CN104371806A - Anti-rust oil containing cerium oxide and preparation method of anti-rust oil - Google Patents

Anti-rust oil containing cerium oxide and preparation method of anti-rust oil Download PDF

Info

Publication number
CN104371806A
CN104371806A CN201410590484.XA CN201410590484A CN104371806A CN 104371806 A CN104371806 A CN 104371806A CN 201410590484 A CN201410590484 A CN 201410590484A CN 104371806 A CN104371806 A CN 104371806A
Authority
CN
China
Prior art keywords
parts
cerium oxide
oil
benzoate
rust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410590484.XA
Other languages
Chinese (zh)
Inventor
傅杨华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEFEI ZHENGTUO DECORATION MATERIALS CO., LTD.
Original Assignee
HEFEI HUAYANG CONSTRUCTION MACHINERY CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEFEI HUAYANG CONSTRUCTION MACHINERY CO Ltd filed Critical HEFEI HUAYANG CONSTRUCTION MACHINERY CO Ltd
Priority to CN201410590484.XA priority Critical patent/CN104371806A/en
Publication of CN104371806A publication Critical patent/CN104371806A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses anti-rust oil containing cerium oxide and a preparation method of the anti-rust oil. The anti-rust oil is prepared from the following raw materials in parts by weight: 58-70 parts of organic silicone oil, 3.5-4.5 parts of barium petroleum sulfonate, 10-12 parts of cerium oxide, 20-25 parts of magnesium hydroxide, 4-6 parts of spirulina powder, 2-3 parts of benzotriazole, 1-3 parts of magnesium stearate, 4-5 parts of triethanolamine oleate, 5-7 parts of sodium dodecyl benzene sulfonate, 3-5 parts of ammonium molybdate, 2-4 parts of microcrystalline cellulose, 5-6 parts of cyclohexylamine benzoate, 3-4 parts of ammonium benzoate, 1-2 parts of sodium hexametaphosphate, 2-4 parts of antioxidant 1010, 3-5 parts of 2-methyl-4-ethylimidazole and 2-4 parts of N-methyl pyrrolidone. According to the method, defects of the prior art are overcome, the anti-rust property of the product is greatly improved, the weather tolerance can be effectively improved by adding cerium oxide rare-earth oxide into the anti-rust oil, the surface tension of an oil film can be improved, and the oil film has good spreadability on the surface of a metal base material. The anti-rust oil can be applied to anti-rust application in various fields.

Description

A kind of containing cerium oxide slushing oil and preparation method thereof
 
Technical field
The present invention relates to a kind of process for treating surface, be specifically related to a kind of containing cerium oxide slushing oil and preparation method thereof.
 
Background technology
Corrosion almost spreads all trades and professions, and its harm is very surprising, so slushing oil just arises at the historic moment.In machinofacture, transport, storage and normal logistics, slushing oil plays very important effect; But the development imbalances of every profession and trade, the production dispersion of processing slushing oil, the multiplex company standard of antirust grease production quality control, the kind that quality is close has different company standards.Though kind increases year by year, good and the bad difficulty point, uses confusion; No matter be in production, store, circulate or in use, have more serious corrosion phenomenon, propose more and more higher requirement to the metallic element of automobile is antirust; But at present industrial production not only lacks effective technique means for various metals alloy is antirust, and antirust valuable product.
 
Summary of the invention
The object of the present invention is to provide a kind of containing cerium oxide slushing oil and preparation method thereof.
The present invention adopts following technical scheme to achieve these goals:
Containing cerium oxide slushing oil, the weight part of its constitutive material is: organic silicone oil 58-70, barium mahogany sulfonate 3.5-4.5, cerium oxide 10-12, magnesium hydroxide 20-25, spirulina powder 4-6,124 Triazole 2-3, Magnesium Stearate 1-3, triethanolamine oleate 4-5, Sodium dodecylbenzene sulfonate 5-7, ammonium molybdate 3-5, Microcrystalline Cellulose 2-4, benzoate amine 5-6, Ammonium benzoate 3-4, Sodium hexametaphosphate 99 1-2, antioxidant 1010 2-4,2-methyl-4-ethyl imidazol(e) 3-5 and N-Methyl pyrrolidone 2-4.
Containing cerium oxide slushing oil, the weight part of its constitutive material is: organic silicone oil 65, barium mahogany sulfonate 4, cerium oxide 11, magnesium hydroxide 22, spirulina powder 5,124 Triazole 2.5, Magnesium Stearate 2, triethanolamine oleate 4.5, Sodium dodecylbenzene sulfonate 6, ammonium molybdate 4, Microcrystalline Cellulose 3, benzoate amine 5.5, Ammonium benzoate 3.5, Sodium hexametaphosphate 99 1.5, antioxidant 1010 3,2-methyl-4-ethyl imidazol(e) 4 and N-Methyl pyrrolidone 3.
Preparation method containing cerium oxide slushing oil, comprises the following steps:
(1) measure organic silicone oil by the weight part of constitutive material, add heated and stirred in reactor, to adding Magnesium Stearate, Sodium dodecylbenzene sulfonate, ammonium molybdate and Sodium hexametaphosphate 99 during 150-160 DEG C, stirring reaction 15-20min;
(2) cerium oxide, magnesium hydroxide and spirulina powder is taken by weight, grind rear mixing respectively, then add appropriate dehydrated alcohol, sinter 40-50 minute after mixing at temperature 600-700 DEG C, after sintering, recycling dehydrated alcohol is that medium milling pulping is for subsequent use;
(4) add the slurry for subsequent use of barium mahogany sulfonate, Microcrystalline Cellulose, benzoate amine, Ammonium benzoate and step (2) in step (1), be warming up to 180-200 DEG C, continue to stir, react after 40-50 minute, be cooled to 40-50 DEG C;
(5) in step (4), add other constitutive material by the weight part of constitutive material, after continuing to stir 4-5h filtration, get product.
Beneficial effect of the present invention:
Instant invention overcomes the deficiencies in the prior art, greatly improve the rust-preventing characteristic of product, adding cerium oxide rare earth oxide at slushing oil effectively can improve weathering resistance, improves the surface tension of oil film, good in the spreadability of metallic substrate surface, the present invention goes in the antirust application of each row.
 
Embodiment
Embodiment 1: containing cerium oxide slushing oil, the weight part (kg) of its constitutive material is: organic silicone oil 65, barium mahogany sulfonate 4, cerium oxide 11, magnesium hydroxide 22, spirulina powder 5,124 Triazole 2.5, Magnesium Stearate 2, triethanolamine oleate 4.5, Sodium dodecylbenzene sulfonate 6, ammonium molybdate 4, Microcrystalline Cellulose 3, benzoate amine 5.5, Ammonium benzoate 3.5, Sodium hexametaphosphate 99 1.5, antioxidant 1010 3,2-methyl-4-ethyl imidazol(e) 4 and N-Methyl pyrrolidone 3.
Preparation method containing cerium oxide slushing oil, comprises the following steps:
(1) measure organic silicone oil by the weight part of constitutive material, add heated and stirred in reactor, add Magnesium Stearate, Sodium dodecylbenzene sulfonate, ammonium molybdate and Sodium hexametaphosphate 99 to when 155 DEG C, stirring reaction 20min;
(2) take cerium oxide, magnesium hydroxide and spirulina powder by weight, grind rear mixing respectively, then add appropriate dehydrated alcohol, sinter 45 minutes after mixing at temperature 650 DEG C, after sintering, recycling dehydrated alcohol is that medium milling pulping is for subsequent use;
(4) add the slurry for subsequent use of barium mahogany sulfonate, Microcrystalline Cellulose, benzoate amine, Ammonium benzoate and step (2) in step (1), be warming up to 190 DEG C, continue to stir, react after 45 minutes, be cooled to 40-50 DEG C;
(5) in step (4), add other constitutive material by the weight part of constitutive material, after continuing to stir 4-5h filtration, get product.
The over-all properties of slushing oil prepared by above-described embodiment 1 is as follows: sticking power/level≤2 grade; 2, neutral salt spray corrosion test (h) >=92; 3, humid heat test (h) > 1100; 4, oil film time of drying (min) 14-15; 5, coating thickness (μm) < 4.1.

Claims (3)

1., containing a cerium oxide slushing oil, it is characterized in that the weight part of its constitutive material is: organic silicone oil 58-70, barium mahogany sulfonate 3.5-4.5, cerium oxide 10-12, magnesium hydroxide 20-25, spirulina powder 4-6,124 Triazole 2-3, Magnesium Stearate 1-3, triethanolamine oleate 4-5, Sodium dodecylbenzene sulfonate 5-7, ammonium molybdate 3-5, Microcrystalline Cellulose 2-4, benzoate amine 5-6, Ammonium benzoate 3-4, Sodium hexametaphosphate 99 1-2, antioxidant 1010 2-4,2-methyl-4-ethyl imidazol(e) 3-5 and N-Methyl pyrrolidone 2-4.
2. according to claim 1 containing cerium oxide slushing oil, it is characterized in that the weight part of its constitutive material is: organic silicone oil 65, barium mahogany sulfonate 4, cerium oxide 11, magnesium hydroxide 22, spirulina powder 5,124 Triazole 2.5, Magnesium Stearate 2, triethanolamine oleate 4.5, Sodium dodecylbenzene sulfonate 6, ammonium molybdate 4, Microcrystalline Cellulose 3, benzoate amine 5.5, Ammonium benzoate 3.5, Sodium hexametaphosphate 99 1.5, antioxidant 1010 3,2-methyl-4-ethyl imidazol(e) 4 and N-Methyl pyrrolidone 3.
3. the preparation method containing cerium oxide slushing oil as claimed in claim 1, is characterized in that comprising the following steps:
(1) measure organic silicone oil by the weight part of constitutive material, add heated and stirred in reactor, to adding Magnesium Stearate, Sodium dodecylbenzene sulfonate, ammonium molybdate and Sodium hexametaphosphate 99 during 150-160 DEG C, stirring reaction 15-20min;
(2) cerium oxide, magnesium hydroxide and spirulina powder is taken by weight, grind rear mixing respectively, then add appropriate dehydrated alcohol, sinter 40-50 minute after mixing at temperature 600-700 DEG C, after sintering, recycling dehydrated alcohol is that medium milling pulping is for subsequent use;
(4) add the slurry for subsequent use of barium mahogany sulfonate, Microcrystalline Cellulose, benzoate amine, Ammonium benzoate and step (2) in step (1), be warming up to 180-200 DEG C, continue to stir, react after 40-50 minute, be cooled to 40-50 DEG C;
(5) in step (4), add other constitutive material by the weight part of constitutive material, after continuing to stir 4-5h filtration, get product.
CN201410590484.XA 2014-10-29 2014-10-29 Anti-rust oil containing cerium oxide and preparation method of anti-rust oil Pending CN104371806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410590484.XA CN104371806A (en) 2014-10-29 2014-10-29 Anti-rust oil containing cerium oxide and preparation method of anti-rust oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410590484.XA CN104371806A (en) 2014-10-29 2014-10-29 Anti-rust oil containing cerium oxide and preparation method of anti-rust oil

Publications (1)

Publication Number Publication Date
CN104371806A true CN104371806A (en) 2015-02-25

Family

ID=52551004

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410590484.XA Pending CN104371806A (en) 2014-10-29 2014-10-29 Anti-rust oil containing cerium oxide and preparation method of anti-rust oil

Country Status (1)

Country Link
CN (1) CN104371806A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318572A (en) * 2016-08-10 2017-01-11 东至县洋湖镇希望皮具厂 Leather product zipper lubricating oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103352217A (en) * 2013-06-21 2013-10-16 安徽省六安市朝晖机械制造有限公司 Surface bluing anti-rust treatment process for workpiece
CN103966005A (en) * 2014-03-28 2014-08-06 安徽九华金润铜业有限公司 Drawing fluid for rapidly drawing copper wire
CN104004567A (en) * 2014-04-25 2014-08-27 蚌埠市鸿安精密机械有限公司 Antirust oil containing rare earth compound

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103352217A (en) * 2013-06-21 2013-10-16 安徽省六安市朝晖机械制造有限公司 Surface bluing anti-rust treatment process for workpiece
CN103966005A (en) * 2014-03-28 2014-08-06 安徽九华金润铜业有限公司 Drawing fluid for rapidly drawing copper wire
CN104004567A (en) * 2014-04-25 2014-08-27 蚌埠市鸿安精密机械有限公司 Antirust oil containing rare earth compound

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
刘程 李江华 刘博 孙丽艳: "《表面活性剂应用手册》", 30 September 2004, 化学工业出版社 *
张大全: "《气相缓蚀剂及其应用》", 30 April 2007, 化学工业出版社 *
王毓民: "《润滑材料与润滑技术》", 31 January 2005, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318572A (en) * 2016-08-10 2017-01-11 东至县洋湖镇希望皮具厂 Leather product zipper lubricating oil

Similar Documents

Publication Publication Date Title
KR101613952B1 (en) Water soluble composition for waterproof coating
CN104177895A (en) Graphene or graphite oxide-based anticorrosive coating and preparation method thereof
CN107653045A (en) Antirust oil and preparation method thereof
CN105542660B (en) A kind of heat molten type protective wax composite
CN103882451B (en) A kind of water base normal temperature rust-removing and antirusting agent and preparation method thereof
CN101348691A (en) Preparation of natural anti-rust lacquer
CN103555104A (en) High molecular material special for corrosion prevention of steel and iron, and preparation method and application process thereof
CN103254796A (en) Anti-rust oil for automobile parts and preparation method thereof
CN105907208A (en) Water-based metal anticorrosion thermal insulation compound paint and preparation method thereof
CN104371806A (en) Anti-rust oil containing cerium oxide and preparation method of anti-rust oil
CN103484215A (en) Dehydrating rust-proof oil
CN103756441A (en) Modified high chlorinated polyethylene antirust coating and preparation method thereof
CN103254795A (en) Damp and heat highly-resistant antirust oil and preparation method thereof
CN103254979B (en) Multi-base-oil anti-rust oil and preparation method thereof
CN107057572A (en) A kind of antirusting paint of automobile chassis and preparation method thereof
CN105647631A (en) A lubricating fluid for high-speed fine wire drawing of copper wires and a preparing method thereof
CN103497805A (en) Rust preventive oil and preparation method thereof
CN103820788B (en) A kind of antirust agent containing modified mullite powder
CN102993817A (en) Metal rust inhibitor containing peregal O
CN103232814A (en) Dehydration anti-rust oil and preparation method thereof
JP6764521B2 (en) Aqueous high temperature heat resistant titanium steel antibonding coating and its use
CN104911578A (en) Green environment-friendly aqueous rust inhibitor and preparation method thereof
CN103484200A (en) Soft film anti-rust oil
CN104531295A (en) Composite flexible-membrane antirust oil
CN103254785A (en) Long-acting anti-rust oil and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20160525

Address after: Luyang District of Hefei City Shouchun road 230001 Anhui province No. 356 merchants International Building room 1407

Applicant after: HEFEI ZHENGTUO DECORATION MATERIALS CO., LTD.

Address before: 230011 Luyang Industrial Park, Fuyang North Road, Luyang District, Anhui, Hefei

Applicant before: Hefei Huayang Construction Machinery Co.,Ltd.

RJ01 Rejection of invention patent application after publication

Application publication date: 20150225

RJ01 Rejection of invention patent application after publication