CN104449115A - 一种柔韧性氟化涂料 - Google Patents

一种柔韧性氟化涂料 Download PDF

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CN104449115A
CN104449115A CN201410608198.1A CN201410608198A CN104449115A CN 104449115 A CN104449115 A CN 104449115A CN 201410608198 A CN201410608198 A CN 201410608198A CN 104449115 A CN104449115 A CN 104449115A
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路坤
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Abstract

本发明公开了一种柔韧性氟化涂料，它是由下述重量份的原料组成的：硅酸钾钠1-2、氟化钠1-2、氟化钙2-3、芳樟醇0.5-1、二异氰酸酯0.3-1、钛酸钾晶须2-4、四甲基硝酸铵1-2、锂基膨润土10-14、癸二酸二辛酯3-4、二月桂酸二丁基锡0.7-1、α-溴代肉桂醛0.1-0.4、二甲基甲酰胺0.6-1、丙烯酸丁酯130-150、醋酸乙烯酯160-200、过硫酸钠0.8-2、椰油酸二乙醇酰胺0.3-0.5、乳化剂OP-102-3、粘结助剂4-6、去离子水500-700，本发明的涂料具有良好的柔韧性和延伸率，还可以用于填补墙体裂缝，耐老化、耐水性强，表面强度高，与基材的粘结性强，抗剥离效果好。

Description

一种柔韧性氟化涂料
技术领域
    本发明主要涉及涂料领域，尤其涉及一种柔韧性氟化涂料。
背景技术
和普通苯丙乳液相比，醋丙乳液具有很多的优越性能：1. 无APEO、无甲醛，健康环保。2. 对比率高、良好的开罐效果。3. 成膜温度低，可适当少加成膜助剂，降低涂料成本。4.漆膜细腻、平整光滑，装饰效果好。5.价格适中，为涂料厂家提供最佳性价比，特别适用于配制高、中、低PVC的高品质的平光和半光环境友好型健康环保内墙乳胶漆。随着醋丙乳液的应用范围不断扩大，进一步提高其粘结性、表面抗性、稳定性等性能可以使其更好的适应现代化建设的需求。
发明内容
本发明目的就是提供一种柔韧性氟化涂料。
本发明是通过以下技术方案实现的：
一种柔韧性氟化涂料，其特征在于它是由下述重量份的原料组成的：
硅酸钾钠1-2、氟化钠1-2、氟化钙2-3、芳樟醇0.5-1、二异氰酸酯0.3-1、钛酸钾晶须2-4、四甲基硝酸铵1-2、锂基膨润土10-14、癸二酸二辛酯3-4、二月桂酸二丁基锡0.7-1、α-溴代肉桂醛0.1-0.4、二甲基甲酰胺0.6-1、丙烯酸丁酯130-150、醋酸乙烯酯160-200、过硫酸钠0.8-2、椰油酸二乙醇酰胺0.3-0.5、乳化剂OP-10 2-3、粘结助剂4-6、去离子水500-700；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯4-6、偏硅酸钠1-2、硫铝酸钙3-5、三甲基六亚甲基二异氰酸酯2-3、烷基酚聚氧乙烯醚1-2、丙烯酸十三氟辛酯2-4、硅丙乳液30-36、去离子水20-25；
A、将偏硅酸钠加入到去离子水中，搅拌均匀，升高温度为50-60℃，滴加烷基酚聚氧乙烯醚，滴加完毕后加入三甲基六亚甲基二异氰酸酯，搅拌至常温；
B、将丙烯酸十三氟辛酯加入到硅丙乳液中，搅拌均匀后加入硫铝酸钙，100-200转/分搅拌分散5-10分钟；
将上述处理后的A、B物料混合，搅拌均匀后加入甲基丙烯酸甲酯，在60-70℃下搅拌反应20-30分钟，冷却至常温，400-600转/分搅拌分散10-15分钟，即得所述粘结助剂。
2、一种如权利要求1所述的柔韧性氟化涂料的制备方法，其特征在于包括以下步骤：
（1）将过硫酸钠，加入到上述去离子水重量的10-15%中，搅拌均匀，得引发剂溶液；
（2）取乳化剂OP-10，加入剩余去离子水重量的60-70%，搅拌均匀，加入α-溴代肉桂醛，搅拌均匀，得预乳液；
（3）取上述丙烯酸丁酯重量的50-60%、醋酸乙烯酯重量的50-60%混合，加入上述预乳液，在60-65℃下搅拌混合30-35分钟，升高温度为70-75℃，加入上述引发剂溶液重量的60-65%，待乳液呈蓝相，保温60-70分钟，得种子乳液；
（4）将剩余的丙烯酸丁酯、醋酸乙烯酯混合，在60-80℃下保温搅拌20-30分钟，搅拌至常温，得混合单体；
（5）取椰油酸二乙醇酰胺与芳樟醇混合，加入剩余去离子水重量的10-15%，搅拌均匀后加入上述混合单体、剩余的引发剂溶液，50-60℃下保温搅拌10-20分钟，得处理液；
（6）在上述种子乳液中滴加上述处理液，滴加时间为90-120分钟，滴加完毕后，在80-90℃下保温50-60分钟，冷却，用200-250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述柔韧性氟化涂料。
本发明的优点是：
    本发明的涂料具有良好的柔韧性和延伸率，还可以用于填补墙体裂缝，耐老化、耐水性强，表面强度高，与基材的粘结性强，抗剥离效果好。
具体实施方式
实施例1
一种柔韧性氟化涂料，其特征在于它是由下述重量份的原料组成的：
硅酸钾钠1、氟化钠2、氟化钙2、芳樟醇0.5、二异氰酸酯0.3、钛酸钾晶须2、四甲基硝酸铵2、锂基膨润土14、癸二酸二辛酯3、二月桂酸二丁基锡0.7、α-溴代肉桂醛0.4、二甲基甲酰胺0.6、丙烯酸丁酯150、醋酸乙烯酯200、过硫酸钠0.8、椰油酸二乙醇酰胺0.5、乳化剂OP-10 3、粘结助剂4、去离子水700；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯6、偏硅酸钠1、硫铝酸钙3、三甲基六亚甲基二异氰酸酯3、烷基酚聚氧乙烯醚2、丙烯酸十三氟辛酯2、硅丙乳液36、去离子水25；
A、将偏硅酸钠加入到去离子水中，搅拌均匀，升高温度为60℃，滴加烷基酚聚氧乙烯醚，滴加完毕后加入三甲基六亚甲基二异氰酸酯，搅拌至常温；
B、将丙烯酸十三氟辛酯加入到硅丙乳液中，搅拌均匀后加入硫铝酸钙，200转/分搅拌分散10分钟；
将上述处理后的A、B物料混合，搅拌均匀后加入甲基丙烯酸甲酯，在70℃下搅拌反应30分钟，冷却至常温，600转/分搅拌分散15分钟，即得所述粘结助剂。
一种柔韧性氟化涂料的制备方法，其特征在于包括以下步骤：
（1）将过硫酸钠，加入到上述去离子水重量的15%中，搅拌均匀，得引发剂溶液；
（2）取乳化剂OP-10，加入剩余去离子水重量的70%，搅拌均匀，加入α-溴代肉桂醛，搅拌均匀，得预乳液；
（3）取上述丙烯酸丁酯重量的60%、醋酸乙烯酯重量的60%混合，加入上述预乳液，在65℃下搅拌混合35分钟，升高温度为75℃，加入上述引发剂溶液重量的65%，待乳液呈蓝相，保温70分钟，得种子乳液；
（4）将剩余的丙烯酸丁酯、醋酸乙烯酯混合，在80℃下保温搅拌30分钟，搅拌至常温，得混合单体；
（5）取椰油酸二乙醇酰胺与芳樟醇混合，加入剩余去离子水重量的15%，搅拌均匀后加入上述混合单体、剩余的引发剂溶液，60℃下保温搅拌20分钟，得处理液；
（6）在上述种子乳液中滴加上述处理液，滴加时间为120分钟，滴加完毕后，在90℃下保温60分钟，冷却，用250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，1200转/分搅拌分散30分钟，即得所述柔韧性氟化涂料。
性能测试：
延伸率：≥300％ ；
不透水性：0.3MPa( 一个小时不透水)。

Claims (2)

1.一种柔韧性氟化涂料，其特征在于它是由下述重量份的原料组成的：
硅酸钾钠1-2、氟化钠1-2、氟化钙2-3、芳樟醇0.5-1、二异氰酸酯0.3-1、钛酸钾晶须2-4、四甲基硝酸铵1-2、锂基膨润土10-14、癸二酸二辛酯3-4、二月桂酸二丁基锡0.7-1、α-溴代肉桂醛0.1-0.4、二甲基甲酰胺0.6-1、丙烯酸丁酯130-150、醋酸乙烯酯160-200、过硫酸钠0.8-2、椰油酸二乙醇酰胺0.3-0.5、乳化剂OP-10 2-3、粘结助剂4-6、去离子水500-700；
所述的粘结助剂是由下述重量份的各原料组成的：
甲基丙烯酸甲酯4-6、偏硅酸钠1-2、硫铝酸钙3-5、三甲基六亚甲基二异氰酸酯2-3、烷基酚聚氧乙烯醚1-2、丙烯酸十三氟辛酯2-4、硅丙乳液30-36、去离子水20-25；
A、将偏硅酸钠加入到去离子水中，搅拌均匀，升高温度为50-60℃，滴加烷基酚聚氧乙烯醚，滴加完毕后加入三甲基六亚甲基二异氰酸酯，搅拌至常温；
B、将丙烯酸十三氟辛酯加入到硅丙乳液中，搅拌均匀后加入硫铝酸钙，100-200转/分搅拌分散5-10分钟；
将上述处理后的A、B物料混合，搅拌均匀后加入甲基丙烯酸甲酯，在60-70℃下搅拌反应20-30分钟，冷却至常温，400-600转/分搅拌分散10-15分钟，即得所述粘结助剂。
2.一种如权利要求1所述的柔韧性氟化涂料的制备方法，其特征在于包括以下步骤：
（1）将过硫酸钠，加入到上述去离子水重量的10-15%中，搅拌均匀，得引发剂溶液；
（2）取乳化剂OP-10，加入剩余去离子水重量的60-70%，搅拌均匀，加入α-溴代肉桂醛，搅拌均匀，得预乳液；
（3）取上述丙烯酸丁酯重量的50-60%、醋酸乙烯酯重量的50-60%混合，加入上述预乳液，在60-65℃下搅拌混合30-35分钟，升高温度为70-75℃，加入上述引发剂溶液重量的60-65%，待乳液呈蓝相，保温60-70分钟，得种子乳液；
（4）将剩余的丙烯酸丁酯、醋酸乙烯酯混合，在60-80℃下保温搅拌20-30分钟，搅拌至常温，得混合单体；
（5）取椰油酸二乙醇酰胺与芳樟醇混合，加入剩余去离子水重量的10-15%，搅拌均匀后加入上述混合单体、剩余的引发剂溶液，50-60℃下保温搅拌10-20分钟，得处理液；
（6）在上述种子乳液中滴加上述处理液，滴加时间为90-120分钟，滴加完毕后，在80-90℃下保温50-60分钟，冷却，用200-250目筛网过滤出料；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述柔韧性氟化涂料。
CN201410608198.1A 2014-11-03 2014-11-03 一种柔韧性氟化涂料 Pending CN104449115A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131816A (zh) * 2015-08-27 2015-12-09 岳西县盛宏工贸有限责任公司 一种金属用纤维涂料及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105131816A (zh) * 2015-08-27 2015-12-09 岳西县盛宏工贸有限责任公司 一种金属用纤维涂料及其制备方法

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