CN104371504A - Environment-friendly paint - Google Patents
Environment-friendly paint Download PDFInfo
- Publication number
- CN104371504A CN104371504A CN201410747745.4A CN201410747745A CN104371504A CN 104371504 A CN104371504 A CN 104371504A CN 201410747745 A CN201410747745 A CN 201410747745A CN 104371504 A CN104371504 A CN 104371504A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides environment-friendly paint. The environment-friendly paint comprises a component A, a component B and a component C which are in a ratio of 1:1:0.5. The component A is composed of a component A1 and a component A2. The component A1 comprises, by weight, 12.5-23 parts of deionized water, 14-30 parts of filler and 1-3 parts of first assistants. The component A2 comprises, by weight, 35-60 parts of water-borne epoxy resin, 10-15 parts of pure acrylic emulsion and 0.5-1 part of second assistant. The component B comprises, by weight, 15.5-30 parts of water-borne curing agents, 43-55 parts of color filler, 2-2.5 parts of third assistants and 22-30 parts of the deionized water. The component C comprises, by weight, 0.3-0.5 part of cellulose, 10-15 parts of light calcium carbonate, 5-10 parts of talcum powder, 15-25 parts of heavy calcium carbonate, 8-12 parts of modified acrylic emulsion, 0.1-0.5 part of sterilizing agent and 1-2 parts of antifreeze. The environment-friendly paint has the advantages of good painting effect, low harmful matter content, soft smell, low production cost, high stability and long service life.
Description
Technical field
The invention discloses a kind of coating, particularly a kind of environmental protection coating material for inner wall surface.
Background technology
Along with the continuous progress of society, people have had higher requirement to interior wall coating, and except ornamental, people more focus on the feature of environmental protection and high-performance.Tradition interior wall coating, as emulsion paint, there is good decorative property, with low cost, the feature of easy construction, but due to paint film itself more loose, really closely knit paint film cannot be formed, there is ventilation property, thus not reach good resistant effect.
Water-base epoxy wall paint is compared emulsion paint and is had more following clear superiority: coatingsurface is fine and close, be not easy to leave a trace, child's scribble water or environment-friendly type solvent are easy to scrub, and coating has superpower scrub resistance, coating not loss of gloss, colour-fast after cleaning.
The aqueous epoxy coating of present commercial type selects conventional liquid bisphenol A type epoxy resin and aqueous amine solidifying agent mostly, although this collocation can solve the series of problems such as resistant, but its feature of environmental protection and long-time operation cannot be met the need of market, universal use also just cannot be obtained.
Summary of the invention
The invention provides a kind of environmental protection coating material, it is made up of the component A of mass ratio 1: 1: 0.5, B component and component C, described component A is made up of pulp stage A1 component and letdown phase A2, wherein, pulp stage A1 component is made up of 12.5-23 mass parts deionized water, 14-30 mass parts filler, 1-3 mass parts first auxiliary agent; Letdown phase A2 component is made up of 35-60 mass parts aqueous epoxy resins, 10-15 mass parts pure-acrylic emulsion, 0.5-1 mass parts second auxiliary agent;
Described B component is made up of 15.5-30 mass parts waterborne curing agent, 43-55 mass parts color stuffing, 2-2.5 mass parts the 3rd auxiliary agent and 22-30 mass parts deionized water;
Wherein said first auxiliary agent is made up of 0.08-0.12 mass parts defoamer, 2.2-2.6 mass parts thickening material and 0.2-0.8 mass parts emulsifying agent; Described second auxiliary agent is made up of 0.3-0.8 mass parts defoamer and 0.2-0.7 mass parts sanitas; Described 3rd auxiliary agent is made up of 0.3-0.7 mass parts emulsifying agent, 0.2-0.4 mass parts wetting agent, 0.05-0.15 mass parts dispersion agent, 1.2-1.8 mass parts defoamer;
Described component C is by 0.3-0.5 parts by mass of cellulose, 10-15 mass parts light calcium carbonate, 5-10 mass parts talcum powder, 15-25 mass parts water-ground limestone, 8-12 mass parts modified acrylic acid emulsion, 0.1-0.5 mass parts sterilant, 1-2 mass parts frostproofer.
Preferably, described color stuffing is made up of 10 ~ 15 mass parts calcium carbonate, 20-30 mass parts titanium dioxide, 4-5 mass parts calcined kaolin, 5-6 mass parts zinc oxide.
Present invention also offers a kind of environmental protection coating material preparation method, it is characterized in that, comprise the following steps:
Component A, B component and component C is taken according to aforesaid mass parts;
Raw material described in component A pulp stage is stirred 60 ~ 120min in 1000 ~ 1200rpm, to make slurry fineness be less than 30 μm, and then adds the raw material described in letdown phase, stir 30 ~ 60min with 600 ~ 800rpm, filter, obtain component A;
Starting material described in B component are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain B component;
Starting material described in component C are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain component C;
Before application, component A, B component mix with 1: 1: 0.5 with component C, stir and get final product.
The present invention has following beneficial effect:
Product painting of the present invention is effective, harmful substance contents is low, smell is soft, production cost is low, good stability, long service life; In film process, there is chemical crosslink reaction, the webbed crosslinked paint film of shape, by the ratio of Reasonable adjustment resin and color stuffing, after making the coating of preparation brush solidification, form airtight physics paint film.The present invention arranges in pairs or groups use pure-acrylic emulsion, reduces the PVC of coating on the one hand, makes resin can be good at coated color stuffing, form closely knit paint film, improves anti-pollution characteristic; Another aspect by above pure-acrylic emulsion grafting to aqueous epoxy resins by emulsification, is utilized steric effect, plays shielding effect, thus reach ageing-resistant effect.
Certainly, implement arbitrary product of the present invention might not need to reach above-described all advantages simultaneously.
Specific embodiment
Embodiment one
Embodiment 1
Present embodiments provide a kind of environmental protection coating material, it is made up of the component A of mass ratio 1: 1: 0.5, B component and component C, described component A is made up of pulp stage A1 component and letdown phase A2, wherein, pulp stage A1 component is made up of 12.5-23 mass parts deionized water, 14-30 mass parts filler, 1-3 mass parts first auxiliary agent; Letdown phase A2 component is made up of 35-60 mass parts aqueous epoxy resins, 10-15 mass parts pure-acrylic emulsion, 0.5-1 mass parts second auxiliary agent;
Described B component is made up of 15.5-30 mass parts waterborne curing agent, 43-55 mass parts color stuffing, 2-2.5 mass parts the 3rd auxiliary agent and 22-30 mass parts deionized water;
Wherein said first auxiliary agent is made up of 0.08-0.12 mass parts defoamer, 2.2-2.6 mass parts thickening material and 0.2-0.8 mass parts emulsifying agent; Described second auxiliary agent is made up of 0.3-0.8 mass parts defoamer and 0.2-0.7 mass parts sanitas; Described 3rd auxiliary agent is made up of 0.3-0.7 mass parts emulsifying agent, 0.2-0.4 mass parts wetting agent, 0.05-0.15 mass parts dispersion agent, 1.2-1.8 mass parts defoamer;
Described component C is by 0.3-0.5 parts by mass of cellulose, 10-15 mass parts light calcium carbonate, 5-10 mass parts talcum powder, 15-25 mass parts water-ground limestone, 8-12 mass parts modified acrylic acid emulsion, 0.1-0.5 mass parts sterilant, 1-2 mass parts frostproofer.
Described color stuffing is made up of 10 ~ 15 mass parts calcium carbonate, 20-30 mass parts titanium dioxide, 4-5 mass parts calcined kaolin, 5-6 mass parts zinc oxide.
Component A, B component and component C is taken by above-mentioned mass parts;
Raw material described in component A pulp stage is stirred 60 ~ 120min in 1000 ~ 1200rpm, to make slurry fineness be less than 30 μm, and then adds the raw material described in letdown phase, stir 30 ~ 60min with 600 ~ 800rpm, filter, obtain component A;
Starting material described in B component are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain B component;
Starting material described in component C are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain component C;
Before application, component A, B component mix with 1: 1: 0.5 with component C, stir and get final product.
Product painting of the present invention is effective, harmful substance contents is low, smell is soft, production cost is low, good stability, long service life; In film process, there is chemical crosslink reaction, the webbed crosslinked paint film of shape, by the ratio of Reasonable adjustment resin and color stuffing, after making the coating of preparation brush solidification, form airtight physics paint film.The present invention arranges in pairs or groups use pure-acrylic emulsion, reduces the PVC of coating on the one hand, makes resin can be good at coated color stuffing, form closely knit paint film, improves anti-pollution characteristic; Another aspect by above pure-acrylic emulsion grafting to aqueous epoxy resins by emulsification, is utilized steric effect, plays shielding effect, thus reach ageing-resistant effect.
The disclosed preferred embodiment of the present invention just sets forth the present invention for helping above.Preferred embodiment does not have all details of detailed descriptionthe, does not limit the embodiment that this invention is only described yet.Obviously, according to the content of this specification sheets, can make many modifications and variations.This specification sheets is chosen and is specifically described these embodiments, is to explain principle of the present invention and practical application better, thus makes art technician understand well and to utilize the present invention.The present invention is only subject to the restriction of claims and four corner and equivalent.
Claims (3)
1. an environmental protection coating material, it is characterized in that, be made up of the component A of mass ratio 1: 1: 0.5, B component and component C, described component A is made up of pulp stage A1 component and letdown phase A2, wherein, pulp stage A1 component is made up of 12.5-23 mass parts deionized water, 14-30 mass parts filler, 1-3 mass parts first auxiliary agent; Letdown phase A2 component is made up of 35-60 mass parts aqueous epoxy resins, 10-15 mass parts pure-acrylic emulsion, 0.5-1 mass parts second auxiliary agent;
Described B component is made up of 15.5-30 mass parts waterborne curing agent, 43-55 mass parts color stuffing, 2-2.5 mass parts the 3rd auxiliary agent and 22-30 mass parts deionized water;
Wherein said first auxiliary agent is made up of 0.08-0.12 mass parts defoamer, 2.2-2.6 mass parts thickening material and 0.2-0.8 mass parts emulsifying agent; Described second auxiliary agent is made up of 0.3-0.8 mass parts defoamer and 0.2-0.7 mass parts sanitas; Described 3rd auxiliary agent is made up of 0.3-0.7 mass parts emulsifying agent, 0.2-0.4 mass parts wetting agent, 0.05-0.15 mass parts dispersion agent, 1.2-1.8 mass parts defoamer;
Described component C is by 0.3-0.5 parts by mass of cellulose, 10-15 mass parts light calcium carbonate, 5-10 mass parts talcum powder, 15-25 mass parts water-ground limestone, 8-12 mass parts modified acrylic acid emulsion, 0.1-0.5 mass parts sterilant, 1-2 mass parts frostproofer.
2. environmental protection coating material as claimed in claim 1, it is characterized in that, described color stuffing is made up of 10 ~ 15 mass parts calcium carbonate, 20-30 mass parts titanium dioxide, 4-5 mass parts calcined kaolin, 5-6 mass parts zinc oxide.
3. a kind of preparation method of environmental protection coating material according to claim 1, is characterized in that, comprise the following steps:
Component A, B component and component C is taken by mass parts according to claim 1;
Raw material described in component A pulp stage is stirred 60 ~ 120min in 1000 ~ 1200rpm, to make slurry fineness be less than 30 μm, and then adds the raw material described in letdown phase, stir 30 ~ 60min with 600 ~ 800rpm, filter, obtain component A;
Starting material described in B component are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain B component;
Starting material described in component C are stirred 60 ~ 90min mixing in 1000 ~ 1200rpm, filters, obtain component C;
Before application, component A, B component mix with 1: 1: 0.5 with component C, stir and get final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410747745.4A CN104371504A (en) | 2014-12-05 | 2014-12-05 | Environment-friendly paint |
Applications Claiming Priority (1)
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CN201410747745.4A CN104371504A (en) | 2014-12-05 | 2014-12-05 | Environment-friendly paint |
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CN104371504A true CN104371504A (en) | 2015-02-25 |
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CN201410747745.4A Pending CN104371504A (en) | 2014-12-05 | 2014-12-05 | Environment-friendly paint |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105400380A (en) * | 2015-11-14 | 2016-03-16 | 合肥标兵凯基新型材料有限公司 | Modified epoxy resin coating |
CN106118147A (en) * | 2016-06-27 | 2016-11-16 | 安徽省思维新型建材有限公司 | Coating for interior wall |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1654564A (en) * | 2004-02-13 | 2005-08-17 | 陈敬福 | Coating for color roof tile and its use method |
CN102757713A (en) * | 2012-08-02 | 2012-10-31 | 广州飞宇建材科技有限公司 | Inner wall coating with high stain resistance and preparation method thereof |
-
2014
- 2014-12-05 CN CN201410747745.4A patent/CN104371504A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1654564A (en) * | 2004-02-13 | 2005-08-17 | 陈敬福 | Coating for color roof tile and its use method |
CN102757713A (en) * | 2012-08-02 | 2012-10-31 | 广州飞宇建材科技有限公司 | Inner wall coating with high stain resistance and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105400380A (en) * | 2015-11-14 | 2016-03-16 | 合肥标兵凯基新型材料有限公司 | Modified epoxy resin coating |
CN106118147A (en) * | 2016-06-27 | 2016-11-16 | 安徽省思维新型建材有限公司 | Coating for interior wall |
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Application publication date: 20150225 |
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