CN104479493B - A kind of epoxy antibiotic paint - Google Patents
A kind of epoxy antibiotic paint Download PDFInfo
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- CN104479493B CN104479493B CN201410699657.1A CN201410699657A CN104479493B CN 104479493 B CN104479493 B CN 104479493B CN 201410699657 A CN201410699657 A CN 201410699657A CN 104479493 B CN104479493 B CN 104479493B
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- antibiotic paint
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- 230000003115 biocidal effect Effects 0.000 title claims abstract description 37
- 239000004593 Epoxy Substances 0.000 title claims abstract description 35
- 239000003973 paint Substances 0.000 title claims abstract description 30
- 150000001412 amines Chemical class 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000013530 defoamer Substances 0.000 claims abstract description 24
- 239000003822 epoxy resin Substances 0.000 claims abstract description 24
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 24
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims abstract description 21
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920000570 polyether Polymers 0.000 claims abstract description 19
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 17
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- 150000004982 aromatic amines Chemical class 0.000 claims abstract description 4
- 150000002118 epoxides Chemical class 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 229920001451 polypropylene glycol Polymers 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000004843 novolac epoxy resin Substances 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 18
- 239000011248 coating agent Substances 0.000 abstract description 13
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000002270 dispersing agent Substances 0.000 abstract description 11
- 230000000845 anti-microbial effect Effects 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004568 cement Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 description 20
- 230000000996 additive effect Effects 0.000 description 20
- 241000894006 Bacteria Species 0.000 description 8
- 238000002309 gasification Methods 0.000 description 7
- 239000003899 bactericide agent Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- 230000002421 anti-septic effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- 230000003211 malignant effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 206010011409 Cross infection Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 206010029803 Nosocomial infection Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of epoxy antibiotic paint, including epoxy resin is the component B that the component A and organic amine of main body are main body, and by weight, component A is：90 ~ 100 parts of epoxy resin, 0 ~ 10 part of epoxide diluent, 0 ~ 15 part of PPG, 0 ~ 2 part of dispersant, 0 ~ 1 part of levelling agent, 0 ~ 2 part of defoamer, 0 ~ 50 part of filler, 0.1 ~ 20 part of molybdenum oxide, 0 ~ 50 part of solvent；Component B is：5 ~ 100 parts of fatty amine, 0 ~ 50 part of aromatic amine, 0 ~ 50 part of amine terminated polyether polyalcohol, 0 ~ 2 part of defoamer, 0 ~ 50 part of filler, 0 ~ 90 part of solvent.Carry out application after component A, B being mixed in proportion when using.The coating can be widely used for the application of the base materials such as metal, plastics, cement, ceramics, and coating has outstanding anti-microbial property and antibacterial durability, and with good adhesive force, hardness and chemical resistance, it is sturdy and durable, it is with strong applicability.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of epoxy antibiotic paint.
Background technology
Bacterium exists everywhere in we live, and hair is this may result in when human infection certain amount pathogenic bacteria
Disease.The approach of the incoming human body of malignant bacteria is a lot, in addition to eat unclean diet beverages, air borne, be greatly by
Cause in contact infection.Article surface institute with bacterium infection and is important malignant bacteria by article surface cross-infection
Circulation way, or even cause disease popularity.Antibiotic property coating can form one layer of antibiotic layer in article surface, can effectively kill
Go out, contain malignant bacteria growth with propagate.
Antibiotic property coating is divided into two parts：A part is bactericide, plays bactericidal action；Another part is carrier, antiseptic
Coating is formed by carrier to be constructed.This two parts is indispensable, depends on each other for existence, and is an entirety.Bactericide determines antibacterial
The bactericidal effect quality of coating, and carrier is more important, bactericide not only needs effectively to be formed in article surface by carrier
Antibiotic layer, more importantly the matching degree of bactericide and carrier determine that can bactericide give full play to its biocidal efficacies.
The antiseptic commonly used in current coating has organic antibacterial agent, titanium dioxide and Nano Silver etc..But, organic bactericide
General also toxic to organisms such as people, titanium dioxide has certain decomposition to carrier, and nano phase ag_2 o is relative wide spectrum
Bactericidal effect, does not poison to human body, but, silver belongs to noble metal, and the cost for preparing nano phase ag_2 o is higher.In fact, receiving
Rice grain has just just started with the research of the effect of human body, also without qualitative, quantitative result of study.Moreover, nanometer silver antimicrobial
The applicability of agent will fail nor very high in salinity environment higher.In recent years, it is subject to as antiseptic using molybdenum oxide
Attract attention.The sterilization mechanism of molybdenum oxide is entirely different with other antiseptics, molybdenum oxide in itself without very strong anti-microbial property, but
Periphery microenvironment can be made in the presence of molybdenum oxide in acidity, so as to play a part of to suppress, kill bacterium.
Carrier in coating is generally polymer, there is alkyd, epoxy, amino, acrylic resin, polyurethane etc..
Can also there are many forms, such as solvent-borne type, water-soluble, emulsion-type, no-solvent type, powder-type as coating.Wherein：Asphalt mixtures modified by epoxy resin
Fat is widely used field and premium properties, and such as adhesion is strong, hardness is high, intensity is high, resistance to acids and bases is strong, resistant to chemical etching strong
The advantages of.
Give full play of how the antibiotic property of antibiotic paint, while also to have good workability and well painting
Layer performance, is the technical problem to be solved in the invention.
The content of the invention
The technical problem to be solved in the present invention is：Overcome the defect of prior art, there is provided a kind of with excellent sterilization
Property and the preferable antibacterial epoxy coating of lasting antibiotic property, adhesive force.
Technical scheme：
A kind of epoxy antibiotic paint, it is characterized in that：Including epoxy resin for the component A and organic amine of main body are the group of main body
Part B, by weight, component A is：90 ~ 100 parts of epoxy resin, 0 ~ 10 part of epoxide diluent, 0 ~ 15 part of PPG, point
0 ~ 2 part of powder, 0 ~ 1 part of levelling agent, 0 ~ 2 part of defoamer, 0 ~ 50 part of filler, 0.1 ~ 20 part of molybdenum oxide, 0 ~ 50 part of solvent；Component B
For：5 ~ 100 parts of fatty amine, 0 ~ 50 part of aromatic amine, 0 ~ 50 part of amine terminated polyether polyalcohol, 0 ~ 2 part of defoamer, 0 ~ 50 part of filler,
0 ~ 90 part of solvent.
Described epoxy antibiotic paint, optimization formula is, in component A：90 ~ 100 parts of epoxy resin, epoxide diluent 1 ~ 5
Part, 5 ~ 10 parts of PPG, 0.05 ~ 1 part of dispersant, 0.02 ~ 0.5 part of levelling agent, 1 ~ 2 part of defoamer, 0 ~ 10 part of filler, oxygen
Change 3 ~ 10 parts of molybdenum, 0 ~ 30 part of solvent；Component B is：80 ~ 100 parts of fatty amine, 5 ~ 10 parts of aromatic amine, amine terminated polyether polyalcohol 5 ~
10 parts, 0 ~ 2 part of defoamer, 0 ~ 50 part of filler, 0 ~ 20 part of solvent.
Described epoxy antibiotic paint, in optimization formula, component A is：100 parts of epoxy resin CYD-128, diluent
5 parts of JX-016, holds 1,400 10 parts of epoxidized polyether Banco, 5 parts of molybdenum oxide, 104 0.3 parts of dispersant B YK-P, defoamer
399 0.06 parts of 530 0.1 parts of BYK-A, levelling agent BYK；Component B：110 parts of fatty amine curing agent, 0.03 part of defoamer.
Described epoxy antibiotic paint, the component A is：862 100 parts of epoxy resin IKOTE, diluent JX-016
5 parts, hold 1,400 10 parts of epoxidized polyether Banco, 2 parts of molybdenum oxide, 2 parts of white carbon, 0.6 part of dispersant B YK-P 104S, froth breaking
530 0.1 parts of agent BYK-A, 0.06 part of levelling agent；Component B is：Fatty amine curing agent AncamineR2726 100 parts, polyethers
8 parts of amine M-1000,0.5 part of diethylenetriamine, 10 parts of toluene, 530 0.03 parts of defoamer BYK-A；Component A is existed when using
Fineness is ground on sand mill less than 50 microns, component B is dispersed into uniform liquid on dispersion machine, takes component A, B by 1-2:1
Mass ratio it is well mixed after spray.
Described epoxy antibiotic paint, preferably component A is：Epoxy resin is produced for sinopec Ba Ling petrochemical industry shares branch company
60 parts of CYD-128 types product and Dutch Shell Co. Ltd's production 40 parts of 862 type products of EPIKOTE, diluent is that Changshu is good
5 parts of the JX-016 types product of hair Chemical Co., Ltd. production, end epoxidized polyether is Co., Ltd's production in nation and chemistry
10 parts of 1400 type products of Banco, 5 parts of molybdenum oxide, dispersant be BYK Additive ＆ Instruments DISPER
0.3 part of BYK-118 types product, defoamer is 0.1 part of 530 type products of BYK Additive ＆ Instruments BYK-A,
Levelling agent is 0.06 part of 399 type products of BYK Additive ＆ Instruments BYK.Component B is：Fatty amine curing agent
It is the Ancamine of US Air gasification chemical product Co., LtdR2726 100 parts of type products and AncamineR2519 type products 10
Part, defoamer is 0.03 part of 530 type products of BYK Additive ＆ Instruments BYK-A.
The epoxy resin includes bisphenol A type epoxy resin, bisphenol F epoxy resin, bisphenol-s epoxy resin, epoxy novolac
One or several in resin；PPG is end ring oxygen PPG or amine terminated polyether polyalcohol.
Described epoxy terminated PPG is one end or multiterminal are the PPG of epoxy radicals, its average molecular matter
Measure is 300 ~ 20000；
Described amine terminated polyether polyalcohol is one end or multiterminal are the PPGs of amino, and relative molecular mass is
300~20000。
Described filler is the one kind in silica, titanium dioxide, calcium carbonate, talcum powder；Solvent is toluene or acetone；Institute
Fatty amine is stated for aliphatic hydrocarbon monoamine or polyamines, or is alicyclic monoamine or polyamines；The fineness of molybdenum oxide is less than 70 microns；The ring
The fineness of oxygen antibiotic paint is 0.02 micron ~ 70 microns.
Positive beneficial effect of the invention：
The coating of epoxy antibiotic paint of the invention has extremely strong adhesive force, weatherability, water resistance and durability, and
With excellent bactericidal properties and lasting antibiotic property, its anti-microbial property, Durable antibacterial are carried out by GB/T 21866-2008 standards
Test, reaches more than 99.95%.
Compared with similar antimicrobial product, great advantage is that security and persistence are good to epoxy antibiotic paint of the invention.By
Antiseptic molybdenum oxide in coating not directly with the pathogenic microorganisms of coating surface（Bacterium, virus, fungi etc.）Contact, but
It is the hydrogen ion of positively charged by by the water-molecule dissociation of coating surface, is formed with the acidic micro-environment of sterilization and bacteriostasis effect,
So as to realize antibacterial action.Epoxy antibiotic paint of the invention realizes contactless sterilization, nontoxic to people, extremely pacifies
Entirely.Further, since molybdenum oxide only plays catalytic action in above process, there is no any consumption and loss, as long as paint film is present, resist
Bacterium effect be maintained for it is constant, so antibacterial action persistently, actual tests and properties of product can be confirmed.
Epoxy antibiotic paint of the invention uses normal temperature cure film forming, and construction technology is simple, is not limited by space enrironment, makes
Used time need only be used while allocating, easy to use.
Epoxy antibiotic paint of the invention can be used for almost all of material surface, including metal, ceramics, plastics, wood
Material etc., adhesive force is good, hardness is high, sturdy and durable, with strong applicability, it is easy to popularization and application.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated.It should be understood that these embodiments are merely to illustrate this
Invention rather than limitation the scope of the present invention.Additionally, after the present invention has been read, those skilled in the art can be to this hair
Bright various modifications may be made or equivalent, and these modifications or equivalent equally fall into the application claim limited range.
Embodiment 1：A kind of epoxy antibiotic paint, including the component A and organic amine that epoxy resin is main body is the group of main body
Part B, respectively by weight,
Wherein component A：5 parts of 100 parts of epoxy resin CYD-128, diluent JX-016, holds epoxidized polyether Banco
1400 10 parts, 5 parts of molybdenum oxide, 104 0.3 parts of dispersant B YK-P, 530 0.1 parts of defoamer BYK-A, levelling agent BYK
399 0.06 parts；Wherein the fineness of molybdenum oxide is less than 70 microns.
Component B：110 parts of fatty amine curing agent, 0.03 part of defoamer.
When using, fineness is ground to after component A is mixed on sand mill less than 50 microns, by component B on dispersion machine
It is dispersed into uniform liquid；Component A, B are taken by 2:1 mass ratio is well mixed, and brushes onto aluminium sheet, dries at room temperature.Its antibacterial
Performance is shown in Table 1.
Raw material sources：Epoxy resin CYD-128, originates from sinopec Ba Ling petrochemical industry shares branch company；Diluent JX-016, produces
From Changhu Jiafa chemistry Co., Ltd.；End epoxidized polyether, originates from nation and chemistry（China）Co., Ltd；Molybdenum oxide originates from Thailand
State city Europe Pood's tungsten Products Co., Ltd；Dispersant, originates from BYK Additive ＆ Instruments；Defoamer, originates from
BYK Additive & Instruments；Levelling agent, originates from BYK Additive ＆ Instruments.
Component B：Fatty amine curing agent, originates from US Air gasification chemical product Co., Ltd；Defoamer, originates from BYK
Additive & Instruments。
Embodiment 2：A kind of epoxy antibiotic paint, including the component A and organic amine that epoxy resin is main body is the group of main body
Part B, respectively by weight,
Component A：5 parts of 862 100 parts of epoxy resin IKOTE, diluent JX-016, holds epoxidized polyether Banco 1400
10 parts, 2 parts of molybdenum oxide, 2 parts of white carbon, 0.6 part of dispersant B YK-P 104S, 530 0.1 parts of defoamer BYK-A, levelling agent
0.06 part.
Component B：Fatty amine curing agent AncamineR2726 100 parts, 8 parts of polyetheramine M-1000, diethylenetriamine 0.5
Part, 10 parts of toluene, 530 0.03 parts of defoamer BYK-A.
When using, component A is ground to fineness less than 50 microns on sand mill, component B is dispersed on dispersion machine
Even liquid；Component A, B are taken by 1.8:After 1 mass ratio mixing, it is sprayed on plastic plate, dries at room temperature.Its anti-microbial property is shown in
Table 1.
Raw material sources：Epoxy resin：Dutch Shell Co. Ltd, diluent：The good hair chemistry in ChangshuLimited LiabilityCompany, end ring oxygen
Polyethers：Nation and chemistry（China）Co., Ltd, molybdenum oxide：Taizhou City Europe Pood's tungsten productIt is limitedCompany, dispersant：BYK
Additive ＆ Instruments, defoamer：BYK Additive ＆ Instruments, levelling agent：BYK Additive
& Instruments。
Component B, fatty amine curing agent：US Air gasification chemical product Co., Ltd, polyetheramine：Huntsman
JEFFAMINE, defoamer：BYK Additive & Instruments.When using, component A is ground to fineness on sand mill
Less than 50 microns, component B is dispersed into uniform liquid on dispersion machine；Component A, B are taken by 1.8:After 1 mass ratio mixing, application
On plastic plate, dry at room temperature.Anti-microbial property is shown in Table 1.
Embodiment 3：A kind of epoxy antibiotic paint, including epoxy is the component B that the component A and organic amine of main body are main body,
Respectively by weight,
Component A：Epoxy resin：60 parts of sinopec Ba Ling petrochemical industry shares branch company CYD-128, Dutch Shell Co. Ltd
862 40 parts of EPIKOTE, diluent：5 parts of Changhu Jiafa chemistry Co., Ltd. JX-016, holds epoxidized polyether：Nation and change
Learn（China）1,400 10 parts of Co., Ltd Banco, 5 parts of molybdenum oxide, dispersant：BYK Additive & Instruments
0.3 part of DISPER BYK-118, defoamer：530 0.1 parts of BYK Additive ＆ Instruments BYK-A, levelling
Agent：399 0.06 parts of BYK Additive ＆ Instruments BYK.
Component B：Fatty amine curing agent：US Air gasification chemical product Co., Ltd AncamineR2726 100 parts, US Air
Gasification chemical product Co., Ltd AncamineR2519 10 parts, defoamer：BYK Additive & Instruments BYK-A
530 0.03 parts；
When using, component A is ground to fineness less than 50 microns on sand mill, component B is dispersed on dispersion machine
Even liquid.Component A, B are taken by 2:1 mass ratio is well mixed to brush onto cement plate, dries at room temperature.Anti-microbial property is shown in Table
1。
A kind of epoxy antibiotic paint of embodiment 4, including epoxy is the component B that the component A and organic amine of main body are main body,
Respectively by weight,
Component A：Epoxy resin：60 parts of sinopec Ba Ling petrochemical industry shares branch company CYD-128,40 parts of titanium dioxide, dilution
Agent：5 parts of Changhu Jiafa chemistry Co., Ltd. JX-016, holds epoxidized polyether：Nation and chemistry（China）Co., Ltd Banco
1400 10 parts, 5 parts of molybdenum oxide, dispersant：0.8 part of BYK Additive ＆ Instruments BYK-P 104S, froth breaking
Agent：530 0.1 parts of BYK Additive ＆ Instruments BYK-A, levelling agent：BYK Additive &
399 0.06 parts of Instruments BYK.
Component B：Fatty amine curing agent：US Air gasification chemical product Co., Ltd AncamineR2726 100 parts, US Air
Gasification chemical product Co., Ltd AncamineR2519 6 parts, defoamer：BYK Additive & Instruments BYK-A
530 0.03 parts.When using, component A is ground to fineness less than 50 microns on sand mill, component B is dispersed on dispersion machine
Uniform liquid.Component A, component B are taken by 3.4:1 ratio is well mixed to brush onto cement plate, dries at room temperature.Antibiotic property
1 can be shown in Table.
The performance of the epoxy antibiotic paint of the invention of table 1
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Anti-microbial property * | ＞ 99.95% | ＞ 99.99% | ＞ 99.75% | ＞ 99.95% |
| Durable antibacterial * | ＞ 99.54% | ＞ 99.99% | ＞ 99.54% | ＞ 99.89% |
| Adhesive force * * | 1 grade | 2 grades | 1 grade | 1 grade |
| Hardness * * * | 4H | 3H | 3H | 5H |
| Surface drying * * * * | 8 | 8 | 10 | 8 |
| Do solid work * * * * | 20 | 23 | 18 | 17 |
In table, * presses GB/T 21866-2008 tests, and * * press GB/T 9286-1998 tests, and * * * press GB/T 6739-
2006 tests, * * * * press GB/T 1728-1979.
Claims (6)
1. a kind of epoxy antibiotic paint, it is characterized in that：Including epoxy resin for the component A and organic amine of main body are the component of main body
B, by weight, in component A：90~100 parts of epoxy resin, 1~5 part of epoxide diluent, 5~10 parts of PPG, point
0.05~1 part of powder, 0.02~0.5 part of levelling agent, 1~2 part of defoamer, 0~10 part of filler, 3~10 parts of molybdenum oxide, solvent 0
~30 parts；Component B is：80~100 parts of fatty amine, 5~10 parts of aromatic amine, 5~10 parts of amine terminated polyether polyalcohol, defoamer 0
~2 parts, 0~50 part of filler, 0~20 part of solvent；
Described component A and the mass ratio of component B are 2:1.
2. epoxy antibiotic paint according to claim 1, it is characterized in that：The epoxy resin includes bisphenol type epoxy tree
One or several in fat, bisphenol F epoxy resin, bisphenol-s epoxy resin, novolac epoxy resin.
3. epoxy antibiotic paint according to claim 1, it is characterized in that：The PPG is end ring oxygen polyether polyols
Alcohol or amine terminated polyether polyalcohol.
4. epoxy antibiotic paint according to claim 3, it is characterized in that：Described epoxy terminated PPG is one end
Or multiterminal are the PPGs of epoxy radicals, its relative molecular mass is 300~20000；
Described amine terminated polyether polyalcohol be one end or multiterminal be amino PPG, relative molecular mass is 300~
20000。
5. epoxy antibiotic paint according to claim 1, it is characterized in that：Described filler is silica, titanium dioxide, carbon
One kind in sour calcium, talcum powder；Solvent is toluene or acetone；The fatty amine is aliphatic hydrocarbon monoamine or polyamines, or is alicyclic
Monoamine or polyamines.
6. epoxy antibiotic paint according to claim 1, it is characterized in that：The fineness of the molybdenum oxide is less than 70 microns；Institute
The fineness for stating epoxy antibiotic paint is 0.02 micron~70 microns.
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| CN105199555A (en) * | 2015-10-28 | 2015-12-30 | 苏州奥莱鑫建材有限公司 | Antirust transparent varnish for building |
| CN105368263A (en) * | 2015-12-21 | 2016-03-02 | 常熟市雷号医疗器械有限公司 | Medical suction head |
| CN106590113A (en) * | 2016-12-09 | 2017-04-26 | 苏州科胜仓储物流设备有限公司 | Reverse osmosis ultralow-pressure airtight sealing strip and preparation method thereof |
| CN109096873A (en) * | 2018-07-08 | 2018-12-28 | 广州尚卓新材料科技有限公司 | A kind of underwater decorative paint of epoxy urea bond |
| CN109627925B (en) * | 2018-11-28 | 2021-07-09 | 三河市安霸生物技术有限公司 | Photocuring antibacterial coating |
| CN113198399B (en) * | 2021-05-20 | 2022-09-06 | 吉林建筑大学 | Phase change microcapsule, preparation method and application thereof, and composite AB coating |
| CN113308171A (en) * | 2021-06-02 | 2021-08-27 | 云南云岭涂料有限公司 | Silver-titanium nano antibacterial basalt flake composite epoxy coating and preparation method thereof |
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| WO2013153124A1 (en) * | 2012-04-10 | 2013-10-17 | AMiSTec GmbH & Co. KG | Composite material with a supporting material and an antimicrobial agent |
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| CN103254737A (en) * | 2013-05-09 | 2013-08-21 | 中国人民解放军海军后勤技术装备研究所 | Metal oil tank mould-proof conductive electrostatic anticorrosive coating |
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| WO2013153124A1 (en) * | 2012-04-10 | 2013-10-17 | AMiSTec GmbH & Co. KG | Composite material with a supporting material and an antimicrobial agent |
| CN103073970A (en) * | 2012-11-23 | 2013-05-01 | 高凡 | Preparation method of novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint |
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