CN104364227B - 乙酸的生产过程 - Google Patents

乙酸的生产过程 Download PDF

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Publication number
CN104364227B
CN104364227B CN201280061183.7A CN201280061183A CN104364227B CN 104364227 B CN104364227 B CN 104364227B CN 201280061183 A CN201280061183 A CN 201280061183A CN 104364227 B CN104364227 B CN 104364227B
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CN
China
Prior art keywords
water
acetic acid
weight
stream
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280061183.7A
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English (en)
Chinese (zh)
Other versions
CN104364227A (zh
Inventor
N·C·哈利南
J·D·赫恩
M·S·帕特尔
M·E·菲茨帕特里克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Lyondell Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Technology LP filed Critical Lyondell Chemical Technology LP
Publication of CN104364227A publication Critical patent/CN104364227A/zh
Application granted granted Critical
Publication of CN104364227B publication Critical patent/CN104364227B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280061183.7A 2011-12-21 2012-12-14 乙酸的生产过程 Expired - Fee Related CN104364227B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161578709P 2011-12-21 2011-12-21
US61/578709 2011-12-21
US13/713930 2012-12-13
US13/713,930 US9090554B2 (en) 2011-12-21 2012-12-13 Process for the manufacture of acetic acid
PCT/US2012/069735 WO2013096118A1 (en) 2011-12-21 2012-12-14 Process for the manufacture of acetic acid

Publications (2)

Publication Number Publication Date
CN104364227A CN104364227A (zh) 2015-02-18
CN104364227B true CN104364227B (zh) 2016-11-09

Family

ID=48669376

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280061183.7A Expired - Fee Related CN104364227B (zh) 2011-12-21 2012-12-14 乙酸的生产过程

Country Status (10)

Country Link
US (1) US9090554B2 (enExample)
EP (1) EP2794542B1 (enExample)
KR (3) KR101950076B1 (enExample)
CN (1) CN104364227B (enExample)
BR (1) BR112014015212B8 (enExample)
CA (1) CA2859037C (enExample)
IN (1) IN2014CN04560A (enExample)
RU (1) RU2583789C2 (enExample)
SG (1) SG11201402858PA (enExample)
WO (1) WO2013096118A1 (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9505696B2 (en) * 2015-02-04 2016-11-29 Celanese International Corporation Process to control HI concentration in residuum stream

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723660A (en) * 1995-04-24 1998-03-03 Daicel Chemical Industries, Ltd. Process for producing acetic acid
CN1449369A (zh) * 2000-07-06 2003-10-15 米兰纽姆石化公司 用于乙酸制备的过程控制
US20100249453A1 (en) * 2009-03-30 2010-09-30 Noel Hallinan Removing hydrocarbon impurities from acetic acid production intermediate

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102922A (en) 1974-12-30 1978-07-25 Monsanto Company Purification of carbonylation products
DE3107731A1 (de) * 1981-02-28 1982-09-16 Basf Ag, 6700 Ludwigshafen Verfahren zur abtrennung organischer jod-verbindungen von carbonylierungsprodukten des methanols, methylacetates und dimethylethers
US5026908A (en) 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5001259A (en) 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
AU8790391A (en) 1990-11-19 1992-05-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
AU639630B2 (en) 1991-01-28 1993-07-29 Celanese International Corporation Removal of carbonyl impurities from carbonylation process stream
GB9106298D0 (en) 1991-03-25 1991-05-08 Bp Chem Int Ltd Process
SG44317A1 (en) 1994-06-15 1997-12-19 Daicel Chem Process for producing high purity acetic acid
US5599976A (en) 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
US5783731A (en) 1995-09-11 1998-07-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
US5817869A (en) 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
US6339171B1 (en) 1996-10-18 2002-01-15 Celanese International Corporation Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream
IN192600B (enExample) 1996-10-18 2004-05-08 Hoechst Celanese Corp
GB9625335D0 (en) 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
US7271293B2 (en) 2004-03-02 2007-09-18 Celanese International Corporation Control method for process of removing permanganate reducing compounds from methanol carbonylation process
US7208624B2 (en) * 2004-03-02 2007-04-24 Celanese International Corporation Process for producing acetic acid
US7855306B2 (en) 2005-04-28 2010-12-21 Celanese International Corporation Process for the production of acetic acid
TWI465424B (zh) 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
US7619113B2 (en) * 2007-09-27 2009-11-17 Celanese International Corporation Method and apparatus for making acetic acid with improved purification
US7790919B2 (en) 2008-03-17 2010-09-07 Lyondell Chemical Technology, L.P. Removing hydrocarbon impurities from acetic acid production process
US7812191B2 (en) 2008-05-07 2010-10-12 Lyondell Chemical Technology, L.P. Removing hydrocarbon impurities from acetic acid by ionic liquid extraction
US7790920B2 (en) 2008-09-11 2010-09-07 Lyondell Chemical Technology, L.P. Preparation of acetic acid

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5723660A (en) * 1995-04-24 1998-03-03 Daicel Chemical Industries, Ltd. Process for producing acetic acid
CN1449369A (zh) * 2000-07-06 2003-10-15 米兰纽姆石化公司 用于乙酸制备的过程控制
US20100249453A1 (en) * 2009-03-30 2010-09-30 Noel Hallinan Removing hydrocarbon impurities from acetic acid production intermediate

Also Published As

Publication number Publication date
CA2859037A1 (en) 2013-06-27
CN104364227A (zh) 2015-02-18
RU2583789C2 (ru) 2016-05-10
SG11201402858PA (en) 2014-09-26
RU2014127297A (ru) 2016-02-10
KR101950076B1 (ko) 2019-05-10
EP2794542B1 (en) 2018-03-21
BR112014015212B8 (pt) 2022-07-12
KR20140100998A (ko) 2014-08-18
US9090554B2 (en) 2015-07-28
BR112014015212B1 (pt) 2020-11-10
KR20170028454A (ko) 2017-03-13
KR20160081997A (ko) 2016-07-08
WO2013096118A1 (en) 2013-06-27
CA2859037C (en) 2016-05-24
BR112014015212A2 (pt) 2017-07-04
EP2794542A1 (en) 2014-10-29
US20130296616A1 (en) 2013-11-07
IN2014CN04560A (enExample) 2015-09-18
EP2794542A4 (en) 2015-05-27

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
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GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20161109