CN104356785A - Ageing-resistant fluorine paint for solar cell backboard and preparation method of ageing-resistant fluorine paint - Google Patents
Ageing-resistant fluorine paint for solar cell backboard and preparation method of ageing-resistant fluorine paint Download PDFInfo
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- CN104356785A CN104356785A CN201410639441.6A CN201410639441A CN104356785A CN 104356785 A CN104356785 A CN 104356785A CN 201410639441 A CN201410639441 A CN 201410639441A CN 104356785 A CN104356785 A CN 104356785A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
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- Photovoltaic Devices (AREA)
Abstract
The invention relates to ageing-resistant fluorine paint for a solar cell backboard and a preparation method of the ageing-resistant fluorine paint. The ageing-resistant fluorine paint for the solar cell backboard comprises the following raw materials in parts by mass: 30-45 parts of fluorocarbon resin, 5-16 parts of hydroxyethyl cellulose, 9-15 parts of lignosulfonate, 20-26 parts of light calcium carbonate, 5-14 parts of graphene, 5-9 parts of polyvinyl alcohol, 5-13 parts of trioctyl citrate, 6-12 parts of sebacic dihydrazide, 15-20 parts of ethanol, and 30-38 parts of water. The paint disclosed by the invention not only has good mechanical property, but also has excellent abrasion resistance. The paint has excellent ageing resistance and corrosion resistance.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of solar cell backboard ageing-resistant fluoro coatings and preparation method thereof.
Background technology
Paint is a kind of mixture decorating and protect article with organic or inorganic material.The origin of paint there is no final conclusion.B.C. 6000, China with mineral compound and pigment dyestuff baking mixed to paint improved.B.C. 1500, in France and Hispanic cavern, paint was for drawing and decoration.B.C. 1500, Egyptian's dyestuff such as indigo and madder manufactured blue and red pigment, but this paint is still far from perfect.In 18th century, due to the exploitation to Semen Lini oil and zinc oxide, paint industry is developed rapidly.In 20th century, painting technology has had significant development, has occurred that clinging power is larger, the paint of higher, fire-retardant, the anticorrosive shades of colour high with thermostability of glossiness.
At present along with the development of sun power, along with the solar paint risen also has good prospect, but existing sun power coating mostly is absorbing coating, and sun power surface coating is less, and still there is many deficiencies.The Chinese patent being 201310580406.7 as application number discloses a kind of aging resistant coating, but its mechanical property is poor; The Chinese patent being 201410207583.5 as application number discloses a kind of anti-ageing epoxy paint, but its wear resistance and ageing resistance are all to be improved.
Therefore how to overcome the deficiencies in the prior art, become the technical barrier that this area is urgently to be resolved hurrily.
Summary of the invention
The object of this invention is to provide a kind of solar cell backboard ageing-resistant fluoro coatings and preparation method thereof, solve the deficiency that existing solar cell backboard coating property is poor.
Present invention employs following technical scheme:
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 30-45 part, Natvosol 5-16 part, sulfonated lignin 9-15 part, light calcium carbonate 20-26 part, Graphene 5-14 part, polyvinyl alcohol 5-9 part, trioctyl lemon acid 5-13 part, sebacic dihydrazide 6-12 part, ethanol 15-20 part, water 30-38 part.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7-14 part, sulfonated lignin 11-13 part, light calcium carbonate 21-25 part, Graphene 7-12 part, polyvinyl alcohol 6-8 part, trioctyl lemon acid 7-11 part, sebacic dihydrazide 8-10 part, ethanol 16-19 part, water 32-36 part.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 34-40 part, Natvosol 8-12 part, sulfonated lignin 12-13 part, light calcium carbonate 22-24 part, Graphene 8-11 part, polyvinyl alcohol 7-8 part, trioctyl lemon acid 8-10 part, sebacic dihydrazide 8-9 part, ethanol 17-18 part, water 34-35 part.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7 parts, sulfonated lignin 11 parts, light calcium carbonate 21 parts, Graphene 7 parts, polyvinyl alcohol 6 parts, trioctyl lemon acid 7 parts, sebacic dihydrazide 8 parts, ethanol 16 parts, 32 parts, water.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 42 parts, Natvosol 14 parts, sulfonated lignin 13 parts, light calcium carbonate 25 parts, Graphene 12 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 11 parts, sebacic dihydrazide 10 parts, ethanol 19 parts, 36 parts, water.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 34 parts, Natvosol 8 parts, sulfonated lignin 12 parts, light calcium carbonate 22 parts, Graphene 8 parts, polyvinyl alcohol 7 parts, trioctyl lemon acid 8 parts, sebacic dihydrazide 8 parts, ethanol 17 parts, 34 parts, water.
The ageing-resistant fluoro coatings of described solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 40 parts, Natvosol 12 parts, sulfonated lignin 13 parts, light calcium carbonate 24 parts, Graphene 11 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 10 parts, sebacic dihydrazide 9 parts, ethanol 18 parts, 35 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 50-60 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
beneficial effect
The present invention is by composite to fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene, polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide, ethanol and hydration reason, gained coating not only has good mechanical property, also has excellent wear resisting property; Gained coating of the present invention has excellent ageing resistance and antiseptic property; Preparation method of the present invention is simple, is suitable for applying on a large scale.
Embodiment
Further illustrate below in conjunction with embodiment.
embodiment 1
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 30 parts, Natvosol 5 parts, sulfonated lignin 9 parts, light calcium carbonate 20 parts, Graphene 5 parts, polyvinyl alcohol 5 parts, trioctyl lemon acid 5 parts, sebacic dihydrazide 6 parts, ethanol 15 parts, 30 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 50 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
embodiment 2
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 45 parts, Natvosol 16 parts, sulfonated lignin 15 parts, light calcium carbonate 26 parts, Graphene 14 parts, polyvinyl alcohol 9 parts, trioctyl lemon acid 13 parts, sebacic dihydrazide 12 parts, ethanol 20 parts, 38 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 60 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
embodiment 3
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7 parts, sulfonated lignin 11 parts, light calcium carbonate 21 parts, Graphene 7 parts, polyvinyl alcohol 6 parts, trioctyl lemon acid 7 parts, sebacic dihydrazide 8 parts, ethanol 16 parts, 32 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 55 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
embodiment 4
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 42 parts, Natvosol 14 parts, sulfonated lignin 13 parts, light calcium carbonate 25 parts, Graphene 12 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 11 parts, sebacic dihydrazide 10 parts, ethanol 19 parts, 36 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 52 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
embodiment 5
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 34 parts, Natvosol 8 parts, sulfonated lignin 12 parts, light calcium carbonate 22 parts, Graphene 8 parts, polyvinyl alcohol 7 parts, trioctyl lemon acid 8 parts, sebacic dihydrazide 8 parts, ethanol 17 parts, 34 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 54 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
embodiment 6
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 40 parts, Natvosol 12 parts, sulfonated lignin 13 parts, light calcium carbonate 24 parts, Graphene 11 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 10 parts, sebacic dihydrazide 9 parts, ethanol 18 parts, 35 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 56 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
reference examples 1
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7 parts, sulfonated lignin 11 parts, light calcium carbonate 21 parts, Graphene 7 parts, polyvinyl alcohol 6 parts, trioctyl lemon acid 7 parts, sebacic dihydrazide 8 parts, ethanol 16 parts, 32 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 55 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
reference examples 2
The ageing-resistant fluoro coatings of solar cell backboard, comprises the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7 parts, sulfonated lignin 11 parts, light calcium carbonate 21 parts, Graphene 7 parts, polyvinyl alcohol 6 parts, trioctyl lemon acid 7 parts, sebacic dihydrazide 8 parts, ethanol 16 parts, 32 parts, water.
The described solar cell backboard preparation method of ageing-resistant fluoro coatings, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 55 DEG C, add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively again, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
performance test
Embodiment 1 to 6, reference examples 1 and 2 gained finished product are carried out performance test, wherein, film aging (artificial acceleration) performance test is carried out to coating gained coating of the present invention, according to " paint film weatherability assessment method ", paint film destruction situation and discoloration is evaluated, the coatingsurface degree of being damaged is divided into 5 grades, 0 represents unchanged, 1 represents very slight, and 2 represent slight, and 3 represent medium, 4 represent comparatively large, and 5 represent serious; Variable color ranking adopts visual colorimetry and passes through its value of chromatism of Instrument measuring.The mensuration of paint film resistance toheat, four blocks of steel sheets apply coating of the present invention, steel plate specification is 60mm × 020mm × 0.5mm, coating thickness 64 μm, test specimens is put into air blast constant temperature oven, place 24h at 160 DEG C, rear taking-up is cooled to room temperature 25 DEG C ± 2 DEG C, checks with or without cracking, bubbling, elephant skin phenomenon.Test-results is as shown in the table:
Table 1 performance test table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Reference examples 1 | Reference examples 2 | |
| Surface drying time, h | 1h | 1h | 1h | 1h | 1h | 1h | 4h | 4h |
| Sticking power (drawing circle method), level | 1 | 1 | 1 | 1 | 1 | 1 | 2 | 2 |
| Wear resistance | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Difference | Difference |
| Variable color grade, level | 1 | 1 | 1 | 1 | 1 | 1 | 4 | 5 |
As can be seen from Table 1, embodiment 3 is most preferred embodiment, and products obtained therefrom of the present invention all has good over-all properties.
Claims (8)
1. the ageing-resistant fluoro coatings of solar cell backboard, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 30-45 part, Natvosol 5-16 part, sulfonated lignin 9-15 part, light calcium carbonate 20-26 part, Graphene 5-14 part, polyvinyl alcohol 5-9 part, trioctyl lemon acid 5-13 part, sebacic dihydrazide 6-12 part, ethanol 15-20 part, water 30-38 part.
2. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7-14 part, sulfonated lignin 11-13 part, light calcium carbonate 21-25 part, Graphene 7-12 part, polyvinyl alcohol 6-8 part, trioctyl lemon acid 7-11 part, sebacic dihydrazide 8-10 part, ethanol 16-19 part, water 32-36 part.
3. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 34-40 part, Natvosol 8-12 part, sulfonated lignin 12-13 part, light calcium carbonate 22-24 part, Graphene 8-11 part, polyvinyl alcohol 7-8 part, trioctyl lemon acid 8-10 part, sebacic dihydrazide 8-9 part, ethanol 17-18 part, water 34-35 part.
4. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 32-42 part, Natvosol 7 parts, sulfonated lignin 11 parts, light calcium carbonate 21 parts, Graphene 7 parts, polyvinyl alcohol 6 parts, trioctyl lemon acid 7 parts, sebacic dihydrazide 8 parts, ethanol 16 parts, 32 parts, water.
5. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 42 parts, Natvosol 14 parts, sulfonated lignin 13 parts, light calcium carbonate 25 parts, Graphene 12 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 11 parts, sebacic dihydrazide 10 parts, ethanol 19 parts, 36 parts, water.
6. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 34 parts, Natvosol 8 parts, sulfonated lignin 12 parts, light calcium carbonate 22 parts, Graphene 8 parts, polyvinyl alcohol 7 parts, trioctyl lemon acid 8 parts, sebacic dihydrazide 8 parts, ethanol 17 parts, 34 parts, water.
7. the ageing-resistant fluoro coatings of solar cell backboard according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: fluorocarbon resin 40 parts, Natvosol 12 parts, sulfonated lignin 13 parts, light calcium carbonate 24 parts, Graphene 11 parts, polyvinyl alcohol 8 parts, trioctyl lemon acid 10 parts, sebacic dihydrazide 9 parts, ethanol 18 parts, 35 parts, water.
8. the solar cell backboard according to claim 1 preparation method of ageing-resistant fluoro coatings, it is characterized in that, step is as follows: according to quality proportioning, successively fluorocarbon resin, Natvosol, sulfonated lignin, light calcium carbonate, Graphene are added to the water, stir, be warming up to 50-60 DEG C, then add polyvinyl alcohol, trioctyl lemon acid, sebacic dihydrazide and ethanol successively, stir, obtain the ageing-resistant fluoro coatings of described sun power solar cell backboard.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410639441.6A CN104356785A (en) | 2014-11-13 | 2014-11-13 | Ageing-resistant fluorine paint for solar cell backboard and preparation method of ageing-resistant fluorine paint |
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| CN201410639441.6A CN104356785A (en) | 2014-11-13 | 2014-11-13 | Ageing-resistant fluorine paint for solar cell backboard and preparation method of ageing-resistant fluorine paint |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338163A (en) * | 2008-08-12 | 2009-01-07 | 山西天时涂料装饰有限公司 | Elastic emulsion paint and method for preparing same |
| JP2009158778A (en) * | 2007-12-27 | 2009-07-16 | Toppan Printing Co Ltd | Solar cell module backsheet laminate |
| CN102516852A (en) * | 2011-12-16 | 2012-06-27 | 新高电子材料（中山）有限公司 | Weather-resistant and high thermal conductive coating, radiating solar rear panel and efficient solar cell panel |
| CN102746754A (en) * | 2012-05-15 | 2012-10-24 | 乐凯胶片股份有限公司 | Environment-friendly solar cell back film |
-
2014
- 2014-11-13 CN CN201410639441.6A patent/CN104356785A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009158778A (en) * | 2007-12-27 | 2009-07-16 | Toppan Printing Co Ltd | Solar cell module backsheet laminate |
| CN101338163A (en) * | 2008-08-12 | 2009-01-07 | 山西天时涂料装饰有限公司 | Elastic emulsion paint and method for preparing same |
| CN102516852A (en) * | 2011-12-16 | 2012-06-27 | 新高电子材料（中山）有限公司 | Weather-resistant and high thermal conductive coating, radiating solar rear panel and efficient solar cell panel |
| WO2013086814A1 (en) * | 2011-12-16 | 2013-06-20 | 新高电子材料（中山）有限公司 | Weather-resistant coating with high thermal conductivity, heat-dissipating solar back sheet, and highly efficient solar cell panel |
| CN102746754A (en) * | 2012-05-15 | 2012-10-24 | 乐凯胶片股份有限公司 | Environment-friendly solar cell back film |
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Application publication date: 20150218 |