CN104351239A - Missible oil containing acetamiprid and lambda-cyhalothrin and application of missible oil - Google Patents
Missible oil containing acetamiprid and lambda-cyhalothrin and application of missible oil Download PDFInfo
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- CN104351239A CN104351239A CN201410636561.0A CN201410636561A CN104351239A CN 104351239 A CN104351239 A CN 104351239A CN 201410636561 A CN201410636561 A CN 201410636561A CN 104351239 A CN104351239 A CN 104351239A
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Abstract
The invention discloses missible oil containing acetamiprid and lambda-cyhalothrin and an application of the missible oil. The active component of the missible oil comprises a mixture of acetamiprid and lambda-cyhalothrin at the mass ratio of (1-20) to 1. The acetamiprid is compounded with lambda-cyhalothrin to prepare a missible oil preparation. The missible oil has a good synergistic interaction effect; the insecticidal spectrum is expanded; the fast-acting property is improved; the drug resistance is delayed; and the missible oil has a good effect on prevention and treatment of insect pests such as aphids, aleyrodids and red spiders in grain crops, vegetables and fruit trees.
Description
Technical field
The present invention relates to a kind of insecticidal preparation, be specifically related to a kind of missible oil and the application of this missible oil in control cereal crops, fruit tree, vegetables insect pest that contain Acetamiprid and gamma cyhalothrin, belong to technical field of pesticide.
Background technology
Gamma cyhalothrin (Lambda-cyhalothrin, chemical name: 3-(2-chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl cyclopropane carboxylic acid alpha-cyano-3-phenoxybenzyl ester) be pyrethroid insecticidal/acaricidal agent, to tag and stomach poison function, without systemic action.To various pests and other insects such as Lepidoptera, coleoptera and Semipteras, and tetranychid, rust mite, goitre mite, tarsonemid etc. have good result, also can be used to prevent and treat multiple earth's surface and public health insect, have certain preventive effect to the insect of sucking mouth parts, but Long-Time Service easily produces resistance to it.
Acetamiprid (Acetamiprid, chemical name: N-(N-cyano group-ethyleneimine base)-N-methyl-2-chloropyridine-5-methylamine) belong to Nitromethylene heterocycle compound, it is a kind of novel pesticide, wide spectrum and have the insecticide of certain acaricidal activity, insect organic phosphor, carbamates and pyrethroid being produced to resistance has special efficacy.Be widely used in paddy rice, especially the control of the aphid, plant hopper, thrips, part lepidoptera pest etc. of vegetables, fruit tree, tealeaves.
The long-term a large amount of of single insecticide use, and easily make insect develop immunity to drugs, and cause dosage increasing, preventive effect reduction, lasting period to shorten, are unfavorable for environment sustainable development.Delaying insect pest one of the conventional method that develops immunity to drugs is carry out composite to the active ingredient of the different mechanism of action.Acetamiprid is different from the gamma cyhalothrin mechanism of action, and the complex preparation of research Acetamiprid and gamma cyhalothrin will have good application prospect.
Summary of the invention
The invention provides a kind of missible oil containing Acetamiprid and gamma cyhalothrin, this missible oil active component comprises Acetamiprid and the high-efficient lambda-cyhalothrin compound mixture of special ratios, there is good synergistic effect, the deficiency that when solving one-component desinsection, drug effect reduces and pesticide resistance produces, expand insecticidal spectrum, slow down drug-fast generation, be beneficial to the sustainable development of environment.
Present invention also offers the application of above-mentioned missible oil in control cereal crops, vegetables, insect pest of the fruit tree.
The present invention is achieved by the following measures:
Contain a missible oil for Acetamiprid and gamma cyhalothrin, active component comprises Acetamiprid and gamma cyhalothrin, and the mass ratio of Acetamiprid and gamma cyhalothrin is 1-20:1, and preferred mass is than being 1-5:1, and more preferably mass ratio is 1:1.
In above-mentioned missible oil, the content of active component is 10-200g/L.
In above-mentioned missible oil, except active component, also comprise auxiliary component, described auxiliary component comprises emulsifier, cosolvent and solvent.
In above-mentioned missible oil, each component content is as follows: active component 10-200g/L, emulsifier 80-120g/L, cosolvent 10-100g/L, balance of solvent.Preferred content is as follows: active component 10-200g/L, emulsifier 100g/L, cosolvent 80 g/L, balance of solvent.
In above-mentioned missible oil, described emulsifier be in phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, calcium dodecyl benzene sulfonate, castor oil polyoxyethylene ether and alkylphenol-polyethenoxy polyethenoxy ether one or more, be preferably mass ratio be the calcium dodecyl benzene sulfonate of 1:1 and the mixture of phenethyl phenol polyoxyethylene poly-oxygen propylene aether.
In above-mentioned missible oil, described cosolvent is ethanol, acetone, NMP(N-methyl pyrrolidone) and cyclohexanone in one or more, be preferably ethanol.
In above-mentioned missible oil, described solvent is one or more in methyl oleate, biodiesel, sec-butyl acetate and S-200 solvent naphtha, is preferably S-200 solvent naphtha.
The preparation method of missible oil is: put in reactor by Acetamiprid, gamma cyhalothrin, solvent, cosolvent, emulsifier, be heated to 50 DEG C, insulated and stirred 30min, obtain Acetamiprid efficient cyhalothrin emulsifiable concentrate.
Missible oil of the present invention is mainly used in preventing and treating the insect pest in cereal crops, vegetables, fruit tree, such as aphid, aleyrodid, two spotted spider mite etc., the aphid especially in fruit and vegetables.
Beneficial effect of the present invention is as follows:
1, active component Acetamiprid and the gamma cyhalothrin of missible oil of the present invention belong to the insecticide of two kinds of different mechanisms of action, and both mutual mixtures can not produce conflict, expand insecticidal spectrum, improve insecticide efficiency;
2, missible oil of the present invention has good synergistic effect through the selection of formula, and preventive effect is higher than single dose, and dosage is little, has delayed the drug-fast generation of insect pest, has been beneficial to environment sustainable development;
3, missible oil of the present invention has special efficacy to the aphid on cereal crops, vegetables, aleyrodid, two spotted spider mite etc., has good application prospect.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, but the present invention is not limited thereto.
Effect experiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First carry out Toxicity Determination according to the abundant method of Sun Yun, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
acetamiprid and high-efficient lambda-cyhalothrin compound are to aphid Toxicity Determination
Test medicine provides by Shandong Weifang Rainbow Chemical Co., Ltd..
Determine that after the effective inhibition concentration scope of each medicament, each medicament establishes a series of concentration process respectively by active constituent content through prerun, if clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule insecticide ", adopt infusion process to measure medicament and mixed after the lethal concentration of 50, and the method for the calculating co-toxicity proposed with (1960) such as Sun Yunpei asks its co-toxicity coefficient.
Computing formula following (take Acetamiprid as standard agent, its toxicity index is 100):
Result of the test is as shown in table 1:
Table 1 Acetamiprid, gamma cyhalothrin and the composite toxicity test analysis of results table to wheat aphid thereof
From table 1, Acetamiprid, gamma cyhalothrin are to the LC of wheat aphid
50be respectively 1.3713mg/L and 0.5021mg/L.The co-toxicity coefficient difference 142.75,131.77,131.52,123.12,120.81 of mass ratio 1:1,2.5:1,5:1,10:1,20:1 of Acetamiprid and gamma cyhalothrin.Acetamiprid and gamma cyhalothrin proportioning 1-20:1 all have certain synergistic effect, wherein with Acetamiprid and gamma cyhalothrin proportioning for synergistic effect during 1-5:1 is obvious, the highest with synergistic effect during 1:1.
Lower mask body enumerates several representative embodiment of the present invention, and non exhaustive.
embodiment 120g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 10g/L, gamma cyhalothrin 10g/L, calcium dodecyl benzene sulfonate 50g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 50g/L, ethanol 80g/L, S-200 solvent naphtha surplus.
Preparation method: Acetamiprid, gamma cyhalothrin, solvent, cosolvent, emulsifier are put in reactor, is heated to 50 DEG C, insulated and stirred 30min, obtains final product.
embodiment 2200g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 143g/L, gamma cyhalothrin 57g/L, calcium dodecyl benzene sulfonate 50g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 50g/L, ethanol 80g/L, S-200 solvent naphtha surplus.Preparation method is with embodiment 1.
embodiment 3120g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 100g/L, gamma cyhalothrin 20g/L, calcium dodecyl benzene sulfonate 50g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 50g/L, ethanol 80g/L, S-200 solvent naphtha surplus.Preparation method is with embodiment 1.
embodiment 433g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 30g/L, gamma cyhalothrin 3g/L, calcium dodecyl benzene sulfonate 50g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 50g/L, ethanol 80g/L, S-200 solvent naphtha surplus.Preparation method is with embodiment 1.
embodiment 563g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 60g/L, gamma cyhalothrin 3g/L, calcium dodecyl benzene sulfonate 50g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 50g/L, ethanol 80g/L, S-200 solvent naphtha surplus.Preparation method is with embodiment 1.
embodiment 640g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 30g/L, gamma cyhalothrin 10g/L, calcium dodecyl benzene sulfonate 60g/L, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 40g/L, ethanol 100g/L, S-200 solvent naphtha surplus.Preparation method is with embodiment 1.
embodiment 728g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 21g/L, gamma cyhalothrin 7g/L, calcium dodecyl benzene sulfonate 40g/L, castor oil polyoxyethylene ether 40g/L, NMP 90g/L, sec-butyl acetate surplus.Preparation method is with embodiment 1.
embodiment 852g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 40g/L, gamma cyhalothrin 12g/L, alkylphenol-polyethenoxy polyethenoxy ether 50g/L, phenethyl phenol polyethenoxy ether 20g/L, calcium dodecyl benzene sulfonate 40g/L, acetone 80g/L, biodiesel surplus.Preparation method is with embodiment 1.
embodiment 910g/L Acetamiprid efficient cyhalothrin emulsifiable concentrate
Formula is: Acetamiprid 5g/L, gamma cyhalothrin 5g/L, castor oil polyoxyethylene ether 70g/L, alkylphenol-polyethenoxy polyethenoxy ether 50g/L, cyclohexanone 10g/L, methyl oleate surplus.Preparation method is with embodiment 1.
The Acetamiprid prepare above-described embodiment and high-efficient lambda-cyhalothrin compound formulation products quality stability are tested, and the results are shown in following table 2.
The missible oil product mass change that table 2 Acetamiprid and high-efficient lambda-cyhalothrin compound obtain
As shown in Table 2, in embodiment 6,7,8,9, degradation after heat storage; And using the embodiment 1-5 of preferred promoter before heat storage and after heat storage, quality is all good, and preferred promoter and auxiliary dosage play key effect in product quality.
acetamiprid and high-efficient lambda-cyhalothrin compound field control effectiveness test measure
1, field trial control wheat aphid
The Acetamiprid prepare above-described embodiment and high-efficient lambda-cyhalothrin compound preparation are prevented and treated wheat aphid situation and are carried out the test of pesticide effectiveness.This experimental establishment is carried out in this locality, and contrast medicament is 70% acetamiprid wettable powder (commercial), 2.5% efficient cyhalothrin emulsifiable concentrate (commercial).
During dispenser, wheat is on the occasion of booting stage, aphid hundred strain worm amount 500-900 head, for aphid contains the initial stage of sending out, sprays medicine 1 time with workers and peasants-16 type knapsack hand sprayer, is watered 750kg is equipped with liquid by per hectare preparation consumption, and conversion community amount of liquid medicine carries out even spraying.Duration of test weather is good, and daily mean temperature is 20 ~ 26.0 DEG C.Dispenser same day without rain, non-rainfall in 15 days after medicine.
investigation method
Investigation insect population radix before dispenser, investigates borer population amount of living, calculate Rectifying efficacies, and viewing test medicament is to the safety of crop for after medicine the 3rd, 7,14 day respectively.
drug effect computational methods
In experimentation, in test scope of medication, the present composition has no adverse effects to wheat, to wheat aphid to prevent and treat result as shown in table 3:
Table 3 treatment agent control wheat paddock aphid field control effectiveness test result
As can be seen from Table 3, effectively can prevent and treat wheat aphid after Acetamiprid and high-efficient lambda-cyhalothrin compound, control efficiency is all better than contrasting medicament.Use the embodiment preventive effect of preferred promoter and optimum ratio will obviously be better than other embodiments, after medicine, 14 days embodiment 1 preventive effects are the highest, can reach more than 95.0%.
2, field trial control cabbage pieris
At a time when dispenser, cabbage pieris contains the initial stage of sending out, and sprays medicine 1 time with workers and peasants-16 type knapsack hand sprayer, is watered 750kg is equipped with liquid by per hectare preparation consumption, and conversion community amount of liquid medicine carries out even spraying.Duration of test weather is good, and daily mean temperature is 20 ~ 28.0 DEG C.Dispenser same day without rain, non-rainfall in 15 days after medicine.
investigation method
Investigation insect population radix before dispenser, investigates borer population amount of living, calculate Rectifying efficacies, and viewing test medicament is to the safety of crop for after medicine the 3rd, 7,14 day respectively.
drug effect computational methods
In experimentation, in test scope of medication, the present composition has no adverse effects to wild cabbage, to cabbage pieris to prevent and treat result as shown in table 4:
Table 4 treatment agent control cabbage field cabbage caterpillar field control effectiveness test result
As can be seen from Table 4, can effectively prevent and treat cabbage field cabbage caterpillar after Acetamiprid and high-efficient lambda-cyhalothrin compound, control efficiency is all better than contrasting medicament.Use the embodiment preventive effect of preferred promoter and optimum ratio will obviously be better than other embodiments, after medicine, 14 days preventive effects the highest can reach more than 95%.
3, field trial control capsicum Bemisia tabaci
At a time when dispenser, capsicum Bemisia tabaci contains the initial stage of sending out, and carries out in green house.Spray medicine 1 time with workers and peasants-16 type knapsack hand sprayer, be watered 750kg be equipped with liquid by per hectare preparation consumption, conversion community amount of liquid medicine carries out even spraying.Duration of test weather is good, and daily mean temperature is 20 ~ 25.0 DEG C.Dispenser same day without rain, non-rainfall in 15 days after medicine.
investigation method
Investigation insect population radix before dispenser, investigates borer population amount of living, calculate Rectifying efficacies, and viewing test medicament is to the safety of crop for after medicine the 3rd, 7,14 day respectively.
drug effect computational methods
In experimentation, in test scope of medication, the present composition has no adverse effects to capsicum, to capsicum Bemisia tabaci to prevent and treat result as shown in table 5 below:
As can be seen from Table 5, effectively can prevent and treat capsicum field Bemisia tabaci after Acetamiprid and high-efficient lambda-cyhalothrin compound, control efficiency is all better than contrasting medicament.Use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiments, after medicine, 14 days preventive effects the highest can reach 97.1%.
Claims (10)
1. contain a missible oil for Acetamiprid and gamma cyhalothrin, it is characterized in that: active component comprises the Acetamiprid and gamma cyhalothrin that mass ratio is 1-20:1.
2. missible oil according to claim 1, is characterized in that: active component comprises the Acetamiprid and gamma cyhalothrin that mass ratio is 1-5:1.
3. missible oil according to claim 2, is characterized in that: active component comprises the Acetamiprid and gamma cyhalothrin that mass ratio is 1:1.
4. the missible oil according to claim 1,2 or 3, is characterized in that: the content of active component is 10-200g/L.
5. the missible oil according to claim 1,2 or 3, is characterized in that: also comprise auxiliary component, described active component and auxiliary agent content as follows: active component 10-200g/L, emulsifier 80-120g/L, cosolvent 10-100g/L, balance of solvent.
6. missible oil according to claim 5, is characterized in that: active component and auxiliary agent content as follows: active component 10-200g/L, emulsifier 100g/L, cosolvent 80g/L, balance of solvent.
7. the missible oil according to claim 5 or 6, is characterized in that: described emulsifier be in phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, calcium dodecyl benzene sulfonate, castor oil polyoxyethylene ether and alkylphenol-polyethenoxy polyethenoxy ether one or more; Described cosolvent is one or more in ethanol, acetone, 1-METHYLPYRROLIDONE and cyclohexanone; Described solvent is one or more in methyl oleate, biodiesel, sec-butyl acetate and S-200 solvent naphtha.
8. the missible oil according to claim 6 or 7, is characterized in that: described emulsifier is mass ratio is the calcium dodecyl benzene sulfonate of 1:1 and the mixture of phenethyl phenol polyoxyethylene poly-oxygen propylene aether; Described cosolvent is ethanol; Described solvent is S-200 solvent naphtha.
9. the application in cereal crops, vegetables, insect pest of the fruit tree prevented and treated by the missible oil containing Acetamiprid and gamma cyhalothrin according to any one of claim 1-8.
10. application according to claim 9, is characterized in that: described insect pest is aphid, aleyrodid or two spotted spider mite.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105325451A (en) * | 2015-11-27 | 2016-02-17 | 沧州大洋化工有限责任公司 | Insecticide composition and preparation method thereof |
| CN105646101A (en) * | 2016-01-05 | 2016-06-08 | 山东潍坊润丰化工股份有限公司 | Acetamiprid/cyhalothrin-containing insecticidal composition and application thereof |
| CN107568250A (en) * | 2017-10-17 | 2018-01-12 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide plain containing aphid is killed |
| RU2673182C1 (en) * | 2018-02-21 | 2018-11-22 | Общество с ограниченной ответственностью "Агро Эксперт Груп" | Insecticide composition |
| CN109964934A (en) * | 2019-04-30 | 2019-07-05 | 江苏艾津农化有限责任公司 | A kind of mixed easily decomposing pesticide EC compound dosage form and preparation method thereof of high-content |
| CN110637827A (en) * | 2019-10-29 | 2020-01-03 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing acetamiprid and pyrethroid |
| CN115968902A (en) * | 2022-12-28 | 2023-04-18 | 宁夏格瑞精细化工有限公司 | Acetamiprid and efficient cyhalothrin-containing aqueous suspension and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102885038A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Microemulsion pesticide and preparation technology thereof |
-
2014
- 2014-11-13 CN CN201410636561.0A patent/CN104351239B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102885038A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Microemulsion pesticide and preparation technology thereof |
Non-Patent Citations (4)
| Title |
|---|
| 无: "登记证号 PD20120180", 《中国农药信息网》 * |
| 无: "登记证号 PD20120961", 《中国农药信息网》 * |
| 无: "登记证号 PD20130609", 《中国农药信息网》 * |
| 无: "登记证号 PD20141513", 《中国农药信息网》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105325451A (en) * | 2015-11-27 | 2016-02-17 | 沧州大洋化工有限责任公司 | Insecticide composition and preparation method thereof |
| CN105646101A (en) * | 2016-01-05 | 2016-06-08 | 山东潍坊润丰化工股份有限公司 | Acetamiprid/cyhalothrin-containing insecticidal composition and application thereof |
| CN107568250A (en) * | 2017-10-17 | 2018-01-12 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide plain containing aphid is killed |
| RU2673182C1 (en) * | 2018-02-21 | 2018-11-22 | Общество с ограниченной ответственностью "Агро Эксперт Груп" | Insecticide composition |
| CN109964934A (en) * | 2019-04-30 | 2019-07-05 | 江苏艾津农化有限责任公司 | A kind of mixed easily decomposing pesticide EC compound dosage form and preparation method thereof of high-content |
| CN110637827A (en) * | 2019-10-29 | 2020-01-03 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing acetamiprid and pyrethroid |
| CN115968902A (en) * | 2022-12-28 | 2023-04-18 | 宁夏格瑞精细化工有限公司 | Acetamiprid and efficient cyhalothrin-containing aqueous suspension and preparation method thereof |
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| CN104351239B (en) | 2016-09-14 |
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Effective date of registration: 20171128 Address after: No. 8, Hai Pu North Road, New River ecological and chemical technology industry base in Pingdu City, Qingdao, Shandong Patentee after: Qingdao run agricultural chemical Co., Ltd. Address before: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. |
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