CN104336042A - Composite pesticide containing nicotine type compound and applications thereof - Google Patents
Composite pesticide containing nicotine type compound and applications thereof Download PDFInfo
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- CN104336042A CN104336042A CN201310312730.0A CN201310312730A CN104336042A CN 104336042 A CN104336042 A CN 104336042A CN 201310312730 A CN201310312730 A CN 201310312730A CN 104336042 A CN104336042 A CN 104336042A
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Abstract
A composite pesticide containing a nicotine type compound is disclosed. Effective components of the composite pesticide comprise the nicotine type compound and dibenzoyl-1-tert-butylhydrazine. The nicotine type compound comprises one and/or a mixture of more selected from clothianidin, imidacloprid, pymetrozine, dinotefuran, thiachloprid, thiamethoxam, and other nicotine type pesticide compounds. The composite pesticide has good control effects for mixed damage of a plurality of pests such as sesamia inferens, chilo suppressalis, tryporyza incertulas, cnaphalocrocis medinalis guenee, nilaparvata lugens, laodelphax striatellus, and sogatella furcifera in rice fields, can effectively control damage of a plurality of snout moth's larvae, plant hoppers, aphid, vegetable diamondback moth, spodoptera litura, and the like for rice and sugarcane, avoids error and waste when a farmer temporarily mixes and uses a plurality of agents at an edge of a field, and enhances control effects.
Description
Technical field
To the present invention relates to a kind of effective ingredient be nicotinoids composition and press down the composite insecticidal medicament eaten hydrazine and combine, and belongs to pesticide field.
Background technology
In south China rice district, the primary pest of paddy rice of causing harm is the insects such as brown planthopper, small brown rice planthopper, white-backed planthopper and pink rice borer, striped rice borer, paddy stem borer and leaf-roller, and this is two classes insect of different nature, and these insects mix or overlapping generation often.
In order to prevent and treat above-mentioned insect, peasant household is when the control of reality laxative, the two or more medicament such as control leaf-roller and control brown back rice plant hopper need be bought, mix spray at the edge of a field to make temporarily, operate random large, dosage is not higher is exactly on the low side, or the proportional jitter of two kinds of medicaments is large, which kind of situation all can cause medication unreasonable, affects control efficiency.
Summary of the invention
For the defect existed in prior art, present inventor has carried out a large amount of experimental studies and combine experiment based on prior art and agricultural chemicals resource, find by by nicotinic insecticide and insect growth regulator, IGR but eating hydrazine combines and is used for preventing and treating leaf-roller and brown back rice plant hopper has fabulous result of use, the obvious synergy of the two, can prevent and treat above-mentioned insect simultaneously effectively.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of composite insecticide containing clothianidin, active ingredient by nicotinoids insecticidal constituent and press down food hydrazine form, described nicotinoids insecticidal constituent comprises a kind of and/or multiple mixture in the nicotinic insecticides such as clothianidin, Imidacloprid, pymetrozine, MTI-446, thiacloprid, Diacloden.
In the present invention, nicotinic insecticide used, as the analeptic of nicotine second choline receptor in central nervous system, in disturbing the signal transmission of cynapse.Have and tag and stomach poison function, have interior absorption, also known as sucking pest, there is killing effect to sucking property such as aphid, plant hopper, leafhopper, trialeurodes vaporariorums.
In the present invention; used presses down food hydrazine; chemical name is N-benzoyl-N '-tert-butylbenzene formylhydrazine; it is a kind of insect growth regulator, IGR; have Lepidoptera, Diptera larvae and suppress feed, accelerate cast off a skin and reduce the effect of laying eggs, to insect with stomach poison function be advocate peace stronger in absorption, after dispenser 2-3 days take effect; lasting period is long, noresidue.
The experiment display that applicant carries out, composite insecticide of the present invention is by these two kinds of chemical classes differences, and the active substance that mechanism of action is different, desinsection object is different is organically combined as a whole, and creates and has complementary functions significantly, have synergistic function.
In the present invention, calculate in mass, the active ingredient of nicotinoids insecticidal constituent accounts for the 0.1-98.0% of composite insecticide effective ingredient, and press down the 1.0-98.0% that food hydrazine accounts for composite insecticide effective ingredient, all the other are the impurity not affecting drug effect.
Preferably, in active ingredient, nicotinoids insecticidal constituent is 1: 1-10 with pressing down the mass ratio eating hydrazine.
Composite insecticide of the present invention, concrete consumption when it uses in farmland can be adjusted as required, the abundant experimental results of applicant in field shows, have under following dosage and kill effect preferably: with mu gauge, nicotinoids insecticidal constituent is 0.1g.a.i-30g.a.i, presses down food hydrazine 1.0g.a.i-60g.a.i (g.a.i represents active ingredient grams).
Composite insecticide of the present invention, can add auxiliary material and be prepared into pesticide field preparation type available arbitrarily, and in order to medication is convenient, be convenient to transport and store, preferred formulation is wetting powder, suspending agent or water dispersible granules.
Above-mentioned auxiliary material is that pesticide field commonly uses auxiliary material, and the present invention does not limit concrete auxiliary material composition and kind, any the art can the various auxiliary material such as auxiliary agent, inserts, wetting agent all can be used for the present invention.
Accordingly, the invention also discloses the application of described composite insecticide on crop such as control paddy rice, vegetables etc. in Lepidoptera, homoptera pest, the application especially in the Homoptera controls of insect such as the lepidoptera pests such as pink rice borer, striped rice borer, paddy stem borer and leaf-roller and brown planthopper, small brown rice planthopper, white back of the body lice.Especially paddy rice, the multiple snout moth's larva of sugarcane, plant hopper, vegetable the moth pests is comprised.
The experiment display that applicant carries out, composite insecticide of the present invention is when mixed of paddy field various pests, once use this composite insecticide, effectively can control and prevent and treat causing harm of many worms such as Lepidoptera, homoptera pest, achieve a medicine multiple-effect, save drug dose, reduce application cost, easy to operate, prevent and treat the effect that quality is high, there is good application prospect and huge market potential.
Embodiment
One, clothianidin embodiment:
1, wetting powder
80% clothianidin/press down food hydrazine wetting powder (20.0: 60.0) 100Kg
The first step: batching, mixing
Take 95% clothianidin quantity of goods produced 21.05Kg (rolling over hundred 20.0Kg), White Carbon black 5Kg, take 97% press down food hydrazine 63.15Kg (rolling over hundred 60.0Kg) in kind, auxiliary agent (NO, LS etc.) 18Kg, light calcium carbonate supplies 100Kg, pour into successively in mixer stir (30 minutes) even.
Second step: pulverize
Female powder of mixing is carried out air-flow crushing, after terminating, the material that main frame material and dust catcher are collected is mixed (10 minutes) again.
3rd step: detect indices qualified, metering, distributing, packaging and finished product.
2, suspending agent
30% clothianidin/press down food hydrazine suspending agent (2.0: 28.0) 100Kg
The first step: batching, shearing
Take 95.0% clothianidin quantity of goods produced 2.1Kg (rolling over hundred 2.0Kg), can with xanthans 0.25Kg, aluminium-magnesium silicate 1.1Kg, the big gun agent 0.3Kg that disappears, take 97.0% press down food hydrazine 28.0Kg (rolling over hundred 28.9Kg) in kind, auxiliary agent (can with triphenoethyl benzene phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether ratio 1: 1) 10Kg, add water and mend worm 100Kg and pour into successively to shear in still and shear (40 minutes) evenly
Second step: grinding
The semi-finished product sheared are ground to suspensibility by grinder up to standard.
3rd step: metering, distributing, packaging and finished product
3, water dispersible granules
60% clothianidin/press down food hydrazine water dispersible granules (3.0: 57.0) 100Kg
The first step: prepare female powder, pulverizing
Take 95% clothianidin quantity of goods produced 3.16Kg (rolling over hundred 3.0Kg), 97% and press down food hydrazine 58.8Kg (rolling over hundred 57Kg) in kind, total effective ingredient be 60Kg, successively pour in mixer stir (30 minutes) evenly after, carry out air-flow crushing, quality inspection is qualified rear for subsequent use.
Second step: dilution mixture
Being 60% by pulverizing qualified female powder dispersant (can use Geropon T/36), wetting agent (can with Tersperse1004, Huntsman), spring solution agent (can with sodium carboxymethyl starch), fillers dilute to making effective ingredient, dropping in agravic mix particles machine and mixing.
3rd step: make softwood
The diluted material made is added in the aqueous solution containing adhesive and be made into softwood
4th step: granulate
By extruding granulator, softwood is made into wet particle
5th step: dry
Dry in fluidized bed dryer formula heated-air circulation oven, be dried to moisture and be less than 3%.
6th step: shaping
Dried particle is put in sifter, screens out bulk and fine powder.
7th step: detection, metering, packing and finished product warehouse-in
Detect every quality index qualified, metering, packing and finished product warehouse-in.
Two, pymetrozine embodiment:
1, wetting powder
50% pymetrozine/press down food hydrazine wetting powder (10.0: 40.0) 100Kg
The first step: batching, mixing
Take 95% pymetrozine quantity of goods produced 11.0Kg (rolling over hundred 10.0Kg), White Carbon black 5Kg, take 97% press down food hydrazine 41.2Kg (rolling over hundred 40.0Kg) in kind, auxiliary agent (D425 etc.) 21.5Kg, Gao Ling soil supplies 100Kg, pour into successively in mixer stir (30 minutes) even.
Second step: pulverize
Female powder of mixing is carried out air-flow crushing, after terminating, the material that main frame material and dust catcher are collected is mixed (10 minutes) again.
3rd step: detect indices qualified, metering, distributing, packaging and finished product.
2, suspending agent
30% pymetrozine/press down food hydrazine suspending agent (8.0: 22.0) 100Kg
The first step: batching, shearing
Take 95.0% pymetrozine quantity of goods produced 8.0Kg (rolling over hundred 8.0Kg), can with xanthans 0.25Kg, aluminium-magnesium silicate 1.1Kg, the big gun agent 0.3Kg that disappears, take 97.0% press down food hydrazine 23.2Kg (rolling over hundred 22.0Kg) in kind, auxiliary agent (can with triphenoethyl benzene phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether ratio 1: 1.2) 13.2Kg, add water and mend worm 100Kg and pour into successively to shear in still and shear (40 minutes) evenly
Second step: grinding
The semi-finished product sheared are ground to suspensibility by grinder up to standard.
3rd step: metering, distributing, packaging and finished product
3, water dispersible granules
60% pymetrozine/press down food hydrazine water dispersible granules (10.0: 50.0) 100Kg
The first step: prepare female powder, pulverizing
Take 95% pymetrozine quantity of goods produced 10.5Kg (rolling over hundred 10.0Kg), 97% and press down food hydrazine 52.6Kg (rolling over hundred 50.0Kg) in kind, total effective ingredient be 60Kg, successively pour in mixer stir (30 minutes) evenly after, carry out air-flow crushing, quality inspection is qualified rear for subsequent use.
Second step: dilution mixture
Being 60% by pulverizing qualified female powder dispersant (can use Geropon T/36), wetting agent (can with Tersperse1004, Huntsman), spring solution agent (can with sodium carboxymethyl starch), fillers dilute to making effective ingredient, dropping in agravic mix particles machine and mixing.
3rd step: make softwood
The diluted material made is added in the aqueous solution containing adhesive and be made into softwood
4th step: granulate
By extruding granulator, softwood is made into wet particle
5th step: dry
Dry in fluidized bed dryer formula heated-air circulation oven, be dried to moisture and be less than 3%.
6th step: shaping
Dried particle is put in sifter, screens out bulk and fine powder.
7th step: detection, metering, packing and finished product warehouse-in
Detect every quality index qualified, metering, packing and finished product warehouse-in.
Three, Imidacloprid embodiment:
1, wetting powder
70% Imidacloprid/press down food hydrazine wetting powder (20.0: 50.0) 100Kg
The first step: batching, mixing
Take 97% Imidacloprid quantity of goods produced 21.05Kg (rolling over hundred 20.0Kg), White Carbon black 5Kg, take 97% press down food hydrazine 51.6Kg (rolling over hundred 50.0Kg) in kind, auxiliary agent (detergent etc.) 12.5Kg, precipitated calcium carbonate supply 100Kg, pour into successively in mixer stir (30 minutes) even.
Second step: pulverize
Female powder of mixing is carried out air-flow crushing, after terminating, the material that main frame material and dust catcher are collected is mixed (10 minutes) again.
3rd step: detect indices qualified, metering, distributing, packaging and finished product.
2, suspending agent
25% Imidacloprid/press down food hydrazine suspending agent (5.0: 20.0) 100Kg
The first step: batching, shearing
Take 97.0% Imidacloprid quantity of goods produced 5.2Kg (rolling over hundred 5.0Kg), can with xanthans 0.25Kg, aluminium-magnesium silicate 1.1Kg, the big gun agent 0.3Kg that disappears, take 97.0% press down food hydrazine 20.0Kg (rolling over hundred 20.6Kg) in kind, auxiliary agent (can with triphenoethyl benzene phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether ratio 1: 1) 11.2Kg, add water and mend worm 100Kg and pour into successively to shear in still and shear (40 minutes) evenly
Second step: grinding
The semi-finished product sheared are ground to suspensibility by grinder up to standard.
3rd step: metering, distributing, packaging and finished product
3, water dispersible granules
65% Imidacloprid/press down food hydrazine water dispersible granules (15.0: 50.0) 100Kg
The first step: prepare female powder, pulverizing
Take 97% Imidacloprid quantity of goods produced 15.5Kg (rolling over hundred 15.0Kg), 97% and press down food hydrazine 51.6Kg (rolling over hundred 50Kg) in kind, total effective ingredient be 65Kg, successively pour in mixer stir (30 minutes) evenly after, carry out air-flow crushing, quality inspection is qualified rear for subsequent use.
Second step: dilution mixture
Being 65% by pulverizing qualified female powder dispersant (can use Geropon T/36), wetting agent (can with Tersperse1004, Huntsman), spring solution agent (can with sodium carboxymethyl starch), fillers dilute to making effective ingredient, dropping in agravic mix particles machine and mixing.
3rd step: make softwood
The diluted material made is added in the aqueous solution containing adhesive and be made into softwood
4th step: granulate
By extruding granulator, softwood is made into wet particle
5th step: dry
Dry in fluidized bed dryer formula heated-air circulation oven, be dried to moisture and be less than 3%.
6th step: shaping
Dried particle is put in sifter, screens out bulk and fine powder.
7th step: detection, metering, packing and finished product warehouse-in
Detect every quality index qualified, metering, packing and finished product warehouse-in.
Four, Diacloden embodiment:
1, wetting powder
70% Diacloden/press down food hydrazine wetting powder (15.0: 550.0) 100Kg
The first step: batching, mixing
Take 92% Diacloden quantity of goods produced 16.3Kg (rolling over hundred 15.0Kg), White Carbon black 5Kg, take 97% press down food hydrazine 56.7Kg (rolling over hundred 55.0Kg) in kind, auxiliary agent (detergent, dispersant etc.) 20.0Kg, high fine particle calcium carbonate supply 100Kg, pour into successively in mixer stir (30 minutes) even.
Second step: pulverize
Female powder of mixing is carried out air-flow crushing, after terminating, the material that main frame material and dust catcher are collected is mixed (10 minutes) again.
3rd step: detect indices qualified, metering, distributing, packaging and finished product.
2, suspending agent
30% Diacloden/press down food hydrazine suspending agent (10.0: 20.0) 100Kg
The first step: batching, shearing
Take 92.0% Diacloden quantity of goods produced 10.9Kg (rolling over hundred 10.0Kg), can with xanthans 0.25Kg, aluminium-magnesium silicate 1.1Kg, the big gun agent 0.3Kg that disappears, take 97.0% press down food hydrazine 21.7Kg (rolling over hundred 20.0Kg) in kind, auxiliary agent (can with triphenoethyl benzene phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether ratio 1: 1) 11.2Kg, add water and mend 100Kg and pour into successively to shear in still and shear (40 minutes) evenly
Second step: grinding
The semi-finished product sheared are ground to suspensibility by grinder up to standard.
3rd step: metering, distributing, packaging and finished product
3, water dispersible granules
60% Diacloden/press down food hydrazine water dispersible granules (13.0: 47.0) 100Kg
The first step: prepare female powder, pulverizing
Take 92% Diacloden quantity of goods produced 14.1Kg (rolling over hundred 13.0Kg), 97% and press down food hydrazine 48.5Kg (rolling over hundred 47.0Kg) in kind, total effective ingredient be 60Kg, successively pour in mixer stir (30 minutes) evenly after, carry out air-flow crushing, quality inspection is qualified rear for subsequent use.
Second step: dilution mixture
Being 60% by pulverizing qualified female powder dispersant (can use Geropon T/36), wetting agent (can with Tersperse1004, Huntsman), spring solution agent (can with sodium carboxymethyl starch), fillers dilute to making effective ingredient, dropping in agravic mix particles machine and mixing.
3rd step: make softwood
The diluted material made is added in the aqueous solution containing adhesive and be made into softwood
4th step: granulate
By extruding granulator, softwood is made into wet particle.
5th step: dry
Dry in fluidized bed dryer formula heated-air circulation oven, be dried to moisture and be less than 3%.
6th step: shaping
Dried particle is put in sifter, screens out bulk and fine powder.
7th step: detection, metering, packing and finished product warehouse-in
Detect every quality index qualified, metering, packing and finished product warehouse-in.
Five, MTI-446 embodiment:
1, wetting powder
80% MTI-446/press down food hydrazine wetting powder (20.0: 60.0) 100Kg
The first step: batching, mixing
Take 92% MTI-446 quantity of goods produced 21.7Kg (rolling over hundred 20.0Kg), White Carbon black 5Kg, take 97% press down food hydrazine 63.15Kg (rolling over hundred 60.0Kg) in kind, auxiliary agent (detergent, diffusant etc.) 18Kg, fine particle calcium carbonate supply 100Kg, pour into successively in mixer stir (30 minutes) even.
Second step: pulverize
Female powder of mixing is carried out air-flow crushing, after terminating, the material that main frame material and dust catcher are collected is mixed (10 minutes) again.
3rd step: detect indices qualified, metering, distributing, packaging and finished product.
2, suspending agent
35% MTI-446/press down food hydrazine suspending agent (10.0: 25.0) 100Kg
The first step: batching, shearing
Take 92.0% MTI-446 quantity of goods produced 11.0Kg (rolling over hundred 10.0Kg), can with xanthans 0.25Kg, aluminium-magnesium silicate 1.2Kg, the big gun agent 0.3Kg that disappears, take 97.0% press down food hydrazine 27.2g (rolling over hundred 25.0Kg) in kind, auxiliary agent (can with triphenoethyl benzene phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether ratio 1: 1) 10.0Kg, add water and mend worm 100Kg and pour into successively to shear in still and shear (40 minutes) evenly
Second step: grinding
The semi-finished product sheared are ground to suspensibility by grinder up to standard.
3rd step: metering, distributing, packaging and finished product
3, water dispersible granules
65% MTI-446/press down food hydrazine water dispersible granules (5: 60.0) 100Kg
The first step: prepare female powder, pulverizing
Take 92% MTI-446 quantity of goods produced 5.4Kg (rolling over hundred 5.0Kg), 97% and press down food hydrazine 65.2Kg (rolling over hundred 60.0Kg) in kind, total effective ingredient be 65Kg, successively pour in mixer stir (30 minutes) evenly after, carry out air-flow crushing, quality inspection is qualified rear for subsequent use.
Second step: dilution mixture
Being 65% by pulverizing qualified female powder dispersant (can use Geropon T/36), wetting agent (can with Tersperse1004, Huntsman), spring solution agent (can with sodium carboxymethyl starch), fillers dilute to making effective ingredient, dropping in agravic mix particles machine and mixing.
3rd step: make softwood
The diluted material made is added in the aqueous solution containing adhesive and be made into softwood
4th step: granulate
By extruding granulator, softwood is made into wet particle
5th step: dry
Dry in fluidized bed dryer formula heated-air circulation oven, be dried to moisture and be less than 3%.
6th step: shaping
Dried particle is put in sifter, screens out bulk and fine powder.
7th step: detection, metering, packing and finished product warehouse-in
Detect every quality index qualified, metering, packing and finished product warehouse-in.
Applicant has carried out indoor and farmland effect experiment research to composite insecticide of the present invention in invention process, and result is as follows:
1. clothianidin is eaten the synergistic effect (co-toxicity coefficient) of hydrazine complexing agent to rice-stem borer 2 instar larvae and brown back rice plant hopper and is measured with pressing down
Carried out clothianidin in indoor and pressed down food hydrazine and composite combined thereof to the bioactive mensuration of rice-stem borer, method press NY/T1154.7-2006 " composite synergy measure " enforcement.
Experimental result: eat hydrazine 1: 3,1: 5,1: 7 three kind of proportioning co-toxicity coefficient to striped rice borer according to clothianidin and be respectively 108.09,113.07,120.34 with pressing down, according to the abundant grade scale of Sun Yun, the co-toxicity coefficient of three kinds of proportionings is all between 80-120, have synergy, wherein the co-toxicity coefficient of 1: 7 proportioning is equal with 120 is synergy;
Same method, the result to the biological activity determination of brown back rice plant hopper: above-mentioned clothianidin is eaten the co-toxicity coefficient of hydrazine three kinds of proportionings to brown back rice plant hopper nymph and is respectively 110.07,95.34,90.80 with pressing down.According to the abundant grade scale of Sun Yun, the co-toxicity coefficient of three kinds of proportionings is all about 100, and show that two medicine compatibility are good, without antagonism, having complementary functions property is strong.
2. compounded pesticides is to the field efficiency test of chilo suppressalis
Applicant has carried out 2 years field trials on Luhe district and other places, test is established and is pressed down food hydrazine (mu effective dose 20g) and clothianidin (mu effective dose 4g) single dose and 30% clothianidin and rh-5849 compound agent (5: 25) 80g, blank, counts 4 process.
Each process plot area 33.34m, randomized arrangement, repeats for three times.
Select two generation striped rice borer and brown back rice plant hopper mixing there is field, the medication when two generation striped rice borer first-instar young peaks, every mu is watered 50Kg, conventional spraying, after medicine 10 days, carries out field efficacy investigation.
Investigation method is that 5 points are got in every community, and often 5 caves, look into 25 caves altogether.
Result treatment mode be two generation striped rice borer: investigation record withered sheath number, add up withered sheath rate, compare with the withered sheath rate in check plot, calculate withered heart control efficiency; Brown back rice plant hopper: investigate and record borer population of living, statistics worm rate alive, compares with check plot worm rate alive, calculates control efficiency.
Result of the test: after medicine 10 days, 30% clothianidin with press down eat hydrazine complexing agent 80g to two generation striped rice borer withered heart preventive effect be 89.1-93.8%; And the alone withered heart preventive effect 82.69-88.21% pressing down food hydrazine; The withered heart preventive effect 41.71-46.38% of alone clothianidin.Adopt Dancan ' s new multipole difference analysis methods analyst respectively to process a significance of difference result: the withered heart preventive effect of 30% clothianidin rh-5849 compound agent to chilo suppressalis is significantly better than clothianidin single dose, and press down that to eat hydrazine single dose suitable; 30% clothianidin and rh-5849 compound agent are 95.64-98.8% to brown back rice plant hopper desinsection preventive effect, and the alone food hydrazine desinsection preventive effect 19.09-24.20% that presses down, alone clothianidin desinsection preventive effect 92.71-98.33%.Dancan ' s new multipole difference analysis methods analyst is adopted respectively to process a significance of difference result: 30% clothianidin rh-5849 compound agent is significantly better than brown back rice plant hopper preventive effect and presses down food hydrazine single dose.
Comprehensive above-mentioned indoor biometrics test (co-toxicity coefficient) and field control effect test, clothianidin eats the composite insecticide that hydrazine is combined to form with pressing down, to rice-stem borer and brown back rice plant hopper, all there is outstanding preventive effect, achieve the expection of two single dose advantages complementation, reach a medicine to striped rice borer and the double object controlled of brown back rice plant hopper two worm.
Claims (7)
1. the composite insecticide containing nicotinoids composition, it is characterized in that active ingredient by nicotinoids insecticidal constituent and press down food hydrazine form, described nicotinoids insecticidal constituent comprises a kind of and/or multiple mixture in the nicotinic insecticides such as clothianidin, Imidacloprid, pymetrozine, MTI-446, thiacloprid, Diacloden.
2. composite insecticide according to claim 1, it is characterized in that calculating in mass, the active ingredient of nicotinoids insecticidal constituent accounts for the 0.1-98.0% of composite insecticide effective ingredient, and press down the 1.0-98.0% that food hydrazine accounts for composite insecticide effective ingredient, all the other are the impurity not affecting drug effect.
3. composite insecticide according to claim 2, is characterized in that in active ingredient, and nicotinoids insecticidal constituent is 1: 1-10 with pressing down the mass ratio eating hydrazine.
4. composite insecticide according to claim 2, is characterized in that with mu gauge, and nicotinoids insecticidal constituent is 0.1g.a.i-30g.a.i, presses down food hydrazine 1.0g.a.i-60g.a.i.
5. composite insecticide according to claim 1, is characterized in that for wetting powder, suspending agent or water dispersible granules, by nicotinoids insecticidal constituent, presses down food hydrazine and auxiliary material and filler are made.
6. the application of the composite insecticide described in above-mentioned arbitrary claim on the crops such as control paddy rice, vegetables, sugarcane in Lepidoptera, homoptera pest.
7. application according to claim 6, is characterized in that described insect comprises paddy rice, the multiple snout moth's larva of sugarcane, plant hopper, vegetable the moth pests.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105707069A (en) * | 2016-04-13 | 2016-06-29 | 南通清安健无水印染研究所（普通合伙） | Preparation method of microencapsulated pesticide for controlling sugarcane borers |
| CN107950592A (en) * | 2017-11-29 | 2018-04-24 | 铜陵市棵松农业科技有限公司 | A kind of rice pest integrated control insecticide |
| CN107950559A (en) * | 2017-11-29 | 2018-04-24 | 铜陵市棵松农业科技有限公司 | A kind of composite insecticide for preventing rice insect pest |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101116443A (en) * | 2007-09-10 | 2008-02-06 | 江苏省农业科学院 | Fipronil and rh-5849 compound insecticide |
| CN102349507A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Pymetrozine-containing ultralow volume liquid agent |
| CN102475391A (en) * | 2010-11-21 | 2012-05-30 | 张晓龙 | Back clamping type sun umbrella |
-
2013
- 2013-07-23 CN CN201310312730.0A patent/CN104336042A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101116443A (en) * | 2007-09-10 | 2008-02-06 | 江苏省农业科学院 | Fipronil and rh-5849 compound insecticide |
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