CN104371165A - High-polymer ceramic composite material - Google Patents
High-polymer ceramic composite material Download PDFInfo
- Publication number
- CN104371165A CN104371165A CN201410585880.3A CN201410585880A CN104371165A CN 104371165 A CN104371165 A CN 104371165A CN 201410585880 A CN201410585880 A CN 201410585880A CN 104371165 A CN104371165 A CN 104371165A
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- parts
- coupling agent
- polymer ceramic
- matrix material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a high-polymer ceramic composite material which is prepared from the following raw materials in parts by weight: 20-40 parts of polyethylene, 10-15 parts of nylon, 30-50 parts of nano ceramic powder, 10-15 parts of glass fiber, 1-5 parts of graphite, 1-5 parts of coupling agent, 1-3 parts of antistatic agent and 1-3 parts of curing agent. The ceramic composite material provided by the invention has the advantages of favorable mechanical strength, favorable toughness, favorable wear resistance, light weight, long service life and low cost, and also has favorable properties in the aspects of flame retardancy, static resistance and the like by utilizing the high hardness and wear resistance of the ceramic and the corrosion resistance and impact resistance of the plastic.
Description
Technical field
The present invention relates to polymeric material field, be specially a kind of polymer ceramic matrix material.
Background technology
Matrix material has the good over-all properties that differing materials is learnt from other's strong points to offset one's weaknesses mutually usually.Matrix material has the feature of two or more material concurrently, can improve the performance of single-material, as improved intensity, increasing toughness and improve dielectric properties etc.As the ceramic composite of high-temperature structural material, be mainly used in aerospace, the departments such as military project.In addition, also various ceramic composite is extensively adopted in fields such as machinery, chemical industry, electronic technology.Ceramic matric composite take pottery as a class matrix material of matrix and various fiber composite.Ceramic matrix can be the high-temperature structural ceramics such as silicon nitride, silicon carbide.These advanced ceramics have the excellent properties such as high temperature resistant, high strength and rigidity, relative weight be lighter, anticorrosive, and its fatal weakness is enbrittled, and when being in stressed condition, can crack, and even fracture causes material failure.And adopt high strength, elastomeric fiber and matrix compound, be then the effective means improving ceramics toughness and reliability.Fiber can stop the expansion of crackle, thus obtains the FRCMC of excellent in toughness.Ceramic matric composite has excellent resistance to elevated temperatures, main as high temperature and high abrasion goods.Its maximum operation (service) temperature depends primarily on matrix characteristics.Plastics macromolecular material, heatproof, resistance to local gas holdup, not as ceramic composite, and there is life-span short, the defect such as maintenance is large in the performance such as wear-resisting, and this hairpin proposes a kind of new technical scheme to ceramic composite.
Summary of the invention
The object of this invention is to provide a kind of high strength, protection against corrosion, lightweight, elastomeric polymer ceramic matrix material.
The present invention is achieved through the following technical solutions:
A kind of polymer ceramic matrix material, comprises the raw material composition of following parts by weight: polyethylene 20 ~ 40 parts, nylon 10 ~ 15 parts, nano-ceramic powder 30 ~ 50 parts, 10 ~ 15 parts, glass fibre, 1 ~ 5 part, graphite, coupling agent 1 ~ 5 part, 1 ~ 3 part, static inhibitor, 1 ~ 3 part, solidifying agent.
Preferably, described coupling agent is Silane coupling agent KH550 or silane coupling agent KH560.
Preferably, described static inhibitor is the cruel amine of oxyethyl group bay.
Preferably, described solidifying agent is m-xylene diamine, mphenylenediamine one or both mixtures wherein.
The invention has the beneficial effects as follows: ceramic composite proposed by the invention has good physical strength, toughness, antiwear characteristics, utilize high rigidity, the wear resisting property of pottery, and the antiseptic property of plastics, shock-resistant ability, simultaneously in fire-retardant, antistatic etc., also there is good performance, and lightweight, long service life, cost is low.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
Embodiment 1
A kind of polymer ceramic matrix material, comprises the raw material composition of following parts by weight: polyethylene 20 parts, nylon 10 parts, nano-ceramic powder 30 parts, 10 parts, glass fibre, 1 part, graphite, Silane coupling agent KH550 1 part, the cruel amine of oxyethyl group bay 1 part, m-xylene diamine 1 part.
Embodiment 2
A kind of polymer ceramic matrix material, comprises the raw material composition of following parts by weight: polyethylene 30 parts, nylon 12 parts, nano-ceramic powder 40 parts, 12 parts, glass fibre, 3 parts, graphite, Silane coupling agent KH550 3 parts, the cruel amine of oxyethyl group bay 2 parts, m-xylene diamine 2 parts.
Embodiment 3
A kind of polymer ceramic matrix material, comprises the raw material composition of following parts by weight: polyethylene 40 parts, nylon 15 parts, nano-ceramic powder 50 parts, 15 parts, glass fibre, 5 parts, graphite, Silane coupling agent KH550 5 parts, the cruel amine of oxyethyl group bay 3 parts, m-xylene diamine 3 parts.
Ceramic composite proposed by the invention has good physical strength, toughness, antiwear characteristics, utilize high rigidity, the wear resisting property of pottery, and the antiseptic property of plastics, shock-resistant ability, simultaneously in fire-retardant, antistatic etc., also there is good performance, and lightweight, long service life, cost is low.
The above is only embodiments of the invention, is not restriction the present invention being made to any other form, and any amendment done according to technical spirit of the present invention or equivalent variations, still belong to the present invention's scope required for protection.
Claims (4)
1. a polymer ceramic matrix material, is characterized in that: the raw material composition comprising following parts by weight: polyethylene 20 ~ 40 parts, nylon 10 ~ 15 parts, nano-ceramic powder 30 ~ 50 parts, 10 ~ 15 parts, glass fibre, 1 ~ 5 part, graphite, coupling agent 1 ~ 5 part, 1 ~ 3 part, static inhibitor, 1 ~ 3 part, solidifying agent.
2. a kind of polymer ceramic matrix material according to claim 1, is characterized in that: described coupling agent is Silane coupling agent KH550 or silane coupling agent KH560.
3. a kind of polymer ceramic matrix material according to claim 1, is characterized in that: described static inhibitor is the cruel amine of oxyethyl group bay.
4. a kind of polymer ceramic matrix material according to claim 1, is characterized in that: described solidifying agent is m-xylene diamine, mphenylenediamine one or both mixtures wherein.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410585880.3A CN104371165A (en) | 2014-10-28 | 2014-10-28 | High-polymer ceramic composite material |
Applications Claiming Priority (1)
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CN201410585880.3A CN104371165A (en) | 2014-10-28 | 2014-10-28 | High-polymer ceramic composite material |
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CN104371165A true CN104371165A (en) | 2015-02-25 |
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CN201410585880.3A Pending CN104371165A (en) | 2014-10-28 | 2014-10-28 | High-polymer ceramic composite material |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105081327A (en) * | 2015-08-28 | 2015-11-25 | 南通高欣耐磨科技股份有限公司 | High-strength and shock-resistance type metal ceramic composite lining plate and preparation method thereof |
CN105088047A (en) * | 2015-08-28 | 2015-11-25 | 南通高欣耐磨科技股份有限公司 | Enhanced metal ceramic abrasion-resistant composite material and preparation method thereof |
CN105670088A (en) * | 2016-04-14 | 2016-06-15 | 季红军 | Preparation method of halogen-free high-fire-retardancy cable material |
CN107118425A (en) * | 2017-06-27 | 2017-09-01 | 苏州菱慧电子科技有限公司 | A kind of wear-resisting high-molecular composite material |
CN107857995A (en) * | 2017-11-08 | 2018-03-30 | 广州维邦新材料科技有限公司 | A kind of automobile connector nylon composite materials and its processing method |
CN108148398A (en) * | 2017-12-23 | 2018-06-12 | 季梅 | A kind of wear-resistant ceramic material and its preparation method and application |
-
2014
- 2014-10-28 CN CN201410585880.3A patent/CN104371165A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105081327A (en) * | 2015-08-28 | 2015-11-25 | 南通高欣耐磨科技股份有限公司 | High-strength and shock-resistance type metal ceramic composite lining plate and preparation method thereof |
CN105088047A (en) * | 2015-08-28 | 2015-11-25 | 南通高欣耐磨科技股份有限公司 | Enhanced metal ceramic abrasion-resistant composite material and preparation method thereof |
WO2017035916A1 (en) * | 2015-08-28 | 2017-03-09 | 南通高欣耐磨科技股份有限公司 | Enhanced cermet wear-resistant composite material and method for fabrication thereof |
CN105670088A (en) * | 2016-04-14 | 2016-06-15 | 季红军 | Preparation method of halogen-free high-fire-retardancy cable material |
CN107118425A (en) * | 2017-06-27 | 2017-09-01 | 苏州菱慧电子科技有限公司 | A kind of wear-resisting high-molecular composite material |
CN107857995A (en) * | 2017-11-08 | 2018-03-30 | 广州维邦新材料科技有限公司 | A kind of automobile connector nylon composite materials and its processing method |
CN108148398A (en) * | 2017-12-23 | 2018-06-12 | 季梅 | A kind of wear-resistant ceramic material and its preparation method and application |
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Application publication date: 20150225 |
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