue to stir 36min, continue to add 3 parts of ethyl acrylates, 0.85 part of benzoyl peroxide stirs, whipping temp is 92 DEG C, churning time is 12min, continuing to add 8 parts of concentration is that the hydrochloric acid of 2.5mol/L stirs, and obtains Polyamide-Polyamsne-Epichlorohydrin.
Steel drum use Synolac baking vanish adopts following technique to prepare: by aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion, vinylbenzene, vinyltriethoxysilane, phenylcarbinol, 2501 modified silane glue, red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate, emulsifying agent, dispersion agent, defoamer, flow agent, mould inhibitor mixes by proportioning, send in reactor and stir, whipping temp is 86 DEG C, churning time is 35h, be cooled to 68 DEG C and add N, N-dimethylethanolamine, monoethanolamine, water-based siccative stirs 62min, add water to stir, obtain steel drum use Synolac baking vanish.
The paint film adhesion 0 grade that the use of steel drum described in embodiment 1-5 Synolac baking vanish is obtained, resistance to 200 DEG C of high temperature 4h are without obvious xanthochromia, the resistance to 30 non-foaming non-corrosives in the sky and water, gloss of film is greater than 92 degree, solvent resistance is good, resistance to butanone wiping can reach 200 times not show-through, salt water resistance soak can reach one week unchanged.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a steel drum use Synolac baking vanish, it is characterized in that, its raw material comprises by weight: aqueous alkide resin 20-35 part, water-based methyl-etherified aminoresin 10-20 part, Polyamide-Polyamsne-Epichlorohydrin 5-15 part, aqueous epoxy emulsion 5-12 part, vinylbenzene 2-5 part, vinyltriethoxysilane 0.5-3.5 part, N, N-dimethylethanolamine 1-2 part, monoethanolamine 1-3 part, phenylcarbinol 2-8 part, 2501 modified silane glue 1-3 parts, red iron oxide 1-3 part, aluminium triphosphate 2-5 part, nano silicon 15-30 part, nano-glass microballon 10-20 part, calcium carbonate 2-8 part, emulsifying agent 1-2 part, dispersion agent 1-2 part, defoamer 1-2 part, flow agent 1-2 part, mould inhibitor 1-3 part, water-based siccative 2-3 part, water 25-45 part.
2. steel drum use Synolac baking vanish according to claim 1, it is characterized in that, Polyamide-Polyamsne-Epichlorohydrin adopts following technique to prepare: by weight by 20-40 part poly hexamethylene adipamide diethylenetriamine, 50-80 part deionized water mixes, 10-16 part epoxy chloropropane is dripped under stirring at normal temperature state, after dropping terminates, be warming up to 60-70 DEG C with the speed of 1-4 DEG C/min under whipped state to continue to stir 20-40min, continue to add 1-5 part ethyl acrylate, 0.5-1 part benzoyl peroxide stirs, whipping temp is 80-95 DEG C, churning time is 5-15min, continuing to add 5-10 part concentration is that the hydrochloric acid of 0.5-4mol/L stirs, obtain Polyamide-Polyamsne-Epichlorohydrin.
3. steel drum use Synolac baking vanish according to claim 1 and 2, it is characterized in that, the weight ratio of aqueous alkide resin, water-based methyl-etherified aminoresin, Polyamide-Polyamsne-Epichlorohydrin, aqueous epoxy emulsion is 25-30:14-18:10-12:8-11.
4. the steel drum use Synolac baking vanish according to any one of claim 1-3, is characterized in that, the weight ratio of Polyamide-Polyamsne-Epichlorohydrin, vinyltriethoxysilane is 10-12:1-2.6.
5. the steel drum use Synolac baking vanish according to any one of claim 1-4, is characterized in that, the weight ratio of vinylbenzene, vinyltriethoxysilane, N, N-dimethylethanolamine, monoethanolamine is 3-4.5:1-2.6:1.2-1.6:2-2.5.
6. the steel drum use Synolac baking vanish according to any one of claim 1-5, is characterized in that, the weight ratio of vinyltriethoxysilane, 2501 modified silane glue is 1-2.6:1.5-2.3.
7. the steel drum use Synolac baking vanish according to any one of claim 1-6, it is characterized in that, the weight ratio of red iron oxide, aluminium triphosphate, nano silicon, nano-glass microballon, calcium carbonate is 1.2-1.8:4-4.6:20-24:12-16:3-5.
8. the steel drum use Synolac baking vanish according to any one of claim 1-7, it is characterized in that, its raw material comprises by weight: aqueous alkide resin 25-30 part, water-based methyl-etherified aminoresin 14-18 part, Polyamide-Polyamsne-Epichlorohydrin 10-12 part, aqueous epoxy emulsion 8-11 part, vinylbenzene 3-4.5 part, vinyltriethoxysilane 1-2.6 part, N, N-dimethylethanolamine 1.2-1.6 part, monoethanolamine 2-2.5 part, phenylcarbinol 4-6 part, 2501 modified silane glue 1.5-2.3 parts, red iron oxide 1.2-1.8 part, aluminium triphosphate 4-4.6 part, nano silicon 20-24 part, nano-glass microballon 12-16 part, calcium carbonate 3-5 part, emulsifying agent 1.2-1.6 part, dispersion agent 1.4-1.8 part, defoamer 1.3-1.5 part, flow agent 1.2-1.6 part, mould inhibitor 2-2.5 part, water-based siccative 2-3 part, water 30-36 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510828232.0A CN105385317A (en) | 2015-11-24 | 2015-11-24 | Water-based alkyd resin stoving varnish for steel drum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510828232.0A CN105385317A (en) | 2015-11-24 | 2015-11-24 | Water-based alkyd resin stoving varnish for steel drum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105385317A true CN105385317A (en) | 2016-03-09 |
Family
ID=55418115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510828232.0A Pending CN105385317A (en) | 2015-11-24 | 2015-11-24 | Water-based alkyd resin stoving varnish for steel drum |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105385317A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221531A (en) * | 2016-08-31 | 2016-12-14 | 泉州阿波罗贸易有限公司 | Water-based acrylic acid top-coat and preparation method thereof and the manufacture method with its faucet sprayed |
| CN107177287A (en) * | 2017-07-10 | 2017-09-19 | 漳州鑫展旺化工有限公司 | A kind of aqueous high-performance priming paint of super acid resistance salt fog and preparation method thereof |
| CN115340786A (en) * | 2022-09-21 | 2022-11-15 | 杨嫦 | Environment-friendly water-based printing ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104072742A (en) * | 2014-06-06 | 2014-10-01 | 华南理工大学 | Epoxy-modified water-based alkyd resin and water-based alkyd amino stoving varnish and preparation method of epoxy-modified water-based alkyd resin and water-based alkyd amino stoving varnish. |
| CN104893519A (en) * | 2015-05-11 | 2015-09-09 | 广德加点化工有限公司 | Modified aqueous alkyd resin coating |
-
2015
- 2015-11-24 CN CN201510828232.0A patent/CN105385317A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104072742A (en) * | 2014-06-06 | 2014-10-01 | 华南理工大学 | Epoxy-modified water-based alkyd resin and water-based alkyd amino stoving varnish and preparation method of epoxy-modified water-based alkyd resin and water-based alkyd amino stoving varnish. |
| CN104893519A (en) * | 2015-05-11 | 2015-09-09 | 广德加点化工有限公司 | Modified aqueous alkyd resin coating |
Non-Patent Citations (2)
| Title |
|---|
| 王云芳等: "PAE与丙烯酰胺接枝共聚改性的研究", 《合成树脂及塑料》 * |
| 耿耀宗: "《现代水性涂料，工艺，配方，应用》", 30 April 2013, 中国石化出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221531A (en) * | 2016-08-31 | 2016-12-14 | 泉州阿波罗贸易有限公司 | Water-based acrylic acid top-coat and preparation method thereof and the manufacture method with its faucet sprayed |
| CN107177287A (en) * | 2017-07-10 | 2017-09-19 | 漳州鑫展旺化工有限公司 | A kind of aqueous high-performance priming paint of super acid resistance salt fog and preparation method thereof |
| CN115340786A (en) * | 2022-09-21 | 2022-11-15 | 杨嫦 | Environment-friendly water-based printing ink and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102108245B (en) | Waterborne polyester modified epoxy polyurethane anticorrosive paint and preparation method thereof | |
| CN102618159A (en) | Water-based polyurethane anticorrosive coating for containers and preparation method for coating | |
| CN106810989A (en) | A kind of aqueous environment protection anticorrosive paint and preparation method thereof | |
| CN104725951A (en) | High-hardness single-component water-based paint | |
| CN103450767A (en) | Super-weather-resistant anti-fouling real stone paint | |
| CN105385317A (en) | Water-based alkyd resin stoving varnish for steel drum | |
| CN103666201A (en) | Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof | |
| CN105400318A (en) | Water-based PVDF fluorocarbon metal stoving varnish for aluminum single plate | |
| CN103709903B (en) | High solid conduction type epoxy zinc rich primer | |
| CN102002318A (en) | Scaly zinc-based inorganic zinc silicate heavy anti-corrosion coating and preparation method thereof | |
| CN103468092A (en) | Water-based coating for surface of mechanical product | |
| CN112778860A (en) | Reflective heat-insulation sand-containing multicolor paint | |
| CN105385283A (en) | Water-based metal stoving varnish for electro-tricycle | |
| CN104725977B (en) | Double-component aqueous epoxy zinc rich primer of heavy antisepsis and preparation method thereof | |
| CN104212207A (en) | Water-based zinc-rich corrosion-resistant paint and preparation method thereof | |
| CN106634448A (en) | Waterborne epoxy flash-rust preventing paint | |
| CN102020922A (en) | Water-based single component container primer | |
| CN105949374A (en) | Preparation method of modified silicone-acrylic water-in-water emulsion for multicolor paint | |
| CN106833200B (en) | Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof | |
| CN110475825A (en) | Directly act on the coating composition of metal | |
| CN106349831A (en) | Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof | |
| CN106243851A (en) | A kind of single-component epoxy anti-corrosive primer and preparation method thereof | |
| CN105238238A (en) | Water-based alkyd paint | |
| CN106752665A (en) | A kind of epoxy fat priming paint and preparation method thereof | |
| CN104004393A (en) | Water-based inorganic zinc-rich anticorrosive paint and preparing method of high-modulus potassium silicate solution |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160309 |
|
| RJ01 | Rejection of invention patent application after publication |