CN104399497B - The acid catalyst of fry starch of konjak - Google Patents
The acid catalyst of fry starch of konjak Download PDFInfo
- Publication number
- CN104399497B CN104399497B CN201410654174.XA CN201410654174A CN104399497B CN 104399497 B CN104399497 B CN 104399497B CN 201410654174 A CN201410654174 A CN 201410654174A CN 104399497 B CN104399497 B CN 104399497B
- Authority
- CN
- China
- Prior art keywords
- konjak
- acid catalyst
- acid
- catalyst
- fry starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920002752 Konjac Polymers 0.000 title claims abstract description 33
- 229920002472 Starch Polymers 0.000 title claims abstract description 29
- 239000008107 starch Substances 0.000 title claims abstract description 29
- 235000019698 starch Nutrition 0.000 title claims abstract description 29
- 235000010485 konjac Nutrition 0.000 title claims abstract description 28
- 239000003377 acid catalyst Substances 0.000 title claims abstract description 19
- 235000007119 Ananas comosus Nutrition 0.000 claims abstract description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 241000234671 Ananas Species 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 12
- 230000004913 activation Effects 0.000 claims description 11
- 239000003610 charcoal Substances 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000003763 carbonization Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 abstract description 12
- 239000002253 acid Substances 0.000 abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 6
- 230000007062 hydrolysis Effects 0.000 abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 4
- 239000011973 solid acid Substances 0.000 abstract description 4
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 230000008929 regeneration Effects 0.000 abstract description 2
- 238000011069 regeneration method Methods 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 abstract description 2
- 244000099147 Ananas comosus Species 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 13
- 235000001014 amino acid Nutrition 0.000 description 3
- -1 aminoacid Aminoacid Chemical class 0.000 description 3
- 241001278826 Amorphophallus Species 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000001093 anti-cancer Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- 244000247812 Amorphophallus rivieri Species 0.000 description 1
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 1
- 206010006187 Breast cancer Diseases 0.000 description 1
- 208000026310 Breast neoplasm Diseases 0.000 description 1
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000205754 Colocasia esculenta Species 0.000 description 1
- 235000006481 Colocasia esculenta Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 244000182067 Fraxinus ornus Species 0.000 description 1
- 235000002917 Fraxinus ornus Nutrition 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- GAMYVSCDDLXAQW-AOIWZFSPSA-N Thermopsosid Natural products O(C)c1c(O)ccc(C=2Oc3c(c(O)cc(O[C@H]4[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O4)c3)C(=O)C=2)c1 GAMYVSCDDLXAQW-AOIWZFSPSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- 150000005693 branched-chain amino acids Chemical class 0.000 description 1
- 201000008275 breast carcinoma Diseases 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000003797 essential amino acid Substances 0.000 description 1
- 235000020776 essential amino acid Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229930003944 flavone Natural products 0.000 description 1
- 235000011949 flavones Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 201000011061 large intestine cancer Diseases 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of acid catalyst of fry starch of konjak, belongs to the preparation field of catalyst.Acid in order to solve conventional hydrolysis fry starch of konjak is usually to adopt liquid hydrochloric acid, there is residual acid and separate difficulty in liquid acid catalyst, catalyst can not be reused, the problem of catalyst high cost, the acid catalyst of the fry starch of konjak that the present invention provides, makes activated carbon, then prepares solid acid catalyst with the activated carbon being obtained with pineapple bran, alternative traditional liquid hydrochloric acid catalyst catalytic treatment fry starch of konjak, will not produce acid waste water；And this solid acid catalyst can be used with repeated collection, can also be reused by acid regeneration after being used for multiple times.
Description
Technical field
The invention belongs to the preparation field of catalyst is and in particular to a kind of acid catalyst of fry starch of konjak.
Background technology
Rhizoma amorphophalli (Amorphopallus konjac) is herbaceos perennial, another name terrible taro, bennet lotus, Rhizoma petasitis japonici, eats
Cut, be mainly utilized is its bulb part, it contains saccharide, protein, (17 kinds of aminoacid, wherein contain 8 kinds to aminoacid
Aminoacid needed by human), vitamin, mineral etc., main component is konjaku powder (glucomannan), has preventing and treating large intestine
Cancer and breast carcinoma, reduction blood fat blood glucose, effect of fat-reducing.
The Amorphophallus Resources very abundant of China, and be Rhizoma amorphophalli manufacturing country maximum in the world, national fine powder annual production 5000
About ton, in the konjaku powder course of processing, isolate by the granule that forms of part such as Rhizoma amorphophalli epidermis is little, lightweight fine powder
(starch, cellulose etc.) is referred to as fry starch of konjak, and its flour extraction is the 60%-80% of konjaku powder, accounts for fine powder mass fraction
30%-40%, the whole nation is produced per year and is flown powder 1500-2000 ton.To Rhizoma amorphophalli, using being concentrated mainly on konjaku powder, (Portugal's manna gathers at present
Sugar), and fry starch of konjak is due to palatability extreme difference (having astringent taste, egg fishy smell and off-odor), and in food industry, utilization rate is not
Height, the winged powder discarded in a large number not only pollutes environment, and is also great waste for Amorphophallus Resources.With international market to essence
The increase of powder demand, how to process fry starch of konjak (side-product in konjaku powder processing) becomes urgently to be resolved hurrily at present asking
Topic.
Fry starch of konjak is nutritious, containing a large amount of carbohydrates (mainly starch) and protein, also contain cellulose,
Fat, 8 kinds of essential amino acids (especially branched-chain amino acid), and its mineral such as calcium, magnesium, ferrum, zinc, phosphorus, copper, manganese, also contain
There are multiple pharmacological active substancies, such as ceramide, flavone compound etc., there is raising immunity, anti-cancer, anticancer, antioxidation, fall
The effect such as pressure.
In exploitation fry starch of konjak, first have to fry starch of konjak is hydrolyzed process.At present, the hydrolysis of fry starch of konjak
Mainly adopt enzyme hydrolysiss, the peptide obtaining can be used for the making and research of Rhizoma amorphophalli polypeptide wine；Fly powder and winged powder Spirit with acid hydrolysis
Be brewed into new research direction.But the acid of hydrolysis fry starch of konjak is usually to adopt liquid hydrochloric acid, and liquid acid catalyst exists surplus
Spent acid separates difficulty, and catalyst can not be reused, the problem of catalyst high cost.
Content of the invention
For solving the above problems, the present invention provides a kind of acid catalyst of fry starch of konjak, adopts the following technical scheme that：
A kind of acid catalyst of fry starch of konjak is it is characterised in that comprise the following steps：
（1）Pineapple bran is dried and is less than 15% to water content, be then crushed to 80 ~ 100 mesh；
（2）Pineapple bran after dries pulverizing is carried out carbonization 45 ~ 60min at 300 DEG C, then heats to 450 ~ 500 DEG C
Carry out activating 10 ~ 15min, obtain final product pineapple bran activation charcoal；
（4）Pineapple bran activation charcoal is put in 1-5w% hydrochloric acid solution, supersound process 1-5h；
（5）After supersound process, the pH value being washed with distilled water to cleaning mixture is 6 ~ 7, and then dries pulverizing obtains final product to 200 mesh
The acid catalyst of described fry starch of konjak.
The present invention has the advantages that：The acid catalyst of the fry starch of konjak that the present invention provides, makes work with pineapple bran
Property charcoal, then be obtained activated carbon prepare solid acid catalyst, alternative traditional liquid hydrochloric acid catalyst catalytic treatment Rhizoma amorphophalli
Winged powder, will not produce acid waste water；And this solid acid catalyst can be used with repeated collection, can also pass through after being used for multiple times
Acid regeneration is reused.
Specific embodiment
Following examples are served only for the present invention is described, are not used to present protection scope of the present invention.
Embodiment 1
A kind of acid catalyst of fry starch of konjak is it is characterised in that comprise the following steps：
（1）Pineapple bran is dried and is less than 15% to water content, be then crushed to 80 mesh；
（2）Pineapple bran after dries pulverizing is carried out carbonization 45 ~ 50min at 300 DEG C, then heats to 450 ~ 480 DEG C
Carry out activating 10min, obtain final product pineapple bran activation charcoal；
（4）Pineapple bran activation charcoal is put in 1-2w% hydrochloric acid solution, supersound process 3h；
（5）After supersound process, the pH value being washed with distilled water to cleaning mixture is 7, and then dries pulverizing obtains final product institute to 200 mesh
The acid catalyst of the fry starch of konjak stated.
Embodiment 2
A kind of acid catalyst of fry starch of konjak is it is characterised in that comprise the following steps：
（1）Pineapple bran is dried and is less than 15% to water content, be then crushed to 100 mesh；
（2）Pineapple bran after dries pulverizing is carried out carbonization 60min at 300 DEG C, then heats to 500 DEG C and activated
10min, obtains final product pineapple bran activation charcoal；
（4）Pineapple bran activation charcoal is put in 1w% hydrochloric acid solution, supersound process 2h；
（5）After supersound process, the pH value being washed with distilled water to cleaning mixture is 7, and then dries pulverizing obtains final product institute to 200 mesh
The acid catalyst of the fry starch of konjak stated.
Embodiment 3
A kind of acid catalyst of fry starch of konjak is it is characterised in that comprise the following steps：
（1）Pineapple bran is dried and is less than 15% to water content, be then crushed to 100 mesh；
（2）Pineapple bran after dries pulverizing is carried out carbonization 50min at 300 DEG C, then heats to 450 DEG C and activated
12min, obtains final product pineapple bran activation charcoal；
（4）Pineapple bran activation charcoal is put in 2w% hydrochloric acid solution, supersound process 5h；
（5）After supersound process, the pH value being washed with distilled water to cleaning mixture is 7, and then dries pulverizing obtains final product institute to 200 mesh
The acid catalyst of the fry starch of konjak stated.
Claims (1)
1. a kind of acid catalyst of fry starch of konjak is it is characterised in that comprise the following steps：
（1）Pineapple bran is dried and is less than 15% to water content, be then crushed to 80 ~ 100 mesh；
（2）Pineapple bran after dries pulverizing is carried out carbonization 45 ~ 60min at 300 DEG C, then heats to 450 ~ 500 DEG C and carry out
Activation 10 ~ 15min, obtains final product pineapple bran activation charcoal；
（4）Pineapple bran activation charcoal is put in 1-5w% hydrochloric acid solution, supersound process 1-5h；
（5）After supersound process, the pH value being washed with distilled water to cleaning mixture is 6 ~ 7, then dries pulverizing obtain final product to 200 mesh described
Fry starch of konjak acid catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410654174.XA CN104399497B (en) | 2014-11-18 | 2014-11-18 | The acid catalyst of fry starch of konjak |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410654174.XA CN104399497B (en) | 2014-11-18 | 2014-11-18 | The acid catalyst of fry starch of konjak |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104399497A CN104399497A (en) | 2015-03-11 |
| CN104399497B true CN104399497B (en) | 2017-03-01 |
Family
ID=52637201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410654174.XA Active CN104399497B (en) | 2014-11-18 | 2014-11-18 | The acid catalyst of fry starch of konjak |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104399497B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103293A (en) * | 1987-05-01 | 1988-11-16 | 河南省长葛县八七活性炭厂 | Utilize novel carbon raw material to prepare process of active carbon |
| CN102730682A (en) * | 2012-07-18 | 2012-10-17 | 太仓市联林活性炭厂 | Technique for preparing activated carbon from tung seed shells |
| CN103084187A (en) * | 2012-12-17 | 2013-05-08 | 常州大学 | Carbon-based solid acid and preparation method thereof |
| CN103449433A (en) * | 2012-06-01 | 2013-12-18 | 中国科学院城市环境研究所 | Method for preparing novel active carbon by using potassium hydroxide activated vegetable luffa sponge |
-
2014
- 2014-11-18 CN CN201410654174.XA patent/CN104399497B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103293A (en) * | 1987-05-01 | 1988-11-16 | 河南省长葛县八七活性炭厂 | Utilize novel carbon raw material to prepare process of active carbon |
| CN103449433A (en) * | 2012-06-01 | 2013-12-18 | 中国科学院城市环境研究所 | Method for preparing novel active carbon by using potassium hydroxide activated vegetable luffa sponge |
| CN102730682A (en) * | 2012-07-18 | 2012-10-17 | 太仓市联林活性炭厂 | Technique for preparing activated carbon from tung seed shells |
| CN103084187A (en) * | 2012-12-17 | 2013-05-08 | 常州大学 | Carbon-based solid acid and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 酸处理活性炭催化臭氧氧化肉桂醛为苯甲醛;秦祖赠 等;《精细化工》;20140228;第31卷(第2期);第202-206页 * |
| 酸改性活性炭对甲苯、甲醇的吸附性能;李立清 等;《化工学报》;20130331;第64卷(第3期);第970-979页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104399497A (en) | 2015-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102657332B (en) | Preparation method for successively producing yak bone marrow oil and ultramicro polypeptide bone calcium powder once | |
| CN101255200B (en) | Technique for producing toasted garlic polysaccharides and allinase by using toasted garlic as raw material | |
| CN102805350A (en) | Method for preparing dietary fibers from wastes and byproducts generated in tangerine processing | |
| CN101797274A (en) | Preparation technology of okra capsule | |
| CN104140471B (en) | A kind of method preparing Rhizoma Dioscoreae high-purity polysaccharide from yam food processing fent | |
| CN105087729A (en) | Tuna bone collagen peptide preparation method | |
| CN105087728A (en) | Preparation method of selenium-chelated collagen peptide with tuna bone collagen serving as source | |
| CN101803731B (en) | Sea cucumber spirulina nutrition tablet and production process thereof | |
| CN105494839A (en) | Rhopilema esculentum polypeptide composite tablet candy and preparation method thereof | |
| CN102839047A (en) | Method for extracting fish oil and producing taurine seafood condiments by using hairtail and leftovers of hairtail | |
| CN103070431B (en) | Kelp extract iodine tablet and preparation method thereof | |
| CN103750455A (en) | Production method for antrodia camphorata beverage | |
| CN102823896B (en) | Puffed food rich in dietary fibers of seaweeds and production method for puffed food | |
| CN102919940B (en) | Natural calcium-rich beverage taking fishbone as raw material and preparation method thereof | |
| CN102342541B (en) | Method for reducing content of fluorine in enzymatic hydrolysate of Euphausia superb by using calcined lime | |
| CN105367680A (en) | Microwave-assisted extraction method for auricularia auriculajudae polysaccharides | |
| CN102775511B (en) | Method for extracting pepper polysaccharide from pepper residue | |
| CN104399497B (en) | The acid catalyst of fry starch of konjak | |
| CN107955081A (en) | The combined extraction method of a variety of nutriments in a kind of sea cucumber | |
| CN103468467A (en) | Alga health care white spirit and preparing method thereof | |
| CN103014107A (en) | Method for preparing shrimp head polypeptide nutrient solution by ultraviolet assistance | |
| CN103005219B (en) | Sow feed and preparation method thereof | |
| CN106085251A (en) | A kind of method extracting gelatin from Ctenopharyngodon idellus fish skin | |
| CN105831343A (en) | Ginseng ginger tea and preparation method thereof | |
| CN105385736A (en) | Preparation process for protein peptide of Tenebrio molitor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Ma Xiaojun Inventor before: Wu Shouyang |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170125 Address after: 325025 Zhejiang city of Wenzhou Province Economic and Technological Development Zone, Binhai Road, Yonghe six Jinyuan 1 Room 501 Applicant after: Ma Xiaojun Address before: 610041 Sichuan city of Chengdu province high tech Zone Dayuan Street No. 49 1 floor Applicant before: CHENGDU LIXIANG FORTUNE INVESTMENT CONSULTING CO., LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190107 Address after: Room 1402, 14th floor, 99 Mingzhu Road, Bengbu City, Anhui Province Patentee after: Bengbu HRABERO Intellectual Property Service Co. Ltd. Address before: Room 501, Yonghe Jinyuan Building, Binhai Sixth Road, Wenzhou Economic and Technological Development Zone, Zhejiang Province Patentee before: Ma Xiaojun |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190710 Address after: 445000 Jinyexiang No.3, Xiaping Township, Hefeng County, Enshi Tujia and Miao Autonomous Prefecture, Hubei Province Patentee after: Hubei Hefeng Sunshine Agricultural Development Co., Ltd. Address before: Room 1402, 14th floor, 99 Mingzhu Road, Bengbu City, Anhui Province Patentee before: Bengbu HRABERO Intellectual Property Service Co. Ltd. |