CN104398404A - Nontoxic nail polish remover and preparation method thereof - Google Patents

Nontoxic nail polish remover and preparation method thereof Download PDF

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Publication number
CN104398404A
CN104398404A CN201410751459.5A CN201410751459A CN104398404A CN 104398404 A CN104398404 A CN 104398404A CN 201410751459 A CN201410751459 A CN 201410751459A CN 104398404 A CN104398404 A CN 104398404A
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China
Prior art keywords
water
avirulence
parts
dimethyl ether
unloads
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CN201410751459.5A
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Chinese (zh)
Inventor
王立志
何卓人
王东宇
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SUZHOU SHENGKELUO ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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SUZHOU SHENGKELUO ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201410751459.5A priority Critical patent/CN104398404A/en
Publication of CN104398404A publication Critical patent/CN104398404A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a nontoxic nail polish remover and a preparation method thereof. The nail polish remover comprises the following ingredients in parts by weight: 70-85 parts of polyoxymethylene dimethyl ether, 14-25 parts of purified water, 0.5-1.0 part of glycerinum, 1-3 parts of a surfactant and 0.03-0.08 part of essence. The preparation method comprises the following steps: adding 14-25 parts of purified water into a stirring kettle, and starting a stirrer, wherein the stirring speed is controlled at 60-70 r/min; adding 1-3 parts of the surfactant (including 0.5-1.5 parts of polyving akohol 200 and 0.5-1.5 parts of polyving akohol 400), and stirring for 10-15 min to prepare a soap solution; then sequentially adding in 0.5-1.0 part of glycerinum, 0.03-0.08 part of essence and 70-85 parts of polyoxymethylene dimethyl ether, stirring for 20-30 min, and mixing water with polyoxymethylene dimethyl ether under the action of polyving akohol to form a microemulsion, wherein the obtained transparent liquid is the nontoxic nail polish remover. The nontoxic nail polish remover is free of any hazardous substance, high in dissolving capacity, free of pungent smell, and free of adverse effects on nails, skin and the human body by adopting water, glycerinum and other ingredients as the assistant ingredients, and the removal of the nail polish only takes a few minutes, or even about ten seconds.

Description

A kind of avirulence unloads first water and preparation method thereof
Technical field
The invention belongs to cosmetic technical field, particularly relate to a kind of avirulence and unload first water and preparation method thereof.
Background technology
For raw material aspect, that sells in the market unloads first water, in order to improve the solvability to nial polish, major part is unloaded first water and is all contained the compositions such as acetone, banana oil (isoamyl acetate), acrylic acid (copolymer), propylene glycol carbonate, ethyl acetate, and these compositions exist certain toxicity and potential safety hazard.
Acetone is widely used in cosmetic field, and CN 104086380A, CN103599020A all adopt acetone as the compositions in beautifying face, preserving moisture, other unload first aquatic products also multiplex acetone make solvent.But this material has certain toxicity, to Eye irritation, can cause bronchitis, the prolonged and repeated contact of skin can cause dermatitis.Long-term suction health can cause dizzy, nauseating, headache, the problem such as dizzy.In addition, this material is used for unloading first water, and the horny layer of nail surface can be caused to become coarse and fragile because of dry.
Banana oil (isoamyl acetate), as cosmetics preservative, is widely used in the occasion of the sterilization and anticorrosion such as floral water, prickly heat liquid.But this material has stimulation to eyes and mucosa, high concentration sucks can cause central nervous system damage.In addition, this material restrains chapped skin, should notice that ventilation is windowed during use.Therefore this material not easily life-time service, composite in unloading Jia Shui field, easily damage health.
In addition, acrylic acid (copolymer), ethyl acetate and propylene glycol carbonate are also compounds conventional in cosmetic field.Acrylic acid has intense stimulus effect to skin, eyes and respiratory tract.Ethyl acetate, to air-sensitive, can absorb water and divide, and moisture can make it slowly decompose and react acid, and prolonged and repeated contact has injury to skin and fingernail.And CN104042512A propylene glycol carbonate is as a kind of raw material of the saturating salubrious moisturizing preventing coating protection frost of a kind of water, but this material sucks, absorption or harmful to health after skin absorbs, and has stimulation to eyes, skin, therefore should not use.
The major defect of prior art: one, raw material has certain toxic and side effects to user, unsuitable life-time service; Its two, it is longer to remove the residual nial polish time, and major part unloads first water to be needed to contact 20-30 minute with fingernail and just nial polish can be washed off, and and direct skin contact; Its three, need by other instruments, damage fingernail itself fineness.
Summary of the invention
The object of the present invention is to provide a kind of avirulence to unload first water and preparation method thereof, being intended to the raw material unloading the existence of first water solved on existing market has certain toxic and side effects to user, unsuitable life-time service; It is longer to remove the residual nial polish time, and major part unloads first water to be needed to contact 20-30 minute with fingernail and just nial polish can be washed off, and and direct skin contact; Need by other instruments, the problem of the fineness of damage fingernail own.
The present invention is achieved in that a kind of avirulence unloads first water, and this avirulence is unloaded first water and comprised according to water parts by weight: 70-85 part polymethoxy dimethyl ether, 14-25 part pure water, 0.5-1.0 part glycerol, 1-3 part surfactant, 0.03-0.08 part essence.
Further, polymethoxy dimethyl ether is molten, with water, glycerol for fingernail protective agent; Surfactant is polyvinyl alcohol 200 and 400, and wherein polyvinyl alcohol 200 and 400 is micro-emulsifier.
Further, this avirulence unloads the using method of first water: will unload first water gauze or cotton pads is dipped in a little, spreads upon gently on the fingernail of coated nial polish, infiltrates for 30 seconds, then dab fingernail with clean gauze or cotton pads.
Another object of the present invention is to provide a kind of avirulence to unload the preparation method of first water, the preparation method that this avirulence unloads first water comprises the following steps:
Step one, first adds in stirred tank by the pure water of 14-25 part pure water, and start agitator, mixing speed controls at 60-70 rev/min;
Step 2, first adds the surfactant of 1-3 part surfactant, and each 0.5 part ~ 1.5 parts of polyvinyl alcohol 200 and 400, stirs and be mixed with soap lye in 10-15 minute;
Step 3, add 0.5-1.0 part glycerol, 0.03-0.08 part essence, 70-85 part polymethoxy dimethyl ether more successively, stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Further, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 14 parts, start agitator, mixing speed controls at 60-70 rev/min, the surfactant first adding 1 part (wherein each 0.5 part of polyvinyl alcohol 200 and 400) stirs and is mixed with soap lye in 10-15 minute, add 0.5 part of glycerol, the essence of 0.03 part, the polymethoxy dimethyl ether of 84.47 parts more successively, stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Further, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 20 parts, start agitator, mixing speed controls at 60-70 rev/min, the surfactant first adding 2 parts (wherein each 1 part of polyvinyl alcohol 200 and 400) stirs 10-15 minute obtained soap lye, add 0.8 part of glycerol, the essence of 0.05 part, the polymethoxy dimethyl ether of 77.15 parts more successively, stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Further, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 25 parts, start agitator, mixing speed controls at 60-70 rev/min, the surfactant first adding 3 parts (wherein each 0.5 part of polyvinyl alcohol 200 and 400) stirs 10-15 minute obtained soap lye, add 1.0 parts of glycerol, the essence of 0.08 part, the polymethoxy dimethyl ether of 70.92 parts more successively, stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Avirulence provided by the invention unloads first water and preparation method thereof, with environment-friendly type solvent polymethoxy dimethyl ether (PODE3-4) for host, by specific surface activating agent, and be aided with the materials such as conventional water, glycerol and realize nontoxic and instant unloading the preparation of first water; The present invention is not containing any harmful substance, and solvability is strong, and removing nial polish only needs even tens seconds a few minutes, auxiliary with the composition such as water, glycerol, to fingernail, skin and human body without ill effect, has no irritating odor.The first water that unloads of the present invention only needs a stirring at normal temperature still just can produce, and technique is simple, nontoxic, and can dissolve rapidly residual nial polish.
The first water that unloads of the present invention adopts environment-friendly type solvent polymethoxy dimethyl ether (PODE 3-4) be main component, chemical molecular formula is CH 3o (CH 2o) 3-4cH 3it is not containing any harmful substance, supplement water, glycerol, surfactant and essence that is medical or food stage, Scavenging activity is strong, cleans fingernail gently, without the need to by other instrument, remove nial polish speed fast, only need within 1 minute, even just can remove nial polish, fragrant tens seconds, make fingernail keep original gloss, long-term or Reusability to fingernail, skin and human body without ill effect.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
The avirulence of the embodiment of the present invention is unloaded first and is comprised according to water parts by weight: 70-85 part polymethoxy dimethyl ether (PODE 3-4), 14-25 part pure water, 0.5-1.0 part glycerol, 1-3 part surfactant, 0.03-0.08 part essence.
With polymethoxy dimethyl ether (PODE 3-4) be the cleaner of solvent; With water, glycerol for fingernail protective agent; Take polyvinyl alcohol as micro-emulsifier;
Polymethoxy dimethyl ether PODE 3-4, have superpower solvability to various oily substance, can remove nial polish fast, its dissolubility in water is 20%, can dissolve each other with the water of 15%.Its consumption is not easily too much, too much easily makes fingernail defat dewater, tarnishes.Very few removal nial polish weak effect, the time is long.Therefore its consumption should control between 70-85 part.
Pure water unloads the solvability of first water for regulating, and can protect fingernail, keeps gloss.Its consumption is more, and protection fingernail effect is better, but removes the reduced capability of nial polish, very few unfavorable protection fingernail gloss.Therefore its consumption should control between 14-25 part.
Glycerin components is used for the moisture of fixing nail surface, prevents fingernail drying from tarnishing.Consumption too much affects the elimination effect unloading first water, and the very few unfavorable fixing moisture of consumption, fingernail is easily dry.Its consumption should control to be advisable between 0.5-1.0 part.
Surfactant is polyvinyl alcohol 200 and 400 mainly.This material is often used as compositions and other suspension dispersants of medical catheter nursing agent, has good emulsifying effectiveness.In the present invention, the effect of this material is micro-emulsifier, can form electric double layer, play and prevent polymethoxy dimethyl ether layering in water, form microemulsion between the hydroxyl of the ether of polymethoxy dimethyl ether and water, makes to unload first water and keeps as clear as crystal.This material can in any proportion with moisture and polymethoxy dimethyl ether miscible.But its consumption too much causes waste, the very few microemulsion being difficult to be formed microemulsion or formation is unstable, causes and unloads the opaque or layering of first water.Therefore, consumption should control between 1-3 part.
Essence is ethyl maltol (3-hydroxyl-2-ethyl-pyrokomane) mainly, food stage, and unload first aqueous vapor taste for regulating, making to unload first glassware for drinking water has fruit aroma abnormal smells from the patient, pure and fresh pleasant.Its consumption is too much unsuitable, and 0.03-0.08 part can obtain better effect.
The preparation method that the avirulence of the embodiment of the present invention unloads first water comprises the following steps:
S101: first the pure water of 14-25 part pure water is added in stirred tank (rustless steel or enamel still), start agitator, mixing speed controls at 60-70 rev/min;
S102: the surfactant (each 0.5 part ~ 1.5 parts of polyvinyl alcohol 200 and 400) first adding 1-3 part surfactant stirs and is mixed with soap lye in 10-15 minute;
S103: add 0.5-1.0 part glycerol, 0.03-0.08 part essence, 70-85 part polymethoxy dimethyl ether more successively, stirs 20-30 minute, under the effect of polyvinyl alcohol, makes water and polymethoxy dimethyl ether (PODE 3-4) form microemulsion, obtain transparent liquid and be avirulence and unload first water;
Specific embodiments of the invention:
Embodiment 1:
Step one, first the pure water of 14 parts is added in stirred tank (rustless steel or enamel still), start agitator, mixing speed controls at 60-70 rev/min, surfactant (wherein each 0.5 part of the polyvinyl alcohol 200 and 400) stirring first adding 1 part is mixed with soap lye in 10-15 minute, then adds 0.5 part of glycerol, the essence of 0.03 part, the polymethoxy dimethyl ether (PODE of 84.47 parts successively 3-4), stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether (PODE 3-4) form microemulsion, obtain transparent liquid and be avirulence and unload first water;
Step 2, obtained unload first water gauze or cotton pads is dipped in a little by above-mentioned, spread upon gently on the fingernail of coated nial polish, infiltrated for 30 seconds, then dab fingernail with clean gauze or cotton pads, nial polish will thoroughly be removed.
Embodiment 2:
Step one, first adds the pure water of 20 parts in stirred tank (rustless steel or enamel still), and start agitator, mixing speed controls at 60-70 rev/min.The surfactant (wherein each 1 part of polyvinyl alcohol 200 and 400) first adding 2 parts stirs 10-15 minute obtained soap lye.Add 0.8 part of glycerol, the essence of 0.05 part, the polymethoxy dimethyl ether (PODE of 77.15 parts more successively 3-4), stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether (PODE 3-4) form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Step 2, obtained unload first water gauze or cotton pads is dipped in a little by above-mentioned, spread upon gently on the fingernail of coated nial polish, infiltrated for 40 seconds, then dab fingernail with clean gauze or cotton pads, nial polish will thoroughly be removed.
Embodiment 3:
Step one, first adds the pure water of 25 parts in stirred tank (rustless steel or enamel still), and start agitator, mixing speed controls at 60-70 rev/min.The surfactant (wherein each 1.5 parts of polyvinyl alcohol 200 and 400) first adding 3 parts stirs 10-15 minute obtained soap lye.Add 1.0 parts of glycerol, the essence of 0.08 part, the polymethoxy dimethyl ether (PODE of 70.92 parts more successively 3-4), stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether (PODE 3-4) form microemulsion, obtain transparent liquid and be avirulence and unload first water.
Step 2, obtained unload first water gauze or cotton pads is dipped in a little by above-mentioned, spread upon gently on the fingernail of coated nial polish, infiltrated for 60 seconds, then dab fingernail with clean gauze or cotton pads, nial polish will thoroughly be removed.
The present invention for host with environment-friendly type solvent polymethoxy dimethyl ether (PODE3-4), by specific surface activating agent, and is aided with the materials such as conventional water, glycerol and realizes nontoxic and instant unloading the preparation of first water; The present invention is not containing any harmful substance, and solvability is strong, and removing nial polish only needs even tens seconds a few minutes, auxiliary with the composition such as water, glycerol, to fingernail, skin and human body without ill effect, has no irritating odor.The first water that unloads of the present invention only needs a stirring at normal temperature still just can produce, and technique is simple, nontoxic, and can dissolve rapidly residual nial polish.
The first water that unloads of the present invention was on October 8th, 2014, deliver to the test of An Mute detection technique company limited of Shenzhen, October 11-2014 years on the 8th October of 2014 test period, numbering: A001R141008059001, after tested: the content of benzene, toluene, ethylbenzene, dimethylbenzene is zero;
The first water that unloads of the present invention was in JIUYUE in 2014 11 days, deliver to the test of An Mute detection technique company limited of Shenzhen, 2014 test periods JIUYUE-2014 years on the 11st JIUYUE 15 days, numbering: A001R140911041002, after tested: the content of multi-ring fragrant footpath, alkylphenol, alkylphenol polyoxyethylene meets and meets the requirements, and there is not the material to human injury.
The first water that unloads of the present invention adopts environment-friendly type solvent polymethoxy dimethyl ether (PODE 3-4) be main component, chemical molecular formula is CH 3o (CH 2o) 3-4cH 3it is not containing any harmful substance, supplement water, glycerol, surfactant and essence that is medical or food stage, Scavenging activity is strong, cleans fingernail gently, without the need to by other instrument, remove nial polish speed fast, only need within 1 minute, even just can remove nial polish, fragrant tens seconds, make fingernail keep original gloss, long-term or Reusability to fingernail, skin and human body without ill effect.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.

Claims (7)

1. avirulence unloads a first water, it is characterized in that, this avirulence is unloaded first water and comprised according to water parts by weight: 70-85 part polymethoxy dimethyl ether, 14-25 part pure water, 0.5-1.0 part glycerol, 1-3 part surfactant, 0.03-0.08 part essence.
2. avirulence as claimed in claim 1 unloads first water, and it is characterized in that, polymethoxy dimethyl ether is molten, with water, glycerol for fingernail protective agent; Surfactant is polyvinyl alcohol 200 and 400, and polyvinyl alcohol 200 and 400 is micro-emulsifier.
3. avirulence as claimed in claim 1 unloads first water, it is characterized in that, this avirulence unloads the using method of first water: will unload first water gauze or cotton pads is dipped in a little, spreads upon on the fingernail of coated nial polish gently, infiltrated for 30 seconds, then dab fingernail with clean gauze or cotton pads.
4. avirulence unloads a preparation method for first water, it is characterized in that, the preparation method that this avirulence unloads first water comprises the following steps:
Step one, first adds in stirred tank by the pure water of 14-25 part pure water, and start agitator, mixing speed controls at 60-70 rev/min;
Step 2, first adds the surfactant of 1-3 part surfactant, stirs and is mixed with soap lye in 10-15 minute;
Step 3, add 0.5-1.0 part glycerol, 0.03-0.08 part essence, 70-85 part polymethoxy dimethyl ether more successively, stir 20-30 minute, under the effect of polyvinyl alcohol, make water and polymethoxy dimethyl ether form microemulsion, obtain transparent liquid and be avirulence and unload first water.
5. avirulence as claimed in claim 4 unloads the preparation method of first water, it is characterized in that, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 14 parts, start agitator, mixing speed controls at 60-70 rev/min, first add the surfactant of 1 part, stir and be mixed with soap lye in 10-15 minute, add 0.5 part of glycerol more successively, the essence of 0.03 part, 84.47 the polymethoxy dimethyl ether of part, stir 20-30 minute, under the effect of polyvinyl alcohol, water and polymethoxy dimethyl ether is made to form microemulsion, obtain transparent liquid to be avirulence and to unload first water.
6. avirulence as claimed in claim 4 unloads the preparation method of first water, it is characterized in that, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 20 parts, start agitator, mixing speed controls at 60-70 rev/min, first add the surfactant of 2 parts, stir 10-15 minute obtained soap lye, add 0.8 part of glycerol more successively, the essence of 0.05 part, 77.15 the polymethoxy dimethyl ether of part, stir 20-30 minute, under the effect of polyvinyl alcohol, water and polymethoxy dimethyl ether is made to form microemulsion, obtain transparent liquid to be avirulence and to unload first water.
7. avirulence as claimed in claim 4 unloads the preparation method of first water, it is characterized in that, the preparation method that this avirulence unloads first water comprises and first adds in stirred tank by the pure water of 25 parts, start agitator, mixing speed controls at 60-70 rev/min, the surfactant first adding 3 parts stirs 10-15 minute obtained soap lye, add 1.0 parts of glycerol more successively, the essence of 0.08 part, 70.92 the polymethoxy dimethyl ether of part, stir 20-30 minute, under the effect of polyvinyl alcohol, water and polymethoxy dimethyl ether is made to form microemulsion, obtain transparent liquid to be avirulence and to unload first water.
CN201410751459.5A 2014-12-11 2014-12-11 Nontoxic nail polish remover and preparation method thereof Pending CN104398404A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107854333A (en) * 2017-12-15 2018-03-30 赵秀云 A kind of asepsis environment-protecting unloads first water
CN108158854A (en) * 2017-12-19 2018-06-15 徐州市国泰生物科技有限公司 One kind unloads first water and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59155474A (en) * 1983-02-22 1984-09-04 Koichi Takamura Remover for paint, etc. and method
CN1596873A (en) * 2003-09-17 2005-03-23 杜洪良 Formula of nail coating remover using lactone kind substance as solvent
CN104031194A (en) * 2014-06-27 2014-09-10 北京东方红升新能源应用技术研究院有限公司 New application of polyoxymethylene dimethyl ether as environment-friendly solvent oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59155474A (en) * 1983-02-22 1984-09-04 Koichi Takamura Remover for paint, etc. and method
CN1596873A (en) * 2003-09-17 2005-03-23 杜洪良 Formula of nail coating remover using lactone kind substance as solvent
CN104031194A (en) * 2014-06-27 2014-09-10 北京东方红升新能源应用技术研究院有限公司 New application of polyoxymethylene dimethyl ether as environment-friendly solvent oil

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Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107854333A (en) * 2017-12-15 2018-03-30 赵秀云 A kind of asepsis environment-protecting unloads first water
CN108158854A (en) * 2017-12-19 2018-06-15 徐州市国泰生物科技有限公司 One kind unloads first water and preparation method thereof

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