CN104419773A - Household leather product dedicated soft sterilizing nursing agent - Google Patents

Household leather product dedicated soft sterilizing nursing agent Download PDF

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Publication number
CN104419773A
CN104419773A CN201310378199.7A CN201310378199A CN104419773A CN 104419773 A CN104419773 A CN 104419773A CN 201310378199 A CN201310378199 A CN 201310378199A CN 104419773 A CN104419773 A CN 104419773A
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CN
China
Prior art keywords
nursing agent
leather
leathercraft
proportionally
embryo
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Pending
Application number
CN201310378199.7A
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Chinese (zh)
Inventor
王海玲
崔瑛
程盼盼
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Qingdao Medical Prevention Disinfection Professional Technology Center
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Qingdao Medical Prevention Disinfection Professional Technology Center
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Application filed by Qingdao Medical Prevention Disinfection Professional Technology Center filed Critical Qingdao Medical Prevention Disinfection Professional Technology Center
Priority to CN201310378199.7A priority Critical patent/CN104419773A/en
Publication of CN104419773A publication Critical patent/CN104419773A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44Guanidine; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/08Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing boron
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention relates to a household leather product dedicated soft sterilizing nursing agent; the nursing agent is prepared by compounding main soft sterilizing components comprising a organosilicon quaternary ammonium salt, chitosan, sodium alginate, water lily embryo gel and other biological nourishing components with glycerol through a special process, is mainly used for being sprayed on the surface of family leather products especially leather clothing and leather bags, so as to achieve the effects of dispelling mold and softening leather texture, also has a long-term antibacterial effect. The nursing agent has the following characteristics: (1) the biological type leather product dedicated nursing agent is strong in permeability, and keeps the leather products soft and nutritious for a long time; (2) the nursing agent has obvious sterilization and mildew-proof effects and resists bacteria for a long time, and sterilizing components have no harm to the leather products; (3) the nursing agent penetrates into deep parts of pores of the leather products, has high adhesion, does not block the pores of the leather products, and does not generate a hardening phenomenon; and (4) the nursing agent increases brightness and smoothness of the leather products, is simple to use, has no need of high temperature and high pressure, and is suitable for family use.

Description

The degerming nursing agent of the special softness of family expenses leathercraft
technical fieldthe present invention relates to the degerming nursing agent of the special softness of a kind of family expenses leathercraft, the degerming composition of main softness is that the biological nourishing composition such as organosilicon quaternary ammonium salt, chitosan, sodium alginate, water lily embryo gel and glycerine are composite, through the degerming nursing agent of softness of special manufacture technics, be mainly used in being sprayed in family the surface of leatherware particularly fur clothing, suitcase, thus reach the effect of dispelling mould, soft cortex, play permanent anti-microbial effect simultaneously.Along with increasing of the level of consumption, pure leathercraft more and more admit by human consumer, its wear-resisting and class makes human consumer more and more like, a pure skin fur clothing or suitcase can use 3 or four years, but can find for the leathercraft used in family, if after summer deposits, the surface of fur clothing will increase the thick mould of one deck to the fur clothing in winter from after wardrobe is taken out the coming year, particularly some in summer humidity the city by seashore, fur clothing is very easy to increase mould.Mouldy leathercraft feel will be hardened, and loses the soft feature that leathercraft itself has, also have some suitcases, belt, leather sheath use of a specified duration after due to external environment daylight, wind or drench with rain leathercraft all can be made to harden.Therefore, leathercraft use softness and degerming product be the eager demands of people.Softening agent kind on market is very many, mainly be divided into chain alkyl positively charged ion, zwitter-ion and anion surfactant, seldom be used alone nonionogenic tenside, mostly these softening agents are for the nursing of leather nursing laundry to leathercraft, the nursing agent kind used for family is fewer, and wherein not containing degerming composition, can not reach degerming and effect that is nappa goods simultaneously, and absorb slow, need the particular surroundings such as high temperature or constant temperature, the leathercraft nursing for mouldy in family, long bacterium is very inapplicable.It is therefore, a kind of that to be suitable for softness, degerming leathercraft special caring agent that family uses be the eager demands of people.Biology of the present invention moistens, softening compositions, can permeate the pore depths in leathercraft rapidly, supplements the nutrients and moisture, recovers softness and the elasticity of leathercraft, reaches the degerming and permanent anti-microbial effect to leathercraft simultaneously.
background technologythe most basic maintenance of leathercraft is exactly mildew-resistant, degerming, and in daily life, leathercraft grow mold is problem the most common, will affect the pliability of leathercraft after long bacterium, makes it lose initial softness and smooth.And mostly the method for the maintenance leathercraft used in average family is to adopt the skin care oil product used in daily life, it is directly applied in the surface of leathercraft, the feature of oiliness skin-protection product is utilized to carry out moist leathercraft, make its brightness that is more smooth and increase leathercraft, although this method uses simple, cost is also lower, if but access times too much after, the blocking of leathercraft pore will be caused, form the thick film of one deck on its surface, softening object can not be played; Although the softening agent used for leathercraft nursing shop can play efficient soft effect, but it is not obvious for mould-proof bacteria-removing effect, wardrobe put into by the fur clothing worn for north of china in winter, leather shoes after nursing will produce thick mould through fur clothing in a summer surface, and give out the smell of " mouldy ", people can not normally be worn.Therefore, a kind of be applicable to that average family uses have again degerming mildew-resistant to the existing soft effect of leathercraft, the degerming nursing agent of the special softness of family expenses leathercraft of long-term antibacterial effect is the eager demands of people.Object of the present invention is just to provide a easy to use, integrate degerming, mildew-resistant, the soft degerming nursing spray of the special softness of family's leathercraft, and reach permanent anti-microbial effect.
summary of the inventionmain points of the present invention are having nourishing, the natural cytokines composition of degermation is used in leather nursing, have absorb quick, degerming rate high, spray simple feature.The formula that the present invention selects is following (component and weight percent % thereof): organosilicon quaternary ammonium salt 4.0-6.0, chitosan 2.0-4.0, sodium alginate 1.0-2.0, polyhexamethylene guanidine 0.8-1.2, water lily embryo gel 15.0-17.0, sea grass polysaccharide 3.0-7.0, glycerine 2.0-5.0, purifying waste water adds to 100.
Organosilicon quaternary ammonium salt is the comparatively ideal antiseptic-germicide of a class over-all properties, is widely used in the world, obtains after utilizing silane and quaternary ammonium salt combination reaction.It has high temperature resistant, water-fastness, lasting effect, and scope of restraining fungi is wide, effectively can suppress the growth of gram-positive microorganism, Gram-negative bacteria, yeast and fungi.98.12 %, 96.86 %, 95.14 % are reached respectively to the bacteriostasis rate after streptococcus aureus, intestinal bacteria and candida albicans 24 h, demonstrate broad-spectrum antimicrobial effect and higher antibiotic rate and safety non-toxic, without causing enzyme reaction.The bacterium of its sterilization mechanism mainly quarternary ammonium salt compound energy adsorption zone negative charge, stops the normal growing system of bacterium and propagating system, thus reaches comprehensive germicidal action.And organosilicon quaternary ammonium salt has the advantages that to increase flexibility, conjunctiva stability, is used in the nursing of leathercraft, leathercraft more softness, high resilience can be made, reach the effect of mildew-resistant simultaneously.
The polysaccharide that chitosan is made up of glucosamine and n acetylglucosamine n polymkeric substance, it can be deacetylated and obtain by the chitosan moiety in crust.It is a kind of bioactive ingredients with high-efficiency antimicrobial, nourishing effect, for the saturating mucosal absorption of polar micromolecules and peptide class and pharmaceutical grade protein can be promoted in the nursing of leathercraft, increase leathercraft to the absorption of nutritive ingredient, by composite to itself and the sodium alginate with the high viscosity adhesivity that can strengthen chitosan afterwards, make it better be attached to the surface of leathercraft, reduce the injury of leathercraft by external environment; Simultaneously chitosan has efficient nourishing effect, is often used to the maintenance action of human body skin, therefore in the maintenance of leathercraft, can increase the pliability of leathercraft and permanent moisturizing; And chitosan has permanent bacteriostatic action, the growth of common bacteria can be suppressed, prevent and treat the mouldy of leathercraft.The simultaneously interpolation of sodium alginate can stablize the system of this formula, the transparency of increase system, avoids the generation of layering, precipitation and particle.
Water lily embryo gel is the nutritive ingredient with viscosity and adhewsive action extract from the embryo of water lily, main containing alkaloid and flavonoid component, the results showed: to the skin of human body, there is strong, the permanent moisturizing of perviousness, nourishing and moistening effect.Therefore, mainly play in the maintenance of leathercraft hardening, the nourishing effect of coarse leathercraft; Simultaneously because water lily has clearing heat and detoxicating effect in the traditional Chinese medical science, permanent drying and antibacterial effect can be played in its surface being sprayed on leathercraft.
Sea grass polysaccharide is a kind of polysaccharose substance with high viscosity, also has abundant hyaluronic acid and aminosugar compound, has effect of efficient nourishing, softening and moisturizing.Because its viscosity ratio is higher, therefore the pore depths being difficult to infiltrate leathercraft with the surface of leathercraft can be adhered to, chitosan and water lily embryo gel then can accelerate it and infiltrate, and the pore depths being stored in leathercraft that thus can be permanent, keeps permanent softness and maintenance action to leathercraft.The anti-microbial effect of sea grass polysaccharide is also obvious simultaneously, all has efficient restraining effect for the fungi such as Candida albicans, mould.
Polyhexamethylene guanidine is the sterilization component of a kind of efficient, wide spectrum, environmental protection, and it is not poisoned human body, and lower concentration does not stimulate skin, does not thus injure leathercraft.Its higher activity and the composite adsorption that can strengthen afterwards bacterium of organosilicon quaternary ammonium salt, increase the osmotic pressure in bacterial film, make its film rupture dead.And the polyhexamethylene guanidine of lower concentration has softening effect to leathercraft, the phenomenon of hardening especially for fur clothing has obvious ramollescence.
The preparation method of product of the present invention is:
(1), by the embryo of water lily after cleaning, use the mode of extruding the effective constituent of embryo to be extruded, after filtration, use lactic acid to regulate PH to be 6, stir;
(2), by Enteromorpha after cleaning, pulverizing, drying, use enzyme extraction method to extract and obtain sea grass polysaccharide;
(3), by proportionally adding in emulsion tank purifying waste water, being heated to 40 DEG C and keeping constant temperature;
(4) be proportionally added in emulsion tank by chitosan powder, be stirred to homogeneous mixture and then use acetic acid to regulate PH to be 6.5, continuing the system that is stirred to is homogeneous transparent shape;
(5), proportionally organosilicon quaternary ammonium salt is added in emulsion tank slowly, stirs;
(6), proportionally sodium alginate, water lily embryo gel, polyhexamethylene guanidine and sea grass polysaccharide are added in emulsion tank according to tandem, stir;
(7), proportionally glycerine is added, regulate PH to be 6.5, stir, go out filling, packing.
The present invention has the following advantages:
(1), the leathercraft special caring agent of biotype, perviousness is strong, permanent softness and the nourishing keeping leathercraft;
(2), degerming, anti-mold effect obvious, for a long time antibacterial, and degerming composition does not injure leathercraft;
(3), infiltrate the pore depths of leathercraft, adhesivity is high, does not block the pore of leathercraft, phenomenon of can not hardening;
(4), increase the brightness of leathercraft and slipperiness, use simple, without the need to high temperature, high pressure, be applicable to family and use.
embodimentbelow in conjunction with embodiment, the present invention is described in further detail:
Be configured according to data listed in Table (weight percent %) and affiliated step thereof:
Formula one:
Organosilicon quaternary ammonium salt 4.0-6.0, chitosan 2.0-4.0, sodium alginate 1.0-2.0, polyhexamethylene guanidine 0.8-1.2, water lily embryo gel 15.0-17.0, sea grass polysaccharide 3.0-7.0, glycerine 2.0-5.0, purifying waste water adds to 100.
Formula two:
Organosilicon quaternary ammonium salt 4.0-5.0, chitosan 2.0-3.0, sodium alginate 1.0-1.5, polyhexamethylene guanidine 0.8-1.0, water lily embryo gel 15.0-16.0, sea grass polysaccharide 3.0-5.0, glycerine 2.0-3.5, purifying waste water adds to 100.
Formula three:
Organosilicon quaternary ammonium salt 5.0-6.0, chitosan 3.0-4.0, sodium alginate 1.5-2.0, polyhexamethylene guanidine 1.0-1.2, water lily embryo gel 16.0-17.0, sea grass polysaccharide 5.0-7.0, glycerine 3.5-5.0, purifying waste water adds to 100.

Claims (2)

1. the present invention relates to the degerming nursing agent of the special softness of family expenses leathercraft, it is characterized in that there is following formula (component and weight percent % thereof): organosilicon quaternary ammonium salt 4.0-6.0, chitosan 2.0-4.0, sodium alginate 1.0-2.0, polyhexamethylene guanidine 0.8-1.2, water lily embryo gel 15.0-17.0, sea grass polysaccharide 3.0-7.0, glycerine 2.0-5.0, purifying waste water adds to 100.
2. the degerming nursing agent of the special softness of family expenses leathercraft according to claim 1, is characterized in that having following step:
(1), by the embryo of water lily after cleaning, use the mode of extruding the effective constituent of embryo to be extruded, after filtration, use lactic acid to regulate PH to be 6, stir;
(2), by Enteromorpha after cleaning, pulverizing, drying, use enzyme extraction method to extract and obtain sea grass polysaccharide;
(3), by proportionally adding in emulsion tank purifying waste water, being heated to 40 DEG C and keeping constant temperature;
(4) be proportionally added in emulsion tank by chitosan powder, be stirred to homogeneous mixture and then use acetic acid to regulate PH to be 6.5, continuing the system that is stirred to is homogeneous transparent shape;
(5), proportionally organosilicon quaternary ammonium salt is added in emulsion tank slowly, stirs;
(6), proportionally sodium alginate, water lily embryo gel, polyhexamethylene guanidine and sea grass polysaccharide are added in emulsion tank according to tandem, stir;
(7), proportionally glycerine is added, regulate PH to be 6.5, stir, go out filling, packing.
CN201310378199.7A 2013-08-28 2013-08-28 Household leather product dedicated soft sterilizing nursing agent Pending CN104419773A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310378199.7A CN104419773A (en) 2013-08-28 2013-08-28 Household leather product dedicated soft sterilizing nursing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310378199.7A CN104419773A (en) 2013-08-28 2013-08-28 Household leather product dedicated soft sterilizing nursing agent

Publications (1)

Publication Number Publication Date
CN104419773A true CN104419773A (en) 2015-03-18

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310378199.7A Pending CN104419773A (en) 2013-08-28 2013-08-28 Household leather product dedicated soft sterilizing nursing agent

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105671223A (en) * 2016-03-03 2016-06-15 广州市迪孚卡乐进出口贸易有限公司 Leather oil cream remover
CN108236723A (en) * 2016-12-27 2018-07-03 中国海洋大学 A kind of composition and its application as coating material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105671223A (en) * 2016-03-03 2016-06-15 广州市迪孚卡乐进出口贸易有限公司 Leather oil cream remover
CN108236723A (en) * 2016-12-27 2018-07-03 中国海洋大学 A kind of composition and its application as coating material

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Application publication date: 20150318

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