CN104476641A - Flexible, antimoth and long-acting modification soak solution for rice straws and use method thereof - Google Patents

Flexible, antimoth and long-acting modification soak solution for rice straws and use method thereof Download PDF

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Publication number
CN104476641A
CN104476641A CN201410691397.3A CN201410691397A CN104476641A CN 104476641 A CN104476641 A CN 104476641A CN 201410691397 A CN201410691397 A CN 201410691397A CN 104476641 A CN104476641 A CN 104476641A
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China
Prior art keywords
parts
soak
rice straws
straw
long
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Pending
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CN201410691397.3A
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Chinese (zh)
Inventor
杨毅
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FUNAN NATURE CRAFTS Co Ltd
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FUNAN NATURE CRAFTS Co Ltd
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Priority to CN201410691397.3A priority Critical patent/CN104476641A/en
Publication of CN104476641A publication Critical patent/CN104476641A/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00—Chemical or physical treatment of reed, straw, or similar material
    • B27K9/007—Straw
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/26—Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/20—Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Forests & Forestry (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Biotechnology (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to the field of modifying treatment of materials for weaving crafts and particularly relates to a flexible, antimoth and long-acting modification soak solution for rice straws and a use method thereof. The soak solution is prepared from the following raw materials in parts by weight: 1-2 parts of sodium pyrrolidone carboxylate, 4-5 parts of butylcellosolve, 0.1-0.2 part of polyhexamethylene guanidine, 8-10 parts of polyisobutylene, 20-25 parts of sodium carbonate, 2-3 parts of azadirachta indica leaves, 250-280 parts of water and 4-5 parts of auxiliaries. The soak solution disclosed by the invention does not contain volatile and toxic organic ingredients, so that operating environments are not polluted; due to the ingredients, such as sodium pyrrolidone carboxylate, polyisobutylene and sodium bicarbonate, cellulose can be effectively softened, the hardness and toughness of the rice straws are improved, the weaving performance is improved, and the rice straws are endowed with a soft and smooth hand feeling; due to the azadirachta indica leaves, polyhexamethylene guanidine and the like, the anticorrosive and antimoth capability of the rice straws can be improved, and the damage caused by bacteria and termites/insects is prevented; the rice straws subjected to soaking treatment are not prone to rupture, are easier in process-shaping and are timesaving and laborsaving during processing, and obtained products are not prone to mildewing and corroding and are bright, flexible and durable.

Description

The soft mothproof long-acting modification soak of a kind of straw and using method thereof
Technical field
The present invention relates to baskets craft material modification process field, be specifically related to the soft mothproof long-acting modification soak of a kind of straw and using method thereof.
Background technology
The handicraft that the natural establishment material such as rattan, wicker, bamboo cane, all kinds of stalks makes has high viewing and admiring and practical value, and product is found a good sale in both at home and abroad, and pole is liked by consumer, and market potential is huge.Due to their biological speciality, exist inflammable, easily split, the shortcoming such as rotten of easily damaging by worms, need in actual use to carry out a series of modification, to improve its mechanical property and physicochemical property, make it more easily process and shipping storage, improve ornamental value and Practical Performance, conventional process means adopt modification liquid to material immersion treatment, therefore, the preparation of modification liquid is particularly important, and desirable modification liquid needs to possess that environment-protecting asepsis, modified effect are lasting, the feature such as do not affect the appearance.
Summary of the invention
The object of the invention is to provide the soft mothproof long-acting modification soak of a kind of straw and using method thereof, and to improve the serviceability of straw, promote practical value, to achieve these goals, the technical solution used in the present invention is as follows:
The soft mothproof long-acting modification soak of a kind of straw and using method thereof, it is characterized in that, this soak is made up of the raw material of following weight portion: pyrrolidone sodium carboxylate 1-2, ethylene glycol monobutyl ether 4-5, the sub-guanidine 0.1-0.2 of poly-hexamethyl, polyisobutene 8-10, sodium acid carbonate 20-25, print chinaberry leaf 2-3, water 250-280, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: polymethylacrylic acid 8-10, hydrazine aluminum sulfate 4-5, titanyl sulfate 1-2, yellow rice wine 15-18, myrica ruba marc 2-4, Ultra Tex 2 6-8; its preparation method is: the water first myrica ruba marc being put into 5 times of its weight portions; decoct 1-1.5h; filter; add polymethylacrylic acid, hydrazine aluminum sulfate, titanyl sulfate after the cooling of gained filtrate, stir, then add other leftover materials; continue stirring and dissolving dispersion 40-50min, obtain auxiliary agent.
The soft mothproof long-acting modification soak of described a kind of straw and using method thereof, its preparation method is: be first added to the water by print chinaberry leaf, decoct 2-3h, filter, when gained filtrate is cooled to 50-60 DEG C, add pyrrolidone sodium carboxylate, poly-hexamethyl sub-guanidine, sodium acid carbonate, be stirred to after material dissolves completely, add other leftover materials again, continue to stir 40-50min, obtain soak.
The soft mothproof long-acting modification soak of described a kind of straw and using method thereof, its using method is: submerged completely by pretreated straw in above-mentioned soak, be heated to 40-50 DEG C, be incubated airtight immersion 18-22h, taking-up clear water is cleaned nature and is dried or dry.
Soak advantage of the present invention is: its raw material adopted is environmental protection composition, not containing volatility toxic organic compound composition, does not pollute environment for use, pyrrolidone sodium carboxylate in raw material, polyisobutene, after the active ingredients such as sodium acid carbonate infiltrate straw inside, can effective softening fibre matter, improve hardness and the toughness of straw, improve knitting property, give the feel of its soft smooth, print chinaberry leaf, the raw materials such as the sub-guanidine of poly-hexamethyl effectively can improve the anticorrosion of straw, mothproof ability, prevent the destruction of bacterium worm ant, soak preparation method of the present invention and using method simple, stable chemical performance, devil liquor recovery process is simple, straw after immersion treatment not frangibility, easier machine-shaping, process is time saving and energy saving, products obtained therefrom is mould corruption not easily, bright soft, durable in use.
Detailed description of the invention
Embodiment
The soak of the present embodiment is obtained by the raw material of following weight portion (kilogram): pyrrolidone sodium carboxylate 2, ethylene glycol monobutyl ether 5, the sub-guanidine 0.1 of poly-hexamethyl, polyisobutene 8, sodium acid carbonate 25, print chinaberry leaf 3, water 280, auxiliary agent 5; Auxiliary agent is made up of the raw material of following weight portion: polymethylacrylic acid 8, hydrazine aluminum sulfate 4, titanyl sulfate 1, yellow rice wine 18, myrica ruba marc 3, Ultra Tex 28; its preparation method is: the water first myrica ruba marc being put into 5 times of its weight portions; decoct 1.5h; filter; add polymethylacrylic acid, hydrazine aluminum sulfate, titanyl sulfate after the cooling of gained filtrate, stir, then add other leftover materials; continue stirring and dissolving dispersion 50min, obtain auxiliary agent.
The soak preparation method of the present embodiment is: be first added to the water by print chinaberry leaf, decoct 3h, filter, when gained filtrate is cooled to 50-60 DEG C, add pyrrolidone sodium carboxylate, poly-hexamethyl sub-guanidine, sodium acid carbonate, be stirred to after material dissolves completely, then add other leftover materials, continue to stir 50min, obtain soak.
Submerged completely in above-mentioned soak by pretreated straw, be heated to 40-50 DEG C, be incubated airtight immersion 20h, taking-up clear water is cleaned nature and is dried or dry, then carries out subsequent handling.In follow-up braiding process, straw impact strength after the process of the present embodiment soak increases by 18.4% compared with the material of conventional process, and bending strength improves 24.3%, and combustion test shows, soak modified straw HRR and reduce by 56.4%, total heat liberation rate, heat release rate reduces by 54.8%.Easier, time saving and energy saving when material after process weaves, product average production time reduces by 14.5%, and product places more than 1 year without problems such as variable color, rotten moth, crackles.

Claims (3)

1. the soft mothproof long-acting modification soak of straw and using method thereof, it is characterized in that, this soak is made up of the raw material of following weight portion: pyrrolidone sodium carboxylate 1-2, ethylene glycol monobutyl ether 4-5, the sub-guanidine 0.1-0.2 of poly-hexamethyl, polyisobutene 8-10, sodium acid carbonate 20-25, print chinaberry leaf 2-3, water 250-280, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: polymethylacrylic acid 8-10, hydrazine aluminum sulfate 4-5, titanyl sulfate 1-2, yellow rice wine 15-18, myrica ruba marc 2-4, Ultra Tex 2 6-8; its preparation method is: the water first myrica ruba marc being put into 5 times of its weight portions; decoct 1-1.5h; filter; add polymethylacrylic acid, hydrazine aluminum sulfate, titanyl sulfate after the cooling of gained filtrate, stir, then add other leftover materials; continue stirring and dissolving dispersion 40-50min, obtain auxiliary agent.
2. the soft mothproof long-acting modification soak of a kind of straw as claimed in claim 1 and using method thereof, its preparation method is: be first added to the water by print chinaberry leaf, decoct 2-3h, filter, when gained filtrate is cooled to 50-60 DEG C, add pyrrolidone sodium carboxylate, poly-hexamethyl sub-guanidine, sodium acid carbonate, be stirred to after material dissolves completely, add other leftover materials again, continue to stir 40-50min, obtain soak.
3. the soft mothproof long-acting modification soak of a kind of straw as claimed in claim 1 and using method thereof, its using method is: submerged completely by pretreated straw in above-mentioned soak, be heated to 40-50 DEG C, be incubated airtight immersion 18-22h, taking-up clear water is cleaned nature and is dried or dry.
CN201410691397.3A 2014-11-27 2014-11-27 Flexible, antimoth and long-acting modification soak solution for rice straws and use method thereof Pending CN104476641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410691397.3A CN104476641A (en) 2014-11-27 2014-11-27 Flexible, antimoth and long-acting modification soak solution for rice straws and use method thereof

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Application Number Priority Date Filing Date Title
CN201410691397.3A CN104476641A (en) 2014-11-27 2014-11-27 Flexible, antimoth and long-acting modification soak solution for rice straws and use method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107157041A (en) * 2017-04-08 2017-09-15 阜南县永盛工艺品有限公司 A kind of processing method for improving levant cotton exocarp anti-mould and anti-moth performance

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101264679A (en) * 2008-04-30 2008-09-17 周觉民 Rattan bamboo plus material and preparation method thereof
CN103264423A (en) * 2013-05-15 2013-08-28 惠州市云立方科技有限公司 Preparation method of water hyacinth rattan
CN104085024A (en) * 2014-06-10 2014-10-08 安徽华宇工艺品集团有限公司 A mothproof brightening willow rattan softener and a preparing method thereof
CN104128980A (en) * 2014-06-25 2014-11-05 阜南县永兴工艺品有限公司 Enhanced mothproof immersion liquid for rattan, and use method thereof
CN104128975A (en) * 2014-06-25 2014-11-05 阜南县永兴工艺品有限公司 Immersion liquid used for rattan having skin-friendly and anti-bacterial functions, and use method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101264679A (en) * 2008-04-30 2008-09-17 周觉民 Rattan bamboo plus material and preparation method thereof
CN103264423A (en) * 2013-05-15 2013-08-28 惠州市云立方科技有限公司 Preparation method of water hyacinth rattan
CN104085024A (en) * 2014-06-10 2014-10-08 安徽华宇工艺品集团有限公司 A mothproof brightening willow rattan softener and a preparing method thereof
CN104128980A (en) * 2014-06-25 2014-11-05 阜南县永兴工艺品有限公司 Enhanced mothproof immersion liquid for rattan, and use method thereof
CN104128975A (en) * 2014-06-25 2014-11-05 阜南县永兴工艺品有限公司 Immersion liquid used for rattan having skin-friendly and anti-bacterial functions, and use method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107157041A (en) * 2017-04-08 2017-09-15 阜南县永盛工艺品有限公司 A kind of processing method for improving levant cotton exocarp anti-mould and anti-moth performance

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Application publication date: 20150401

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