CN104419065A - Polypropylene-blended soft infusion bag and preparation method thereof - Google Patents
Polypropylene-blended soft infusion bag and preparation method thereof Download PDFInfo
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- CN104419065A CN104419065A CN201310393309.7A CN201310393309A CN104419065A CN 104419065 A CN104419065 A CN 104419065A CN 201310393309 A CN201310393309 A CN 201310393309A CN 104419065 A CN104419065 A CN 104419065A
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- bag
- styrene
- polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/28—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of blown tubular films, e.g. by inflation
- B29C55/285—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of blown tubular films, e.g. by inflation by using internal mechanical means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
The invention discloses a polypropylene-blended soft infusion bag and a preparation method thereof. The polypropylene-blended soft infusion bag is characterized in that a bag body and an interface formed in the top end of the bag body are formed at one step, and the soft infusion bag is prepared by blending a medical polypropylene copolymer, a styrene-ethylene/butylene-styrene copolymer or a hydrogenated styrene-isoprene-butadiene block copolymer. The preparation method comprises the steps of firstly, carrying out injection molding to form a bag blank; and then, carrying out two-way stretching and blow molding to form a blow-molded medical bag. By using the preparation method, defects of a non-pvc infusion bag are overcome, the raw material of the medical bag does not depend on a foreign non-pvc film any more, and the diversification of the preparation raw material is realized; meanwhile, the bag and the interface are formed at one step, so that the problems of liquid leakage and pollution caused by secondary welding of a non-pvc soft bag and the interface are avoided; and compared with the existing medical bag, the polypropylene-blended soft infusion bag is more transparent, more flexible, low in cost and high in qualified finished product rate and is more adapted to industrial production.
Description
Technical field
The present invention relates to polypropene blended transfusion flexible bag goods and preparation method thereof, particularly relate to and a kind ofly can replace polypropene blended transfusion flexible bag of the soft bag of multi-layer co-extrusion infusion and preparation method thereof, belong to A61J1/10 (2006.01) the I technical field in IPC International Patent Classification (IPC).
Background technology
This product combines all advantages of the transfusion of pp Plastic Bottle and non-PVC soft bag transfusion, due to monomer disposal molding, by bag body and filling oral area disposal molding, form an entirety, only weld with combination cover after filling, without periphery heat-sealing and the welding of mouth pipe, when overcoming the welding of PP TYPE mouth pipe, seepage and the phenomenon of leakage is caused because of the inconsistent generation rosin joint of fusing point, fundamentally solving the international and domestic infusion solutions industry of long-standing problem because of packing technique and technique causes the difficult problem of stealth " Micro blazed-grating " risk, quality product is more guaranteed, and, carry out continuously protecting at hundred grades completely from bag to filling and sealing, decrease link and the pollution brought that infusion bag keeps in because of centre, really accomplish system, fill with, the envelope trinity, product is safer, health, stable, reliably.Achieve safety, stable, continuous, efficient productive target.
Publication number is that the Chinese utility model patent of CN201139760 provides one " blow molding medical bag ", the starting material that this medical bag uses are medical grade polypropylene multipolymer, styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer, adopt hollow blow molding fabrication techniques, comprise bag, bag is provided with filling exit and the suspension ring of protrusion, described bag, filling exit and suspension ring are formed in one structure, solve existing non-PVC material infusion bag Problems existing.But, this technical scheme does not relate to the raw-material concrete composition that medical bag uses further, more detailed disclosure is not carried out to the one-body molded manufacture craft of medical bag, verification is retrieved: about the material and preparation method thereof of blow molded medical bag, do not see more concrete report at home and abroad through the applicant.Therefore, material finding out suitable polypropene blended transfusion flexible bag and preparation method thereof still needs those skilled in the art to make creationary research work further.
Summary of the invention
The object of the invention is to the problems referred to above solving prior art existence, by Improvement repeatedly, give polypropene blended transfusion flexible bag and preparation method thereof, this product is except having with except the advantage of existing medical bag, namely the deficiency of non-PVC material infusion bag is overcome, the raw material of medical bag is made no longer to rely on external non-PVC film, achieve the diversification making raw material, simultaneously due to by bag and the disposable making of interface shaping, what avoid non-PVC-soft-bag and interface welds the leakage and pollution problem that cause again, also have more transparent than existing medical bag, more pliable and tougher, cost is low, the high feature with more adapting to suitability for industrialized production of product qualified rate.
The technical scheme that the present invention provides is: polypropene blended transfusion flexible bag, for by bag, the disposable making of interface on bag top is shaping, be characterized in that the material of this transfusion flexible bag is a kind of pharmaceutical grade polypropylene copolymer (STM866 or R6400 or R530) and styrene-ethylene/butylene-styrene multipolymer (G1645MO) or hydrogenated styrene foreign matter diene butadiene block copolymer (HYBRAR 7311F), wherein the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer is 15 ~ 23%, the weight percentage of polypropylene copolymer is 77 ~ 85%.
The preparation method of the polypropene blended transfusion flexible bag that the present invention provides, is characterized in being made up of following steps.
(1) injection moulding bag base.
Injection moulding machine installs a bag mold tool, start barrel heating, working temperature is 200 DEG C to 240 DEG C, then in the hopper of injection moulding machine, pharmaceutical grade plastic raw materials is filled it up with, the material of this product is a kind of pharmaceutical grade polypropylene copolymer (STM866 or R6400 or R530) and styrene-ethylene/butylene-styrene multipolymer (G1645MO) or hydrogenated styrene foreign matter diene butadiene block copolymer (HYBRAR 7311F), wherein the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer is 15 ~ 23%, the weight percentage of polypropylene copolymer is 77 ~ 85%, after Heating temperature reaches, start injection moulding machine, plastic pellet is through the mixing effect of injecting machine material tube inner screw, by solid state transformed be molten state, under barrel inner screw applied pressure, by the plastic injection progressive die tool of molten state, the bag base of solid is become after cooling, the demoulding obtains a bag base product.
(2) two-way stretch blowing.
Bag base being put into reason base machine makes it line up in an orderly manner, through the transmission of upper base system, the heating system entering blow moulding machine heats, heating system is revolving, and bag base is heated to 110 DEG C ~ 150 DEG C, and the bag base heated enters blow mold, in blow mold, the longitudinal stretching of drawn bar and horizontal blowing, then through cooling, become polypropene blended transfusion flexible bag.
Compared with prior art, the invention has the beneficial effects as follows: except having with except the advantage of existing medical bag, namely the deficiency of non-PVC material infusion bag is overcome, the raw material of medical bag is made no longer to rely on external non-PVC film, achieve the diversification making raw material, simultaneously due to by bag and the disposable making of interface shaping, what avoid non-PVC-soft-bag and interface welds the leakage and pollution problem that cause again, also have more transparent than existing medical bag, more pliable and tougher, cost is low, product qualified rate is high and more adapt to the feature of suitability for industrialized production.
Embodiment
Embodiment 1.
First on injection moulding machine, install a bag mold tool, start barrel heating, working temperature is 210 DEG C, pharmaceutical grade plastic raw materials is filled it up with in the hopper of injection moulding machine, this raw material is 15 ~ 23% by the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer, the weight percentage of polypropylene copolymer is 77 ~ 85%, , after Heating temperature reaches, start injection moulding machine, plastic pellet is through the mixing effect of injecting machine material tube inner screw, by solid state transformed be molten state, under barrel inner screw applied pressure, by the plastic injection progressive die tool of molten state, the bag base of solid is become after cooling, the demoulding obtains a bag base product, again bag base is put into reason base machine to line up in an orderly manner, through the transmission of upper base system, the heating system entering blow moulding machine heats, heating system is revolving, and bag base is heated to 120 DEG C, and the bag base heated enters blow mold, in blow mold, the longitudinal stretching of drawn bar and horizontal blowing, then through cooling, become blow molded medical bag.
In the present embodiment, the pharmaceutical grade plastic raw materials of polypropene blended transfusion flexible bag is:
(1) G1645MO(15%)+STM866(85%), or
(2) G1645MO(23%)+STM866(77%), or
(3) HYBRAR 7311F (15%)+STM866(85%) or
(4)HYBRAR 7311F(23%)+ STM866(77%)。
Mix according to the above ratio, obtain through granulator granulation.The G1645MO that the present embodiment uses is the production of Ke Teng Polymer Company of the U.S., and STM866 is that Taiwan Li Changrong chemical company produces.The commercial product code of HYBRAR 7311F Kuraray Co., Ltd. production pharmaceutical grade plastic prod.
Embodiment 2.
First on injection moulding machine, install a bag mold tool, start barrel heating, working temperature is 220 DEG C, pharmaceutical grade plastic raw materials is filled it up with in the hopper of injection moulding machine, this raw material is 15 ~ 23% by the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer, the weight percentage of polypropylene copolymer is 77 ~ 85%, after Heating temperature reaches, start injection moulding machine, plastic pellet is through the mixing effect of injecting machine material tube inner screw, by solid state transformed be molten state, under barrel inner screw applied pressure, by the plastic injection progressive die tool of molten state, the bag base of solid is become after cooling, the demoulding obtains a bag base product, again bag base is put into reason base machine to line up in an orderly manner, through the transmission of upper base system, the heating system entering blow moulding machine heats, heating system is revolving, and bag base is heated to 130 DEG C, and the bag base heated enters blow mold, in blow mold, the longitudinal stretching of drawn bar and horizontal blowing, then through cooling, become blow molded medical bag.
In the present embodiment, the pharmaceutical grade plastic raw materials of polypropene blended transfusion flexible bag is:
(1) G1645MO(15%)+R6400 or R530(85%), or
(2) G1645MO(23%)+R6400 or R530(77%), or
(3) HYBRAR 7311F (15%)+R6400 or R530(85%), or
(4) HYBRAR 7311F (23%)+R6400 or R530(77%).
Mix according to the above ratio, obtain through granulator granulation.The G1645MO that the present embodiment uses is the commercial product code of the pharmaceutical grade plastic prod of Ke Teng Polymer Company of U.S. production and sales; HYBRAR 7311F is the commercial product code of the pharmaceutical grade plastic packet product of Kuraray Co., Ltd. production and sales; R6400, R530 are the commercial product code of the pharmaceutical grade plastic packet product that LG Corp of South Korea is produced.
Claims (2)
1. polypropene blended transfusion flexible bag, by bag, the disposable making of interface on bag top is shaping, be characterized in that the material of this transfusion flexible bag is a kind of pharmaceutical grade polypropylene copolymer (STM866 or R6400 or R530) and styrene-ethylene/butylene-styrene multipolymer (G1645MO) or hydrogenated styrene foreign matter diene butadiene block copolymer (HYBRAR 7311F), wherein the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer is 15 ~ 23%, the weight percentage of polypropylene copolymer is 77 ~ 85%.
2. the preparation method of blow molded medical bag according to claim 1, is characterized in that being made up of following steps: (1) injection moulding bag base:
Injection moulding machine installs a bag mold tool, start barrel heating, working temperature is 200 DEG C to 240 DEG C, then in the hopper of injection moulding machine, pharmaceutical grade plastic raw materials is filled it up with, the material of this this medical bag is a kind of pharmaceutical grade polypropylene copolymer (STM866 or R6400 or R530) and styrene-ethylene/butylene-styrene multipolymer (G1645MO) or hydrogenated styrene foreign matter diene butadiene block copolymer (HYBRAR 7311F), wherein the weight percentage of styrene-ethylene/butylene-styrene multipolymer or hydrogenated styrene foreign matter diene butadiene block copolymer is 15 ~ 23%, the weight percentage of polypropylene copolymer is 77 ~ 85%, after Heating temperature reaches, start injection moulding machine, plastic pellet is through the mixing effect of injecting machine material tube inner screw, by solid state transformed be molten state, under barrel inner screw applied pressure, by the plastic injection progressive die tool of molten state, the bag base of solid is become after cooling, the demoulding obtains a bag base product,
(2) two-way stretch blowing:
Bag base being put into reason base machine makes it line up in an orderly manner again, through the transmission of upper base system, the heating system entering blow moulding machine heats, heating system is revolving, and bag base is heated to 110 DEG C ~ 150 DEG C, and the bag base heated enters blow mold, in blow mold, the longitudinal stretching of drawn bar and horizontal blowing, then through cooling, become polypropene blended transfusion flexible bag.
Priority Applications (1)
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CN201310393309.7A CN104419065A (en) | 2013-09-03 | 2013-09-03 | Polypropylene-blended soft infusion bag and preparation method thereof |
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CN201310393309.7A CN104419065A (en) | 2013-09-03 | 2013-09-03 | Polypropylene-blended soft infusion bag and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109304854A (en) * | 2018-12-04 | 2019-02-05 | 广西裕源药业有限公司 | Upright polypropylene transfusion flexible bag production technology |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486818A (en) * | 2008-01-18 | 2009-07-22 | 常州弘拓塑胶材料有限公司 | Thermoplastic elastomer materials |
CN101780855A (en) * | 2010-02-09 | 2010-07-21 | 南京泰邦生物医用材料有限公司 | Five-layer coextrusion transfusion medicine packing film and manufacturing method thereof |
CN102018623A (en) * | 2009-09-23 | 2011-04-20 | 辽宁九洲龙跃药业有限公司 | Blow molded medical bag and preparation method thereof |
-
2013
- 2013-09-03 CN CN201310393309.7A patent/CN104419065A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486818A (en) * | 2008-01-18 | 2009-07-22 | 常州弘拓塑胶材料有限公司 | Thermoplastic elastomer materials |
CN102018623A (en) * | 2009-09-23 | 2011-04-20 | 辽宁九洲龙跃药业有限公司 | Blow molded medical bag and preparation method thereof |
CN101780855A (en) * | 2010-02-09 | 2010-07-21 | 南京泰邦生物医用材料有限公司 | Five-layer coextrusion transfusion medicine packing film and manufacturing method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109304854A (en) * | 2018-12-04 | 2019-02-05 | 广西裕源药业有限公司 | Upright polypropylene transfusion flexible bag production technology |
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