CN104441820A - Multilayer composite artificial travertine plate as well as composition and preparation method thereof - Google Patents

Multilayer composite artificial travertine plate as well as composition and preparation method thereof Download PDF

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Publication number
CN104441820A
CN104441820A CN201410659466.2A CN201410659466A CN104441820A CN 104441820 A CN104441820 A CN 104441820A CN 201410659466 A CN201410659466 A CN 201410659466A CN 104441820 A CN104441820 A CN 104441820A
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China
Prior art keywords
surface layer
multilayer composite
composition
stone slab
hole stone
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Granted
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CN201410659466.2A
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CN104441820B (en
Inventor
陈国迈
陈迈华
由继业
夏艺
周仁道
梁贝贝
孙祥山
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SHANGHAI APE STONE CO Ltd
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SHANGHAI APE STONE CO Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B13/00Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
    • B32B13/14Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material next to a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements

Abstract

The invention provides a multilayer composite artificial travertine plate composition. The multilayer composite artificial travertine plate composition comprises a surface layer composition, an intermediate reinforcing layer and bottom layer sizing agent; the intermediate reinforcing layer is made from alkali-resisting gridding cloth; the surface layer composition comprises surface layer mill base, amphoteric metal and surface layer sizing agent. The invention also provides a multilayer composite artificial travertine plate prepared from the composition. The multilayer composite artificial travertine plate comprises a surface layer, an intermediate reinforcing layer and a bottom layer; the surface layer is prepared from the surface layer composition. The invention also provides a preparation method of the artificial travertine plate. The preparation method comprises the steps of coating a mold with the surface layer mill base, spraying a layer of amphoteric metal, pouring the surface layer sizing agent into the mold, laying the alkali-resisting gridding cloth, pouring the bottom layer sizing agent, and then carrying out the demolding and surface treatment to obtain the artificial travertine plate. The hole size, hole layout and surface grains of the prepared travertine plate can be adjusted according to the requirement of customers; moreover, the prepared travertine plate is light in weight and has the crack-proof effect; the preparation method is flexible to operate and low in cost.

Description

A kind of artificial hole stone slab of MULTILAYER COMPOSITE and composition and method of making the same thereof
Technical field
The present invention relates to a kind of hole stone slab, particularly relate to a kind of artificial hole stone slab and composition and method of making the same thereof of MULTILAYER COMPOSITE.
Background technology
Hole stone is that the formal name used at school of its stone material is travertine or calcareous tufa, commercial, is classified as marble class because there are many holes on the surface of stone material and gain the name.The mankind are for a long time far away to the use age of this stone material, can represent Romanistic building---and wrestling ring is exactly the former masterpiece of hole stone.
Natural cavity stone rich texture is gentle, clear-cut texture, the sheet material reasonable organization made, concavo-convex harmony, there is nature, simple and unsophisticated decorative effect, the advantage building of decoration can being impelled to have strong culture and history charm because it is distinctive, and enjoy people to favor, be a kind of building and ornament materials of top grade always.But because natural cavity stone intensity is poor, easily cracked, limited cost of drawing materials is high, and its hole distribution is uneven, deep mixed and there is aberration, thus limits a large amount of uses of people.So people wish to develop a kind of form and decorative effect close to natural cavity stone and the artificial stone that intensity is high, price is low, carry out alternative natural cavity stone.
CN102442807A discloses a kind of Lightweight composite travertine and preparation method thereof, the method utilizes blowing agent to foam in blowing agent to be formed after foam, and the compound mixing gained with other components is poured into and obtains in mould.The foam shape formed due to blowing agent is mostly spherical, comparison rule, so the hole stone utilizing this method to obtain can not regulate the shape of hole according to demand, and relative to the irregular holes of natural cavity stone, the hole stone that the present invention obtains is nature not, lacks artistry.
CN101020336A discloses a kind of artificial hole stone with true hole and preparation method thereof, the method utilizes with natural high-quality hole masonry as mould kind, using flexible material as turning over the obtained software mould of mold materials, realize making hole stone have the effect of the hole of true nature.But the method is too idealized, get rid of the complexity making software mould, the software mould just removed in the raw material after solidifying is exactly very difficult.
CN101407427A discloses a kind of production method of burrow stone imitation ceramic tile, and the method mainly by adding the pore forming particles obtained in conjunction with rice bran and/or wooden chaff mixing granulation for stick with former wax, realizes the imitative hole stone structure in ceramic tile.But, when removing pore forming particles, as described in expository writing, former wax is by after heat sublimation, and remaining rice bran and/or wooden chaff brush, in fact, still can remain former wax and rice bran and/or wooden chaff in the hole of the finished product finally obtained, not only can affect use, also can affect attractive in appearance.
Summary of the invention
In order to overcome the deficiency in currently available technology, realizing a kind of method of production hole stone of more convenient high-quality, the invention provides a kind of artificial hole stone slab and composition and method of making the same thereof of MULTILAYER COMPOSITE.The artificial hole stone slab of this MULTILAYER COMPOSITE not only its hole size, hole layout and superficial makings all can regulate according to the demand of client, and has the feature of lightweight cracking resistance, and its preparation method also has flexible operation, the advantage such as with low cost in addition.
The theme of first aspect present invention is a kind of artificial hole stone slab composition of MULTILAYER COMPOSITE, it is characterized in that, described artificial hole stone slab composition comprises surface layer composition, middle enhancement Layer and base pastes:
Described middle enhancement Layer is alkaline-resisting grid cloth;
Described surface layer composition comprises surface layer mill base, amphoteric metal and surface layer slurry;
Wherein, the component of described surface layer mill base and weight proportion thereof comprise:
Binder Materials 90-95 part,
Pigment 4-10 part;
Wherein, the component of described surface layer slurry and weight proportion thereof comprise:
Wherein, the component of described base pastes and weight proportion thereof comprise:
According to a kind of preferred embodiment of the present invention first aspect, wherein, described amphoteric metal comprise in beryllium, aluminium, gallium, zinc, germanium, indium, tin, antimony, thallium, lead, bismuth, polonium any one or a few, be preferably aluminium, can be aluminium foil, aluminium bits, any one or a few in aluminium wire, more preferably 5-80 order aluminium, wherein, most preferably is 20-60 order aluminium foil.
According to a kind of preferred embodiment of the present invention first aspect, wherein, described Binder Materials comprises organic Binder Materials and inorganic coagulation material, wherein, be preferably inorganic coagulation material, comprise hydraulic cementing materials and on-hydraulic Binder Materials, be more preferably the lime in the portland cement in hydraulic cementing materials, aluminate cement, sulphate aluminium cement and/or on-hydraulic Binder Materials, any one or a few in gypsum, most preferably be portland cement.
According to a kind of preferred embodiment of the present invention first aspect, wherein, described aggregate comprise in natural colour sand, artificial color sand, river sand any one or a few, preferred 20-120 order.
According to a kind of preferred embodiment of the present invention first aspect, wherein, the various pigment that described pigment can select the art conventional, as market is sold carbon black, iron oxide, cobalt oxide, titanium dioxide, pigment red 122 (main component is 2,9-dimethylquinacridone), organic light yellow, phthalocyanine blue, peacock green, lemon yellow, copper sulphate, acrylic paints etc.
According to a kind of preferred embodiment of the present invention first aspect, wherein, described mineral admixture comprise in flyash, breeze, stone flour, volcanic ash, silica flour any one or several.
According to a kind of preferred embodiment of the present invention first aspect, wherein, described plasticiser, thickener, defoamer, set retarder all belong to polymeric additive, wherein:
Described plasticiser is preferably polycarboxylic acids dehydragent, the synthon of described polycarboxylic acids dehydragent comprises polyoxy alkane alkenyl monomer, also comprise methacrylic acid, acrylic acid, maleic acid (or maleic anhydride), (methyl) allyl sulphonic acid, the salt of styrene sulfonic acid or above-mentioned acid or ester or other derivative, also comprise sulfonated melamine compound condensation product, sulphonated naphtalene formaldehyde condensation product, modified lignosulfonates etc.Wherein, described polyoxy alkane alkenyl monomer can contain polyoxyethylene groups, polyoxypropylene base.
Wherein, described thickener comprise in cellulose family, polyacrylate, bentonite, association type polyurethanes any one or a few, be more preferably, the homopolymers of methylcellulose, carboxyl alkyl cellulose, hydroxy alkyl cellulose, (methyl) acrylic acid or its ester or salt or copolymer.
Wherein, described defoamer comprises any one or a few in silicon ether Copolymer, organosiloxane, polyethers and phosphate.
Wherein, described set retarder comprises any one or a few of lignosulfonates and the weak acid such as derivative, hydroxycarboxylic acid and its esters, carbohydrate, zinc oxide, boric acid, phosphoric acid and its esters.
The theme of second aspect present invention is a kind of artificial hole stone slab of the MULTILAYER COMPOSITE prepared by composition described in claim 1, it is characterized in that, described artificial hole stone slab comprises surface layer, middle enhancement Layer and bottom:
Described middle enhancement Layer is alkaline-resisting grid cloth, between described surface layer and bottom;
Described surface layer is the preparation of described surface layer composition, comprise color top layer prepared by described surface layer mill base and surface layer basic unit prepared by described surface layer slurry, described surface layer basic unit and color top layer contact portion react containing described amphoteric metal and described surface layer mill base, surface layer slurry the hole formed at least partly.
The theme of third aspect present invention is the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE described in a kind of second aspect theme, and described preparation method comprises:
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: the component of surface layer mill base, surface layer slurry and base pastes and weight proportion preparation surface layer mill base, surface layer slurry and base pastes according to first aspect;
Step 3: described surface layer mill base is coated on described die surface;
Step 4: amphoteric metal is spread on described surface layer mill base;
Step 5: described surface layer slurry is built in described mould;
Step 6: alkaline-resisting grid cloth is laid on described surface layer slurry;
Step 7: described base pastes is cast on described alkaline-resisting grid cloth;
Step 8: maintenance is after at least 10 hours under 10-100 DEG C of temperature conditions, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
According to a kind of preferred embodiment of third aspect of the present invention, wherein, described step 2 according to first aspect subject content described in component and weight proportion prepare surface layer mill base, surface layer slurry and base pastes, wherein, preferably, the preparation of described surface layer slurry and base pastes is dropped in mixer at component, and mix suitable quantity of water, wherein:
Component and the weight proportion thereof of described surface layer mill base comprise:
Binder Materials 90-95 part,
Pigment 4-10 part;
Component and the weight proportion thereof of described surface layer slurry comprise:
Component and the weight proportion thereof of described base pastes comprise:
According to a kind of preferred embodiment of third aspect of the present invention, wherein, in described step 8, described temperature is preferably 20-50 DEG C, and described curing time is preferably 12-24 hour.
According to a kind of preferred embodiment of third aspect of the present invention, wherein, in described step 8, described surface treatment comprise in polishing, polishing, ball blast any one or a few.
The present invention utilizes the hydroxide ion in amphoteric metal and cement to react generation gas, and gas is trapped in slurry in expansion process, forms hole on slip surface.The MULTILAYER COMPOSITE artificial hole stone slab not only good decorating effect that the present invention produces, have extremely strong expressive force, hole size, hole layout and superficial makings all can regulate according to the demand of client, and have the feature of lightweight, cracking resistance.In addition, compared with prior art, it is convenient that preparation method of the present invention produces, and can effectively save production cost, and has very strong operability.
Detailed description of the invention
First aspect present invention provides a kind of artificial hole stone slab composition of MULTILAYER COMPOSITE, it is characterized in that, described artificial hole stone slab composition comprises surface layer composition, middle enhancement Layer and base pastes:
Described middle enhancement Layer is alkaline-resisting grid cloth;
Described surface layer composition comprises surface layer mill base, amphoteric metal and surface layer slurry;
Wherein, the component of described surface layer mill base and weight proportion thereof comprise:
Binder Materials 90-95 part,
Pigment 4-10 part;
Wherein, the component of described surface layer slurry and weight proportion thereof comprise:
Wherein, the component of described base pastes and weight proportion thereof comprise:
Second aspect present invention provides a kind of artificial hole stone slab of the MULTILAYER COMPOSITE prepared by composition described in claim 1, it is characterized in that, described artificial hole stone slab comprises surface layer, middle enhancement Layer and bottom:
Described middle enhancement Layer is alkaline-resisting grid cloth, between described surface layer and bottom;
Described surface layer is the preparation of described surface layer composition, comprise color top layer prepared by described surface layer mill base and surface layer basic unit prepared by described surface layer slurry, described surface layer basic unit and color top layer contact portion react containing described amphoteric metal and described surface layer mill base, surface layer slurry the hole formed at least partly.
Third aspect present invention provides the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE described in a kind of second aspect theme, and described preparation method comprises:
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: the component of surface layer mill base, surface layer slurry and base pastes and weight proportion preparation surface layer mill base, surface layer slurry and base pastes according to first aspect;
Step 3: described surface layer mill base is coated on described die surface;
Step 4: amphoteric metal is spread on described surface layer mill base;
Step 5: described surface layer slurry is built in described mould;
Step 6: alkaline-resisting grid cloth is laid on described surface layer slurry;
Step 7: described base pastes is cast on described alkaline-resisting grid cloth;
Step 8: maintenance is after at least 10 hours under 10-100 DEG C of temperature conditions, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
Below for the artificial hole stone slab of MULTILAYER COMPOSITE provided by the invention and composition and method of making the same thereof, the technical scheme of described artificial hole stone slab and composition and method of making the same thereof is described in detail, to explain the present invention better.
embodiment 1
One, the component of surface layer mill base, surface layer slurry and base pastes and weight proportion thereof
(1) component of surface layer mill base and weight proportion thereof comprise:
Portland cement 95 parts;
Pigment lemon yellow 5 parts.
(2) component of surface layer slurry and weight proportion thereof comprise:
(3) component of base pastes and weight proportion thereof comprise:
Two, the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: put in mixer after each component of Binder Materials, pigment, aggregate, mineral admixture, polymeric additive is weighed by above-mentioned weight proportion, mix appropriate water, preparation surface layer mill base, surface layer slurry and base pastes are for subsequent use;
Step 3: the surface layer mill base prepared is coated on described die surface;
Step 4: 20-40 order aluminium foil is spread on described surface layer mill base according to customer demand pattern;
Step 5: the surface layer slurry prepared is built in described mould;
Step 6: the alkaline-resisting grid cloth cut in advance is laid on described surface layer slurry;
Step 7: the base pastes prepared is cast on described alkaline-resisting grid cloth;
Step 8: under 20-50 DEG C of temperature conditions after maintenance 12-24 hour, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
embodiment 2
One, the component of surface layer mill base, surface layer slurry and base pastes and weight proportion thereof
(1) component of surface layer mill base and weight proportion thereof comprise:
Portland cement 95 parts;
Pigment iron oxide red 4 parts;
Pigment iron oxide black 1 part.
(2) component of surface layer slurry and weight proportion thereof comprise:
(3) component of base pastes and weight proportion thereof comprise:
Two, the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: put in mixer after each component of Binder Materials, pigment, aggregate, mineral admixture, polymeric additive is weighed by above-mentioned weight proportion, mix appropriate water, preparation surface layer mill base, surface layer slurry and base pastes are for subsequent use;
Step 3: the surface layer mill base prepared is coated on described die surface;
Step 4: 20-40 order aluminium foil is spread on described surface layer mill base according to customer demand pattern;
Step 5: the surface layer slurry prepared is built in described mould;
Step 6: the alkaline-resisting grid cloth cut in advance is laid on described surface layer slurry;
Step 7: the base pastes prepared is cast on described alkaline-resisting grid cloth;
Step 8: under 20-50 DEG C of temperature conditions after maintenance 12-24 hour, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
embodiment 3
One, the component of surface layer mill base, surface layer slurry and base pastes and weight proportion thereof
(1) component of surface layer mill base 1 and weight proportion thereof comprise:
Portland cement 95 parts,
Pigment lemon yellow 5 parts;
Component and the weight proportion thereof of surface layer mill base 2 comprise:
Portland cement 95 parts,
Orange 5 parts of pigment.
(2) component of surface layer slurry and weight proportion thereof comprise:
(3) component of base pastes and weight proportion thereof comprise:
Two, the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: put in mixer after each component of Binder Materials, pigment, aggregate, mineral admixture, polymeric additive is weighed by above-mentioned weight proportion, mix appropriate water, preparation surface layer mill base 1 and surface layer mill base 2, surface layer slurry and base pastes for subsequent use;
Step 3: the surface layer mill base 1 prepared and surface layer mill base 2 are coated on described die surface according to particular texture;
Step 4: 30 ~ 60 order aluminium foils are spread on described surface layer mill base according to customer demand pattern;
Step 5: the surface layer slurry prepared is built in described mould;
Step 6: the alkaline-resisting grid cloth cut in advance is laid on described surface layer slurry;
Step 7: the base pastes prepared is cast on described alkaline-resisting grid cloth;
Step 8: under 20-50 DEG C of temperature conditions after maintenance 12-24 hour, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
Artificial hole stone prepared by above-mentioned 3 embodiments, compared with the conventional method, having method uniqueness, produce feature that is flexible, with low cost, simple to operate, good decorating effect, is a kind of external wall decorative material of higher gears.
Be described in detail specific embodiments of the invention above, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.

Claims (10)

1. an artificial hole stone slab composition for MULTILAYER COMPOSITE, is characterized in that, described artificial hole stone slab composition comprises surface layer composition, middle enhancement Layer and base pastes:
Described middle enhancement Layer is alkaline-resisting grid cloth;
Described surface layer composition comprises surface layer mill base, amphoteric metal and surface layer slurry;
Wherein, the component of described surface layer mill base and weight proportion thereof comprise:
Binder Materials 90-95 part,
Pigment 4-10 part;
Wherein, the component of described surface layer slurry and weight proportion thereof comprise:
Wherein, the component of described base pastes and weight proportion thereof comprise:
2. the artificial hole stone slab composition of MULTILAYER COMPOSITE according to claim 1, is characterized in that, described amphoteric metal comprise in aluminium foil, aluminium bits, aluminium wire any one or a few.
3. the artificial hole stone slab composition of MULTILAYER COMPOSITE according to claim 1, is characterized in that, described Binder Materials comprise in portland cement, aluminate cement, sulphate aluminium cement, lime, gypsum any one or a few.
4. the artificial hole stone slab composition of MULTILAYER COMPOSITE according to claim 1, is characterized in that, described aggregate comprise in natural colour sand, artificial color sand, river sand any one or a few.
5. the artificial hole stone slab composition of MULTILAYER COMPOSITE according to claim 1, it is characterized in that, described aggregate is 20-120 order.
6. the artificial hole stone slab composition of MULTILAYER COMPOSITE according to claim 1, is characterized in that, described mineral admixture comprise in flyash, breeze, stone flour, volcanic ash, silica flour any one or several.
7. an artificial hole stone slab for the MULTILAYER COMPOSITE prepared by composition described in claim 1, is characterized in that, described artificial hole stone slab comprises surface layer, middle enhancement Layer and bottom:
Described middle enhancement Layer is alkaline-resisting grid cloth, between described surface layer and bottom;
Described surface layer is the preparation of described surface layer composition, comprise color top layer prepared by described surface layer mill base and surface layer basic unit prepared by described surface layer slurry, described surface layer basic unit and color top layer contact portion react containing described amphoteric metal and described surface layer mill base, surface layer slurry the hole formed at least partly.
8. a preparation method for the artificial hole stone slab of MULTILAYER COMPOSITE described in claim 7, it is characterized in that, described preparation method comprises:
Step 1: prepare mould, and injector surface is for subsequent use;
Step 2: the component of surface layer mill base, surface layer slurry and base pastes and weight proportion preparation surface layer mill base, surface layer slurry and base pastes according to claim 1;
Step 3: described surface layer mill base is coated on described die surface;
Step 4: amphoteric metal is spread on described surface layer mill base;
Step 5: described surface layer slurry is built in described mould;
Step 6: alkaline-resisting grid cloth is laid on described surface layer slurry;
Step 7: described base pastes is cast on described alkaline-resisting grid cloth;
Step 8: maintenance is after at least 10 hours under 10-100 DEG C of temperature conditions, through the demoulding and surface treatment, namely obtains the artificial hole stone slab of MULTILAYER COMPOSITE.
9. the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE according to claim 8, it is characterized in that, in described step 8, described temperature is 20-50 DEG C, and described curing time is 12-24 hour.
10. the preparation method of the artificial hole stone slab of MULTILAYER COMPOSITE according to claim 8, is characterized in that, in described step 8, described surface treatment comprise in polishing, polishing, ball blast any one or a few.
CN201410659466.2A 2014-11-18 2014-11-18 The artificial hole stone slab of a kind of MULTILAYER COMPOSITE and combinations thereof thing and preparation method thereof Active CN104441820B (en)

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CN105086698A (en) * 2015-07-31 2015-11-25 上海古猿人石材有限公司 Method for producing flexible finish material
CN106812277A (en) * 2017-01-25 2017-06-09 张建中 A kind of artificial hole stone heat insulation decoration integrated plate and preparation method thereof
CN116835913A (en) * 2023-07-05 2023-10-03 江苏百代节能建材有限公司 Light high-strength soft stone brick and preparation method thereof

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CN103755278A (en) * 2013-12-30 2014-04-30 上海古猿人石材有限公司 Artificial ecological stone slab for decoration and preparation method thereof
CN104402492A (en) * 2014-11-18 2015-03-11 上海古猿人石材有限公司 Nature-imitated travertine as well as composition and manufacture method thereof

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CN105086698A (en) * 2015-07-31 2015-11-25 上海古猿人石材有限公司 Method for producing flexible finish material
CN105086698B (en) * 2015-07-31 2017-07-25 上海古猿人石材有限公司 A kind of production method of flexible finishing material
CN106812277A (en) * 2017-01-25 2017-06-09 张建中 A kind of artificial hole stone heat insulation decoration integrated plate and preparation method thereof
CN116835913A (en) * 2023-07-05 2023-10-03 江苏百代节能建材有限公司 Light high-strength soft stone brick and preparation method thereof
CN116835913B (en) * 2023-07-05 2023-12-19 江苏百代节能建材有限公司 Light high-strength soft stone brick and preparation method thereof

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