CN104430323A - Controlled-release pesticide granules - Google Patents
Controlled-release pesticide granules Download PDFInfo
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- CN104430323A CN104430323A CN201410688352.0A CN201410688352A CN104430323A CN 104430323 A CN104430323 A CN 104430323A CN 201410688352 A CN201410688352 A CN 201410688352A CN 104430323 A CN104430323 A CN 104430323A
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Abstract
The invention discloses controlled-release pesticide granules prepared from natural or industrial and agricultural waste organic and inorganic materials and a bonder. The controlled-release pesticide granules are spherical or elliptical; a spherical body comprises a core layer and a wrapper layer; the core layer is made from a mixture of an organic matter, an inorganic matter and a pesticide active component; the wrapper layer is made from an organic material. The controlled-release pesticide granules are an environment-friendly product and can be widely applied to prevention and control of agricultural pests.
Description
Technical field
The present invention relates to a kind of sustained releasing pesticide granule and preparation method thereof, particularly, this sustained releasing pesticide granule in spherical shape or ellipsoid shape, spheroid divide sandwich layer and integument two-layer, sandwich layer is organic matter, inanimate matter and pesticide activity component mixture, and integument is organic material.Sustained-release pesticides preparation method of granules is: the absorption carrier of first preparation organic matter and inanimate matter mixing; Then, pesticide activity component is adsorbed on mixture carrier, with adhesive, above-mentioned organic matter and inanimate matter material is bonded into sandwich layer; Finally, the sandwich layer of preparation is wrapped up organic material and obtains integument, obtain sustained releasing pesticide granule.
This sustained releasing pesticide granule organic matter used, inanimate matter material and the adhesive overwhelming majority is natural materials or agriculture and industry waste, and prepared pesticide slow-release granule is environmentally friendly product, can be widely used in the control of agricultural pest.
Background technology
Sustained-release pesticides refers to according to damage by disease and insect pests occurrence rule, feature and environmental condition, is made agricultural chemicals dosage as required, specific time by manufacturing process, is discharged sustainedly and stably, to reach economic, safety, effectively disease and pest control object.Sustained releasing pesticide granule refers to and to be adsorbed in by pesticide original medicine on the organic and inorganic carrier of porous, wrap up with adhesive, adhesive is bonded into organic and inanimate matter raw material the particle of certain diameter simultaneously, final formation have necessarily wrap up intensity, can the granule of Co ntrolled release agricultural chemicals speed.Pesticide activity component in particle by dissolving, permeating and diffusion, slowly release, and rate of release can be controlled by regulating amount of binder, kind and a particle size etc.Sustained-release pesticides has following advantage: (1) the releasing dosage of sustained-release pesticides and time can control, and the functional of medicament is improved; (2) sustained-release pesticides is owing to there being the parcel of adhesive, and agricultural chemicals is degraded in the environment, loss speed reduces greatly, effectively can extend the lasting period of medicament, reduces the usage amount of agricultural chemicals; (3) sustained-release pesticides can Co ntrolled release, makes that high toxicity agricultural chemicals is low to be poisoned, and avoids or alleviate the pollution of high-toxic pesticide to environment.
Agriculturally sustained releasing pesticide granule used contains a large amount of chemical industry additive at present, if prolonged application is in farmland, certain risk can be caused to agricultural product security, the present invention is directed to this problem, large absolutely number material selection natural materials or agriculture and industry waste, the sustained releasing pesticide granule of preparation is environmentally friendly product.
Summary of the invention
Sustained releasing pesticide granule of the present invention, its feature is: be spherical or ellipsoid shape.Spheroid divide sandwich layer and integument two-layer, sandwich layer is inanimate matter, organic matter and pesticide activity component mixture, and integument is organic material.Sphere diameter: sandwich layer diameter is 1-20mm, integument thickness is 0.5-5mm.
Organic matter comprises: in straw, fowl and animal excrement, wood chip, sawdust, tobacco leftovers, Chinese herbal medicine offcuts, vinasse, bagasse one or more.
Inanimate matter comprises: in flyash, zeolite, clay brick powder, diatomite, bentonite, potter's clay, charcoal, opal, lime stone, dolomite one or more.
Adhesive comprises: sodium alginate, starch, gum Arabic, urea-formaldehyde glue, epoxy glue, hide glue, gelatine one or several.
Pesticide activity component comprises: the one in insecticide, bactericide, miticide, nematocide, weed killer herbicide or plant growth regulator or two or more.
Sustained releasing pesticide granule preparation method of the present invention, comprises the following steps:
(1) prepare absorption carrier, inanimate matter and organic raw material are dried respectively, pulverize, mixed as absorption carrier;
(2) pesticide activity component is adsorbed on carrier, pesticide active ingredient wiring solution-forming is sprayed on absorption carrier, and stirs, dry for standby;
(3) prepare sandwich layer, adhesive is melted into liquid state, be sprayed on the (2) prepared carrier containing pesticide activity component of step with Sprayable, sandwich layer be prepared into 1-20mm diameter particle by comminutor, dry for standby;
(4) prepare integument, adhesive is melted into liquid state, be sprayed on the (3) described sandwich layer of step with Sprayable, wrap up organic material, organic material thickness 0.5-5mm, dries and obtains pesticide slow-release granule;
The ratio of organic matter, inanimate matter in sustained releasing pesticide granule sandwich layer of the present invention, organic matter/inanimate matter is from 10/1 to 1/10, is preferably 5/1 to 1/5, then is preferably 2/1 to 1/2.
The present invention with organic and inanimate matter mixture for core, inanimate matter material hole is many, adsorptivity dose is large, but water proofing property is poor, organic materials adsorption is weaker than inanimate matter material, but water proofing property is relatively good, both mixing reach the effect of the absorption of balance agricultural chemicals and release, the organic material of sandwich layer outer wrapping one deck, further guarantee pesticide activity component slow releasing, in soil, reaches the result extending drug effect.
The present invention proves through overtesting, and slow-releasing granules can effectively extend the farm chemical release phase, reduces unit interval burst size, serves the effect of sustained-release pesticides active substance.
Raw material of the present invention easily obtain, and cost is low, and slow-releasing granules preparation method is simple, and suit large area to popularize use.
Accompanying drawing explanation
Fig. 1 spherical shape sustained releasing pesticide granule structure.
Fig. 2 ellipsoid shape sustained releasing pesticide granule structure.
Fig. 3 Imidacloprid sustained-release granular formulation release rate profile figure.
Embodiment
Embodiment 1: prepare benzene first Fluoxastrobin sustained-release granular formulation
Sawdust/flyash (ratio 1/1) 1Kg
Sawdust 200g
Benzene first Fluoxastrobin (12.5% Difenoconazole, 20% Fluoxastrobin) missible oil 100mL
Starch 200g
Water 1Kg
(1) sawdust, flyash respectively get 500g, and remove impurity, 60 DEG C of oven dry, then two kinds of materials are mixed by ground 50 mesh sieves;
(2) benzene first Fluoxastrobin (12.5% Difenoconazole, 20% Fluoxastrobin) missible oil is sprayed on sawdust and flyash with Sprayable, fully mixes, 60 DEG C of dry for standby;
(3) getting 200g starch adds in 1kg water, 80 DEG C of gelatinizations 1 hour;
(4) on comminutor, the starch solution of gelatinization is sprayed on the (2) described sawdust of step and flyash, is prepared into the spherical sandwich layer of 1-20mm, 60 DEG C of dry for standby;
(5) continue to spray the good starch solution of gelatinization to the sandwich layer of drying on comminutor, add 200g sawdust powder, prepare integument, integument thickness 0.5-5mm, 60 DEG C of oven dry;
(6) obtain benzene first Fluoxastrobin sustained-release granular formulation.
Embodiment 2: prepare Imidacloprid sustained-release granular formulation
Rice straw powder/clay brick powder (ratio 1/2) 0.9Kg
Rice straw powder 200g
Imidacloprid (60% active ingredient) missible oil 100mL
Gum Arabic 200g
Water 1Kg
(1) rice straw, clay brick powder are removed impurity, 60 DEG C of oven dry, ground 50 mesh sieves, then get 300g rice straw powder respectively, 600g clay brick powder mix;
(2) Imidacloprid (60% active ingredient) missible oil is sprayed on the (1) described rice straw powder of step and clay brick powder with Sprayable, fully mix, 60 DEG C of dry for standby;
(3)getting 200g gum Arabic adds in 1kg water, and 80 DEG C are heated 1 hour;
(4)gumwater is sprayed at by comminutor on the (2) described rice straw powder of step and clay brick powder, is prepared into the spherical sandwich layer of 1-20mm, 60 DEG C of dry for standby;
(5)continue to spray gumwater to the sandwich layer of drying on comminutor, add 200g rice straw powder, prepare integument, integument thickness 0.5-5mm, 60 DEG C of oven dry;
(6) obtain Imidacloprid sustained-release granular formulation.
Embodiment 3: prepare thiophene sulphur Acetochlor sustained-release granular formulation
Vinasse/Chinese herbal medicine offcuts/bentonite (ratio 1/1/3) 1.0Kg
Rice straw powder 200g
Thiophene sulphur Acetochlor (0.3% thifensulfuron methyl, 49.7% Acetochlor) missible oil 300mL
Gum Arabic/sodium alginate (ratio 1/1) 200g
Water 1Kg
(1) rice straw, vinasse, Chinese herbal medicine offcuts, bentonite are removed impurity, 60 DEG C of oven dry, ground 50 mesh sieves, then get 200g vinasse respectively, 200g Chinese herbal medicine offcuts, 600g bentonite mix;
(2) thiophene sulphur Acetochlor (0.3% thifensulfuron methyl, 49.7% Acetochlor) missible oil is sprayed on the (1) described vinasse/Chinese herbal medicine offcuts/bentonite mixtures of step with Sprayable, fully mix, 60 DEG C of dry for standby;
(3) getting 200g gum Arabic/sodium alginate (ratio 1/1) adds in 1kg water, and 80 DEG C are heated 1 hour;
(4) on comminutor, gum Arabic/sodium alginate soln is sprayed at step 2) described in vinasse/Chinese herbal medicine offcuts/bentonite mixtures on, be prepared into the spherical sandwich layer of 1-20mm, 60 DEG C of dry for standby;
(5) continue to spray gum Arabic/sodium alginate soln to the sandwich layer of drying on comminutor, add 200g rice straw powder, prepare integument, integument thickness 0.5-5mm, 60 DEG C of oven dry;
(6) obtain thiophene sulphur Acetochlor sustained-release granular formulation.
Embodiment 4: preparation Avermectin sustained-release granular formulation
Sawdust/vinasse/Chinese herbal medicine offcuts/clay brick powder (ratio 1/1/1/2) 1.0Kg
Sawdust 200g
Avermectin (5% active ingredient) missible oil 100mL
Starch 200g
Water 1Kg
(1) sawdust, vinasse, Chinese herbal medicine offcuts, clay brick powder are removed impurity, 60 DEG C of oven dry, ground 50 mesh sieves, then get 200g sawdust respectively, 200g vinasse, 200g Chinese herbal medicine offcuts, 400g clay brick powder mix;
(2) Avermectin (5% active ingredient) missible oil is sprayed on the (1) described sawdust/vinasse/Chinese herbal medicine offcuts/clay brick powder mixture of step with Sprayable, fully mix, 60 DEG C of dry for standby;
(3) getting 200g starch adds in 1kg water, 80 DEG C of Heat Gelatinization 1 hour;
(4) on comminutor, the starch solution that gelatinization is good is sprayed on the (2) described sawdust/vinasse/Chinese herbal medicine offcuts/clay brick powder mixture of step, is prepared into the spherical sandwich layer of 1-20mm, 60 DEG C of dry for standby;
(5) the sandwich layer continuing oven dry (4) described to step on comminutor sprays the good starch solution of gelatinization, adds 200g rice straw powder, prepares integument, integument thickness 0.5-5mm, 60 DEG C of oven dry;
(6) obtain Avermectin sustained-release granular formulation.
Embodiment 5: carbosulfan sustained-release granular formulation
Tobacco leftovers/limestone powder (ratio 1/4) 1.0Kg
Tobacco leftovers 200g
Carbosulfan (20% active ingredient) missible oil 100mL
Gum Arabic 200g
Water 1Kg
(1) tobacco leftovers, limestone powder are removed impurity, 60 DEG C of oven dry, ground 50 mesh sieves, then get 200g tobacco leftovers respectively, 800g limestone powder mix;
(2) carbosulfan (20% active ingredient) missible oil is sprayed on the (1) described tobacco leftovers/limestone powder mixture of step with Sprayable, fully mix, 60 DEG C of dry for standby;
(3) getting 200g gum Arabic adds in 1kg water, 80 DEG C of heating for dissolving 1 hour;
(4) on comminutor, gumwater is sprayed on the (2) described tobacco leftovers/limestone powder mixture of step, is prepared into the spherical sandwich layer of 1-20mm, 60 DEG C of dry for standby;
(5) the sandwich layer continuing oven dry (4) described to step on comminutor sprays the good gumwater of gelatinization, adds 200g tobacco leftovers powder, prepares integument, integument thickness 0.5-5mm, 60 DEG C of oven dry;
(6) obtain carbosulfan sustained-release granular formulation.
Example 6: sustained releasing pesticide granule washing tests
Get the above-mentioned 10g Imidacloprid sustained-release granular formulation prepared and put into the flowerpot that soil is housed, after granule is embedded with soil, constantly carry out drip washing to soil with flowing water, water velocity controls at 20mL/min, collect a leacheate at regular intervals, measure the content of Imidacloprid in leacheate.To be sprayed directly in soil after the dilution of 0.1mL Imidacloprid missible oil, carry out washing tests as a control group after embedding, water velocity controls equally at 20mL/min, collects a leacheate at regular intervals, measures the content of Imidacloprid in leacheate.Imidacloprid rate of release is in table 1, and release rate profile figure is shown in Fig. 3.
Table 1
Claims (6)
1. a sustained releasing pesticide granule, it is characterized in that: sustained-release pesticides particle is spherical or ellipsoid shape, spheroid (with upper sphere and spheroid for different concepts) comprises two-layer: sandwich layer and integument, sandwich layer is inanimate matter, organic matter and pesticide activity component mixture, and integument is organic material.
2. sustained releasing pesticide granule according to claim 1, is characterized in that: preparation method comprises the following steps
(1) inanimate matter and organic raw material are dried respectively, pulverize, mixed as absorption carrier;
(2) pesticide activity component is adsorbed on the (1) described absorption carrier of step;
(3) with adhesive, the carrier being adsorbed with pesticide activity component that step is (2) described is made spherical particle, dry for standby, as sandwich layer;
(4) with adhesive, the sandwich layer that step is (3) described is wrapped up the organic material of one deck, obtain integument, dry and obtain sustained-release pesticides particle.
3. sustained releasing pesticide granule according to claim 1, is characterized in that: described organic matter material be in straw, fowl and animal excrement, wood chip, sawdust, tobacco leftovers, Chinese herbal medicine offcuts, vinasse, bagasse one or more.
4. sustained releasing pesticide granule according to claim 1, is characterized in that: described inanimate matter raw material be in flyash, zeolite, clay brick powder, diatomite, bentonite, potter's clay, charcoal, opal, lime stone, dolomite one or more.
5. sustained releasing pesticide granule according to claim 1, is characterized in that: described pesticide activity component is one in insecticide, bactericide, miticide, nematocide, weed killer herbicide or plant growth regulator or two or more.
6. sustained releasing pesticide granule preparation method according to claim 2, is characterized in that: described adhesive be sodium alginate, starch, gum Arabic, urea-formaldehyde glue, epoxy glue, hide glue, gelatine one or several.
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CN105854798A (en) * | 2016-04-14 | 2016-08-17 | 中国农业科学院植物保护研究所 | Preparing method for biochar and method for loading imidacloprid on biochar |
CN106035322A (en) * | 2016-05-25 | 2016-10-26 | 广西南宁农事帮农业科技服务有限公司 | Controlled-release pesticide granules and preparation method therefor |
CN106187643A (en) * | 2016-07-26 | 2016-12-07 | 华中农业大学 | The organic embedded object of straw and function bacterium is utilized to prepare method and the product of organo-mineral complexing Controlled Release Fertilizer |
CN106479512A (en) * | 2016-10-11 | 2017-03-08 | 山东农业大学 | A kind of soil conditioner that can prevent and treat plant roots area hydrops disease |
CN106518502A (en) * | 2016-12-30 | 2017-03-22 | 北京中农富源生物工程技术有限公司 | Plant sendanin slow-release fertilizer, and preparation method and application thereof |
CN106614553A (en) * | 2016-11-08 | 2017-05-10 | 长安大学 | Pesticide slow-release agent and preparation method thereof |
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CN107183019A (en) * | 2017-06-01 | 2017-09-22 | 华中农业大学 | A kind of compound bio charcoal base carrier and preparation method and application with pesticide slow-release performance |
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CN108174876A (en) * | 2018-01-30 | 2018-06-19 | 安徽省厚博生态农业有限公司 | A kind of booth vegetable slow-release compound disinfectant and its preparation |
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CN109601533A (en) * | 2019-01-29 | 2019-04-12 | 刘宏波 | A kind of slow controlled release granular pesticide and preparation method thereof |
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CN110563510A (en) * | 2019-09-30 | 2019-12-13 | 中国有色桂林矿产地质研究院有限公司 | potassium fertilizer loaded slow-release degradable porous material and preparation method thereof |
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