CN104479519A - Preparation method of 1,4-butanediol aliphatic dicarboxylic ester coating - Google Patents
Preparation method of 1,4-butanediol aliphatic dicarboxylic ester coating Download PDFInfo
- Publication number
- CN104479519A CN104479519A CN201410741602.2A CN201410741602A CN104479519A CN 104479519 A CN104479519 A CN 104479519A CN 201410741602 A CN201410741602 A CN 201410741602A CN 104479519 A CN104479519 A CN 104479519A
- Authority
- CN
- China
- Prior art keywords
- parts
- aliphatic dicarboxylic
- stirring
- coating
- acetone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 15
- 238000000576 coating method Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 150000002148 esters Chemical class 0.000 title claims abstract description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N 1,4-butanediol Substances OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000003756 stirring Methods 0.000 claims abstract description 18
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940107816 ammonium iodide Drugs 0.000 claims abstract description 13
- 239000010425 asbestos Substances 0.000 claims abstract description 13
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- -1 polysiloxane Polymers 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract 3
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 10
- 238000006253 efflorescence Methods 0.000 description 3
- 206010037844 rash Diseases 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The invention relates to a 1,4-butanediol aliphatic dicarboxylic ester coating. The coating is prepared from the following raw materials in parts by weight: 55-65 parts of 1,4-butanediol, 30-35 parts of aliphatic dicarboxylic acid, 3-5 parts of dicyandiamide, 5-10 parts of polyether modified polysiloxane, 12-14 parts of acetone, 5-10 parts of ammonium iodide, 10-15 parts of asbestos powder and 45-50 parts of deionized water. A preparation method comprises the following steps: adding 1,4-butanediol and aliphatic dicarboxylic acid to a reaction kettle, and heating the materials to react at 150-180 DEG C for 24-36 hours; then adding polyether modified polysiloxane and acetone, stirring the materials uniformly, and reacting at 70-80 DEG C for 5-8 hours; finally adding ammonium iodide, asbestos powder and deionized water while stirring, and stirring the materials for 3-7 hours, thus obtaining the coating.
Description
Technical field
The present invention relates to a kind of coating, is a kind of Isosorbide-5-Nitrae butyleneglycol aliphatics di-carboxylic acid ester paint specifically.
Background technology
Polyurethane paint and polyurethane(s) paint.Its paint film is tough, and gloss is plentiful, strong adhesion, water proof and wearable, erosion resistance.Be widely used in high-class woodenware furniture, also can be used for metallic surface.Its shortcoming mainly contains wet and bubbles, and the problems such as film efflorescence, the same with Polyester Paint, it also exists the problem of flavescence equally.
Summary of the invention
For above-mentioned deficiency of the prior art, the invention provides a kind of moisture resistance, anti-efflorescence, nondiscoloration, the Isosorbide-5-Nitrae butyleneglycol aliphatics di-carboxylic acid ester paint faded and preparation method.
The technical solution used in the present invention is: a kind of 1,4 butyleneglycol aliphatics di-carboxylic acid ester paints, by following raw material mass mixture ratio: 1,4 butyleneglycol 55-65 parts, aliphatic dicarboxylic acid 30-35 part, Dyhard RU 100 3-5 part, polyethers upgrading polysiloxane 5-10 part, acetone 12-14 part, ammonium iodide 5-10 part, asbestos powder 10-15 part, deionized water 45-50 part.
A kind of Isosorbide-5-Nitrae butyleneglycol aliphatics dicarboxylic esters preparation method for coating, comprises the following steps:
Isosorbide-5-Nitrae butyleneglycol, aliphatic dicarboxylic acid are added in reactor and heats 150-180 DEG C of reaction 24-36 hour;
Add polyethers upgrading polysiloxane again, acetone stirs, at 70-80 DEG C of reaction 5-8 hour;
Finally in stirring, add ammonium iodide, asbestos powder, deionized water and stirring 3-7 hour, obtain coating.
Polyester coating of the present invention, on the basis of traditional coating, adopts polyethers upgrading polysiloxane, acetone, ammonium iodide and asbestos powder effectively to improve its moisture resistance, efflorescence and performance of fading, applied widely.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment one
A kind of 1,4 butyleneglycol aliphatics di-carboxylic acid ester paints, by following raw material mass mixture ratio: Isosorbide-5-Nitrae butyleneglycol 65 parts, aliphatic dicarboxylic acid 35 parts, Dyhard RU 100 5 parts, polyethers upgrading polysiloxane 10 parts, 14 parts, acetone, ammonium iodide 10 parts, asbestos powder 15 parts, deionized water 50 parts.
Preparation method comprises the following steps:
Isosorbide-5-Nitrae butyleneglycol, aliphatic dicarboxylic acid are added heating 180 DEG C in reactor and react 36 hours;
Add polyethers upgrading polysiloxane again, acetone stirs, 80 DEG C of reactions 8 hours;
Last in stirring, add ammonium iodide, asbestos powder, deionized water and stirring 7 hours, obtain coating.
Embodiment two
A kind of 1,4 butyleneglycol aliphatics di-carboxylic acid ester paints, by following raw material mass mixture ratio: Isosorbide-5-Nitrae butyleneglycol 55 parts, aliphatic dicarboxylic acid 30 parts, Dyhard RU 100 3 parts, polyethers upgrading polysiloxane 5 parts, 12 parts, acetone, ammonium iodide 5 parts, asbestos powder 10 parts, deionized water 45 parts.
Preparation method comprises the following steps:
Isosorbide-5-Nitrae butyleneglycol, aliphatic dicarboxylic acid are added heating 150 DEG C in reactor and react 24 hours;
Add polyethers upgrading polysiloxane again, acetone stirs, 70 DEG C of reactions 5 hours;
Last in stirring, add ammonium iodide, asbestos powder, deionized water and stirring 3 hours, obtain coating.
Embodiment three
A kind of 1,4 butyleneglycol aliphatics di-carboxylic acid ester paints, by following raw material mass mixture ratio: Isosorbide-5-Nitrae butyleneglycol 60 parts, aliphatic dicarboxylic acid 33 parts, Dyhard RU 100 4 parts, polyethers upgrading polysiloxane 6 parts, 13 parts, acetone, ammonium iodide 6 parts, asbestos powder 12 parts, deionized water 48 parts.
Preparation method comprises the following steps:
Isosorbide-5-Nitrae butyleneglycol, aliphatic dicarboxylic acid are added heating 160 DEG C in reactor and react 29 hours;
Add polyethers upgrading polysiloxane again, acetone stirs, 73 DEG C of reactions 6 hours;
Last in stirring, add ammonium iodide, asbestos powder, deionized water and stirring 5 hours, obtain coating.
Claims (1)
1. a butyleneglycol aliphatics dicarboxylic esters preparation method for coating; comprise the following steps:; by following raw material mass mixture ratio: 1; 4 butyleneglycol 55-65 parts, aliphatic dicarboxylic acid 30-35 part, Dyhard RU 100 3-5 part, polyethers upgrading polysiloxane 5-10 part, acetone 12-14 part, ammonium iodide 5-10 part, asbestos powder 10-15 part, deionized water 45-50 part;
Isosorbide-5-Nitrae butyleneglycol, aliphatic dicarboxylic acid are added in reactor and heats 150-180 DEG C of reaction 24-36 hour;
Add polyethers upgrading polysiloxane again, acetone stirs, at 70-80 DEG C of reaction 5-8 hour;
Finally in stirring, add ammonium iodide, asbestos powder, deionized water and stirring 3-7 hour, obtain coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741602.2A CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410741602.2A CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104479519A true CN104479519A (en) | 2015-04-01 |
| CN104479519B CN104479519B (en) | 2016-12-28 |
Family
ID=52754132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410741602.2A Active CN104479519B (en) | 2014-12-09 | 2014-12-09 | A kind of BDO aliphatic dicarboxylic acid ester paint preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104479519B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5420227A (en) * | 1992-12-14 | 1995-05-30 | Hoechst Ag | Modified acid polyesters and their use as curing agents in heat-curable binders |
| CN1333303A (en) * | 2000-07-11 | 2002-01-30 | 索鲁蒂奥地利有限公司 | Low molecular weight aliphatic polyester polylol, its preparation and use in high performance paint composition |
| CN1483049A (en) * | 2000-09-05 | 2004-03-17 | ���ձ���ī��ѧ��ҵ��ʽ���� | Unsaturated polyester resin composition |
| CN101910245A (en) * | 2007-12-27 | 2010-12-08 | 三菱化学株式会社 | Method for producing aliphatic polyester |
| JP2014133824A (en) * | 2013-01-10 | 2014-07-24 | Mitsubishi Chemicals Corp | Method for producing aliphatic polyester |
-
2014
- 2014-12-09 CN CN201410741602.2A patent/CN104479519B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5420227A (en) * | 1992-12-14 | 1995-05-30 | Hoechst Ag | Modified acid polyesters and their use as curing agents in heat-curable binders |
| CN1333303A (en) * | 2000-07-11 | 2002-01-30 | 索鲁蒂奥地利有限公司 | Low molecular weight aliphatic polyester polylol, its preparation and use in high performance paint composition |
| CN1483049A (en) * | 2000-09-05 | 2004-03-17 | ���ձ���ī��ѧ��ҵ��ʽ���� | Unsaturated polyester resin composition |
| CN101910245A (en) * | 2007-12-27 | 2010-12-08 | 三菱化学株式会社 | Method for producing aliphatic polyester |
| JP2014133824A (en) * | 2013-01-10 | 2014-07-24 | Mitsubishi Chemicals Corp | Method for producing aliphatic polyester |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104479519B (en) | 2016-12-28 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160825 Address after: 225400 Jiangsu city of Taizhou province Taixing City Economic Development Zone Industrial Park East Road No. 18 Dai Wang Applicant after: Zhang Heqing Address before: 225400 Binjiang, Jiangsu, Taixing Town, Tongjiang Road, Applicant before: TAIXING HEQING MACHINERY FITTINGS FACTORY |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20161114 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Yukui Address before: 225400 Jiangsu city of Taizhou province Taixing City Economic Development Zone Industrial Park East Road No. 18 Dai Wang Applicant before: Zhang Heqing |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee after: Gu Yukui Address before: 266000 No. nine water East Road, Licang District, Qingdao, Shandong, 320 Patentee before: Gu Yukui |
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| CP02 | Change in the address of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181106 Address after: 311200 Linjiang Industrial Park, Xiaoshan District, Hangzhou, Zhejiang (farm two) Patentee after: Hangzhou Sanlong New Material Co., Ltd. Address before: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee before: Gu Yukui |
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| TR01 | Transfer of patent right |