CN104356745A - High-stability UV (Ultraviolet) light curable water-based ink for glass - Google Patents
High-stability UV (Ultraviolet) light curable water-based ink for glass Download PDFInfo
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- CN104356745A CN104356745A CN201410585281.1A CN201410585281A CN104356745A CN 104356745 A CN104356745 A CN 104356745A CN 201410585281 A CN201410585281 A CN 201410585281A CN 104356745 A CN104356745 A CN 104356745A
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- curable water
- high stability
- glass high
- borne ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of coatings, in particular to high-stability UV (Ultraviolet) light curable water-based ink for glass. The high-stability UV light curable water-based ink for the glass is prepared by the following raw materials in part by weight: 50-60 parts of acrylate modified polysiloxane prepolymer, 1-2 parts of pigment, 2-5 parts of a photopolymerization initiator, 10-20 parts of an active diluent, 1-5 parts of an antifoaming agent and 100-120 parts of an aqueous solvent. The high-stability UV light curable water-based ink has the advantages that the storage stability, the curing rate, the flexibility and the hardness are good, energy sources are saved, the environmental protection is facilitated, the process is simplified, the product quality is improved, and the development prospect is wide.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of glass high stability UV-curable water-borne ink.
Background technology
In recent years, along with people are to the reinforcement gradually of the pay attention to day by day of environment protection and environmental regulation, various countries are more and more limited for the discharge of volatile organic matter contained in traditional solvent based coating.Therefore, the Main way that the low stain even water-borne coatings of nonpollution environment friendly, photo-cured coating have become coating manufacture is developed.
The water-borne coatings of ultraviolet light polymerization combines the advantage of water-based technology and UV-curing technology, have that curing speed is fast, environmental friendliness and the advantage such as energy-conservation, simultaneously, it also overcomes the shortcoming such as skin irritation that traditional UV-curing technology brings and the film performance difference that water-based technology is brought, be many traditional coatings incomparable.
Along with development in science and technology, the raising of people's standard of living, for the continuous lifting of target level of product quality, general coating on the market can not meet new standard new demand with rapid changepl. never-ending changes and improvements, is therefore badly in need of a kind of high performance ultraviolet-curing paint.
Summary of the invention
The present invention is directed to above-mentioned background technology, a kind of glass high stability UV-curable water-borne ink is provided.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
A kind of glass high stability UV-curable water-borne ink, is characterized in that: count by weight, is prepared from by following raw material: acrylate modified polysiloxane pre polymers body: 50 ~ 60 parts; Pigment: 1 ~ 2 part; Photoepolymerizationinitiater initiater: 2 ~ 5 parts; Reactive thinner: 10 ~ 20 parts; Defoamer: 1 ~ 5 part; Aqueous solvent: 100 ~ 120 parts;
Described acrylate modified polysiloxane pre polymers body is prepared from by following steps: mixed with gamma-methyl allyl acyloxypropyl trimethoxysilane by two terminal hydroxyl dimethyl-polysiloxanes and add stirring, add dibutyl tin laurate again, be heated to 80 ~ 100 DEG C, continue 8 ~ 10h, purify and get final product.
Further, described a kind of glass high stability UV-curable water-borne ink is counted by weight, is prepared from: acrylate modified polysiloxane pre polymers body: 55 parts by following raw material; Pigment: 1 part; Photoepolymerizationinitiater initiater: 5 parts; Reactive thinner: 15 parts; Defoamer: 3 parts; Aqueous solvent: 100 parts.
Further, described reactive thinner is pentaerythritol triacrylate or dipentaerythritol five acrylate.
Further, described Photoepolymerizationinitiater initiater is benzoin methyl ether, Benzoin ethyl ether or said mixture.
Further, described defoamer is tributyl phosphate.
Further, described aqueous solvent is propyl alcohol and water mixture.
Present invention also offers a kind of making method of above-mentioned a kind of glass high stability UV-curable water-borne ink, comprise the following steps: by acrylate modified polysiloxane pre polymers body, pigment, reactive thinner, defoamer, aqueous solvent, abundant mixing is also heated to 30 ~ 50 DEG C of stirring 10 ~ 30min, add Photoepolymerizationinitiater initiater again, stir, then leave standstill cooling and get final product.
The invention provides a kind of glass high stability UV-curable water-borne ink, beneficial effect is as follows:
A kind of glass high stability UV-curable water-borne ink of the present invention, with two hydroxy-terminated polysiloxanes and gamma-methyl allyl acyloxypropyl trimethoxysilane for single main body prepares acrylate modified polysiloxane prepolymers, possesses good preservation stability, solidification rate, snappiness and hardness; Coordinate suitable Photoepolymerizationinitiater initiater, reactive thinner, defoamer etc. to make anti-stick coating, there is moderate application viscosity, good adhesive power and higher adhesion residual rate.Save energy of the present invention, environmental, Simplified flowsheet, improve the quality of products, there is vast potential for future development.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of glass high stability UV-curable water-borne ink is counted by weight, is prepared from: acrylate modified polysiloxane pre polymers body: 55 parts by following raw material; Pigment: 1 part; Benzoin methyl ether: 5 parts; Pentaerythritol triacrylate: 15 parts; Tributyl phosphate: 3 parts; Propyl alcohol and water mixed solvent: 100 parts.
Described acrylate modified polysiloxane pre polymers body is prepared from by following steps: mixed with gamma-methyl allyl acyloxypropyl trimethoxysilane by two terminal hydroxyl dimethyl-polysiloxanes and add stirring, add dibutyl tin laurate again, be heated to 80 DEG C, continue 8h, purify and get final product.
By acrylate modified polysiloxane pre polymers body, pigment, pentaerythritol triacrylate, tributyl phosphate, propyl alcohol and water mixed solvent, abundant mixing is also heated to 30 DEG C of stirring 10min, add benzoin methyl ether again, stir, then leave standstill cooling and namely obtain a kind of glass high stability UV-curable water-borne ink.
Embodiment 2:
Described a kind of glass high stability UV-curable water-borne ink is counted by weight, is prepared from: acrylate modified polysiloxane pre polymers body: 60 parts by following raw material; Pigment: 2 parts; Benzoin ethyl ether: 4 parts; Dipentaerythritol five acrylate: 18 parts; Tributyl phosphate: 5 parts; Propyl alcohol and water mixed solvent: 120 parts.
Described acrylate modified polysiloxane pre polymers body is prepared from by following steps: mixed with gamma-methyl allyl acyloxypropyl trimethoxysilane by two terminal hydroxyl dimethyl-polysiloxanes and add stirring, add dibutyl tin laurate again, be heated to 100 DEG C, continue 10h, purify and get final product.
By acrylate modified polysiloxane pre polymers body, pigment, dipentaerythritol five acrylate, tributyl phosphate, propyl alcohol and water mixed solvent, abundant mixing is also heated to 50 DEG C of stirring 30min, add Benzoin ethyl ether again, stir, then leave standstill cooling and namely obtain a kind of glass high stability UV-curable water-borne ink.
Claims (7)
1. a glass high stability UV-curable water-borne ink, is characterized in that: count by weight, is prepared from by following raw material: acrylate modified polysiloxane pre polymers body: 50 ~ 60 parts; Pigment: 1 ~ 2 part; Photoepolymerizationinitiater initiater: 2 ~ 5 parts; Reactive thinner: 10 ~ 20 parts; Defoamer: 1 ~ 5 part; Aqueous solvent: 100 ~ 120 parts;
Described acrylate modified polysiloxane pre polymers body is prepared from by following steps: mixed with gamma-methyl allyl acyloxypropyl trimethoxysilane by two terminal hydroxyl dimethyl-polysiloxanes and add stirring, add dibutyl tin laurate again, be heated to 80 ~ 100 DEG C, continue 8 ~ 10h, purify and get final product.
2. a kind of glass high stability UV-curable water-borne ink according to claim 1, it is characterized in that: described a kind of glass high stability UV-curable water-borne ink is counted by weight, is prepared from: acrylate modified polysiloxane pre polymers body: 55 parts by following raw material; Pigment: 1 part; Photoepolymerizationinitiater initiater: 5 parts; Reactive thinner: 15 parts; Defoamer: 3 parts; Aqueous solvent: 100 parts.
3. a kind of glass high stability UV-curable water-borne ink according to claim 1, is characterized in that: described reactive thinner is pentaerythritol triacrylate or dipentaerythritol five acrylate.
4. a kind of glass high stability UV-curable water-borne ink according to claim 1, is characterized in that: described Photoepolymerizationinitiater initiater is benzoin methyl ether, Benzoin ethyl ether or said mixture.
5. a kind of glass high stability UV-curable water-borne ink according to claim 1, is characterized in that: described defoamer is tributyl phosphate.
6. a kind of glass high stability UV-curable water-borne ink according to claim 1, is characterized in that: described aqueous solvent is propyl alcohol and water mixture.
7. a kind of glass high stability UV-curable water-borne ink according to claim 1, it is characterized in that: the making method of described a kind of glass high stability UV-curable water-borne ink, comprise the following steps: by acrylate modified polysiloxane pre polymers body, pigment, reactive thinner, defoamer, aqueous solvent, abundant mixing is also heated to 30 ~ 50 DEG C of stirring 10 ~ 30min, add Photoepolymerizationinitiater initiater again, stir, then leave standstill cooling and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410585281.1A CN104356745B (en) | 2014-10-28 | 2014-10-28 | A kind of glass high stability UV-curable water-borne ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410585281.1A CN104356745B (en) | 2014-10-28 | 2014-10-28 | A kind of glass high stability UV-curable water-borne ink |
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| CN104356745A true CN104356745A (en) | 2015-02-18 |
| CN104356745B CN104356745B (en) | 2016-03-02 |
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| CN201410585281.1A Active CN104356745B (en) | 2014-10-28 | 2014-10-28 | A kind of glass high stability UV-curable water-borne ink |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1431357A1 (en) * | 2001-08-09 | 2004-06-23 | Vitro Europa, Ltd. | Ultraviolet radiation-curable paint composition and the method of applying same to glass substrates |
| CN102153912A (en) * | 2011-03-10 | 2011-08-17 | 安徽师范大学 | Single-component glass printing ink |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN102911559A (en) * | 2012-11-22 | 2013-02-06 | 南京瑞固聚合物有限公司 | Anti-after tack acrylic latex for water-based ink |
-
2014
- 2014-10-28 CN CN201410585281.1A patent/CN104356745B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1431357A1 (en) * | 2001-08-09 | 2004-06-23 | Vitro Europa, Ltd. | Ultraviolet radiation-curable paint composition and the method of applying same to glass substrates |
| CN102153912A (en) * | 2011-03-10 | 2011-08-17 | 安徽师范大学 | Single-component glass printing ink |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN102911559A (en) * | 2012-11-22 | 2013-02-06 | 南京瑞固聚合物有限公司 | Anti-after tack acrylic latex for water-based ink |
Non-Patent Citations (1)
| Title |
|---|
| 甘禄铜等: "可紫外光／湿气双重固化聚硅氧烷丙烯酸酯树脂的合成与表征", 《化工新型材料》 * |
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| CN104356745B (en) | 2016-03-02 |
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| C06 | Publication | ||
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Inventor after: Qin Guoqiang Inventor before: Xi Xiaoshan Inventor before: Wang Jun Inventor before: Huang Bo |
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Effective date of registration: 20170710 Address after: 528000, No. 2 Industrial Avenue, West North Sea, Beijiao Town, Shunde District, Guangdong, Foshan Patentee after: Foshan city Shunde District gazelle Glass Industry Co. Ltd. Address before: 610000 Sichuan city of Chengdu province high tech Zone Shiyang Industrial Park Patentee before: Chengdu Nashuo Technology Co., Ltd. |