CN106349831A - Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof - Google Patents
Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof Download PDFInfo
- Publication number
- CN106349831A CN106349831A CN201610738882.0A CN201610738882A CN106349831A CN 106349831 A CN106349831 A CN 106349831A CN 201610738882 A CN201610738882 A CN 201610738882A CN 106349831 A CN106349831 A CN 106349831A
- Authority
- CN
- China
- Prior art keywords
- water
- aqueouss
- component
- high hydroxyl
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and a preparation method thereof. The coating comprises a component A and a component B, wherein the component A comprises water-based-high-hydroxyl-fluorocarbon resin, water-based hydroxy acrylic resin, rutile type titanium dioxide, nano barium sulfate, hardness-increasing ceramic additives, nano silica dispersion, water-based dispersant, water-based defoaming agent 1, water-based defoaming agent 2, water-based flatting agent, water-based wetting agent, neutralizing agent, water-based ultraviolet absorber, water-based polyamide wax slurry, deionized water and film-forming additives; the component B is hydrophilic isocyanate curing agent. The preparation method includes blending the component A and the component B according to the ratio of 6:1. The water-based-high-hydroxyl-fluorocarbon anti-corrosion coating has the advantages that the coating is fast in drying, high in hardness, high in toughness, good in wear resistance and excellent in chemical resistance, the weather resistance of the coating reaches 3000h, and the coating can replace solvent type fluorocarbon coating to be applied to various steel-structure protection, building materials, buildings, vehicles, rail transit, petroleum and petrochemical, and the like.
Description
Technical field
The invention belongs to technical field of coatings is and in particular to a kind of aqueouss high hydroxyl fluorine carbon anticorrosive paint and preparation method thereof.
Background technology
The sixties in last century, the oiliness fluorine carbon that pennwalt company of the U.S. successfully develops with polyvinylidene fluoride as base material applies
Material.The eighties, Japan AGC company develops feve, makes oiliness fluorocarbon coating from high-temperature baking film forming, is improved to room temperature
It is achieved that the ideal of application at the construction field (site), this is two quantum jumps of fluorocarbon coating industry for solidification.
Because fluorocarbon coating has the advantages that super-weathering resistance and excellent stain resistance, abrasion resistance, corrosion resistance, can be wide
General apply in external coatings such as inorganic, organic material, metal materials, be the industry such as Aeronautics and Astronautics, building, chemical industry, household electrical appliances
Provide excellent coating material.
But expensive due to oiliness fluorocarbon coating, there are a large amount of solvents volatilizations during production and use, unfavorable
In environmental conservation.Oiliness fluorocarbon coating typically forms for bi-component again, and construction is more complicated, even the fluorine carbon of normal temperature cure applies
Material, also higher to construction requirement, if strictly proportioning can not be carried out in the ratio of regulation, film performance will be had a strong impact on.Base
In above-mentioned reason, need exploitation one kind badly and both there is oiliness fluorocarbon coating excellent specific property, again easy construction, price is suitable, meet
The aqueous fluorocarbon coating of environmental requirement.
Content of the invention
The technical problem solving: the purpose of the present invention is to overcome the deficiencies in the prior art and provide a kind of aqueouss high hydroxyl fluorine carbon
Anticorrosive paint and preparation method thereof, gained coating has the excellent spy of drying speed, hardness height, toughness height, excellent wear resistance, chemical resistance
Point, weatherability can reach 3000h.
Technical scheme: a kind of aqueouss high hydroxyl fluorine carbon anticorrosive paint, including a component and b component, a component is included with weight portion
The following raw material of meter: aqueouss high hydroxyl fluorocarbon resin 40-50 part, water based acrylic resin 5-10 part, Rutile type titanium dioxide
20-25 part, nano barium sulfate 5-10 part, Hardening ceramic additive 0.5-3 part, Nano silicon dioxide dispersion 0.1-0.3 part, water
Property dispersant 0.2-0.4 part, aqueous defoamer 1 0.1-0.2 part, aqueous defoamer 2 0.1-0.2 part, aqueous levelling agent 0.1-
0.2 part, aqueous wetting agent 0.1-0.2 part, nertralizer 0.2-0.5 part, aquosity ultraviolet light absorbent 0.4-0.8 part, aqueouss polyamides
Amine wax liquor 2-4 part, deionized water 11.2-12.7 part, coalescents 1-2 part；B component is hydrophilic isocyanide ester firming agent.
Further, a component also includes Mannitol 0.01-0.05 part and/or terpineol 0.01-0.03 part.
The preparation method of above-mentioned aqueouss high hydroxyl fluorine carbon anticorrosive paint, be by a component and b component by 6:1 proportioning paint, its
Middle a component is prepared by following steps:
Step 1, deionized water, aqueous dispersion, aqueouss foam inhibitor, coalescents mixing, stirring obtain mixture a；
Step 2, adds Rutile type titanium dioxide, nano barium sulfate, aqueous polyamide wax liquor, nanometer two in mixture a
Silica dispersion, Hardening ceramic additive, stirring, it is ground to fineness and reaches less than 20 μm, obtain mixture b；
Step 3, adds aqueouss high hydroxyl fluorocarbon resin, water based acrylic resin, stirring in mixture b, is mixed
Compound c；
Aqueous defoamer, aqueous wetting agent, aqueous levelling agent, aquosity ultraviolet light are absorbed by step 4 under agitation
Agent, antimildew disinfectant add in mixture c, dispersion, add nertralizer, obtain final product.
Further, in step 1, stirring condition is 300-400rpm, 5-10min.
Further, in step 2, stirring condition is 400-600rpm, 5-10min.
Further, in step 3, stirring condition is 400-600rpm, 15-20min.
Further, in step 4, mixing speed is 400-600rpm, and dispersion condition is 400-600rpm, 15-20min.
Further, also need in step 2 add Mannitol 0.01-0.05 part.
Further, also need in step 3 add terpineol 0.01-0.03 part.
Beneficial effect: the aqueouss high hydroxyl fluorine carbon anticorrosive paint of the present invention have drying speed, hardness height, toughness height, excellent wear resistance,
The excellent feature of chemical resistance, weatherability can reach 3000h, and alternative solvent-borne type fluorocarbon coating is applied to all kinds of steel constructions to be prevented
Shield, building materials, building, vehicle, track traffic, petroleum and petrochemical industry etc..
Specific embodiment
The raw material that following examples adopt is as follows:
Aqueouss high hydroxyl fluorocarbon resin (srf-e630 Hua Tongrui speeds)
Water based acrylic resin (a2695 Cohan wound)
Rutile type titanium dioxide (706 Du Pont)
Nano barium sulfate (bs80 Beijing gold zebra)
Aqueous polyamide wax liquor (it is prosperous that Hua is found in aqh-800 Shenzhen)
Nano silicon dioxide dispersion (wv33 sea ease chemistry)
Hardening pottery flour additive agent (mt801 Chongqing wheat figure science and technology)
Dispersant (zwd1 U.S. Troy)
Defoamer 1 (d209w U.S. Troy)
Defoamer 2 (nxz section is peaceful)
Levelling agent (67 this chemistry of sea inscription)
Wetting agent (960 sea ease chemistry)
Aquosity ultraviolet light absorbent (1406 Beijing addition)
Coalescents (dpm LG-DOW)
Nertralizer (this chemistry of amp-95 sea inscription)
Hydrophilic isocyanate resin (n3900 Bayer)
In each embodiment, a component proportion is as shown in the table:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Aqueouss high hydroxyl fluorocarbon resin | 40 | 45 | 50 | 50 | 50 | 50 |
| Water based acrylic resin | 10 | 8 | 5 | 5 | 5 | 5 |
| Rutile type titanium dioxide | 25 | 22 | 20 | 20 | 20 | 20 |
| Nano barium sulfate | 8 | 6 | 5 | 5 | 5 | 5 |
| Aqueous polyamide wax liquor | 4 | 2 | 3 | 3 | 3 | 3 |
| Nano silicon dioxide dispersion | 0.2 | 0.3 | 0.1 | 0.1 | 0.1 | 0.1 |
| Aqueous dispersion | 0.4 | 0.3 | 0.2 | 0.2 | 0.2 | 0.2 |
| Aqueous wetting agent | 0.1 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Aqueous defoamer 1 | 0.1 | 0.2 | 0.1 | 0.1 | 0.1 | 0.1 |
| Aqueous defoamer 2 | 0.2 | 0.1 | 0.2 | 0.2 | 0.2 | 0.2 |
| Aqueous levelling agent | 0.1 | 0.2 | 0.1 | 0.1 | 0.1 | 0.1 |
| Aquosity ultraviolet light absorbent | 1 | 0.8 | 0.5 | 0.5 | 0.5 | 0.5 |
| dpm | 1 | 2 | 2 | 2 | 2 | 2 |
| Deionized water | 9.4 | 12.9 | 10.6 | 10.6 | 10.6 | 10.6 |
| Hardening pottery flour additive agent | 0.5 | 1 | 3 | 3 | 3 | 3 |
| Mannitol | 0 | 0 | 0 | 0.04 | 0 | 0.04 |
| Terpineol | 0 | 0 | 0 | 0 | 0.01 | 0.01 |
Preparation method is:
1. deionized water, aqueous dispersion, aqueouss foam inhibitor, coalescents are added together and stirred using 300-400 rev/min
Mix 5-10 minute；
2. add Rutile type titanium dioxide, nano barium sulfate, aqueous polyamide wax liquor, Nano silicon dioxide dispersion, increasing
Hard ceramic additive, using 400-600 rev/min of stirring 5-10 minute, is ground to fineness using sand mill and reaches less than 20 microns；
3. add aqueouss high hydroxyl fluorocarbon resin, water based acrylic resin to divide using 400-600 rev/min of stirring 15-20
Clock；
4. side adopts 400-600 rev/min to add aqueous defoamer, aqueous wetting agent, aqueous levelling agent, aqueouss while stirring
UV absorbers, using 400-600 rev/min of dispersion 15-20 minute.
5. adopt 400-600 rev/min to add nertralizer while stirring, gained coating ph value is adjusted between 8-9.
Dry plate is realized: a component: b component=6:1 proportioning, carries out the adjustment of spray viscosity using deionized-distilled water, will spray
Apply viscosity and be adjusted to 20-25s (t-4 cup), spray layer 2-3, dry plate is placed in 25 DEG C of calorstats from detection in dry 48 hours routinely
Can, ripening tested artificial ageing resistance performance, chemical resistance after 7 days, and the dry plate film thickness of type inspection controls at 50-60 μm.
Execution standard: be dried according to gb/t1728, adhesive force according to gb/t1720, impact according to gb/t1732, toughness according to
According to gb/t1731, gloss according to gb/t1743, hardness according to gb/t6739, resistance to water foundation gb/t1733, abrasion resistance foundation
Gb/t9266, chemical resistance are according to gb/t23987, resistance to neutral salt spray according to gb/t1771, artificial ageing resistance foundation gb/
T14522, cold-hot cyclicity are according to gb/t9755.All properties with compare 1 (cn103965669a) and comparison 2 (cn
104341880 a) are contrasted, and result is as follows:
Be can be seen that by above test result and add Hardening pottery flour additive agent in formula system, with carrying of amount
Rise, the hardness of paint film, chemical resistance are all had a distinct increment, especially shows abrasion resistance aspect, Hardening pottery in embodiment 3
Flour additive agent addition be 3% when, directly by abrasion resistance by 15000 times show-through rise to 25000 times not show-through.Embodiment 4
The addition of middle Mannitol, can improve the resistance to impact of paint film；Add terpineol in embodiment 5, paint film can be improved further
Acidproof and alkali resistance；Add while Mannitol and terpineol moreover it is possible to strengthen the cold-hot cyclicity of paint film.
Claims (9)
1. a kind of aqueouss high hydroxyl fluorine carbon anticorrosive paint, including a component and b component it is characterised in that: a component is included with weight portion
The following raw material of meter: aqueouss high hydroxyl fluorocarbon resin 40-50 part, water based acrylic resin 5-10 part, Rutile type titanium dioxide
20-25 part, nano barium sulfate 5-10 part, Hardening ceramic additive 0.5-3 part, Nano silicon dioxide dispersion 0.1-0.3 part, water
Property dispersant 0.2-0.4 part, aqueous defoamer 1 0.1-0.2 part, aqueous defoamer 2 0.1-0.2 part, aqueous levelling agent 0.1-
0.2 part, aqueous wetting agent 0.1-0.2 part, nertralizer 0.2-0.5 part, aquosity ultraviolet light absorbent 0.4-0.8 part, aqueouss polyamides
Amine wax liquor 2-4 part, deionized water 11.2-12.7 part, coalescents 1-2 part；B component is hydrophilic isocyanide ester firming agent.
2. aqueouss according to claim 1 high hydroxyl fluorine carbon anticorrosive paint it is characterised in that: a component also includes Mannitol
0.01-0.05 part and/or terpineol 0.01-0.03 part.
3. the high hydroxyl of the aqueouss described in claim 1 fluorine carbon anticorrosive paint preparation method it is characterised in that: be by a component and b group
Divide the proportioning paint pressing 6:1, wherein a component is prepared by following steps:
Step 1, deionized water, aqueous dispersion, aqueouss foam inhibitor, coalescents mixing, stirring obtain mixture a；
Step 2, adds Rutile type titanium dioxide, nano barium sulfate, aqueous polyamide wax liquor, nanometer titanium dioxide in mixture a
Silicon dispersion, Hardening ceramic additive, stirring, it is ground to fineness and reaches less than 20 μm, obtain mixture b；
Step 3, adds aqueouss high hydroxyl fluorocarbon resin, water based acrylic resin, stirring in mixture b, obtains mixture
c；
Step 4, under agitation by aqueous defoamer, aqueous wetting agent, aqueous levelling agent, aquosity ultraviolet light absorbent, anti-
Mould antibacterial adds in mixture c, dispersion, adds nertralizer, obtains final product.
4. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: stir in step 1
The condition of mixing is 300-400rpm, 5-10min.
5. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: stir in step 2
The condition of mixing is 400-600rpm, 5-10min.
6. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: stir in step 3
The condition of mixing is 400-600rpm, 15-20min.
7. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: stir in step 4
Mixing speed is 400-600rpm, and dispersion condition is 400-600rpm, 15-20min.
8. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: in step 2 also
Need to add Mannitol 0.01-0.05 part.
9. aqueouss according to claim 3 high hydroxyl fluorine carbon anticorrosive paint preparation method it is characterised in that: in step 3 also
Need to add terpineol 0.01-0.03 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610738882.0A CN106349831A (en) | 2016-08-26 | 2016-08-26 | Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610738882.0A CN106349831A (en) | 2016-08-26 | 2016-08-26 | Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106349831A true CN106349831A (en) | 2017-01-25 |
Family
ID=57855617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610738882.0A Pending CN106349831A (en) | 2016-08-26 | 2016-08-26 | Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106349831A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285699A (en) * | 2018-01-30 | 2018-07-17 | 华南理工大学 | A kind of wind electricity blade water-thinned nanometer paint and the preparation method and application thereof |
| CN109913119A (en) * | 2019-04-01 | 2019-06-21 | 中建七局第二建筑有限公司 | A kind of building scaffold modified amide wax liquor antirusting paint and preparation method thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
| CN116496686A (en) * | 2023-05-09 | 2023-07-28 | 广东电网有限责任公司 | Integrated paint for surface treatment of power grid equipment and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792639A (en) * | 2010-04-02 | 2010-08-04 | 德莱特恩环保涂料(北京)有限公司 | Wear-resisting scratch-resisting weather-proof polyurethane coating and preparation method thereof |
| CN102604493A (en) * | 2012-03-19 | 2012-07-25 | 东莞大宝化工制品有限公司 | Dual-solution type fluorocarbon coating |
| CN102675998A (en) * | 2012-03-20 | 2012-09-19 | 河北晨阳工贸集团有限公司 | Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat |
| CN102850871A (en) * | 2011-06-29 | 2013-01-02 | 比亚迪股份有限公司 | Coating material and preparation method thereof |
| CN105820738A (en) * | 2016-05-13 | 2016-08-03 | 厦门富思特新材料科技有限公司 | High-hardness two-component waterborne polyurethane floor paint and preparing method thereof |
-
2016
- 2016-08-26 CN CN201610738882.0A patent/CN106349831A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792639A (en) * | 2010-04-02 | 2010-08-04 | 德莱特恩环保涂料(北京)有限公司 | Wear-resisting scratch-resisting weather-proof polyurethane coating and preparation method thereof |
| CN102850871A (en) * | 2011-06-29 | 2013-01-02 | 比亚迪股份有限公司 | Coating material and preparation method thereof |
| CN102604493A (en) * | 2012-03-19 | 2012-07-25 | 东莞大宝化工制品有限公司 | Dual-solution type fluorocarbon coating |
| CN102675998A (en) * | 2012-03-20 | 2012-09-19 | 河北晨阳工贸集团有限公司 | Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat |
| CN105820738A (en) * | 2016-05-13 | 2016-08-03 | 厦门富思特新材料科技有限公司 | High-hardness two-component waterborne polyurethane floor paint and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄可龙: "《精细化学品技术手册》", 30 June 1994 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285699A (en) * | 2018-01-30 | 2018-07-17 | 华南理工大学 | A kind of wind electricity blade water-thinned nanometer paint and the preparation method and application thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
| CN109913119A (en) * | 2019-04-01 | 2019-06-21 | 中建七局第二建筑有限公司 | A kind of building scaffold modified amide wax liquor antirusting paint and preparation method thereof |
| CN116496686A (en) * | 2023-05-09 | 2023-07-28 | 广东电网有限责任公司 | Integrated paint for surface treatment of power grid equipment and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102108245B (en) | Waterborne polyester modified epoxy polyurethane anticorrosive paint and preparation method thereof | |
| CN102134430B (en) | Water-based anticorrosion primer and preparation method thereof | |
| CN102134427B (en) | Water-based acrylic finish paint and preparation method thereof | |
| CN106047075A (en) | Preparation method of water-based priming paint, intermediate paint, finishing paint and varnish applied to 25 type passenger car | |
| CN106349831A (en) | Water-based-high-hydroxyl-fluorocarbon anti-corrosion coating and preparation method thereof | |
| CN102731052A (en) | Aqueous organic-inorganic composite coating and preparation method thereof | |
| CN108165151A (en) | A kind of watersoluble fluorine-carbon modified acrylic polyurethane finish paint and preparation method thereof | |
| CN108129966B (en) | Chlorinated polyether emulsion water-based anticorrosive paint | |
| CN107964317A (en) | Water soluble acrylic acid amino-stoving varnish and preparation method thereof | |
| CN104804636B (en) | The automobile-used aqueous finish paint of self-drying type, the automobile-used aqueous primer surfacer of self-drying type and preparation method and application method | |
| CN108329739B (en) | A kind of super-hydrophobic composite anti-corrosive coating of zinc-rich and preparation method thereof | |
| CN111073475A (en) | Water-based high-temperature-resistant polyester amino baking coating, preparation method and use method | |
| CN108003748A (en) | A kind of engineering machinery epoxy primer and preparation method thereof | |
| CN104530944A (en) | Preparation method of ultrahigh-solid-content super-fast-drying anticorrosion primer | |
| CN108250957B (en) | Graphene modified water-in-film type anticorrosive resin and preparation method thereof | |
| CN107474700A (en) | A kind of environment-friendly type aqueous creeper tread dip-coating paint and preparation method thereof | |
| CN103468092A (en) | Water-based coating for surface of mechanical product | |
| CN107652729A (en) | A kind of municipal environment-friendly type aqueous protective paint of iron guardrail and preparation method thereof | |
| CN107216802B (en) | Aqueous automobile accessory anticorrosive paint and preparation method thereof | |
| CN108192437B (en) | Water-based high-temperature metallic paint capable of being used for wet-on-wet floating-free system and construction process thereof | |
| CN107384168A (en) | Container high abrasion aqueous finish paint and preparation method thereof | |
| CN1986653A (en) | Outer wall putty | |
| CN116042053A (en) | Water-based epoxy primer, water-based polyurethane finish and water-based anticorrosive paint | |
| CN106280954A (en) | A kind of aqueous polyurethane coating of high rigidity and preparation method thereof | |
| CN109836967B (en) | Water-based bi-component epoxy anti-corrosion primer for water-based paint and solvent-based paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170125 |