CN104448741B - 高性能含卤阻燃长纤维增强聚乳酸复合材料及其制备方法 - Google Patents
高性能含卤阻燃长纤维增强聚乳酸复合材料及其制备方法 Download PDFInfo
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- CN104448741B CN104448741B CN201410708758.0A CN201410708758A CN104448741B CN 104448741 B CN104448741 B CN 104448741B CN 201410708758 A CN201410708758 A CN 201410708758A CN 104448741 B CN104448741 B CN 104448741B
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- retardant
- long fiber
- fiber reinforcement
- compatilizer
- lactic acid
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- 239000000835 fiber Substances 0.000 title claims abstract description 58
- 239000003063 flame retardant Substances 0.000 title claims abstract description 42
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 37
- 150000002367 halogens Chemical class 0.000 title claims abstract description 37
- 230000002787 reinforcement Effects 0.000 title claims abstract description 24
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 239000004310 lactic acid Substances 0.000 title claims abstract description 20
- 235000014655 lactic acid Nutrition 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000004626 polylactic acid Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 32
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 32
- 239000012745 toughening agent Substances 0.000 claims abstract description 27
- 239000004970 Chain extender Substances 0.000 claims abstract description 18
- 238000005470 impregnation Methods 0.000 claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000007598 dipping method Methods 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 15
- 239000002270 dispersing agent Substances 0.000 claims description 13
- 238000001125 extrusion Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 8
- 229920005989 resin Polymers 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 7
- 229920001577 copolymer Polymers 0.000 abstract description 6
- PFNROQCAJVOSIR-UHFFFAOYSA-N oxiran-2-ylmethyl 2-methylprop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound CC(=C)C(=O)OCC1CO1.N#CC=CC=CC1=CC=CC=C1 PFNROQCAJVOSIR-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005253 cladding Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- WSEFPKKOUNRCAJ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;octadecanoic acid Chemical group OCC(CO)(CO)CO.CCCCCCCCCCCCCCCCCC(O)=O WSEFPKKOUNRCAJ-UHFFFAOYSA-N 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- 240000000797 Hibiscus cannabinus Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OXIKLRTYAYRAOE-CMDGGOBGSA-N (e)-3-(1-benzyl-3-pyridin-3-ylpyrazol-4-yl)prop-2-enoic acid Chemical group N1=C(C=2C=NC=CC=2)C(/C=C/C(=O)O)=CN1CC1=CC=CC=C1 OXIKLRTYAYRAOE-CMDGGOBGSA-N 0.000 description 1
- XMCXTGRBAIZQCC-AATRIKPKSA-N (e)-3-[2-[n-acetyl-3-(trifluoromethyl)anilino]-1,3-thiazol-4-yl]prop-2-enoic acid Chemical group C=1C=CC(C(F)(F)F)=CC=1N(C(=O)C)C1=NC(\C=C\C(O)=O)=CS1 XMCXTGRBAIZQCC-AATRIKPKSA-N 0.000 description 1
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 description 1
- 244000198134 Agave sisalana Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 229920001431 Long-fiber-reinforced thermoplastic Polymers 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ABXSJIXCMARDGV-UHFFFAOYSA-N [N].[Br] Chemical compound [N].[Br] ABXSJIXCMARDGV-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
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CN201410708758.0A CN104448741B (zh) | 2014-12-01 | 2014-12-01 | 高性能含卤阻燃长纤维增强聚乳酸复合材料及其制备方法 |
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CN201410708758.0A CN104448741B (zh) | 2014-12-01 | 2014-12-01 | 高性能含卤阻燃长纤维增强聚乳酸复合材料及其制备方法 |
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CN104448741A CN104448741A (zh) | 2015-03-25 |
CN104448741B true CN104448741B (zh) | 2016-09-21 |
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CN108456371A (zh) * | 2018-02-07 | 2018-08-28 | 晖腾工业科技有限公司 | 一种改性as树脂复合材料 |
CN111793338B (zh) * | 2020-08-17 | 2023-06-23 | 郑州大学 | 一种复配型无卤阻燃植物纤维增强聚乳酸材料及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1795560A1 (en) * | 2004-09-03 | 2007-06-13 | Adeka Corporation | Polylactic acid resin composition, moldings, and process for production thereof |
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CN101235192A (zh) * | 2007-02-02 | 2008-08-06 | 东丽纤维研究所(中国)有限公司 | 聚乳酸和植物纤维复合材料及其制备方法 |
CN102276964A (zh) * | 2011-06-21 | 2011-12-14 | 东莞劲胜精密组件股份有限公司 | 一种可降解工程塑料及其制备方法 |
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EP1795560A1 (en) * | 2004-09-03 | 2007-06-13 | Adeka Corporation | Polylactic acid resin composition, moldings, and process for production thereof |
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Denomination of invention: Halogen-contained, flame-retardant and long-fiber-reinforced PLA (polylactic acid) composite material with high performance and preparation method of composite material Effective date of registration: 20180504 Granted publication date: 20160921 Pledgee: Baiyun branch of Guiyang Bank Co., Ltd. Pledgor: Guizhou Kaikete Material Co., Ltd. Registration number: 2018520000006 |
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Denomination of invention: Halogen-contained, flame-retardant and long-fiber-reinforced PLA (polylactic acid) composite material with high performance and preparation method of composite material Effective date of registration: 20180607 Granted publication date: 20160921 Pledgee: Baiyun branch of Guiyang Bank Co., Ltd. Pledgor: Guizhou Kaikete Material Co., Ltd. Registration number: 2018520000007 |
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Denomination of invention: Halogen-contained, flame-retardant and long-fiber-reinforced PLA (polylactic acid) composite material with high performance and preparation method of composite material Effective date of registration: 20190926 Granted publication date: 20160921 Pledgee: Baiyun branch of Guiyang Bank Co., Ltd. Pledgor: Guizhou Kaikete Material Co., Ltd. Registration number: Y2019520000009 |
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